Under the background of Sino-US trade friction,soybean,as an important variety in the important and export trade of agricultural products,has become a key bargaining chip. After the Ministry of Commerce of China annou...Under the background of Sino-US trade friction,soybean,as an important variety in the important and export trade of agricultural products,has become a key bargaining chip. After the Ministry of Commerce of China announced the counter list of agricultural products including soybean,the price fluctuations of domestic soybean and related agricultural products are rapidly expanding. Under the background of SinoUS trade friction,taking the soybean-producing areas in Heilongjiang as an example,the impact of Sino-US trade friction on the important and export pattern of soybean in Heilongjiang was explored to provide a certain theoretical basis for the development of soybean industry in Heilongjiang.展开更多
The four-dimensional(4D) printing technology, as a combination of additive manufacturing and smart materials, has attracted increasing research interest in recent years. The bilayer structures printed with smart mater...The four-dimensional(4D) printing technology, as a combination of additive manufacturing and smart materials, has attracted increasing research interest in recent years. The bilayer structures printed with smart materials using this technology can realize complicated deformation under some special stimuli due to the material properties.The deformation prediction of bilayer structures can make the design process more rapid and thus is of great importance. However, the previous works on deformation prediction of bilayer structures rarely study the complicated deformations or the influence of the printing process on deformation. Thus, this paper proposes a new method to predict the complicated deformations of temperature-sensitive 4D printed bilayer structures,in particular to the bilayer structures based on temperature-driven shape-memory polymers(SMPs) and fabricated using the fused deposition modeling(FDM) technology. The programming process to the material during printing is revealed and considered in the simulation model. Simulation results are compared with experiments to verify the validity of the method. The advantages of this method are stable convergence and high efficiency,as the three-dimensional(3D) problem is converted to a two-dimensional(2D) problem.The simulation parameters in the model can be further associated with the printing parameters, which shows good application prospect in 4D printed bilayer structure design.展开更多
The tribological properties of self-lubricating composites are influenced by many variables and complex mechanisms.Data-driven methods,including machine learning(ML)algorithms,can yield a better comprehensive understa...The tribological properties of self-lubricating composites are influenced by many variables and complex mechanisms.Data-driven methods,including machine learning(ML)algorithms,can yield a better comprehensive understanding of complex problems under the influence of multiple parameters,typically for how tribological performances and material properties correlate.Correlation of friction coefficients and wear rates of copper/aluminum-graphite(Cu/Al-graphite)self-lubricating composites with their inherent material properties(composition,lubricant content,particle size,processing process,and interfacial bonding strength)and the variables related to the testing method(normal load,sliding speed,and sliding distance)were analyzed using traditional approaches,followed by modeling and prediction of tribological properties through five different ML algorithms,namely support vector machine(SVM),K-Nearest neighbor(KNN),random forest(RF),eXtreme gradient boosting(XGBoost),and least-squares boosting(LSBoost),based on the tribology experimental data.Results demonstrated that ML models could satisfactorily predict friction coefficient and wear rate from the material properties and testing method variables data.Herein,the LSBoost model based on the integrated learning algorithm presented the best prediction performance for friction coefficients and wear rates,with R^(2) of 0.9219 and 0.9243,respectively.Feature importance analysis also revealed that the content of graphite and the hardness of the matrix have the greatest influence on the friction coefficients,and the normal load,the content of graphite,and the hardness of the matrix influence the wear rates the most.展开更多
