Rapidly monitoring regional water quality and the changing trend is of great practical and scientific significance,especially for the Beijing-Tianjin-Hebei(BTH)region of China where water resources are relatively scar...Rapidly monitoring regional water quality and the changing trend is of great practical and scientific significance,especially for the Beijing-Tianjin-Hebei(BTH)region of China where water resources are relatively scarce and inland water bodies are generally small.The remote sensing data of the GF 1 satellite launched in 2013 have characteristics of high spatial and temporal resolution,which can be used for the dynamic monitoring of the water environment in small lakes and reservoirs.However,the water quality remote sensing monitoring model based on the GF 1 satellite data for lakes and reservoirs in BTH is still lacking because of the considerable differences in the optical characteristics of the lakes and reservoirs.In this paper,the typical reservoirs in BTH-Guanting Reservoir,Yuqiao Reservoir,Panjiakou Reservoir,and Daheiting Reservoir are taken as the study areas.In the atmospheric correction of GF 1-WFV,the relative radiation normalized atmospheric correction was adopted after comparing it with other methods,such as 6 S and FLAASH.In the water clarity retrieval,a water color hue angle based model was proposed and outperformed other available published models,with the R 2 of 0.74 and MRE of 31.7%.The clarity products of the four typical reservoirs in the BTH region in 2013-2019 were produced using the GF 1-WFV data.Based on the products,temporal and spatial changes in clarity were analyzed,and the main influencing factors for each water body were discussed.It was found that the clarity of Guanting,Daheiting,and Panjiakou reservoirs showed an upward trend during this period,while that of Yuqiao Reservoir showed a downward trend.In the influencing factors,the water level of the water bodies can be an important factor related to the water clarity changes in this region.展开更多
The Moderate Resolution Imaging Spectroradiometer(MODIS)surface reflectance data were used to analyze the temporal and spatial distribution characteristics of water clarity(Z_(sd))in the Jiaozhou Bay,Qingdao,China,in ...The Moderate Resolution Imaging Spectroradiometer(MODIS)surface reflectance data were used to analyze the temporal and spatial distribution characteristics of water clarity(Z_(sd))in the Jiaozhou Bay,Qingdao,China,in the Yellow Sea from 2000 to 2018.Z_(sd)retrieval models were regionally optimized using in-situ data with coincident MODIS images,and then were used to retrieve the Z_(sd) products in Jiaozhou Bay from 2000-2018.The analysis of the Z_(sd) results suggests that the spatial distribution of relative Z_(sd) spatial characteristics in Jiaozhou Bay was stable,being higher Z_(sd) in the southeast and a lower Z_(sd) in the northwest.The annual mean Z_(sd) in Jiaozhou Bay showed a significant upward trend,with an annual increase of approximately 0.02 m.Water depth and wind speed were important factors affecting the spatial distribution and annual variation of Z_(sd) in Jiaozhou Bay,respectively.展开更多
Objective: Accurate staging of patients with pancreatic cancer is crucial to clarify whether meaningful resection is indeed possible. Staging laparoscopy has been suggested as a tool for staging which may spare up to ...Objective: Accurate staging of patients with pancreatic cancer is crucial to clarify whether meaningful resection is indeed possible. Staging laparoscopy has been suggested as a tool for staging which may spare up to two-fifth of these patients from undergoing nontherapeutic laparotomy. A controversy exists, however, as to whether the procedure should be used routinely or selectively in these patients with no evidence of metastasis on noninvasive staging. This review aims to evaluate the available literature critically, identify its limitations and address the existing controversies. Methods: The current available English literature was reviewed on this topic. Results: A direct and conclusive comparison of the controversial literature is difficult because of inconsistent use of high-quality CT scans, different study designs and dissimilarity of judgment for non-resectability among patients staged by laparoscopy. However, recent studies reveal that not more than 14% of the patients benefit from diagnostic laparoscopy when a dual-contrast thin cut and 3-D digital reformatting CT scan has been performed previously. Conclusion: We conclude that routine use of diagnostic laparoscopy does not appear warranted in all patients with pancreatic cancer, especially for patients with early-staged pancreatic cancer or non-pancreatic periampullary cancers, because diagnostic laparoscopy is costly and ultrasonography is largely operator-dependent. Rather, selective use is appropriate, especially in patients with a large primary tumor, a tumor in the body or tail of the pancreas, equivocal findings of metastasis on CT, the presence of ascites, severe weight loss, hypoalbuminemia, and a markedly elevated CA 19–9.展开更多
