Human disturbances are considered to break reproduction barriers among species.Significant increases in hybridization events have been reported among a large number of taxonomic groups in anthropogenic environments,pr...Human disturbances are considered to break reproduction barriers among species.Significant increases in hybridization events have been reported among a large number of taxonomic groups in anthropogenic environments,providing novel insights into species evolution mechanisms and conservation management in the Anthropocene.The Eastern Golden Frog(Pelophylax plancyi)and BlackSpotted Frog(P.nigromaculatus)are two sympatric anuran species with a long history of mitochondrial genome introgression in highly urbanized continental East Asia.However,there is only limited understanding of the pattern of their contemporary hybridization and factors influencing their interspecific relationship under anthropogenic disturbances.Here,interspecific hybridization between P.plancyi and P.nigromaculatus at the population level was investigated in Shanghai.All except two haplotypes obtained from both species in Shanghai were mixed together,and located in the introgression clade,implying multiple ancient mitochondrial introgression events occurred in the populations of our study area.Asymmetric genetic introgression was detected by microsatellite markers,with 0.7%of P.plancyi and 14.6%of P.nigromaculatus identified as contemporary admixed individuals.Consistent with the trend of population density,higher genetic diversity of neutral microsatellite loci was found in the more abundant P.plancyi;however,variation in mitochondrial(Cyt-b)and nuclear(POMC)genes was higher in relatively rare P.nigromaculatus.The population density of P.plancyi and number of water patches within local habitats were significantly positively correlated with both occurrences and proportions of admixed individuals in the populations of P.plancyi and P.nigromaculatus.Considering the prevalent transformation of habitats in urbanized areas,these results imply that a high population density in isolated artificially altered habitats is likely to increase interspecific hybridization.Thus,population monitoring and improvement of landscape connectivity between habitats would be needed to control the intensity of interspecific hybridization between P.plancyi and P.nigromaculatus in anthropogenic-disturbed environments.展开更多
The recent advances in aqueous magnesium-ion hybrid supercapacitor(MHSC)have attracted great attention as it brings together the benefits of high energy density,high power density,and synchronously addresses cost and ...The recent advances in aqueous magnesium-ion hybrid supercapacitor(MHSC)have attracted great attention as it brings together the benefits of high energy density,high power density,and synchronously addresses cost and safety issues.However,the freeze of aqueous electrolytes discourages aqueous MHSC from operating at low-temperature conditions.Here,a low-concentration aqueous solution of 4 mol L^(-1) Mg(ClO_(4))_(2) is devised for its low freezing point(-67℃)and ultra-high ionic conductivity(3.37 mS cm^(-1) at-50℃).Both physical characterizations and computational simulations revealed that the Mg(ClO_(4))_(2) can effectively disrupt the original hydrogen bond network among water molecules via transmuting the electrolyte structure,thus yielding a low freezing point.Thus,the Mg(ClO_(4))_(2) electrolytes endue aqueous MHSC with a wider temperature operation range(-50℃–25℃)and a higher energy density of 103.9 Wh kg^(-1) at 3.68 kW kg^(-1) over commonly used magnesium salts(i.e.,MgSO_(4) and Mg(NO_(3))_(2))electrolytes.Furthermore,a quasi-solid-state MHSC based on polyacrylamide-based hydrogel electrolyte holds superior low-temperature performance,excellentflexibility,and high safety.This work pioneers a convenient,cheap,and eco-friendly tactic to procure low-temperature aqueous magnesium-ion energy storage device.展开更多
Li metal is considered an ideal anode material for application in the next-generation secondary batteries.However,the commercial application of Li metal batteries has not yet been achieved due to the safety concern ca...Li metal is considered an ideal anode material for application in the next-generation secondary batteries.However,the commercial application of Li metal batteries has not yet been achieved due to the safety concern caused by Li dendrites growth.Despite the fact that many recent experimental studies found that external pressure suppresses the Li dendrites growth,the mechanism of the external pressure effect on Li dendrites remains poorly understood on the atomic scale.Herein,the large-scale molecular dynamics simulations of Li dendrites growth under different external pressure were performed with a machine learning potential,which has the quantum-mechanical accuracy.The simulation results reveal that the external pressure promotes the process of Li self-healing.With the increase of external pressure,the hole defects and Li dendrites would gradually fuse and disappear.This work provides a new perspective for understanding the mechanism for the impact of external pressure on Li dendrites.展开更多
