The stabilization of non-precious metals as isolated active sites with high loading density over nitrogendoped carbon materials is essential for realizing the industrial application of single atom catalysts.However,ac...The stabilization of non-precious metals as isolated active sites with high loading density over nitrogendoped carbon materials is essential for realizing the industrial application of single atom catalysts.However,achieving high loading of single cobalt active sites with greatly enhanced oxygen reduction reaction(ORR)activity and stability remains challenging.Here,an efficient approach was described to create a single atom cobalt electrocatalyst(Co SAs/NC)which possesses enhanced mesoporosity and specific surface area that greatly favor the mass transportation and exposure of accessible active sites.The electronic structure of the catalyst by the strong metal-support interaction has been elucidated through experimental characterizations and theoretical calculations.Due to dramatically enhanced mass transport and electron transfer endowed by morphology and electronic structure engineering,Co SAs/NC exhibits remarkable ORR performance with excellent activity(onset and half-wave potentials of 1.04 V(RHE)and 0.90 V(RHE),Tafel slope of 69.8 mV dec^(-1)and J_(k) of 18.8 mA cm^(-2)at 0.85 V)and stability(7 mV activity decay after 10,000 cycles).In additio n,the catalyst demonstrates great promise as an alternative to traditional Pt/C catalyst in zinc-air batteries while maintaining high performance in terms of high specific capacity of(796.1 mAh/g_(Zn)),power density(175.4 mW/cm^(2)),and long-term cycling stability(140 h).This study presents a facile approach to design SACs with highly accessible active sites for electrochemical transformations.展开更多
In this paper, we investigate the global existence and long time behavior of strong solutions for compressible nematic liquid crystal flows in threedimensional whole space. The global existence of strong solutions is ...In this paper, we investigate the global existence and long time behavior of strong solutions for compressible nematic liquid crystal flows in threedimensional whole space. The global existence of strong solutions is obtained by the standard energy method under the condition that the initial data are close to the constant equilibrium state in H2-framework. If the initial datas in Ll-norm are finite additionally, the optimal time decay rates of strong solutions are established. With the help of Fourier splitting method, one also establishes optimal time decay rates for the higher order spatial derivatives of director.展开更多
基金supported by the Postdoctoral Research Foundation of China(2019M661247,2020T130091)Scientific Research Foundation for Returned Scholars of Heilongjiang Province of China(719900091)+1 种基金Program for Overseas Talents Introduction of Northeast Petroleum University(15041260303)Heilongjiang Touyan Innovation Team Program。
文摘The stabilization of non-precious metals as isolated active sites with high loading density over nitrogendoped carbon materials is essential for realizing the industrial application of single atom catalysts.However,achieving high loading of single cobalt active sites with greatly enhanced oxygen reduction reaction(ORR)activity and stability remains challenging.Here,an efficient approach was described to create a single atom cobalt electrocatalyst(Co SAs/NC)which possesses enhanced mesoporosity and specific surface area that greatly favor the mass transportation and exposure of accessible active sites.The electronic structure of the catalyst by the strong metal-support interaction has been elucidated through experimental characterizations and theoretical calculations.Due to dramatically enhanced mass transport and electron transfer endowed by morphology and electronic structure engineering,Co SAs/NC exhibits remarkable ORR performance with excellent activity(onset and half-wave potentials of 1.04 V(RHE)and 0.90 V(RHE),Tafel slope of 69.8 mV dec^(-1)and J_(k) of 18.8 mA cm^(-2)at 0.85 V)and stability(7 mV activity decay after 10,000 cycles).In additio n,the catalyst demonstrates great promise as an alternative to traditional Pt/C catalyst in zinc-air batteries while maintaining high performance in terms of high specific capacity of(796.1 mAh/g_(Zn)),power density(175.4 mW/cm^(2)),and long-term cycling stability(140 h).This study presents a facile approach to design SACs with highly accessible active sites for electrochemical transformations.
文摘In this paper, we investigate the global existence and long time behavior of strong solutions for compressible nematic liquid crystal flows in threedimensional whole space. The global existence of strong solutions is obtained by the standard energy method under the condition that the initial data are close to the constant equilibrium state in H2-framework. If the initial datas in Ll-norm are finite additionally, the optimal time decay rates of strong solutions are established. With the help of Fourier splitting method, one also establishes optimal time decay rates for the higher order spatial derivatives of director.