Cyanobacterial harmful algal blooms(CyanoHABs)in inland waters are now among the most pressing environmental issues worldwide,especially in China.Satellite remote sensing has limitations in monitoring CyanoHABs in sma...Cyanobacterial harmful algal blooms(CyanoHABs)in inland waters are now among the most pressing environmental issues worldwide,especially in China.Satellite remote sensing has limitations in monitoring CyanoHABs in small water bodies due to spatial and temporal resolution limitations.While literature and news media have the potential to supplement satellite remote sensing in monitoring CyanoHABs,they have currently not received sufficient attention.In this study,we combined information on the distributions of CyanoHABs from literature and media for the first time to comprehensively assess the spatiotemporal variation in CyanoHABs in China.We collected,cleaned,validated,and organized data from literature and media on CyanoHABs in China,resulting in the establishment of a comprehensive database on CyanoHABs in China's inland waters(ChinaCyanoDB)covering 198 water bodies,525 records for 1950-2021.The majority of water bodies with CyanoHABs(CyanoWaters)are located in the eastern China,mainly concentrated in the middle and lower Yangtze region,with a clear upward trend in their number over the last four decades.The ChinaCyanoDB and analytical results can provide valuable data support for monitoring and managing CyanoHABs in China while the database construction method may also be applied to other countries and regions.展开更多
The effects of tourmaline on nitrogen removal performance and biofilm structures were comparatively investigated in two identical laboratory-scale sequencing batch biofilm reactors(SBBRs)(denoted SBBR1 and SBBR2) ...The effects of tourmaline on nitrogen removal performance and biofilm structures were comparatively investigated in two identical laboratory-scale sequencing batch biofilm reactors(SBBRs)(denoted SBBR1 and SBBR2) at different nitrogen loading rates(NLRs) varying from(0.24 ± 0.01) to(1.26 ± 0.02) g N/(L·day). SBBR1 was operated in parallel with SBBR2, but SBBR1 was filled with polyurethane foam loaded tourmaline(TPU) carriers and another(SBBR2) filled with polyurethane foam(PU) carriers. Results obtained from this study showed that the excellent and stable performance of SBBR1 was obtained. Ammonia nitrogen removal and total nitrogen removal were higher in SBBR1 than that in SBBR2 with increase of NLR. At an NLR of(0.24 ± 0.01) g N/(L·day), the majority of the spherical and elliptical bacteria were surrounded by the extracellular polymeric substance(EPS) and bacillus or filamentous bacteria in two SBBRs biofilms. When NLR increased to(1.26 ± 0.02) g N/(L·day), the clusters were more obvious in the SBBR1 biofilm than that in the SBBR2 biofilm. Bacteria in SBBR1 were inclined to synthesis more EPS, and the formed EPS could protect the bacteria from free ammonia(FA) under extreme condition NLR(1.26 ± 0.02) g N/(L·day). The results of polymerase chain reaction-denaturing gradient gel electrophoresis analysis showed that the microbial community similarity in SBBR2 decreased more obviously than that in SBBR1 with the increase of NLR, which the microbial community in SBBR1 was relatively stable.展开更多
