Titanium(Ti)alloys are widely used in high-tech fields like aerospace and biomedical engineering.Laser additive manufacturing(LAM),as an innovative technology,is the key driver for the development of Ti alloys.Despite...Titanium(Ti)alloys are widely used in high-tech fields like aerospace and biomedical engineering.Laser additive manufacturing(LAM),as an innovative technology,is the key driver for the development of Ti alloys.Despite the significant advancements in LAM of Ti alloys,there remain challenges that need further research and development efforts.To recap the potential of LAM high-performance Ti alloy,this article systematically reviews LAM Ti alloys with up-to-date information on process,materials,and properties.Several feasible solutions to advance LAM Ti alloys are reviewed,including intelligent process parameters optimization,LAM process innovation with auxiliary fields and novel Ti alloys customization for LAM.The auxiliary energy fields(e.g.thermal,acoustic,mechanical deformation and magnetic fields)can affect the melt pool dynamics and solidification behaviour during LAM of Ti alloys,altering microstructures and mechanical performances.Different kinds of novel Ti alloys customized for LAM,like peritecticα-Ti,eutectoid(α+β)-Ti,hybrid(α+β)-Ti,isomorphousβ-Ti and eutecticβ-Ti alloys are reviewed in detail.Furthermore,machine learning in accelerating the LAM process optimization and new materials development is also outlooked.This review summarizes the material properties and performance envelops and benchmarks the research achievements in LAM of Ti alloys.In addition,the perspectives and further trends in LAM of Ti alloys are also highlighted.展开更多
The feasibility of manufacturing Ti-6Al-4V samples through a combination of laser-aided additive manufacturing with powder(LAAM_(p))and wire(LAAM_(w))was explored.A process study was first conducted to successfully ci...The feasibility of manufacturing Ti-6Al-4V samples through a combination of laser-aided additive manufacturing with powder(LAAM_(p))and wire(LAAM_(w))was explored.A process study was first conducted to successfully circumvent defects in Ti-6Al-4V deposits for LAAM_(p) and LAAM_(w),respectively.With the optimized process parameters,robust interfaces were achieved between powder/wire deposits and the forged substrate,as well as between powder and wire deposits.Microstructure characterization results revealed the epitaxial prior β grains in the deposited Ti-6Al-4V,wherein the powder deposit was dominated by a finerα′microstructure and the wire deposit was characterized by lamellar α phases.The mechanisms of microstructure formation and correlation with mechanical behavior were analyzed and discussed.The mechanical properties of the interfacial samples can meet the requirements of the relevant Aerospace Material Specifications(AMS 6932)even without post heat treatment.No fracture occurred within the interfacial area,further suggesting the robust interface.The findings of this study highlighted the feasibility of combining LAAM_(p) and LAAM_(w) in the direct manufacturing of Ti-6Al-4V parts in accordance with the required dimensional resolution and deposition rate,together with sound strength and ductility balance in the as-built condition.展开更多
The quenching-induced residual stress in ultrahigh strength Al-Zn-Mg-Cu alloys has a great influence on their precipitation behaviour in subsequent heat treatment and the properties of the final products.In the presen...The quenching-induced residual stress in ultrahigh strength Al-Zn-Mg-Cu alloys has a great influence on their precipitation behaviour in subsequent heat treatment and the properties of the final products.In the present work,the cladding quenching method was employed for 7085 Al alloy slabs to tailor different quenching residual stresses.Then the effects of quenching residual stress on the precipitation behaviour of the 7085 Al alloy were investigated through finite element analysis,residual stress and hardness distri-bution measurements and microstructural examinations.The results indicate that the reduction in resid-ual stress increases with increasing cladding layer thickness.For a cladding layer thickness in the range of 1-1.4 mm,the residual stress is almost eliminated.The hardness at the surface of the aged sample with a large compressive residual stress is decreased,while the hardness at the centre of the sample with a large tensile residual stress is increased.The hardness is approximately identical between the aged sam-ples with little or no residual stress.The elastic lattice distortion caused by residual stress is found to promote the nucleation of precipitates during the artificial ageing process.The in-depth mechanisms for the effect of quenching residual stress on the precipitation of 7085 Al alloy are also discussed.展开更多
