The star-forming clumps in star-bursting dwarf galaxies provide valuable insights into understanding the evolution of dwarf galaxies.In this paper,we focus on five star-bursting dwarf galaxies featuring off-centered c...The star-forming clumps in star-bursting dwarf galaxies provide valuable insights into understanding the evolution of dwarf galaxies.In this paper,we focus on five star-bursting dwarf galaxies featuring off-centered clumps in the Mapping Nearby Galaxies at Apache Point Observatory survey.Using the stellar population synthesis software Fitting Analysis using Differential evolution Optimization,we obtain the spatially resolved distribution of the star formation history,which allows us to construct the g-band images of the five galaxies at different ages.These images can help us to probe the evolution of the morphological structures of these galaxies.While images of a stellar population older than 1 Gyr are typically smooth,images of a stellar population younger than 1 Gyr reveal significant clumps,including multiple clumps which appear at different locations and even different ages.To study the evolutionary connections of these five galaxies to other dwarf galaxies before their star-forming clumps appear,we construct the images of the stellar populations older than three age nodes,and define them to be the images of the"host"galaxies.We find that the properties such as the central surface brightness and the effective radii of the hosts of the five galaxies are in between those of dwarf ellipticals(dEs)and dwarf irregulars(dIrrs),with two clearly more similar to dEs and one more similar to dIrrs.Among the five galaxies,8257-3704 is particularly interesting,as it shows a previous starburst event that is not quite visible from its gri image,but only visible from images of the stellar population at a few hundred million years.The star-forming clump associated with this event may have appeared at around 600 Myr ago and disappeared at around 40 Myr ago.展开更多
A two-photon near infrared(NIR)fluorescence turn-on sensor with high selectivity and sensitivity for Zn^(2+)detection has been developed.This sensor exhibits a large Stokes'shift(-300 nm)and can be excited from 90...A two-photon near infrared(NIR)fluorescence turn-on sensor with high selectivity and sensitivity for Zn^(2+)detection has been developed.This sensor exhibits a large Stokes'shift(-300 nm)and can be excited from 900 to 1000 nm,with an emission wavelength of-785 nm,making it ideal for imaging in biological tissues.The sensor's high selectivity for Zn^(2+)over other structurally similar cations,such as Cd^(2+),makes it a promising tool for monitoring zinc ion levels in biological systems.Given the high concentration of zinc in thrombi,this sensor could provide a useful tool for in vivo thrombus imaging.展开更多
Understanding how summer warming influences the parent and daughter shoot production in a perennial clonal grass is vital for comprehending the response of grassland productivity to global warming.Here,we conducted a s...Understanding how summer warming influences the parent and daughter shoot production in a perennial clonal grass is vital for comprehending the response of grassland productivity to global warming.Here,we conducted a simulated experiment using potted Leymus chinensis,to study the relationship between the photosynthetic activ-ity of parent shoots and the production of daughter shoots under a whole(90 days)summer warming scenario(+3°C).The results showed that the biomass of parents and buds decreased by 25.52%and 33.45%,respectively,under warming conditions.The reduction in parent shoot biomass due to warming directly resulted from decreased leaf area(18.03%),chlorophyll a(18.27%),chlorophyll b(29.21%)content,as well as a reduction in net photosynthetic rate(7.32%)and the maximum quantum efficiency of photosystem II(PSII)photochemistry(4.29%).The decline in daughter shoot biomass was linked to a decrease in daughter shoot number(33.33%)by warming.However,the number of belowground buds increased by 46.43%.The results indicated that long-term summer warming reduces biomass accumulation in parent shoot by increasing both limitation of stoma and non-stoma.Consequently,the parent shoot allocates relatively more biomass to the belowground organs to maintain the survival and growth of buds.Overall,buds,as a potential aboveground population,could remedy for the cur-rent loss of parent shoot density by increasing the number of future daughter shoots if summer warming subsides.展开更多
The ability to navigate long distances is essential for many animals to locate shelter,food,and breeding grounds.Magnetic sense has evolved in various migratory and homing species to orient them based on the geomagnet...The ability to navigate long distances is essential for many animals to locate shelter,food,and breeding grounds.Magnetic sense has evolved in various migratory and homing species to orient them based on the geomagnetic field.A highly conserved ironsulfur cluster assembly protein IscA is proposed as an animal magnetoreceptor(MagR).Iron-sulfur cluster binding is also suggested to play an essential role in MagR magnetism and is thus critical in animal magnetoreception.In the current study,we provide evidence for distinct iron binding and iron-sulfur cluster binding in MagR in pigeons,an avian species that relies on the geomagnetic field for navigation and homing.Pigeon MagR showed significantly higher total iron content from both iron-and ironsulfur binding.Y65 in pigeon MagR was shown to directly mediate mononuclear iron binding,and its mutation abolished iron-binding capacity of the protein.Surprisingly,both iron binding and iron-sulfur binding demonstrated synergistic effects,and thus appear to be integral and indispensable to pigeon MagR magnetism.These results not only extend our current understanding of the origin and complexity of MagR magnetism,but also imply a possible molecular explanation for the huge diversity in animal magnetoreception.展开更多