Earth abundant O3-type NaFe_(0.5)Mn_(0.5)O_(2)layered oxide is regarded as one of the most promising cathodes for sodium ion batteries due to its low cost and high energy density.However,its poor structural stability ...Earth abundant O3-type NaFe_(0.5)Mn_(0.5)O_(2)layered oxide is regarded as one of the most promising cathodes for sodium ion batteries due to its low cost and high energy density.However,its poor structural stability and cycle life strongly impede the practical application.Herein,the dynamic phase evolution as well as charge compensation mechanism of O3-type NaFe_(0.5)Mn_(0.5)O_(2)cathode during sodiation/desodiation are revealed by a systemic study with operando X-ray diffraction and X-ray absorption spectroscopy,high resolution neutron powder diffraction and neutron pair distribution functions.The layered structure experiences a phase transition of O3→P3→OP2→ramsdellite during the desodiation,and a new O3’phase is observed at the end of the discharge state(1.5 V).The density functional theory(DFT)calculations and nPDF results suggest that depletion of Na^(+)ions induces the movement of Fe into Na layer resulting the formation of an inert ramsdellite phase thus causing the loss of capacity and structural integrity.Meanwhile,the operando XAS clarified the voltage regions for active Mn^(3+)/Mn^(4+)and Fe^(3+)/Fe^(4+)redox couples.This work points out the universal underneath problem for Fe-based layered oxide cathodes when cycled at high voltage and highlights the importance to suppress Fe migration regarding the design of high energy O3-type cathodes for sodium ion batteries.展开更多
Two-dimensional(2D)antiferroelectric materials have raised great research interest over the last decade.Here,we reveal a type of 2D antiferroelectric(AFE)crystal where the AFE polarization direction can be switched by...Two-dimensional(2D)antiferroelectric materials have raised great research interest over the last decade.Here,we reveal a type of 2D antiferroelectric(AFE)crystal where the AFE polarization direction can be switched by a certain degree in the 2D plane.Such 2D functional materials are realized by stacking the exfoliated wurtzite(wz)monolayers with“self-healable”nature,which host strongly coupled ferroelasticity/antiferroelectricity and benign stability.The AFE candidates,i.e.,Zn X and Cd X(X=S,Se,Te),are all semiconductors with direct bandgap atΓpoint,which harbors switchable antiferroelectricity and ferroelasticity with low transition barriers,hidden spin polarization,as well as giant in-plane negative Poisson's ratio(NPR),enabling the co-tunability of hidden spin characteristics and auxetic magnitudes via AFE switching.The 2D AFE wz crystals provide a platform to probe the interplay of 2D antiferroelectricity,ferroelasticity,NPR,and spin effects,shedding new light on the rich physics and device design in wz semiconductors.展开更多
With the rapid development of semiconductors,the number of materials needed to be polished sharply increases.The material properties vary significantly,posing challenges to chemical mechanical polishing(CMP).According...With the rapid development of semiconductors,the number of materials needed to be polished sharply increases.The material properties vary significantly,posing challenges to chemical mechanical polishing(CMP).Accordingly,the study aimed to classify the material removal mechanism.Based on the CMP and atomic force microscopy results,the six representative metals can be preliminarily classified into two groups,presumably due to different material removal modes.From the tribology perspective,the first group of Cu,Co,and Ni may mainly rely on the mechanical plowing effect.After adding H_(2)O_(2),corrosion can be first enhanced and then suppressed,affecting the surface mechanical strength.Consequently,the material removal rate(MRR)and the surface roughness increase and decrease.By comparison,the second group of Ta,Ru,and Ti may primarily depend on the chemical bonding effect.Adding H_(2)O_(2)can promote oxidation,increasing interfacial chemical bonds.Therefore,the MRR increases,and the surface roughness decreases and levels off.In addition,CMP can be regulated by tuning the synergistic effect of oxidation,complexation,and dissolution for mechanical plowing,while tuning the synergistic effect of oxidation and ionic strength for chemical bonding.The findings provide mechanistic insight into the material removal mechanism in CMP.展开更多
Recently, machine learning(ML) has become a widely used technique in materials science study. Most work focuses on predicting the rule and overall trend by building a machine learning model. However,new insights are o...Recently, machine learning(ML) has become a widely used technique in materials science study. Most work focuses on predicting the rule and overall trend by building a machine learning model. However,new insights are often learnt from exceptions against the overall trend. In this work, we demonstrate that how unusual structures are discovered from exceptions when machine learning is used to get the relationship between atomic and electronic structures based on big data from high-throughput calculation database. For example, after training an ML model for the relationship between atomic and electronic structures of crystals, we find AgO2 F, an unusual structure with both Ag3+and O22à, from structures whose band gap deviates much from the prediction made by our model. A further investigation on this structure might shed light into the research on anionic redox in transition metal oxides of Li-ion batteries.展开更多
Coronavirus disease 2019(COVID-19),caused by severe acute respiratory syndrome coronavirus 2(SARS-CoV-2),is an ongoing pandemic that poses a great threat to human health worldwide.As the humoral immune response plays ...Coronavirus disease 2019(COVID-19),caused by severe acute respiratory syndrome coronavirus 2(SARS-CoV-2),is an ongoing pandemic that poses a great threat to human health worldwide.As the humoral immune response plays essential roles in disease occurrence and development,understanding the dynamics and characteristics of virus-specific humoral immunity in SARS-CoV-2-infected patients is of great importance for controlling this disease.In this review,we summarize the characteristics of the humoral immune response after SARS-CoV-2 infection and further emphasize the potential applications and therapeutic prospects of SARSCoV-2-specific humoral immunity and the critical role of this immunity in vaccine development.Notably,serological antibody testing based on the humoral immune response can guide public health measures and control strategies;however,it is not recommended for population surveys in areas with very low prevalence.Existing evidence suggests that asymptomatic individuals have a weaker immune response to SARS-CoV-2 infection,whereas SARS-CoV-2-infected children have a more effective humoral immune response than adults.The correlations between antibody(especially neutralizing antibody)titers and protection against SARS-CoV-2 reinfection should be further examined.In addition,the emergence of cross-reactions among different coronavirus antigens in the development of screening technology and the risk of antibody-dependent enhancement related to SARS-CoV-2 vaccination should be given further attention.展开更多
