Effect of safety valve types on the gas venting behavior and thermal runaway hazard severity of large-format prismatic lithium iron phosphate batteries

The safety valve is an important component to ensure the safe operation of lithium-ion batteries(LIBs).However,the effect of safety valve type on the thermal runaway(TR)and gas venting behavior of LIBs,as well as the TR hazard severity of LIBs,are not known.In this paper,the TR and gas venting behavior of three 100 A h lithium iron phosphate(LFP)batteries with different safety valves are investigated under overheating.Compared to previous studies,the main contribution of this work is in studying and evaluating the effect of gas venting behavior and TR hazard severity of LFP batteries with three safety valve types.Two significant results are obtained:(Ⅰ)the safety valve type dominates over gas venting pressure of battery during safety venting,the maximum gas venting pressure of LFP batteries with a round safety valve is 3320 Pa,which is one order of magnitude higher than other batteries with oval or cavity safety valve;(Ⅱ)the LFP battery with oval safety valve has the lowest TR hazard as shown by the TR hazard assessment model based on gray-fuzzy analytic hierarchy process.This study reveals the effect of safety valve type on TR and gas venting,providing a clear direction for the safety valve design.

Early warning method for thermal runaway of lithium-ion batteries under thermal abuse condition based on online electrochemical impedance monitoring

Early warning of thermal runaway(TR)of lithium-ion batteries(LIBs)is a significant challenge in current application scenarios.Timely and effective TR early warning technology is urgently required considering the current fire safety situation of LIBs.In this work,we report an early warning method of TR with online electrochemical impedance spectroscopy(EIS)monitoring,which overcomes the shortcomings of warning methods based on traditional signals such as temperature,gas,and pressure with obvious delay and high cost.With in-situ data acquisition through accelerating rate calorimeter(ARC)-EIS test,the crucial features of TR were extracted using the RReliefF algorithm.TR mechanisms corresponding to the features at specific frequencies were analyzed.Finally,a three-level warning strategy for single battery,series module,and parallel module was formulated,which can successfully send out an early warning signal ahead of the self-heating temperature of battery under thermal abuse condition.The technology can provide a reliable basis for the timely intervention of battery thermal management and fire protection systems and is expected to be applied to electric vehicles and energy storage devices to realize early warning and improve battery safety.

The efficiency and toxicity of dodecafluoro-2-methylpentan-3-one in suppressing lithium-ion battery fire

Currently,the effective and clean suppression of lithium-ion battery(LIB)fires remains a challenge.The present work investigates the use of various inhibitor doses(Xin)of dodecafluoro-2-methylpentan-3-one(C_(6) F_(12)O)in 300 Ah LIBs,and systematically examines the thermal and toxic hazards of the extinguished batteries via real scale combustion and gas analysis.The inhibitor is shown to be completely effective.The inhibition mechanism involves a combination of chemical inhibition and physical cooling.While the chemical inhibition effect tends to saturate with increasing Xin,the physical cooling remains effective at higher inhibitor doses.However,extinguishing the battery fire with a high Xin of C_(6)F_(12)O is found to incur serious toxicity problems.These results are expected to provide a guideline for the design of inhibitor doses for the suppression of LIB fires.

Insight into the structural evolution and thermal behavior of LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2) cathode under deep charge

By virtue of the crucial effect of the crystal structure and transition metal(TM)redox evolution on the performance of LiNi_(x)Co_(y)Mn_(z)O_(2)(NCM)cathode,systematical investigation is carried out to better understand the charge mechanism upon deep charging.Based on the results of X-ray diffraction and highresolution transmission electron microscope,phase transformations existing on particle surface are promoted by high potential because of the deeper lithium vacancies,accompanied by more substantial structure instability.Soft X-ray absorption spectroscopy indicates that Ni acts as the major contributor to charge compensation while Co displays a remarkable redox activity over the deep charge range.The elevated integrated intensity of pre-edge in O K-edge spectra reveals the extensive amount of holes formed in O 2 p orbitals and the enhanced hybridization of TM 3 d-O 2 p orbitals.Considering the close relationship between thermal behavior and structural evolution,the tendency of phase transitions and O_(2) release upon heating is accelerated by voltage rise,demonstrating the aggravated instability due to deeper Li utilization.Remaining Li contents in NCM are employed to estimate the amount of oxygen released in structural transformation and its detrimental effect on stability declares Li contentdependent characteristics.Furthermore,the extended Li vacancies,higher proportion of Ni4+and stronger orbital hybridization are considered as three factors impeding the thermal stability of the highlydelithiated NCM.