In this work, a novel heterojunction composite Ag_(2)S/KTa_(x)Nb_(1-x)O_(3)was designed and synthesized through a combination of hydrothermal and precipitation procedures. The Ta/Nb ratio of the KTa_(x)Nb_(1-x)O_(3)an...In this work, a novel heterojunction composite Ag_(2)S/KTa_(x)Nb_(1-x)O_(3)was designed and synthesized through a combination of hydrothermal and precipitation procedures. The Ta/Nb ratio of the KTa_(x)Nb_(1-x)O_(3)and the Ag_(2)S content were optimized. The best 0.5% Ag_(2)S/KTa_(0.5)Nb_(0.5)O_(3)(KTN) sample presents an enhanced photocatalytic performance in ammonia synthesis than KTN and Ag_(2)S. Under simulated sunlight, the NH_(3)generation rate of 0.5% Ag_(2)S/KTN reaches 2.0 times that of pure KTN. Under visible light, the reaction rate ratio of the two catalysts is 6.0.XRD, XPS, and TEM analysis revealed that Ag2S was intimately decorated on the KTN nanocubes surface, which promoted the electron transfer between the two semiconductors. The band structure investigation indicated that the Ag_(2)S/KTN heterojunction established a type-Ⅱ band alignment with intimate contact, thus realizing the effective transfer and separation of photogenerated carriers. The change in charge separation was considered as the main reason for the enhanced photocatalytic performance. Interestingly, the Ag_(2)S/KTN composite exhibited higher NH3generation performance under the combined action of ultrasonic vibration and simulated sunlight. The enhanced piezo-photocatalytic performance can be ascribed that the piezoelectric effect of KTN improved the bulk separation of charge carriers in KTN. This study not only provides a potential catalyst for photocatalytic nitrogen fixation but also shows new ideas for the design of highly efficient catalysts via semiconductor modification and external field coupling.展开更多
In this work,Ag/Bi_(5)O_(7)I nanocomposite was prepared and firstly applied in piezo/photocatalytic reduction of N2 to NH3 and methyl orange(MO)degradation.Bi_(5)O_(7)I was synthesized via a hydrothermal-calcination m...In this work,Ag/Bi_(5)O_(7)I nanocomposite was prepared and firstly applied in piezo/photocatalytic reduction of N2 to NH3 and methyl orange(MO)degradation.Bi_(5)O_(7)I was synthesized via a hydrothermal-calcination method and shows nanorods morphology.Ag nanoparticles(NPs)were photo deposited on the Bi_(5)O_(7)I nanorods as electron trappers to improve the spatial separation of charge carriers,which was confirmed via XPS,TEM,and electronic chemical analyses.The catalytic test indicates that Bi_(5)O_(7)I presents the piezoelectric-like behavior,while the loading of Ag NPs can strengthen the character.Under ultrasonic vibration,the optimal Ag/Bi_(5)O_(7)I presents high efficiency in MO degradation.The degradation rate is determined to be 0.033 min1,which is 4.7 folds faster than that of Bi_(5)O_(7)I.The Ag/Bi_(5)O_(7)I also presents a high performance in piezocatalytic N2 fixation.The piezocatalytic NH3 generation rate reaches 65.4 μmol L^(-1)g^(-1)h^(-1)with water as a hole scavenger.The addition of methanol can hasten the piezoelectric catalytic reaction.Interestingly,when ultrasonic vibration and light irradiation simultaneously act on the Ag/Bi_(5)O_(7)I catalyst,higher performance in NH3 generation and MO degradation is observed.However,due to the weak adhesion of Ag NPs,some Ag NPs would fall off from the Bi_(5)O_(7)I surface under long-term ultrasonic vibration,which would greatly reduce the piezoelectric catalytic performance.This result indicates that a strong binding force is required when preparing the piezoelectric composite catalyst.The current work provides new insights for the development of highly efficient catalysts that can use multiple energies.展开更多
The continuous improvement of the cyber threat intelligence sharing mechanism provides new ideas to deal with Advanced Persistent Threats(APT).Extracting attack behaviors,i.e.,Tactics,Techniques,Procedures(TTP)from Cy...The continuous improvement of the cyber threat intelligence sharing mechanism provides new ideas to deal with Advanced Persistent Threats(APT).Extracting attack behaviors,i.e.,Tactics,Techniques,Procedures(TTP)from Cyber Threat Intelligence(CTI)can facilitate APT actors’profiling for an immediate response.However,it is difficult for traditional manual methods to analyze attack behaviors from cyber threat intelligence due to its heterogeneous nature.Based on the Adversarial Tactics,Techniques and Common Knowledge(ATT&CK)of threat behavior description,this paper proposes a threat behavioral knowledge extraction framework that integrates Heterogeneous Text Network(HTN)and Graph Convolutional Network(GCN)to solve this issue.It leverages the hierarchical correlation relationships of attack techniques and tactics in the ATT&CK to construct a text network of heterogeneous cyber threat intelligence.With the help of the Bidirectional EncoderRepresentation fromTransformers(BERT)pretraining model to analyze the contextual semantics of cyber threat intelligence,the task of threat behavior identification is transformed into a text classification task,which automatically extracts attack behavior in CTI,then identifies the malware and advanced threat actors.The experimental results show that F1 achieve 94.86%and 92.15%for the multi-label classification tasks of tactics and techniques.Extend the experiment to verify the method’s effectiveness in identifying the malware and threat actors in APT attacks.The F1 for malware and advanced threat actors identification task reached 98.45%and 99.48%,which are better than the benchmark model in the experiment and achieve state of the art.The model can effectivelymodel threat intelligence text data and acquire knowledge and experience migration by correlating implied features with a priori knowledge to compensate for insufficient sample data and improve the classification performance and recognition ability of threat behavior in text.展开更多