Solar-driven N_(2) fixation using a photocatalyst in water presents a promising alternative to the traditional Haber-Bosch process in terms of both energy efficiency and environmental concern.At present,the product of...Solar-driven N_(2) fixation using a photocatalyst in water presents a promising alternative to the traditional Haber-Bosch process in terms of both energy efficiency and environmental concern.At present,the product of solar N_(2) fixation is either NH_(4)^(+)or NO_(3)^(-).Few reports described the simultaneous formation of ammonia(NH_(4)^(+))and nitrate(NO_(3)^(-))by a photocatalytic reaction and the related mechanism.In this work,we report a strategy to photocatalytically fix nitrogen through simultaneous reduction and oxidation to produce NH_(4)^(+)and NO_(3)^(-)byW18O49 nanowires in pure water.The underlying mechanism of wavelength-dependent N_(2) fixation in the presence of surface defects is proposed,with an emphasis on oxygen vacancies that not only facilitate the activation and dissociation of N_(2) but also improve light absorption and the separation of the photoexcited carriers.Both NH_(4)^(+)and NO_(3)^(-)can be produced in pure water under a simulated solar light and even till the wavelength reaching 730 nm.The maximum quantum efficiency reaches 9%at 365 nm.Theoretical calculation reveals that disproportionation reaction of the N_(2) molecule is more energetically favorable than either reduction or oxidation alone.It is worth noting that the molar fraction of NH_(4)^(+)in the total product(NH_(4)^(+)plus NO_(3)^(-))shows an inverted volcano shape from 365nm to 730 nm.The increased fraction of NO_(3)^(-)from 365 nm to around 427 nm results from the competition between the oxygen evolution reaction(OER)at W sites without oxygen vacancies and the N_(2) oxidation reaction(NOR)at oxygen vacancy sites,which is driven by the intrinsically delocalized photoexcited holes.From 427nm to 730 nm,NOR is energetically restricted due to its higher equilibrium potential than that of OER,accompanied by the localized photoexcited holes on oxygen vacancies.Full disproportionation of N_(2) is achieved within a range of wavelength from~427nm to~515 nm.This work presents a rational strategy to efficiently utilize the photoexcited carriers and optimize the photocatalyst for practical nitrogen fixation.展开更多
The photocatalytic conversion of CO_(2)into sustainable,green fuels and value-added chemicals is believed to be an appealing method to overcome both the energy crisis and environmental problems.Numerous efforts have b...The photocatalytic conversion of CO_(2)into sustainable,green fuels and value-added chemicals is believed to be an appealing method to overcome both the energy crisis and environmental problems.Numerous efforts have been dedicated to enhance the CO_(2)conversion efficiency and selectivity through developing photocatalysts and CO_(2)reduction systems in recent years.This review gives an overview of the latest progress in photocatalysts for visible-light photocatalytic CO_(2)conversion and recent research advances of heterogeneous photocatalytic CO_(2)conversion systems.Furthermore,The roles of cocatalyst and heterojunctions to increase the efficiency of charge transfer,separation and visible light excitation are discussed.Finally,the challenges and perspectives for visible-light-driven photocatalytic conversion of CO_(2)are proposed.展开更多
The development of next-generation layered oxide cathodes for high-energy-density electrical vehicle Li-ion batteries(LIBs)is an urgent topic.The existing method is achieved by continuously increasing the Ni contents ...The development of next-generation layered oxide cathodes for high-energy-density electrical vehicle Li-ion batteries(LIBs)is an urgent topic.The existing method is achieved by continuously increasing the Ni contents of Ni-based layered oxides,but it has been limited to LiNiO_(2).To break this limit and attain increased energy densities,a promising strategy,which involves the introduction of excess Li ions into transition metal(TM)layers to form Li-excess compounds Li_(2)MO_(3)(M is a TM cation),has attracted enormous interest recently.However,another strategy,which has been neglected in recent years,involves the insertion of an extra layer of Li ions between the TM and original Li layers to form Li_(2)MO_(2).In this study,typical reversible Li_(2)NiO_(3) and 1T-Li_(2)NiO_(2) were selected as two representative cathodes to break the limit of LiNiO_(2),thereby availing comprehensive comparison with LiNiO_(2) regarding their overall properties as cathodes from a theoretical perspective.Interestingly,dissimilar to the Ni^(3+)/Ni^(4+)monoelectron cationic redox associated with LiNiO_(2),a polaronic anionic redox reaction occurs in Li_(2)NiO_(3),while a reversible Ni^(2+)/Ni^(4+)double-electron redox reaction accompanied by insulator-metal transition occurs in Li_(2)NiO_(2).Owing to this double-electron cationic activity,Li_(2)NiO_(2) exhibits absolute advantages over the other two materials(LiNiO_(2) and Li_(2)NiO_(3))as cathodes for LIBs in terms of the capacity,energy density,electronic conductivity,and thermal stability,thus rendering it the most promising candidate for next-generation layered oxide cathodes with high energy densities to break the limit of LiNiO_(2).展开更多