Magnesium matrix composites are a new generation of biocompatible implant materials,but they will inevitably undergo simultaneous wear and corrosion in the human body.In this study,hydroxyapatite(Ca10(PO4)6(OH)2,HA)is...Magnesium matrix composites are a new generation of biocompatible implant materials,but they will inevitably undergo simultaneous wear and corrosion in the human body.In this study,hydroxyapatite(Ca10(PO4)6(OH)2,HA)is used in a magnesium matrix composite to study its effects on the corrosion–wear behavior.Two samples(a magnesium alloy composed of Mg,Zn,and Zr(ZK60)alloy and ZK60/10HA composite)were fabricated using the powder metallurgy(PM)process.Their corrosion–wear behavior was investigated using the sliding wear test in a simulated body fluid(SBF).At all the sliding velocities tested,the corrosion–wear resistance of ZK60/10HA was superior to ZK60.At a sliding velocity of 942.5 mm/min,ZK60/10HA demonstrated a 42%improvement in corrosion–wear resistance compared to ZK60.For ZK60,the main wear mechanism under dry conditions was abrasion,while the wear mechanisms in the SBF were abrasion and corrosion.For ZK60/10HA,the wear mechanisms under dry conditions were abrasion and delamination,while in SBF they were mainly abrasion and corrosion,accompanied by slight delamination.The results indicated that HA particles can be used as an effective corrosion–wear inhibitor in biocompatible magnesium matrix composites.展开更多
The metastableα’phase and dislocation characteristics(e.g.,density and constituents)are of vital importance for the mechanical responses of(α+β)titanium alloys.In this work,to reveal the in-depth decomposition mec...The metastableα’phase and dislocation characteristics(e.g.,density and constituents)are of vital importance for the mechanical responses of(α+β)titanium alloys.In this work,to reveal the in-depth decomposition mechanisms of dislocations and metastableα’and their influences on mechanical properties in a Ti-6Al-4V(α+β)alloy,the thermal stability of different microstructures tailored by various cooling approaches were investigated utilizing scanning electron microscope,electron backscattered diffraction,transmission electron microscope and X-ray diffraction line profile analysis.The results showed that the initial characteristics ofα’andαlaths and dislocation density were influenced by the cooling methods remarkably.The thermal stability of Ti-6Al-4V alloy increased with decreasing cooling rate.The improvement in thermal stability can be ascribed by the decrement in dislocations,partitioning of the alloying elements and grain orientations variation of theα’lath andαphase.It is also found that the plastic strain accommodation ofβ→α’transformation was dominated by dislocations.During stabilization annealing treatments,the,and dislocations simultaneously decomposed.The decomposition of dislocations and metastableα’phase during various stabilization annealing and the particular twins and stacking faults microstructures formed during quenching have a great influence on the properties of the studied Ti-6Al-4V alloy.展开更多
Recent years witnessed a growing research interest in graphene-reinforced aluminum matrix composites(GRAMCs).Compared with conventionalreinforcements of aluminum matrix composites(AMCs),graphene possesses manyattracti...Recent years witnessed a growing research interest in graphene-reinforced aluminum matrix composites(GRAMCs).Compared with conventionalreinforcements of aluminum matrix composites(AMCs),graphene possesses manyattractive characteristics such as extremely high strength and modulus,unique self-lubricating property,high thermal conductivity(TC)and electrical conductivity(EC),andlow coefficient of thermal expansion(CTE).A lot of studies have demonstrated that theincorporation of graphene into Al or Al alloy can effectively enhance mechanical andphysical properties of the Al matrix.The purpose of this work is aimed to trace recentdevelopment of GRAMCs.Initially,this paper covers a brief overview of fabricationmethods of GRAMCs.Then,mechanical,tribological,thermal and electrical properties ofrecently developed GRAMCs are presented and discussed.Finally,challenges andcorresponding solutions related to GRAMCs are reviewed.展开更多
基金financially supported by the Young Individual Research Grants(Grant No:M22K3c0097)Singapore RIE 2025 plan and Singapore Aerospace Programme Cycle 16(Grant No:M2215a0073)led by C Tan+2 种基金supported by the Singapore A*STAR Career Development Funds(Grant No:C210812047)the National Natural Science Foundation of China(52174361 and 52374385)the support by US NSF DMR-2104933。