NGC 1266 is a lenticular galaxy(S0)hosting an active galactic nucleus(AGN),and known to contain a large amount of shocked gas.We compare the luminosity ratio of mid-J CO lines to IR continuum with star-forming galaxie...NGC 1266 is a lenticular galaxy(S0)hosting an active galactic nucleus(AGN),and known to contain a large amount of shocked gas.We compare the luminosity ratio of mid-J CO lines to IR continuum with star-forming galaxies(SFGs),and then model the CO spectral line energy distribution(SLED).We confirm that in the mid-and high-J regions(J_(up)=4-13),the C-type shock(v_(s)=25 km s^(-1),n_(H)=5×10^(4)cm^(-3))can reproduce the CO observations well.The galaxy spectral energy distribution(SED)is constructed and modeled by the code X-CIGALE and obtains a set of physical parameters including the star formation rate(SFR,1.17±0.47 M_(⊙)yr^(-1)).Also,our work provides SFR derivation of[C II]from the neutral hydrogen regions only(1.38±0.14 M_(⊙)yr^(-1)).Previous studies have illusive conclusions on the AGN or starburst nature of the NGC 1266 nucleus.Our SED model shows that the hidden AGN in the system is intrinsically low-luminosity,consequently the infrared luminosity of the AGN does not reach the expected level.Archival data from Nu STAR hard X-ray observations in the 3-79 keV band shows a marginal detection,disfavoring presence of an obscured luminous AGN and implying that a compact starburst is more likely dominant for the NGC 1266 nucleus.展开更多
Transition metal and rare earth intermetallics have been a fertile playground for research of various quantum states.We report detailed magnetic studies on Sm Mn_(2)Ge_(2),an anisotropic itinerant magnet with multiple...Transition metal and rare earth intermetallics have been a fertile playground for research of various quantum states.We report detailed magnetic studies on Sm Mn_(2)Ge_(2),an anisotropic itinerant magnet with multiple magnetic phases.The critical behavior of the ferromagnetic phase transition is investigated by employing the modified Arrott plot with the Kouvel-Fisher method.The critical temperature TCis determined to be around 342.7 K with critical exponents ofβ=0.417 andγ=1.122,and the interaction function is found to be J(r)~r^(-4.68),suggesting the coexistence of long-range and shortrange magnetic interactions.Our results contribute to the understanding of complex magnetism in Sm Mn_(2)Ge_(2),which may provide fundamental guidance in future spintronic applications.展开更多
We report polarization reversal periodically controlled by the electric field in multiferroic MnWO_(4) with a pulsed field up to 52 T.The electric polarization cannot be reversed by successive opposite electric fields...We report polarization reversal periodically controlled by the electric field in multiferroic MnWO_(4) with a pulsed field up to 52 T.The electric polarization cannot be reversed by successive opposite electric fields in low magnetic fields(<14 T)at 4.2 K,whereas polarization reversal is directly achieved by two opposite electric fields under high magnetic fields(<45 T).Interestingly,the polarization curve of rising and falling fields for H∥u(magnetic easy axis)is irreversible when the magnetic field is close to 52 T.In this case,the rising and falling polarization curves can be individually reversed by the electric field,and thus require five cycles to recover to the initial condition by the order of the applied electric fields(+E,-E,-E,+E,+E).In addition,we find that ferroelectric phaseⅣcan be tuned from parallel to antiparallel in relation to ferroelectric phase AF2 by applying a magnetic field approximated to the c axis.展开更多
An outburst of coal and gas is a major hazard in underground coal mining. It is generally accepted that an outburst occurs when certain conditions of stress, coal gassiness and physical-mechanical properties of coal a...An outburst of coal and gas is a major hazard in underground coal mining. It is generally accepted that an outburst occurs when certain conditions of stress, coal gassiness and physical-mechanical properties of coal are met. Outbursting is recognized as a two-step process, i.e., initiation and development. In this paper, we present a fully-coupled solid and fluid code to model the entire process of an outburst. The deformation, failure and fracture of solid (coal) are modeled with the discrete element method, and the flow of fluid (gas and water) such as free flow and Darcy flow are modeled with the lattice Boltzmann method. These two methods are coupled in a two-way process, i.e., the solid part provides a moving boundary condition and transfers momentum to the fluid, while the fluid exerts a dragging force upon the solid. Gas desorption from coal occurs at the solid-fluid boundary, and gas diffusion is implemented in the solid code where particles are assumed to be porous. A simple 2D example to simulate the process of an outburst with the model is also presented in this paper to demonstrate the capability of the coupled model.展开更多
Wuhan National High Magnetic Field Center(WHMFC)at Huazhong University of Science and Technology is one of the top-class research centers in the world,which can offer pulsed fields up to 90.6 T with different field wa...Wuhan National High Magnetic Field Center(WHMFC)at Huazhong University of Science and Technology is one of the top-class research centers in the world,which can offer pulsed fields up to 90.6 T with different field waveforms for scientific research and has passed the final evaluation of the Chinese government in 2014.This paper will give a brief introduction of the facility and the development status of pulsed magnetic fields research at WHMFC.In addition,it will describe the application development of pulsed magnetic fields in both scientific and industrial research.展开更多