Monolayers of layered materials,such as graphite and molybdenum dichalcogenides,have been the focus of materials science in the last decades.Here,we reveal benign stability and intriguing physical properties in the th...Monolayers of layered materials,such as graphite and molybdenum dichalcogenides,have been the focus of materials science in the last decades.Here,we reveal benign stability and intriguing physical properties in the thinnest monolayer wurtzite(wz)semiconductors,which can be exfoliated from their bulk and stacked to reform the wz crystals.The candidate ZnX and CdX(X=S,Se,Te)monolayers possess low cleavage energy and direct bandgaps,which harbor strongly coupled ferroelectricity and ferroelasticity with low transition barriers,giant in-plane negative Poisson’s ratio,as well as giant Rashba spin splitting,enabling the co-tunability of spin splitting and auxetic magnitudes via multiferroic switching.These wz monolayers can be used as building blocks of devices structures,due to their inherent“self-healable”capacity,which offer more flexibility for semiconductor fabrication and provide a natural platform to probe the interplay of multiple physical effects,bringing light into the rich physics in tetrahedral semiconductors.展开更多
The coronavirus disease 2019(COVID-19)pandemic,caused by severe acute respiratory syndrome coronavirus 2(SARS-CoV-2),is a major ongoing challenge to global health.After being infected by SARS-CoV-2,a specific humoral ...The coronavirus disease 2019(COVID-19)pandemic,caused by severe acute respiratory syndrome coronavirus 2(SARS-CoV-2),is a major ongoing challenge to global health.After being infected by SARS-CoV-2,a specific humoral immune response may be rapidly induced in the host to restrain the viral infection via the production of neutralizing antibodies(NAbs),which are also useful for preventing reinfection[1,2].However,there is a lack of comprehensive understanding of the mechanisms underlying SARS CoV-2 specifc humoral immunity and alterations in immunoglobulin M(1gM)and G(1gG)levels in humans during viral infection.展开更多
The outbreak of the severe acute respiratory syndrome coronavirus 2(SARS-CoV-2)infection in December 2019 caused a huge blow to both global public health and global economy.At the early stage of the coronavirus diseas...The outbreak of the severe acute respiratory syndrome coronavirus 2(SARS-CoV-2)infection in December 2019 caused a huge blow to both global public health and global economy.At the early stage of the coronavirus disease 2019(COVID-19)epidemic,asymptomatic individuals with SARS-CoV-2 infection were ignored,without appropriate identification and isolation.However,asymptomatic individuals proved to comprise a high proportion of all SARS-CoV-2-infected individuals,which greatly contributed to the rapid and wide spread of this disease.In this review,we summarize the latest advances in epidemiological characteristics,diagnostic assessment methods,factors related to the establishment of SARS-CoV-2 asymptomatic infection,as well as humoral immune features after SARS-CoV-2 infection or vaccination in asymptomatic individuals,which would contribute to effective control of ongoing COVID-19 epidemic.展开更多
基金supported by the National Natural Science Foundation of China(32071529)the Yangtze Delta Estuarine Wetland Ecosystem Observation and Research Station(Z202204)+1 种基金Shanghai Key Lab for Urban Ecological Processes and EcoRestoration(SHUES2020B06,SHUES2021C04)the Fundamental Research Funds for the Central Universities.
文摘Human disturbances are considered to break reproduction barriers among species.Significant increases in hybridization events have been reported among a large number of taxonomic groups in anthropogenic environments,providing novel insights into species evolution mechanisms and conservation management in the Anthropocene.The Eastern Golden Frog(Pelophylax plancyi)and BlackSpotted Frog(P.nigromaculatus)are two sympatric anuran species with a long history of mitochondrial genome introgression in highly urbanized continental East Asia.However,there is only limited understanding of the pattern of their contemporary hybridization and factors influencing their interspecific relationship under anthropogenic disturbances.Here,interspecific hybridization between P.plancyi and P.nigromaculatus at the population level was investigated in Shanghai.All except two haplotypes obtained from both species in Shanghai were mixed together,and located in the introgression clade,implying multiple ancient mitochondrial introgression events occurred in the populations of our study area.Asymmetric genetic introgression was detected by microsatellite markers,with 0.7%of P.plancyi and 14.6%of P.nigromaculatus identified as contemporary admixed individuals.Consistent with the trend of population density,higher genetic diversity of neutral microsatellite loci was found in the more abundant P.plancyi;however,variation in mitochondrial(Cyt-b)and nuclear(POMC)genes was higher in relatively rare P.nigromaculatus.The population density of P.plancyi and number of water patches within local habitats were significantly positively correlated with both occurrences and proportions of admixed individuals in the populations of P.plancyi and P.nigromaculatus.Considering the prevalent transformation of habitats in urbanized areas,these results imply that a high population density in isolated artificially altered habitats is likely to increase interspecific hybridization.Thus,population monitoring and improvement of landscape connectivity between habitats would be needed to control the intensity of interspecific hybridization between P.plancyi and P.nigromaculatus in anthropogenic-disturbed environments.