Cubic boron nitride(cBN)with high hardness,thermal conductivity,wear resistance,and chemical inertness has become the most promising abrasive and machining material.Due to the difficulty of fabricating pure cBN body,g...Cubic boron nitride(cBN)with high hardness,thermal conductivity,wear resistance,and chemical inertness has become the most promising abrasive and machining material.Due to the difficulty of fabricating pure cBN body,generally,some binders are incorporated among cBN particles to prepare polycrystalline cubic boron nitride(PcBN).Hence,the binders play a critical factor to the performances of PcBN composites.In this study,the PcBN composites with three binder systems containing ceramic and metal phases were fabricated by spark plasma sintering(SPS)from 1400 to 1700℃.The sintering behaviors and mechanical properties of the composites were investigated.Results show that the effect of binder formulas on mechanical properties mainly related to the compactness,mechanical performances,and thermal expansion coefficient of binder phases,which affect the carrying capacity of the composites and the bonding strength between binder phases and cBN particles.The PcBN composite with SiAlON phase as binder presented optimal flexural strength(465±29 MPa)and fracture toughness(5.62±0.37 MPa·m^(1/2)),attributing to the synergistic effect similar to transgranular and intergranular fractures.Meanwhile,the excellent mechanical properties can be maintained a comparable level when the temperature even rises to 800℃.Due to the weak bonding strength and high porosity,the PcBN composites with Al_(2)O_(3)–ZrO_(2)(3Y)and Al–Ti binder systems exhibited inferior mechanical properties.The possible mechanisms to explain these results were also analyzed.展开更多
The high strength and toughness of natural materials are mainly determined by a combination of mechanisms operating at different length scales,which can be used as a strategy to reduce the intrinsic brittleness of cer...The high strength and toughness of natural materials are mainly determined by a combination of mechanisms operating at different length scales,which can be used as a strategy to reduce the intrinsic brittleness of ceramics.Inspired by the architectures of bamboo,the polycrystalline cubic boron nitride/hexagonal boron nitride(PcBN/hBN)fibrous monolithic ceramics with a long fiber arrangement structure was constructed with PcBN fiber cells and hBN cell boundaries,and its crack resistance responses and tribological performances were investigated.The composite ceramic failed in a non-brittle manner with the rising resistance curve(R-curve)behavior,which was attributed to multiscale crack effects in the hierarchical architecture.The maximum crack growth toughness was extremely high(approximately 21 MPa×m^(1/2)),corresponding to a 270%increase over the crack initiation toughness.Excellent fracture resistance could be retained even above 1000℃.Moreover,the composite ceramic exhibited low and stable friction coefficients(approximately 0.33)when paired with a Si_(3)N_(4)pin at high temperature(1000℃),owing to the lubrication function of hBN cell boundaries with weak van der Waals forces and a small amount of liquid B_(2)O_(3)produced.As a result,a synergistic improvement of mechanical and tribological properties at high temperature(1000℃)was realized by combining bionic structure and tribological design.It provides important theoretical and technical support for expanding the application of self-lubricating composite ceramics in harsh environments.展开更多
Synthetic zircon(ZrSiO_(4))ceramics are typically fabricated at elevated temperatures(over 1500℃),which would lead to high manufacturing cost.Meanwhile,reports about preparing ZrSiO_(4)-based ceramic composites via c...Synthetic zircon(ZrSiO_(4))ceramics are typically fabricated at elevated temperatures(over 1500℃),which would lead to high manufacturing cost.Meanwhile,reports about preparing ZrSiO_(4)-based ceramic composites via controlling the solid-state reaction between zirconia(ZrO_(2))and silica(SiO_(2))are limited.In this work,we proposed a low-temperature strategy to flexibly design and fabricate ZrSiO_(4)-based ceramic composites via doping and tuning the solid-state reaction.Two ceramic composites and ZrSiO_(4) ceramics were in-situ prepared by reactive fast hot pressing(FHP)at approximately 1250℃ based on the proposed strategy,i.e.,a ZrSiO_(4)-SiO_(2) dual-phase composite with bicontinuous interpenetrating and hierarchical microstructures,a ZrSiO_(4)-ZrO_(2) dual-phase composite with a microstructure of ZrO_(2) submicron-and nano-particles embedded in a micron ZrSiO_(4) matrix,and ZrSiO_(4) ceramics with a small amount of residual ZrO_(2) nanoparticles.The results showed that the phase compositions,microstructure configurations,mechanical properties,and wear resistance of the materials can be flexibly regulated by the proposed strategy.Hence,ZrSiO_(4)-based ceramic composites with different properties can be easily fabricated based on different application scenarios.These findings would offer useful guidance for researchers to flexibly fabricate ZrSiO_(4)-based ceramic composites at low temperatures and tailor their microstructures and properties through doping and tuning the solid-state reaction.展开更多