A total of 128 Simao pine trees (Pinus kesiya var. langbianensis) from three regions of Pu'er City, Yunnan Province, People's Republic of China, were destructively sampled to obtain tree aboveground biomass (AGB...A total of 128 Simao pine trees (Pinus kesiya var. langbianensis) from three regions of Pu'er City, Yunnan Province, People's Republic of China, were destructively sampled to obtain tree aboveground biomass (AGB). Tree variables such as diameter at breast height and total height, and topographical factors such as altitude, aspect of slope, and degree of slope were recorded. We considered the region and site quality classes as the ran- dom-effects, and the topographic variables as the fixed- effects. We fitted a total of eight models as follows: least- squares nonlinear models (BM), least-squares nonlinear models with the topographic factors (BMT), nonlinear mixed-effects models with region as single random-effects (NLME-RE), nonlinear mixed-effects models with site as single random-effects (NLME-SE), nonlinear mixed-ef- fects models with the two-level nested region and site random-effects (TLNLME), NLME-RE with the fixed-ef- fects of topographic factors (NLMET-RE), NLME-SE with the fixed-effects of topographic factors (NLMET-SE), and TLNLME with the fixed-effects of topographic factors (TLNLMET). The eight models were compared by modelfitting and prediction statistics. The results showed: model fitting was improved by considering random-effects of region or site, or both. The models with the fixed-effects of topographic factors had better model fitting. According to AIC and BIC, the model fitting was ranked as TLNLME 〉 NLMET-RE 〉 NLME-RE.〉 NLMET-SE 〉 TLNLMET 〉 NLME-SE 〉 BMT 〉 BM. The differences among these models for model prediction were small. The model pre- diction was ranked as TLNLME 〉 NLME-RE 〉 NLME- SE 〉 NLMET-RE 〉 NLMET-SE 〉 TLNLMET 〉 BMT 〉 BM. However, all eight models had relatively high prediction precision (〉90 %). Thus, the best model should be chosen based on the available data when using the model to predict individual tree AGB.展开更多
The interest in ionic liquids(IL) is motivated by its unique properties, such as negligible vapor pressure, thermal stability, wide electrochemical stability window, and tunability of properties. ILs have been highlig...The interest in ionic liquids(IL) is motivated by its unique properties, such as negligible vapor pressure, thermal stability, wide electrochemical stability window, and tunability of properties. ILs have been highlighted as solvents for liquid-liquid extraction and liquid membrane separation. To further expand its application in separation field, the ionic liquid membranes(ILMs) and its separation technology have been proposed and developed rapidly. This paper is to give a comprehensive overview on the recent applications of ILMs for the separation of various compounds, including organic compounds, mixed gases, and metal ions. Firstly, ILMs was classified into supported ionic liquid membranes(SILMs) and quasi-solidified ionic liquid membranes(QSILMs) according to the immobilization method of ILs. Then, preparation methods of ILMs, membrane stability as well as applications of ILMs in the separation of various mixtures were reviewed. Followed this, transport mechanisms of gaseous mixtures and organic compounds were elucidated in order to better understand the separation process of ILMs. This tutorial review intends to not only offer an overview on the development of ILMs but also provide a guide for ILMs preparations and applications.展开更多
The development of alternative CO_2 capture solvents such as ionic liquids(ILs) and nanoparticle organic hybrid materials(NOHMs) have provided interesting options for CO_2 capture. In this study, CO_2 interactions wit...The development of alternative CO_2 capture solvents such as ionic liquids(ILs) and nanoparticle organic hybrid materials(NOHMs) have provided interesting options for CO_2 capture. In this study, CO_2 interactions with 1,3-dimethylimidazolium dimethylphosphate([MMIM]DMP),1-ethyl-3-methylimidazolium dimethylphosphate([EMIM]DMP) and 1-ethyl-3-methylimidazolium diethylphosphate([EMIM]DEP) that contain inorganic ester groups based on phosphate, were investigated using ATR FT-IR spectroscopy. CO_2-induced swelling, CO_2 diffusivity and CO_2 capture capacity were simultaneously measured to identify CO_2 capture mechanisms, kinetics and diffusion behaviors as a function of the alkyl chain length of the cation. Henry's law constants of CO_2 were found to be in the range of 4-11 MPa, which is in agreement with those reported in other studies.展开更多
The cone-jet in electrohydrodynamic atomization has been widely applied into numerous industrial fields owing to micro-sized drops with narrow distribution and high charge.The electrified jet emits from a single capil...The cone-jet in electrohydrodynamic atomization has been widely applied into numerous industrial fields owing to micro-sized drops with narrow distribution and high charge.The electrified jet emits from a single capillary sheathed with quartz tube is visualized versus operating parameters and physical properties,and breakup instabilities are also discussed.The range of operating parameters for a steady conejet broadens,as well as the minimum flow rate.Taylor cone angle decreases with an increase in flow rate,while increases as electric potential increasing.The jet breakup length decreases with an increase in flow rate and conductivity,while increases as electric potential increasing.The diffusion angle increases as flow rate increasing,while decrease as electric potential and conductivity increasing.Much clearer whipping instabilities are observed with an increase in“electro-Weber”number and conductivity.The completion in disturbance or/and suppression from axial and radial stresses,drag force dominates the variation.Meanwhile,for a large flow rate,the transition from varicose instabilities to whipping instabilities is found.The whipping instabilities are clearly observed for high conductivity due to much more free ions in liquid.For much higher conductivity,an intermittent electrified jet appears and shows an umbrella plume,and breakup length sharply shortens.展开更多