基金supported by Shenzhen Science and Technology Innovation Committee(Nos.JCYJ20190806145609284,GJHZ20190820091203667,JSGG20201102161000002,SGD-X20201103095607022)Guangdong Basic and Applied Basic Research Foundation(2020A1515010716)+1 种基金Guangdong Introducing Innovative and Entrepreneurial Teams Program(2019ZT08Z656)P.H.would like to acknowledge Shenzhen Science and Technology Program(KQTD20190929172522-248).
文摘The recent advances in aqueous magnesium-ion hybrid supercapacitor(MHSC)have attracted great attention as it brings together the benefits of high energy density,high power density,and synchronously addresses cost and safety issues.However,the freeze of aqueous electrolytes discourages aqueous MHSC from operating at low-temperature conditions.Here,a low-concentration aqueous solution of 4 mol L^(-1) Mg(ClO_(4))_(2) is devised for its low freezing point(-67℃)and ultra-high ionic conductivity(3.37 mS cm^(-1) at-50℃).Both physical characterizations and computational simulations revealed that the Mg(ClO_(4))_(2) can effectively disrupt the original hydrogen bond network among water molecules via transmuting the electrolyte structure,thus yielding a low freezing point.Thus,the Mg(ClO_(4))_(2) electrolytes endue aqueous MHSC with a wider temperature operation range(-50℃–25℃)and a higher energy density of 103.9 Wh kg^(-1) at 3.68 kW kg^(-1) over commonly used magnesium salts(i.e.,MgSO_(4) and Mg(NO_(3))_(2))electrolytes.Furthermore,a quasi-solid-state MHSC based on polyacrylamide-based hydrogel electrolyte holds superior low-temperature performance,excellentflexibility,and high safety.This work pioneers a convenient,cheap,and eco-friendly tactic to procure low-temperature aqueous magnesium-ion energy storage device.
基金supported by the National Natural Science Foundation of China(No.52272180,No.12174162,No.51962010)the Shenzhen Science and Technology Research Grant(No.20220810123501001)the IER Foundation 2021(IERF202104)。
文摘Li metal is considered an ideal anode material for application in the next-generation secondary batteries.However,the commercial application of Li metal batteries has not yet been achieved due to the safety concern caused by Li dendrites growth.Despite the fact that many recent experimental studies found that external pressure suppresses the Li dendrites growth,the mechanism of the external pressure effect on Li dendrites remains poorly understood on the atomic scale.Herein,the large-scale molecular dynamics simulations of Li dendrites growth under different external pressure were performed with a machine learning potential,which has the quantum-mechanical accuracy.The simulation results reveal that the external pressure promotes the process of Li self-healing.With the increase of external pressure,the hole defects and Li dendrites would gradually fuse and disappear.This work provides a new perspective for understanding the mechanism for the impact of external pressure on Li dendrites.
基金financial support of the Guangdong Basic and Applied Basic Research Foundation(2019A1515110897 and 2019B1515120028)。
文摘Earth abundant O3-type NaFe_(0.5)Mn_(0.5)O_(2)layered oxide is regarded as one of the most promising cathodes for sodium ion batteries due to its low cost and high energy density.However,its poor structural stability and cycle life strongly impede the practical application.Herein,the dynamic phase evolution as well as charge compensation mechanism of O3-type NaFe_(0.5)Mn_(0.5)O_(2)cathode during sodiation/desodiation are revealed by a systemic study with operando X-ray diffraction and X-ray absorption spectroscopy,high resolution neutron powder diffraction and neutron pair distribution functions.The layered structure experiences a phase transition of O3→P3→OP2→ramsdellite during the desodiation,and a new O3’phase is observed at the end of the discharge state(1.5 V).The density functional theory(DFT)calculations and nPDF results suggest that depletion of Na^(+)ions induces the movement of Fe into Na layer resulting the formation of an inert ramsdellite phase thus causing the loss of capacity and structural integrity.Meanwhile,the operando XAS clarified the voltage regions for active Mn^(3+)/Mn^(4+)and Fe^(3+)/Fe^(4+)redox couples.This work points out the universal underneath problem for Fe-based layered oxide cathodes when cycled at high voltage and highlights the importance to suppress Fe migration regarding the design of high energy O3-type cathodes for sodium ion batteries.