文摘Titanium(Ti)alloys are widely used in high-tech fields like aerospace and biomedical engineering.Laser additive manufacturing(LAM),as an innovative technology,is the key driver for the development of Ti alloys.Despite the significant advancements in LAM of Ti alloys,there remain challenges that need further research and development efforts.To recap the potential of LAM high-performance Ti alloy,this article systematically reviews LAM Ti alloys with up-to-date information on process,materials,and properties.Several feasible solutions to advance LAM Ti alloys are reviewed,including intelligent process parameters optimization,LAM process innovation with auxiliary fields and novel Ti alloys customization for LAM.The auxiliary energy fields(e.g.thermal,acoustic,mechanical deformation and magnetic fields)can affect the melt pool dynamics and solidification behaviour during LAM of Ti alloys,altering microstructures and mechanical performances.Different kinds of novel Ti alloys customized for LAM,like peritecticα-Ti,eutectoid(α+β)-Ti,hybrid(α+β)-Ti,isomorphousβ-Ti and eutecticβ-Ti alloys are reviewed in detail.Furthermore,machine learning in accelerating the LAM process optimization and new materials development is also outlooked.This review summarizes the material properties and performance envelops and benchmarks the research achievements in LAM of Ti alloys.In addition,the perspectives and further trends in LAM of Ti alloys are also highlighted.
基金financially supported by the Agency for Science,Technology and Research(A*Star),Republic of Singapore,under the Aerospace Consortium Cycle 12“Characterization of the Effect of Wire and Powder Deposited Materials”(No.A1815a0078)。
文摘The feasibility of manufacturing Ti-6Al-4V samples through a combination of laser-aided additive manufacturing with powder(LAAM_(p))and wire(LAAM_(w))was explored.A process study was first conducted to successfully circumvent defects in Ti-6Al-4V deposits for LAAM_(p) and LAAM_(w),respectively.With the optimized process parameters,robust interfaces were achieved between powder/wire deposits and the forged substrate,as well as between powder and wire deposits.Microstructure characterization results revealed the epitaxial prior β grains in the deposited Ti-6Al-4V,wherein the powder deposit was dominated by a finerα′microstructure and the wire deposit was characterized by lamellar α phases.The mechanisms of microstructure formation and correlation with mechanical behavior were analyzed and discussed.The mechanical properties of the interfacial samples can meet the requirements of the relevant Aerospace Material Specifications(AMS 6932)even without post heat treatment.No fracture occurred within the interfacial area,further suggesting the robust interface.The findings of this study highlighted the feasibility of combining LAAM_(p) and LAAM_(w) in the direct manufacturing of Ti-6Al-4V parts in accordance with the required dimensional resolution and deposition rate,together with sound strength and ductility balance in the as-built condition.
基金supported by the Nation Natural Science Foun-dation of China(No.51874127)Postgraduate Scientific Re-search Innovation Project of Hunan Province(No.CX20210403).
文摘The quenching-induced residual stress in ultrahigh strength Al-Zn-Mg-Cu alloys has a great influence on their precipitation behaviour in subsequent heat treatment and the properties of the final products.In the present work,the cladding quenching method was employed for 7085 Al alloy slabs to tailor different quenching residual stresses.Then the effects of quenching residual stress on the precipitation behaviour of the 7085 Al alloy were investigated through finite element analysis,residual stress and hardness distri-bution measurements and microstructural examinations.The results indicate that the reduction in resid-ual stress increases with increasing cladding layer thickness.For a cladding layer thickness in the range of 1-1.4 mm,the residual stress is almost eliminated.The hardness at the surface of the aged sample with a large compressive residual stress is decreased,while the hardness at the centre of the sample with a large tensile residual stress is increased.The hardness is approximately identical between the aged sam-ples with little or no residual stress.The elastic lattice distortion caused by residual stress is found to promote the nucleation of precipitates during the artificial ageing process.The in-depth mechanisms for the effect of quenching residual stress on the precipitation of 7085 Al alloy are also discussed.