基金supported by National Key R&D Program of China(Nos.2019YFA0405501 and 2022YFF0503402)the National Natural Science Foundation of China(NSFC,Nos.12233005 and 12041302)+6 种基金support from the Natural Science Foundation of Shanghai(Project Number:22ZR1473000)the Program of Shanghai Academic Research Leader(No.22XD1404200)supports from the CAS Pioneer Hundred Talents ProgramUSTC Research Funds of the Double First-Class Initiativethe NSFC grant 12273037the NSFC grants 12033004,12333003support from the NSFC through grants 12273091 and U2031139。
文摘The star-forming clumps in star-bursting dwarf galaxies provide valuable insights into understanding the evolution of dwarf galaxies.In this paper,we focus on five star-bursting dwarf galaxies featuring off-centered clumps in the Mapping Nearby Galaxies at Apache Point Observatory survey.Using the stellar population synthesis software Fitting Analysis using Differential evolution Optimization,we obtain the spatially resolved distribution of the star formation history,which allows us to construct the g-band images of the five galaxies at different ages.These images can help us to probe the evolution of the morphological structures of these galaxies.While images of a stellar population older than 1 Gyr are typically smooth,images of a stellar population younger than 1 Gyr reveal significant clumps,including multiple clumps which appear at different locations and even different ages.To study the evolutionary connections of these five galaxies to other dwarf galaxies before their star-forming clumps appear,we construct the images of the stellar populations older than three age nodes,and define them to be the images of the"host"galaxies.We find that the properties such as the central surface brightness and the effective radii of the hosts of the five galaxies are in between those of dwarf ellipticals(dEs)and dwarf irregulars(dIrrs),with two clearly more similar to dEs and one more similar to dIrrs.Among the five galaxies,8257-3704 is particularly interesting,as it shows a previous starburst event that is not quite visible from its gri image,but only visible from images of the stellar population at a few hundred million years.The star-forming clump associated with this event may have appeared at around 600 Myr ago and disappeared at around 40 Myr ago.
基金supported by the National Institute of Health(Grant Nos.:1R15EB014546-01A1,K25AG061282).
文摘A two-photon near infrared(NIR)fluorescence turn-on sensor with high selectivity and sensitivity for Zn^(2+)detection has been developed.This sensor exhibits a large Stokes'shift(-300 nm)and can be excited from 900 to 1000 nm,with an emission wavelength of-785 nm,making it ideal for imaging in biological tissues.The sensor's high selectivity for Zn^(2+)over other structurally similar cations,such as Cd^(2+),makes it a promising tool for monitoring zinc ion levels in biological systems.Given the high concentration of zinc in thrombi,this sensor could provide a useful tool for in vivo thrombus imaging.
基金funded by the NSFC(32371669)the Science and Technology Talent Project for Distinguished Young Scholars of Jilin Province(20240602009RC)+1 种基金the NSF of Jilin Province(20240101207JC)the Scientific Research Project of the Department of Education,Jilin Province(JJKH20230687KJ).
文摘Understanding how summer warming influences the parent and daughter shoot production in a perennial clonal grass is vital for comprehending the response of grassland productivity to global warming.Here,we conducted a simulated experiment using potted Leymus chinensis,to study the relationship between the photosynthetic activ-ity of parent shoots and the production of daughter shoots under a whole(90 days)summer warming scenario(+3°C).The results showed that the biomass of parents and buds decreased by 25.52%and 33.45%,respectively,under warming conditions.The reduction in parent shoot biomass due to warming directly resulted from decreased leaf area(18.03%),chlorophyll a(18.27%),chlorophyll b(29.21%)content,as well as a reduction in net photosynthetic rate(7.32%)and the maximum quantum efficiency of photosystem II(PSII)photochemistry(4.29%).The decline in daughter shoot biomass was linked to a decrease in daughter shoot number(33.33%)by warming.However,the number of belowground buds increased by 46.43%.The results indicated that long-term summer warming reduces biomass accumulation in parent shoot by increasing both limitation of stoma and non-stoma.Consequently,the parent shoot allocates relatively more biomass to the belowground organs to maintain the survival and growth of buds.Overall,buds,as a potential aboveground population,could remedy for the cur-rent loss of parent shoot density by increasing the number of future daughter shoots if summer warming subsides.
基金supported by the National Natural Science Foundation of China(31640001 to C.X.,U21A20148 to X.Z.and C.X.)the Presidential Foundation of Hefei Institutes of Physical Science,Chinese Academy of Sciences(Y96XC11131,E26CCG27,and E26CCD15 to C.X.)。
文摘The ability to navigate long distances is essential for many animals to locate shelter,food,and breeding grounds.Magnetic sense has evolved in various migratory and homing species to orient them based on the geomagnetic field.A highly conserved ironsulfur cluster assembly protein IscA is proposed as an animal magnetoreceptor(MagR).Iron-sulfur cluster binding is also suggested to play an essential role in MagR magnetism and is thus critical in animal magnetoreception.In the current study,we provide evidence for distinct iron binding and iron-sulfur cluster binding in MagR in pigeons,an avian species that relies on the geomagnetic field for navigation and homing.Pigeon MagR showed significantly higher total iron content from both iron-and ironsulfur binding.Y65 in pigeon MagR was shown to directly mediate mononuclear iron binding,and its mutation abolished iron-binding capacity of the protein.Surprisingly,both iron binding and iron-sulfur binding demonstrated synergistic effects,and thus appear to be integral and indispensable to pigeon MagR magnetism.These results not only extend our current understanding of the origin and complexity of MagR magnetism,but also imply a possible molecular explanation for the huge diversity in animal magnetoreception.