基金supported by Natural Science Foundation of Guangdong Province,China (Grant Nos.2022A1515011990 and 2023A1515030086)National Natural Science Foundation of China (Grant Nos.11774239,11804230 and 61827815)+2 种基金National Key R&D Program of China (Grant No.2019YFB2204500)Shenzhen Science and Technology Innovation Commission (Grant Nos.JCYJ20220531102601004,KQTD20180412181422399 and JCYJ20180507181858539)High-Level University Construction Funds of SZU (Grant Nos.860-000002081209 and 860-000002110711)。
文摘Two-dimensional(2D)antiferroelectric materials have raised great research interest over the last decade.Here,we reveal a type of 2D antiferroelectric(AFE)crystal where the AFE polarization direction can be switched by a certain degree in the 2D plane.Such 2D functional materials are realized by stacking the exfoliated wurtzite(wz)monolayers with“self-healable”nature,which host strongly coupled ferroelasticity/antiferroelectricity and benign stability.The AFE candidates,i.e.,Zn X and Cd X(X=S,Se,Te),are all semiconductors with direct bandgap atΓpoint,which harbors switchable antiferroelectricity and ferroelasticity with low transition barriers,hidden spin polarization,as well as giant in-plane negative Poisson's ratio(NPR),enabling the co-tunability of hidden spin characteristics and auxetic magnitudes via AFE switching.The 2D AFE wz crystals provide a platform to probe the interplay of 2D antiferroelectricity,ferroelasticity,NPR,and spin effects,shedding new light on the rich physics and device design in wz semiconductors.
基金support by the National Natural Science Foundation of China(51975488 and 51991373)National Key R&D Program of China(2020YFA0711001)Fundamental Research Funds for the Central Universities(2682021CG011).
文摘With the rapid development of semiconductors,the number of materials needed to be polished sharply increases.The material properties vary significantly,posing challenges to chemical mechanical polishing(CMP).Accordingly,the study aimed to classify the material removal mechanism.Based on the CMP and atomic force microscopy results,the six representative metals can be preliminarily classified into two groups,presumably due to different material removal modes.From the tribology perspective,the first group of Cu,Co,and Ni may mainly rely on the mechanical plowing effect.After adding H_(2)O_(2),corrosion can be first enhanced and then suppressed,affecting the surface mechanical strength.Consequently,the material removal rate(MRR)and the surface roughness increase and decrease.By comparison,the second group of Ta,Ru,and Ti may primarily depend on the chemical bonding effect.Adding H_(2)O_(2)can promote oxidation,increasing interfacial chemical bonds.Therefore,the MRR increases,and the surface roughness decreases and levels off.In addition,CMP can be regulated by tuning the synergistic effect of oxidation,complexation,and dissolution for mechanical plowing,while tuning the synergistic effect of oxidation and ionic strength for chemical bonding.The findings provide mechanistic insight into the material removal mechanism in CMP.
基金supported by the Director, Office of Science (SC), Basic Energy Science (BES), Materials Science and Engineering Division (MSED), of the US Department of Energy (DOE) under Contract No. DE-AC02-05CH11231 through the Materials Theory program (KC2301) under Contract No. DE-AC02-05CH11231financially supported by the National Key R&D Program of China (2016YFB0700600)+1 种基金Shenzhen Science and Technology Research Grant (ZDSYS201707281026184)Guangdong Keylab Project (2017B0303010130)
文摘Recently, machine learning(ML) has become a widely used technique in materials science study. Most work focuses on predicting the rule and overall trend by building a machine learning model. However,new insights are often learnt from exceptions against the overall trend. In this work, we demonstrate that how unusual structures are discovered from exceptions when machine learning is used to get the relationship between atomic and electronic structures based on big data from high-throughput calculation database. For example, after training an ML model for the relationship between atomic and electronic structures of crystals, we find AgO2 F, an unusual structure with both Ag3+and O22à, from structures whose band gap deviates much from the prediction made by our model. A further investigation on this structure might shed light into the research on anionic redox in transition metal oxides of Li-ion batteries.