Precise in-situ and ex-situ study on thermal behavior of LiNi_(1/3)Co_(1/3)Mn_(1/3)O_(2)/graphite coin cell:From part to the whole cell

Multiple mode calorimetry and C80 micro-calorimeter are used to investigate the impact of cathode and anode on heat generation of lithium ion battery.The thermal behaviors of LiNi_(x)Co_(y)Mn_(z)O_(2)/graphite full cell are discussed under normal operating and elevating temperature.Affected by negative entropy change,lithium intercalation presents more exotherms than deintercalation for both electrode materials.The contributions of irreversible and reversible heat to the total heat generation of graphite are evaluated.The phase transitions correlated with voltages and lithium contents are determined.Based on the analysis of half-cell,the effect of two electrodes(with the same capacity)on overall heat generation is nearly the same and anode of full cell plays a key role in charging while cathode dominates in discharging.Thermal behaviors of lithiated graphite and delithiated LiNi_(x)Co_(y)Mn_(z)O_(2) electrolyte and their coexisting system are identified to further explore their influence on battery safety.The breakdown of solid electrolyte interface(SEI)at around 82℃ is considered as a crucial factor affecting the thermal stability of full cell.The oxidation of electrolyte induced by oxygen released from cathode material turns out to be one of the main heat sources.These accurate results are of great significance to improve the existing thermal management system and provide basic data for the prediction of battery performance.

A review on research of fire dynamics in high-rise buildings

Since serious fire occurred frequently in recent years, fire safety of high-rise building has attracted extensive attention. A National Basic Research Program （973 program） of China has been set up by Ministry of Science and Technology （MOST） of China in 2012 to meet the research requirements of fire safety in high-rise buildings. This paper reviews the current state of art of research on fire dynamics of high-rise buildings, including the up-to-date progress of this project. The following three subjects on fire dynamics of high-rise buildings are addressed in this review： the ejected flame and fire plume behavior over facade out of the compartment window, the flame spread behavior over facade thermal insulation materiMs, and the buoyancy-driven smoke transportation characteristics along long vertical channels in high-rise buildings. Prospective future works are discussed and summarized.

Transition-metal redox evolution and its effect on thermal stability of LiNixCoyMnzO_(2) based on synchrotron soft X-ray absorption spectroscopy

Based on the synchrotron soft X-ray absorption spectroscopy experiments,the fundamental electronic structures of layered Li NixCoyMnzO_(2)(NCM)are investigated systematically and the data of transitionmetal(TM)L-and O K-edges spectra are collected.Distribution of Ni ions under different oxidation states is evaluated according to linear combination fit.It is found that the ratio of Ni^(4+)expands with the increase of Ni since it dominates in charge compensation during charging,and that the existence of Ni^(3+)is nearly negligible in delithiated NCM.The valence state of Co also strongly depends on Ni content,the perceptible position shift of Co L_(3)-edge absorption peak towards higher energy in Ni-rich material agrees well with the small voltage plateau at around 4.2 V.The stability of Mn is verified as no obvious spectral change with the Mn L-edge is observed.Moreover,as Ni content rises,the O 2p holes near the Femi level increases with higher oxidation state of Ni,indicating the enhanced hybridization of O 2p-TM 3 d.Delithiated NCMs with higher Ni content are prior to lose electron existing in highly hybridized Ni3 dO 2 p bands upon heating,which accounts for the pronounced O_(2)release in phase transitions and the deterioration in thermal stability.These detailed observation of the electronic structure evolution is one of the key ingredients to improving the electrochemical and thermal performance of NCM.

Correlating electrochemical performance and heat generation of Li plating for lithium-ion battery with fluoroethylene carbonate additive

1.Introduction With the superior performance of high energy density,lightweight and long life span,lithium-ion battery(LIB)are perceived as an attractive and reliable power source for modern-used portable electronics,ecofriendly electric vehicles and power distribution,and thereby a remarkable solution to assuage energy dependence on fossil fuel and environmental concern.Nevertheless,the unexpected Li plating together with the Li dendrites growth on graphite anode surface has been a profound hindrance to the practical application of LIB,of which induces inferior Coulombic efficiency,poor lifespan and safety concern[1].