基金Tliis study was supported by National Natural Science Foundation of China(Nos.51574118 and 51674118).
文摘Magnesium matrix composites are a new generation of biocompatible implant materials,but they will inevitably undergo simultaneous wear and corrosion in the human body.In this study,hydroxyapatite(Ca10(PO4)6(OH)2,HA)is used in a magnesium matrix composite to study its effects on the corrosion–wear behavior.Two samples(a magnesium alloy composed of Mg,Zn,and Zr(ZK60)alloy and ZK60/10HA composite)were fabricated using the powder metallurgy(PM)process.Their corrosion–wear behavior was investigated using the sliding wear test in a simulated body fluid(SBF).At all the sliding velocities tested,the corrosion–wear resistance of ZK60/10HA was superior to ZK60.At a sliding velocity of 942.5 mm/min,ZK60/10HA demonstrated a 42%improvement in corrosion–wear resistance compared to ZK60.For ZK60,the main wear mechanism under dry conditions was abrasion,while the wear mechanisms in the SBF were abrasion and corrosion.For ZK60/10HA,the wear mechanisms under dry conditions were abrasion and delamination,while in SBF they were mainly abrasion and corrosion,accompanied by slight delamination.The results indicated that HA particles can be used as an effective corrosion–wear inhibitor in biocompatible magnesium matrix composites.
基金supported by the National Natural Science Foundation of China(51774124,52074114)Hunan Provincial Natural Science Foundation of China(2019JJ40017,2020JJ5062)Graduate Training and Innovation Practice Base of Hunan Province。
文摘The metastableα’phase and dislocation characteristics(e.g.,density and constituents)are of vital importance for the mechanical responses of(α+β)titanium alloys.In this work,to reveal the in-depth decomposition mechanisms of dislocations and metastableα’and their influences on mechanical properties in a Ti-6Al-4V(α+β)alloy,the thermal stability of different microstructures tailored by various cooling approaches were investigated utilizing scanning electron microscope,electron backscattered diffraction,transmission electron microscope and X-ray diffraction line profile analysis.The results showed that the initial characteristics ofα’andαlaths and dislocation density were influenced by the cooling methods remarkably.The thermal stability of Ti-6Al-4V alloy increased with decreasing cooling rate.The improvement in thermal stability can be ascribed by the decrement in dislocations,partitioning of the alloying elements and grain orientations variation of theα’lath andαphase.It is also found that the plastic strain accommodation ofβ→α’transformation was dominated by dislocations.During stabilization annealing treatments,the,and dislocations simultaneously decomposed.The decomposition of dislocations and metastableα’phase during various stabilization annealing and the particular twins and stacking faults microstructures formed during quenching have a great influence on the properties of the studied Ti-6Al-4V alloy.
基金supported by the National Natural Science Foundation of China(Grant No.51774124)the Natural Science Foundation of Hunan Province(Grant No.2019JJ40017).
文摘Recent years witnessed a growing research interest in graphene-reinforced aluminum matrix composites(GRAMCs).Compared with conventionalreinforcements of aluminum matrix composites(AMCs),graphene possesses manyattractive characteristics such as extremely high strength and modulus,unique self-lubricating property,high thermal conductivity(TC)and electrical conductivity(EC),andlow coefficient of thermal expansion(CTE).A lot of studies have demonstrated that theincorporation of graphene into Al or Al alloy can effectively enhance mechanical andphysical properties of the Al matrix.The purpose of this work is aimed to trace recentdevelopment of GRAMCs.Initially,this paper covers a brief overview of fabricationmethods of GRAMCs.Then,mechanical,tribological,thermal and electrical properties ofrecently developed GRAMCs are presented and discussed.Finally,challenges andcorresponding solutions related to GRAMCs are reviewed.