基金supported by the Major National S&T Program Grant(2017ZX10202203 and 2017ZX10302201 to AH)the Science&Technology Commission of China,the Emergency Project(cstc2020jscx-fyzx0053 to AH)+3 种基金the Science&Technology Commission of Chongqing,the National Natural Science Foundation of China(82002131 to YL)the Natural Science Foundation Project of CQ CSTC(cstc2020jcyjmsxmX0081 to YL)the foundation(KJCXZD2020018 to YL,CYS21244 to JZ)the Chongqing Municipal Education Commission,and the COVID-19 Emergency Project(CQMUNCP0207 to YL)from Chongqing Medical University。
文摘Coronavirus disease 2019(COVID-19),caused by severe acute respiratory syndrome coronavirus 2(SARS-CoV-2),is an ongoing pandemic that poses a great threat to human health worldwide.As the humoral immune response plays essential roles in disease occurrence and development,understanding the dynamics and characteristics of virus-specific humoral immunity in SARS-CoV-2-infected patients is of great importance for controlling this disease.In this review,we summarize the characteristics of the humoral immune response after SARS-CoV-2 infection and further emphasize the potential applications and therapeutic prospects of SARSCoV-2-specific humoral immunity and the critical role of this immunity in vaccine development.Notably,serological antibody testing based on the humoral immune response can guide public health measures and control strategies;however,it is not recommended for population surveys in areas with very low prevalence.Existing evidence suggests that asymptomatic individuals have a weaker immune response to SARS-CoV-2 infection,whereas SARS-CoV-2-infected children have a more effective humoral immune response than adults.The correlations between antibody(especially neutralizing antibody)titers and protection against SARS-CoV-2 reinfection should be further examined.In addition,the emergence of cross-reactions among different coronavirus antigens in the development of screening technology and the risk of antibody-dependent enhancement related to SARS-CoV-2 vaccination should be given further attention.
基金The research was financially supported by the National Key R&D Program of China(2016YFB0700600)the Guangdong Innovation Team Project(No.2013N080)+2 种基金the Soft Science Research Project of Guangdong Province(No.2017B030301013)the Shenzhen Science and Technology Research Grant(ZDSYS201707281026184)the Shenzhen Peacock Plan(KQTD2014062714543296).
文摘Solar-driven N_(2) fixation using a photocatalyst in water presents a promising alternative to the traditional Haber-Bosch process in terms of both energy efficiency and environmental concern.At present,the product of solar N_(2) fixation is either NH_(4)^(+)or NO_(3)^(-).Few reports described the simultaneous formation of ammonia(NH_(4)^(+))and nitrate(NO_(3)^(-))by a photocatalytic reaction and the related mechanism.In this work,we report a strategy to photocatalytically fix nitrogen through simultaneous reduction and oxidation to produce NH_(4)^(+)and NO_(3)^(-)byW18O49 nanowires in pure water.The underlying mechanism of wavelength-dependent N_(2) fixation in the presence of surface defects is proposed,with an emphasis on oxygen vacancies that not only facilitate the activation and dissociation of N_(2) but also improve light absorption and the separation of the photoexcited carriers.Both NH_(4)^(+)and NO_(3)^(-)can be produced in pure water under a simulated solar light and even till the wavelength reaching 730 nm.The maximum quantum efficiency reaches 9%at 365 nm.Theoretical calculation reveals that disproportionation reaction of the N_(2) molecule is more energetically favorable than either reduction or oxidation alone.It is worth noting that the molar fraction of NH_(4)^(+)in the total product(NH_(4)^(+)plus NO_(3)^(-))shows an inverted volcano shape from 365nm to 730 nm.The increased fraction of NO_(3)^(-)from 365 nm to around 427 nm results from the competition between the oxygen evolution reaction(OER)at W sites without oxygen vacancies and the N_(2) oxidation reaction(NOR)at oxygen vacancy sites,which is driven by the intrinsically delocalized photoexcited holes.From 427nm to 730 nm,NOR is energetically restricted due to its higher equilibrium potential than that of OER,accompanied by the localized photoexcited holes on oxygen vacancies.Full disproportionation of N_(2) is achieved within a range of wavelength from~427nm to~515 nm.This work presents a rational strategy to efficiently utilize the photoexcited carriers and optimize the photocatalyst for practical nitrogen fixation.
文摘The photocatalytic conversion of CO_(2)into sustainable,green fuels and value-added chemicals is believed to be an appealing method to overcome both the energy crisis and environmental problems.Numerous efforts have been dedicated to enhance the CO_(2)conversion efficiency and selectivity through developing photocatalysts and CO_(2)reduction systems in recent years.This review gives an overview of the latest progress in photocatalysts for visible-light photocatalytic CO_(2)conversion and recent research advances of heterogeneous photocatalytic CO_(2)conversion systems.Furthermore,The roles of cocatalyst and heterojunctions to increase the efficiency of charge transfer,separation and visible light excitation are discussed.Finally,the challenges and perspectives for visible-light-driven photocatalytic conversion of CO_(2)are proposed.