High-entropy carbides are a nascent group of ceramics that are promising for high-temperature applications due to the combination of good stability,high hardness(H),high strength,and superior creep resistance that the...High-entropy carbides are a nascent group of ceramics that are promising for high-temperature applications due to the combination of good stability,high hardness(H),high strength,and superior creep resistance that they display.Due to high melting points and low lattice diffusion coefficients,however,the high-entropy carbides are usually difficult to consolidate to a nearly full density.To cope with this challenge,herein,binary carbides including TiC,V_(8)C_(7),NbC,Mo_(2)C,and WC with different carbon stoichiometry were used to prepare dense high-entropy(TiVNbMoW)C_(4.375),and the influence of carbon vacancy on formation ability and mechanical properties of carbon-deficient high-entropy(TiVNbMoW)C_(4.375) were investigated.Intriguingly,although the starting binary carbides have different crystal structures and carbon stoichiometry,the as-prepared high-entropy material showed a rock-salt structure with a relatively high density(98.1%)and good mechanical properties with hardness of 19.4±0.4 GPa and fracture toughness(KIC)of 4.02 MPa·m^(1/2).More importantly,the high-entropy(TiVNbMoW)C_(4.375) exhibited low coefficient of friction(COF)at room temperature(RT)and 800℃.Wear rate(W)gradually increased with the temperature rising,which were attributed to the formation of low-hardness oxidation films at high temperatures to aggravate wear.At 800℃,lubricating films formed from sufficient oxidation products of V_(2)O_(5) and MoO_(3) effectively improved tribological behavior of the high-entropy(TiVNbMoW)C_(4.375).Wear mechanisms were mainly abrasive wear resulting from grain pullout and brittle fracture as well as oxidation wear generated from high-temperature reactions.These results are useful as valuable guidance and reference to the synthesis of high-entropy ceramics(HECs)for sliding parts under high-temperature serving conditions.展开更多
基金Supported by Tianjin Third National Agricultural Census Project (TJ2016NP023)
文摘Under the background of Sino-US trade friction,soybean,as an important variety in the important and export trade of agricultural products,has become a key bargaining chip. After the Ministry of Commerce of China announced the counter list of agricultural products including soybean,the price fluctuations of domestic soybean and related agricultural products are rapidly expanding. Under the background of SinoUS trade friction,taking the soybean-producing areas in Heilongjiang as an example,the impact of Sino-US trade friction on the important and export pattern of soybean in Heilongjiang was explored to provide a certain theoretical basis for the development of soybean industry in Heilongjiang.
基金the National Natural Science Foundation of China(Nos.52130501 and 52075479)the National Key R&D Program of China(No.2018YFB1700804)。
文摘The four-dimensional(4D) printing technology, as a combination of additive manufacturing and smart materials, has attracted increasing research interest in recent years. The bilayer structures printed with smart materials using this technology can realize complicated deformation under some special stimuli due to the material properties.The deformation prediction of bilayer structures can make the design process more rapid and thus is of great importance. However, the previous works on deformation prediction of bilayer structures rarely study the complicated deformations or the influence of the printing process on deformation. Thus, this paper proposes a new method to predict the complicated deformations of temperature-sensitive 4D printed bilayer structures,in particular to the bilayer structures based on temperature-driven shape-memory polymers(SMPs) and fabricated using the fused deposition modeling(FDM) technology. The programming process to the material during printing is revealed and considered in the simulation model. Simulation results are compared with experiments to verify the validity of the method. The advantages of this method are stable convergence and high efficiency,as the three-dimensional(3D) problem is converted to a two-dimensional(2D) problem.The simulation parameters in the model can be further associated with the printing parameters, which shows good application prospect in 4D printed bilayer structure design.
基金the National Key R&D Program of China(Grant No.2022YFB3809000)the Intellectual Property Program of Gansu(Grant No.22ZSCQ043).