基金financially supported by National Natural Science Foundation of China (Grant No. 22172144)Nature Science Foundation of Zhejiang Province (Grant No. LY20B030004)。
文摘In this work, a novel heterojunction composite Ag_(2)S/KTa_(x)Nb_(1-x)O_(3)was designed and synthesized through a combination of hydrothermal and precipitation procedures. The Ta/Nb ratio of the KTa_(x)Nb_(1-x)O_(3)and the Ag_(2)S content were optimized. The best 0.5% Ag_(2)S/KTa_(0.5)Nb_(0.5)O_(3)(KTN) sample presents an enhanced photocatalytic performance in ammonia synthesis than KTN and Ag_(2)S. Under simulated sunlight, the NH_(3)generation rate of 0.5% Ag_(2)S/KTN reaches 2.0 times that of pure KTN. Under visible light, the reaction rate ratio of the two catalysts is 6.0.XRD, XPS, and TEM analysis revealed that Ag2S was intimately decorated on the KTN nanocubes surface, which promoted the electron transfer between the two semiconductors. The band structure investigation indicated that the Ag_(2)S/KTN heterojunction established a type-Ⅱ band alignment with intimate contact, thus realizing the effective transfer and separation of photogenerated carriers. The change in charge separation was considered as the main reason for the enhanced photocatalytic performance. Interestingly, the Ag_(2)S/KTN composite exhibited higher NH3generation performance under the combined action of ultrasonic vibration and simulated sunlight. The enhanced piezo-photocatalytic performance can be ascribed that the piezoelectric effect of KTN improved the bulk separation of charge carriers in KTN. This study not only provides a potential catalyst for photocatalytic nitrogen fixation but also shows new ideas for the design of highly efficient catalysts via semiconductor modification and external field coupling.
基金supported by Nature Science Foundation of Zhejiang Province(Grant No.LY20B030004).
文摘In this work,Ag/Bi_(5)O_(7)I nanocomposite was prepared and firstly applied in piezo/photocatalytic reduction of N2 to NH3 and methyl orange(MO)degradation.Bi_(5)O_(7)I was synthesized via a hydrothermal-calcination method and shows nanorods morphology.Ag nanoparticles(NPs)were photo deposited on the Bi_(5)O_(7)I nanorods as electron trappers to improve the spatial separation of charge carriers,which was confirmed via XPS,TEM,and electronic chemical analyses.The catalytic test indicates that Bi_(5)O_(7)I presents the piezoelectric-like behavior,while the loading of Ag NPs can strengthen the character.Under ultrasonic vibration,the optimal Ag/Bi_(5)O_(7)I presents high efficiency in MO degradation.The degradation rate is determined to be 0.033 min1,which is 4.7 folds faster than that of Bi_(5)O_(7)I.The Ag/Bi_(5)O_(7)I also presents a high performance in piezocatalytic N2 fixation.The piezocatalytic NH3 generation rate reaches 65.4 μmol L^(-1)g^(-1)h^(-1)with water as a hole scavenger.The addition of methanol can hasten the piezoelectric catalytic reaction.Interestingly,when ultrasonic vibration and light irradiation simultaneously act on the Ag/Bi_(5)O_(7)I catalyst,higher performance in NH3 generation and MO degradation is observed.However,due to the weak adhesion of Ag NPs,some Ag NPs would fall off from the Bi_(5)O_(7)I surface under long-term ultrasonic vibration,which would greatly reduce the piezoelectric catalytic performance.This result indicates that a strong binding force is required when preparing the piezoelectric composite catalyst.The current work provides new insights for the development of highly efficient catalysts that can use multiple energies.
基金supported by China’s National Key R&D Program,No.2019QY1404the National Natural Science Foundation of China,Grant No.U20A20161,U1836103the Basic Strengthening Program Project,No.2019-JCJQ-ZD-113.
文摘The continuous improvement of the cyber threat intelligence sharing mechanism provides new ideas to deal with Advanced Persistent Threats(APT).Extracting attack behaviors,i.e.,Tactics,Techniques,Procedures(TTP)from Cyber Threat Intelligence(CTI)can facilitate APT actors’profiling for an immediate response.However,it is difficult for traditional manual methods to analyze attack behaviors from cyber threat intelligence due to its heterogeneous nature.Based on the Adversarial Tactics,Techniques and Common Knowledge(ATT&CK)of threat behavior description,this paper proposes a threat behavioral knowledge extraction framework that integrates Heterogeneous Text Network(HTN)and Graph Convolutional Network(GCN)to solve this issue.It leverages the hierarchical correlation relationships of attack techniques and tactics in the ATT&CK to construct a text network of heterogeneous cyber threat intelligence.With the help of the Bidirectional EncoderRepresentation fromTransformers(BERT)pretraining model to analyze the contextual semantics of cyber threat intelligence,the task of threat behavior identification is transformed into a text classification task,which automatically extracts attack behavior in CTI,then identifies the malware and advanced threat actors.The experimental results show that F1 achieve 94.86%and 92.15%for the multi-label classification tasks of tactics and techniques.Extend the experiment to verify the method’s effectiveness in identifying the malware and threat actors in APT attacks.The F1 for malware and advanced threat actors identification task reached 98.45%and 99.48%,which are better than the benchmark model in the experiment and achieve state of the art.The model can effectivelymodel threat intelligence text data and acquire knowledge and experience migration by correlating implied features with a priori knowledge to compensate for insufficient sample data and improve the classification performance and recognition ability of threat behavior in text.