基金financially supported by the starting fund of Peking University,Shenzhen Graduate School and Fujian Science&Technology Innovation Laboratory for Energy Devices of China(21C-LAB)。
文摘The development of next-generation layered oxide cathodes for high-energy-density electrical vehicle Li-ion batteries(LIBs)is an urgent topic.The existing method is achieved by continuously increasing the Ni contents of Ni-based layered oxides,but it has been limited to LiNiO_(2).To break this limit and attain increased energy densities,a promising strategy,which involves the introduction of excess Li ions into transition metal(TM)layers to form Li-excess compounds Li_(2)MO_(3)(M is a TM cation),has attracted enormous interest recently.However,another strategy,which has been neglected in recent years,involves the insertion of an extra layer of Li ions between the TM and original Li layers to form Li_(2)MO_(2).In this study,typical reversible Li_(2)NiO_(3) and 1T-Li_(2)NiO_(2) were selected as two representative cathodes to break the limit of LiNiO_(2),thereby availing comprehensive comparison with LiNiO_(2) regarding their overall properties as cathodes from a theoretical perspective.Interestingly,dissimilar to the Ni^(3+)/Ni^(4+)monoelectron cationic redox associated with LiNiO_(2),a polaronic anionic redox reaction occurs in Li_(2)NiO_(3),while a reversible Ni^(2+)/Ni^(4+)double-electron redox reaction accompanied by insulator-metal transition occurs in Li_(2)NiO_(2).Owing to this double-electron cationic activity,Li_(2)NiO_(2) exhibits absolute advantages over the other two materials(LiNiO_(2) and Li_(2)NiO_(3))as cathodes for LIBs in terms of the capacity,energy density,electronic conductivity,and thermal stability,thus rendering it the most promising candidate for next-generation layered oxide cathodes with high energy densities to break the limit of LiNiO_(2).
基金This work is supported by National Natural Science Foundation of China(Grant Nos.11804230,11774239,61827815)Shenzhen Science and Technology Innovation Commission(Grant Nos.KQTD20170810105439418,KQTD20180412181422399,JCYJ20180507181858539,ZDSYS201707271554071)High-Level University Construction Funds of SZU(Grant No.860-000002081209 and 860-000002110711).
文摘Monolayers of layered materials,such as graphite and molybdenum dichalcogenides,have been the focus of materials science in the last decades.Here,we reveal benign stability and intriguing physical properties in the thinnest monolayer wurtzite(wz)semiconductors,which can be exfoliated from their bulk and stacked to reform the wz crystals.The candidate ZnX and CdX(X=S,Se,Te)monolayers possess low cleavage energy and direct bandgaps,which harbor strongly coupled ferroelectricity and ferroelasticity with low transition barriers,giant in-plane negative Poisson’s ratio,as well as giant Rashba spin splitting,enabling the co-tunability of spin splitting and auxetic magnitudes via multiferroic switching.These wz monolayers can be used as building blocks of devices structures,due to their inherent“self-healable”capacity,which offer more flexibility for semiconductor fabrication and provide a natural platform to probe the interplay of multiple physical effects,bringing light into the rich physics in tetrahedral semiconductors.
基金financially supported by the Starting Fund of Peking University Shenzhen Graduate School and Fujian Science&Technology Innovation Laboratory for Energy Devices of China(21C-LAB)the National Natural Science Foundation of China(12174162)。
基金the Major National S&T Program Grant(2017ZX10202203 and 2017ZX10302201 to AH)from the Science and Technology Commission of Chinathe Emergency Project(cstc2020jscx-fyzx0053 to AH)from the Science&Technology Commission of Chongqing+3 种基金the National Natural Science Foundation of China(82002131 to YL)the Natural Science Foundation Project of CQ CSTC(cstc2020jcyj-msxmX0081 to YL)the COVID-19 Emergency Project(CQMUNCP0207 to YL)the Scientific Research Staring Foundation of Chongqing Medical University(X9729 to YL)from Chongqing Medical University.
文摘The coronavirus disease 2019(COVID-19)pandemic,caused by severe acute respiratory syndrome coronavirus 2(SARS-CoV-2),is a major ongoing challenge to global health.After being infected by SARS-CoV-2,a specific humoral immune response may be rapidly induced in the host to restrain the viral infection via the production of neutralizing antibodies(NAbs),which are also useful for preventing reinfection[1,2].However,there is a lack of comprehensive understanding of the mechanisms underlying SARS CoV-2 specifc humoral immunity and alterations in immunoglobulin M(1gM)and G(1gG)levels in humans during viral infection.
基金This work was supported by the Emergency Project(cstc2020jscx-fyzx0053)from the Science&Technology Commission of Chongqingthe National Natural Science Foundation of China(82002131)+2 种基金the Natural Science Founda-tion Project of CQ CSTC(cstc2020jcyj-msxmX0081)the foundation(KJCXZD2020018,CY210407)from Chongqing Municipal Education Commissionthe COVID-19 Emer-gency Project(CQMUNCP0207)from Chongqing Medical University.
文摘The outbreak of the severe acute respiratory syndrome coronavirus 2(SARS-CoV-2)infection in December 2019 caused a huge blow to both global public health and global economy.At the early stage of the coronavirus disease 2019(COVID-19)epidemic,asymptomatic individuals with SARS-CoV-2 infection were ignored,without appropriate identification and isolation.However,asymptomatic individuals proved to comprise a high proportion of all SARS-CoV-2-infected individuals,which greatly contributed to the rapid and wide spread of this disease.In this review,we summarize the latest advances in epidemiological characteristics,diagnostic assessment methods,factors related to the establishment of SARS-CoV-2 asymptomatic infection,as well as humoral immune features after SARS-CoV-2 infection or vaccination in asymptomatic individuals,which would contribute to effective control of ongoing COVID-19 epidemic.