文摘The tribological properties of self-lubricating composites are influenced by many variables and complex mechanisms.Data-driven methods,including machine learning(ML)algorithms,can yield a better comprehensive understanding of complex problems under the influence of multiple parameters,typically for how tribological performances and material properties correlate.Correlation of friction coefficients and wear rates of copper/aluminum-graphite(Cu/Al-graphite)self-lubricating composites with their inherent material properties(composition,lubricant content,particle size,processing process,and interfacial bonding strength)and the variables related to the testing method(normal load,sliding speed,and sliding distance)were analyzed using traditional approaches,followed by modeling and prediction of tribological properties through five different ML algorithms,namely support vector machine(SVM),K-Nearest neighbor(KNN),random forest(RF),eXtreme gradient boosting(XGBoost),and least-squares boosting(LSBoost),based on the tribology experimental data.Results demonstrated that ML models could satisfactorily predict friction coefficient and wear rate from the material properties and testing method variables data.Herein,the LSBoost model based on the integrated learning algorithm presented the best prediction performance for friction coefficients and wear rates,with R^(2) of 0.9219 and 0.9243,respectively.Feature importance analysis also revealed that the content of graphite and the hardness of the matrix have the greatest influence on the friction coefficients,and the normal load,the content of graphite,and the hardness of the matrix influence the wear rates the most.
基金This work was supported by the National Natural Science Foundation of China(No.51775534)the West Light Foundation of the Chinese Academy of Sciences(2019)the LICP Cooperation Foundation for Young Scholars(No.HZJJ21-07).
文摘Cubic boron nitride(cBN)with high hardness,thermal conductivity,wear resistance,and chemical inertness has become the most promising abrasive and machining material.Due to the difficulty of fabricating pure cBN body,generally,some binders are incorporated among cBN particles to prepare polycrystalline cubic boron nitride(PcBN).Hence,the binders play a critical factor to the performances of PcBN composites.In this study,the PcBN composites with three binder systems containing ceramic and metal phases were fabricated by spark plasma sintering(SPS)from 1400 to 1700℃.The sintering behaviors and mechanical properties of the composites were investigated.Results show that the effect of binder formulas on mechanical properties mainly related to the compactness,mechanical performances,and thermal expansion coefficient of binder phases,which affect the carrying capacity of the composites and the bonding strength between binder phases and cBN particles.The PcBN composite with SiAlON phase as binder presented optimal flexural strength(465±29 MPa)and fracture toughness(5.62±0.37 MPa·m^(1/2)),attributing to the synergistic effect similar to transgranular and intergranular fractures.Meanwhile,the excellent mechanical properties can be maintained a comparable level when the temperature even rises to 800℃.Due to the weak bonding strength and high porosity,the PcBN composites with Al_(2)O_(3)–ZrO_(2)(3Y)and Al–Ti binder systems exhibited inferior mechanical properties.The possible mechanisms to explain these results were also analyzed.
基金This work was supported by the National Natural Science Foundation of China(Grant No.52005486)the Science and Technology Planning Project of Chengguan District of Lanzhou City(Grant No.2021JSCX0030)the Major National R&D Projects(Grant No.J2019-IV-0020-0088)。
文摘The high strength and toughness of natural materials are mainly determined by a combination of mechanisms operating at different length scales,which can be used as a strategy to reduce the intrinsic brittleness of ceramics.Inspired by the architectures of bamboo,the polycrystalline cubic boron nitride/hexagonal boron nitride(PcBN/hBN)fibrous monolithic ceramics with a long fiber arrangement structure was constructed with PcBN fiber cells and hBN cell boundaries,and its crack resistance responses and tribological performances were investigated.The composite ceramic failed in a non-brittle manner with the rising resistance curve(R-curve)behavior,which was attributed to multiscale crack effects in the hierarchical architecture.The maximum crack growth toughness was extremely high(approximately 21 MPa×m^(1/2)),corresponding to a 270%increase over the crack initiation toughness.Excellent fracture resistance could be retained even above 1000℃.Moreover,the composite ceramic exhibited low and stable friction coefficients(approximately 0.33)when paired with a Si_(3)N_(4)pin at high temperature(1000℃),owing to the lubrication function of hBN cell boundaries with weak van der Waals forces and a small amount of liquid B_(2)O_(3)produced.As a result,a synergistic improvement of mechanical and tribological properties at high temperature(1000℃)was realized by combining bionic structure and tribological design.It provides important theoretical and technical support for expanding the application of self-lubricating composite ceramics in harsh environments.