基金supported by the National Natural Science Foundation of China(NSFC Grant Nos.12033004,U1831205,12173079 and 12221003)the science research grants from the China Manned Space Project with Nos.CMS-CSST-2021A06 and CMS-CSST-2021-B02。
文摘NGC 1266 is a lenticular galaxy(S0)hosting an active galactic nucleus(AGN),and known to contain a large amount of shocked gas.We compare the luminosity ratio of mid-J CO lines to IR continuum with star-forming galaxies(SFGs),and then model the CO spectral line energy distribution(SLED).We confirm that in the mid-and high-J regions(J_(up)=4-13),the C-type shock(v_(s)=25 km s^(-1),n_(H)=5×10^(4)cm^(-3))can reproduce the CO observations well.The galaxy spectral energy distribution(SED)is constructed and modeled by the code X-CIGALE and obtains a set of physical parameters including the star formation rate(SFR,1.17±0.47 M_(⊙)yr^(-1)).Also,our work provides SFR derivation of[C II]from the neutral hydrogen regions only(1.38±0.14 M_(⊙)yr^(-1)).Previous studies have illusive conclusions on the AGN or starburst nature of the NGC 1266 nucleus.Our SED model shows that the hidden AGN in the system is intrinsically low-luminosity,consequently the infrared luminosity of the AGN does not reach the expected level.Archival data from Nu STAR hard X-ray observations in the 3-79 keV band shows a marginal detection,disfavoring presence of an obscured luminous AGN and implying that a compact starburst is more likely dominant for the NGC 1266 nucleus.
基金supported by the National Key Research and Development Program of China(Grant No.2021YFA1600204)the Innovation Program for Quantum Science and Technology(Grant No.2021ZD0302802)+2 种基金the National Natural Science Foundation of China(Grant Nos.U1832214,U2032213,12104461,and 12074135)the High Magnetic Field Laboratory of Anhuisupported by the Start-up Project of Anhui University(Grant No.S020318001/020)。
文摘Transition metal and rare earth intermetallics have been a fertile playground for research of various quantum states.We report detailed magnetic studies on Sm Mn_(2)Ge_(2),an anisotropic itinerant magnet with multiple magnetic phases.The critical behavior of the ferromagnetic phase transition is investigated by employing the modified Arrott plot with the Kouvel-Fisher method.The critical temperature TCis determined to be around 342.7 K with critical exponents ofβ=0.417 andγ=1.122,and the interaction function is found to be J(r)~r^(-4.68),suggesting the coexistence of long-range and shortrange magnetic interactions.Our results contribute to the understanding of complex magnetism in Sm Mn_(2)Ge_(2),which may provide fundamental guidance in future spintronic applications.
基金Project supported by the National Natural Science Foundation of China (Grant Nos.12074135,12104388,and 52272219)Nanyang Normal University,the Natural Science Foundation of Henan Province (Grant Nos.222300420255 and 232300421220)the Key Scientific and Technological Projiect of Technology Depeartment of Henan Province of China (Grant Nos.222102230105 and 212102210448)。
文摘We report polarization reversal periodically controlled by the electric field in multiferroic MnWO_(4) with a pulsed field up to 52 T.The electric polarization cannot be reversed by successive opposite electric fields in low magnetic fields(<14 T)at 4.2 K,whereas polarization reversal is directly achieved by two opposite electric fields under high magnetic fields(<45 T).Interestingly,the polarization curve of rising and falling fields for H∥u(magnetic easy axis)is irreversible when the magnetic field is close to 52 T.In this case,the rising and falling polarization curves can be individually reversed by the electric field,and thus require five cycles to recover to the initial condition by the order of the applied electric fields(+E,-E,-E,+E,+E).In addition,we find that ferroelectric phaseⅣcan be tuned from parallel to antiparallel in relation to ferroelectric phase AF2 by applying a magnetic field approximated to the c axis.
文摘An outburst of coal and gas is a major hazard in underground coal mining. It is generally accepted that an outburst occurs when certain conditions of stress, coal gassiness and physical-mechanical properties of coal are met. Outbursting is recognized as a two-step process, i.e., initiation and development. In this paper, we present a fully-coupled solid and fluid code to model the entire process of an outburst. The deformation, failure and fracture of solid (coal) are modeled with the discrete element method, and the flow of fluid (gas and water) such as free flow and Darcy flow are modeled with the lattice Boltzmann method. These two methods are coupled in a two-way process, i.e., the solid part provides a moving boundary condition and transfers momentum to the fluid, while the fluid exerts a dragging force upon the solid. Gas desorption from coal occurs at the solid-fluid boundary, and gas diffusion is implemented in the solid code where particles are assumed to be porous. A simple 2D example to simulate the process of an outburst with the model is also presented in this paper to demonstrate the capability of the coupled model.
基金We gratefully acknowledge the financial support of the National Key Research and Development Program of China(2016YFA0401700).
文摘Wuhan National High Magnetic Field Center(WHMFC)at Huazhong University of Science and Technology is one of the top-class research centers in the world,which can offer pulsed fields up to 90.6 T with different field waveforms for scientific research and has passed the final evaluation of the Chinese government in 2014.This paper will give a brief introduction of the facility and the development status of pulsed magnetic fields research at WHMFC.In addition,it will describe the application development of pulsed magnetic fields in both scientific and industrial research.