Editorial: Special subject on the mechanical behavior of fire dynamics in high-rise buildings

With rapid economic and social development in China, high-rise buildings have continuously sprung up since 2006. However, several big fire accidents in high-rise buildings such as the Beijing Television Cultural Center fire in 2009 and the Shanghai Jing＇an District fire in 2010 etc. have claimed people＇s lives and caused huge amounts of economic and property losses,

Multi-Branch Fractional Multi-Bit Differential Detection of Continuous Phase Modulation with Decision Feedback

Differential detection of continuous phase modulation suffers from significant intersymbol interference. To reduce bit error rate, multi-branch fractional multi-bit differential detection (MFMDD) with decision feed-back is proposed. By introducing decision feedback in multi-bit differential detected signals, severe inter-symbol interference can be removed. Simulation results show that the proposed structure can greatly im-proves the performance compared with MFMDD without decision feedback, and the performance of 9 FMDD is very near to the performance of the coherent detection.

A dynamic interaction assessment method for disaster management based on extended DEMATEL

With the frequent occurrence of various disasters,serious damage has been caused to social and economic development.Therefore,disaster management plays an increasingly significant role in controlling disasters and reducing losses.This study aims to provide a dynamic interaction assessment method for the emergency management department to manage disasters.For this purpose,the classical Decision-Making Trial and Evaluation Laboratory(DEMATEL)method is first extended with bipolar 2-tuple linguistic information to model both the negative and positive influences among factors involved in coping with disaster.Then,the weights of influential factors are determined according to their total interaction relationships derived by extended DEMATEL.After that,the performances or states of factors are suggested to be appraised under a bipolar 2-tuple linguistic environment.Further,the performance or state simulation rule of factors is proposed based on their initial states and the interactions among them during disaster management.According to the simulation results,a weighted average operator is employed to obtain the overall performance values of emergency scenarios.Finally,an illustrative example and comparative analysis are presented for elucidating the feasibility and usefulness of the suggested method.Results of a case study show that the proposed method has the abilities to capture the interactions among influential factors and explore how the factors and their interactions affect disaster management.The proposed method could provide valuable information to emergency management departments for managing disasters more effectively.

Experimental and LES investigation of flame propagation in a hydrogen/air mixture in a combustion vessel

This work presents an experimental and numerical investigation of premixed flame propagation in a hydrogen/air mixture in a closed combustion vessel.In the experiment,high-speed schlieren video photography and pressure sensor are used to examine the flame dynamics and pressure transient.In the numerical study,a large eddy simulation(LES)based on a RNG sub-grid approach and a LES combustion model is applied to reproduce experimental observations.The effects of four physical phenomena on the burning velocity are considered in the combustion model,and the impact of grid type on the combustion dynamics is examined in the LES calculations.The flame experiences four stages both in experiment and LES calculations with structured and unstructured grids,i.e.,spherical flame,finger-shaped flame,flame with its skirt in contact with the sidewalls,and tulip-shaped flame.The flame speed and pressure in the vessel develop with periodical oscillations in both the experiment and LES simulations due to the interaction of flame front with pressure wave.The numerical simulations compare well with the detailed experimental measurements,especially in term of the flame shape and position,pressure build-up,and periodical oscillation behaviors.The LES combustion model is successfully validated against the bench-scale experiment.It is put into evidence that mesh type has an impact to a certain extent on the numerical combustion dynamics,and the LES calculation on structured grid canpredict the flame dynamics and pressure rise more accurately than that on unstructured grid with the same mesh resolution.The flame shape is more asymmetrical in the LES on an unstructured grid than that on a structured grid,and both the flame speed and the pressure rise at the later flame stage are underestimated in the LES on the unstructured grid.

Can the Shanghai LNG Price Index indicate Chinese market?An econometric investigation using price discovery theory

China became the world's second largest liquefied natural gas(LNG)importer in 2018 but has faced extremely high import costs due to a lack of bargaining power.Assessments of the Shanghai LNG Price Index,first released in 2015,are vital for improving the understanding of these cost dynamics.This paper,using the LNG price index data from the Shanghai Petroleum and Gas Exchange(SHPGX)coupled with domestic and international LNG prices from July 1,2015 to December 31,2018,estimates several econometric models to evaluate the long-term and short-term equilibriums of the Shanghai LNG Price Index,the responses to market information shocks and the leading or lagging relationships with LNG and alternative energy prices from other agencies.The results show that the LNG price index of the SHPGX has already exhibited a long-term equilibrium and short-term adjustment mechanisms to reflect the average price level and market movements,but the market information transparency and price discovery efficiency of the index are still inadequate.China's LNG market is still relatively independent of other natural gas markets,and marketization reforms are under way in China.The influence of the SHPGX LNG price index on the trading decisions of market participants is expected to improve with further development of China's LNG reforms,the formation of a natural gas entry-exit system,and the increasing liquidity of the hub.