基金the financial support of the National Natural Science Foundation of China(52102084)Natural Science Foundation of Hunan Province(2022JJ30718)+1 种基金the financial support of the Youth Innovation Promotion Association Chinese Academy of Sciences(CAS)(2022428)the Science Fund of Shandong Laboratory of Yantai Advanced Materials and Green Manufacturing(AMGM2021A08).
文摘Synthetic zircon(ZrSiO_(4))ceramics are typically fabricated at elevated temperatures(over 1500℃),which would lead to high manufacturing cost.Meanwhile,reports about preparing ZrSiO_(4)-based ceramic composites via controlling the solid-state reaction between zirconia(ZrO_(2))and silica(SiO_(2))are limited.In this work,we proposed a low-temperature strategy to flexibly design and fabricate ZrSiO_(4)-based ceramic composites via doping and tuning the solid-state reaction.Two ceramic composites and ZrSiO_(4) ceramics were in-situ prepared by reactive fast hot pressing(FHP)at approximately 1250℃ based on the proposed strategy,i.e.,a ZrSiO_(4)-SiO_(2) dual-phase composite with bicontinuous interpenetrating and hierarchical microstructures,a ZrSiO_(4)-ZrO_(2) dual-phase composite with a microstructure of ZrO_(2) submicron-and nano-particles embedded in a micron ZrSiO_(4) matrix,and ZrSiO_(4) ceramics with a small amount of residual ZrO_(2) nanoparticles.The results showed that the phase compositions,microstructure configurations,mechanical properties,and wear resistance of the materials can be flexibly regulated by the proposed strategy.Hence,ZrSiO_(4)-based ceramic composites with different properties can be easily fabricated based on different application scenarios.These findings would offer useful guidance for researchers to flexibly fabricate ZrSiO_(4)-based ceramic composites at low temperatures and tailor their microstructures and properties through doping and tuning the solid-state reaction.
基金supported by the National Natural Science Foundation of China (51902317)the Key Research Program of the Chinese Academy of Sciences (XDPB24)+1 种基金the State Key Laboratory of New Ceramic and Fine Processing Tsinghua University (KF201911)the Key Research and Development Project of Gansu Province (20YF8GA001).
文摘High-entropy carbides are a nascent group of ceramics that are promising for high-temperature applications due to the combination of good stability,high hardness(H),high strength,and superior creep resistance that they display.Due to high melting points and low lattice diffusion coefficients,however,the high-entropy carbides are usually difficult to consolidate to a nearly full density.To cope with this challenge,herein,binary carbides including TiC,V_(8)C_(7),NbC,Mo_(2)C,and WC with different carbon stoichiometry were used to prepare dense high-entropy(TiVNbMoW)C_(4.375),and the influence of carbon vacancy on formation ability and mechanical properties of carbon-deficient high-entropy(TiVNbMoW)C_(4.375) were investigated.Intriguingly,although the starting binary carbides have different crystal structures and carbon stoichiometry,the as-prepared high-entropy material showed a rock-salt structure with a relatively high density(98.1%)and good mechanical properties with hardness of 19.4±0.4 GPa and fracture toughness(KIC)of 4.02 MPa·m^(1/2).More importantly,the high-entropy(TiVNbMoW)C_(4.375) exhibited low coefficient of friction(COF)at room temperature(RT)and 800℃.Wear rate(W)gradually increased with the temperature rising,which were attributed to the formation of low-hardness oxidation films at high temperatures to aggravate wear.At 800℃,lubricating films formed from sufficient oxidation products of V_(2)O_(5) and MoO_(3) effectively improved tribological behavior of the high-entropy(TiVNbMoW)C_(4.375).Wear mechanisms were mainly abrasive wear resulting from grain pullout and brittle fracture as well as oxidation wear generated from high-temperature reactions.These results are useful as valuable guidance and reference to the synthesis of high-entropy ceramics(HECs)for sliding parts under high-temperature serving conditions.