基金supported by National Natural Science Foundation of China(Grant No.3116015731560209)Application Fundamental Research Plan Project of Yunnan Province,China(Grant No.2012FD027)
文摘A total of 128 Simao pine trees (Pinus kesiya var. langbianensis) from three regions of Pu'er City, Yunnan Province, People's Republic of China, were destructively sampled to obtain tree aboveground biomass (AGB). Tree variables such as diameter at breast height and total height, and topographical factors such as altitude, aspect of slope, and degree of slope were recorded. We considered the region and site quality classes as the ran- dom-effects, and the topographic variables as the fixed- effects. We fitted a total of eight models as follows: least- squares nonlinear models (BM), least-squares nonlinear models with the topographic factors (BMT), nonlinear mixed-effects models with region as single random-effects (NLME-RE), nonlinear mixed-effects models with site as single random-effects (NLME-SE), nonlinear mixed-ef- fects models with the two-level nested region and site random-effects (TLNLME), NLME-RE with the fixed-ef- fects of topographic factors (NLMET-RE), NLME-SE with the fixed-effects of topographic factors (NLMET-SE), and TLNLME with the fixed-effects of topographic factors (TLNLMET). The eight models were compared by modelfitting and prediction statistics. The results showed: model fitting was improved by considering random-effects of region or site, or both. The models with the fixed-effects of topographic factors had better model fitting. According to AIC and BIC, the model fitting was ranked as TLNLME 〉 NLMET-RE 〉 NLME-RE.〉 NLMET-SE 〉 TLNLMET 〉 NLME-SE 〉 BMT 〉 BM. The differences among these models for model prediction were small. The model pre- diction was ranked as TLNLME 〉 NLME-RE 〉 NLME- SE 〉 NLMET-RE 〉 NLMET-SE 〉 TLNLMET 〉 BMT 〉 BM. However, all eight models had relatively high prediction precision (〉90 %). Thus, the best model should be chosen based on the available data when using the model to predict individual tree AGB.
基金supported by the National Natural Science Foundation of China(21406235 and U1407111)the National High Technology Research and Development Program of China(863 Program,2014AA021006)
文摘The interest in ionic liquids(IL) is motivated by its unique properties, such as negligible vapor pressure, thermal stability, wide electrochemical stability window, and tunability of properties. ILs have been highlighted as solvents for liquid-liquid extraction and liquid membrane separation. To further expand its application in separation field, the ionic liquid membranes(ILMs) and its separation technology have been proposed and developed rapidly. This paper is to give a comprehensive overview on the recent applications of ILMs for the separation of various compounds, including organic compounds, mixed gases, and metal ions. Firstly, ILMs was classified into supported ionic liquid membranes(SILMs) and quasi-solidified ionic liquid membranes(QSILMs) according to the immobilization method of ILs. Then, preparation methods of ILMs, membrane stability as well as applications of ILMs in the separation of various mixtures were reviewed. Followed this, transport mechanisms of gaseous mixtures and organic compounds were elucidated in order to better understand the separation process of ILMs. This tutorial review intends to not only offer an overview on the development of ILMs but also provide a guide for ILMs preparations and applications.
基金supported by the National Natural Science Foundation of China (21206165 and U1407111)
文摘The development of alternative CO_2 capture solvents such as ionic liquids(ILs) and nanoparticle organic hybrid materials(NOHMs) have provided interesting options for CO_2 capture. In this study, CO_2 interactions with 1,3-dimethylimidazolium dimethylphosphate([MMIM]DMP),1-ethyl-3-methylimidazolium dimethylphosphate([EMIM]DMP) and 1-ethyl-3-methylimidazolium diethylphosphate([EMIM]DEP) that contain inorganic ester groups based on phosphate, were investigated using ATR FT-IR spectroscopy. CO_2-induced swelling, CO_2 diffusivity and CO_2 capture capacity were simultaneously measured to identify CO_2 capture mechanisms, kinetics and diffusion behaviors as a function of the alkyl chain length of the cation. Henry's law constants of CO_2 were found to be in the range of 4-11 MPa, which is in agreement with those reported in other studies.
基金National Natural Science Foundation of China(52076105)Natural Science Foundation of Jiangsu Province(BK20171301)。
文摘The cone-jet in electrohydrodynamic atomization has been widely applied into numerous industrial fields owing to micro-sized drops with narrow distribution and high charge.The electrified jet emits from a single capillary sheathed with quartz tube is visualized versus operating parameters and physical properties,and breakup instabilities are also discussed.The range of operating parameters for a steady conejet broadens,as well as the minimum flow rate.Taylor cone angle decreases with an increase in flow rate,while increases as electric potential increasing.The jet breakup length decreases with an increase in flow rate and conductivity,while increases as electric potential increasing.The diffusion angle increases as flow rate increasing,while decrease as electric potential and conductivity increasing.Much clearer whipping instabilities are observed with an increase in“electro-Weber”number and conductivity.The completion in disturbance or/and suppression from axial and radial stresses,drag force dominates the variation.Meanwhile,for a large flow rate,the transition from varicose instabilities to whipping instabilities is found.The whipping instabilities are clearly observed for high conductivity due to much more free ions in liquid.For much higher conductivity,an intermittent electrified jet appears and shows an umbrella plume,and breakup length sharply shortens.