Priority Areas of Biodiversity Conservation(PABCs) are the key areas for future biodiversity conservation in China. In this study, we used 5 dynamic global vegetation models(DGVMs) to simulate the ecosystem function c...Priority Areas of Biodiversity Conservation(PABCs) are the key areas for future biodiversity conservation in China. In this study, we used 5 dynamic global vegetation models(DGVMs) to simulate the ecosystem function changes under future climate change scenario in the 32 terrestrial PABCs. We selected vegetation coverage,vegetation productivity, and ecosystem carbon balance as the indicators to describe the ecosystem function changes.The results indicate that woody vegetation coverage will greatly increase in the Loess Plateau Region, the North China Plain, and the Lower Hilly Region of South China.The future climate change will have great impact on the original vegetation in alpine meadow and arid and semiarid regions. The vegetation productivity of most PABCs will enhance in the coming 100 years. The largest increment will take place in the southwestern regions with high elevation. The PABCs in the Desert Region of InnerMongolia-Xinjiang Plateau are with fastest productivity climbing, and these areas are also with more carbon sink accumulation in the future. DGVM will be a new efficient tool for evaluating ecosystem function changes in future in large scale. This study is expected to provide technical support for the future ecosystem management and biodiversity conservation under climate change.展开更多
"2020年后全球生物多样性框架"是当前《生物多样性公约》谈判的焦点议题之一。本文阐述了框架制定的背景,介绍了"2020年后全球生物多样性框架"不限成员名额工作组(Open Ended Working Group, OEWG),的谈判过程,综..."2020年后全球生物多样性框架"是当前《生物多样性公约》谈判的焦点议题之一。本文阐述了框架制定的背景,介绍了"2020年后全球生物多样性框架"不限成员名额工作组(Open Ended Working Group, OEWG),的谈判过程,综合分析了缔约方在各有关磋商进程中的观点,以及目前缔约方对框架各个要素的共识和分歧,评估了框架的制定进展,并就框架的设计提出四点展望:(1)阐明转型变革的具体实施路径;(2)平衡反映公约三大目标;(3)加强与其他全球治理进程的协同;(4)强化框架对全球及缔约方履约进展的评估和审查。最后提出对我国的建议:(1)及时更新国家生物多样性战略与行动计划(National Biodiversity Strategies and Action Plans, NBSAP);(2)加强国内生物多样性工作的协调;(3)继续加强生态环境执法和责任机制。为缔约方更好参与框架制定进程,深入了解框架及其磋商进展提供参考,并为下一步框架制定提供参考。展开更多
The United Nations 2030 Agenda for Sustainable Development provides an important framework for economic,social,and environmental action.A comprehensive indicator system to aid in the systematic implementation and moni...The United Nations 2030 Agenda for Sustainable Development provides an important framework for economic,social,and environmental action.A comprehensive indicator system to aid in the systematic implementation and monitoring of progress toward the Sustainable Development Goals(SDGs)is unfortunately limited in many countries due to lack of data.The availability of a growing amount of multi-source data and rapid advancements in big data methods and infrastructure provide unique opportunities to mitigate these data shortages and develop innovative methodologies for comparatively monitoring SDGs.Big Earth Data,a special class of big data with spatial attributes,holds tremendous potential to facilitate science,technology,and innovation toward implementing SDGs around the world.Several programs and initiatives in China have invested in Big Earth Data infrastructure and capabilities,and have successfully carried out case studies to demonstrate their utility in sustainability science.This paper presents implementations of Big Earth Data in evaluating SDG indicators,including the development of new algorithms,indicator expansion(for SDG 11.4.1)and indicator extension(for SDG 11.3.1),introduction of a biodiversity risk index as a more effective analysis method for SDG 15.5.1,and several new high-quality data products,such as global net ecosystem productivity,high-resolution global mountain green cover index,and endangered species richness.These innovations are used to present a comprehensive analysis of SDGs 2,6,11,13,14,and 15 from 2010 to 2020 in China utilizing Big Earth Data,concluding that all six SDGs are on schedule to be achieved by 2030.展开更多
Forel-Ule(FU)index of water color is an important parameter in traditional water quality investigations.We retrieved the FU index of the largest 10 lakes in China during 2000-2012 from MODerate-resolution Imaging Spec...Forel-Ule(FU)index of water color is an important parameter in traditional water quality investigations.We retrieved the FU index of the largest 10 lakes in China during 2000-2012 from MODerate-resolution Imaging Spectroradiometer surface reflectance product(MOD09)images.Since FU index is an optical parameter,it can be derived from optical remote sensing data by direct formulas,which is invariant with region and season.Based on validation by in situ measured reflectance data,the FU index products are reliable,with average relative error of 7.7%.FU index can be used to roughly assess water clarity:the clearer a water body is,and the bluer it is in color,the smaller its FU index is.FU index can also be used to roughly classify trophic state into three classes:oligotrophic,mesotrophic,and eutrophic.We analyzed the spatial,interannual,and seasonal variations of the FU index and its implications for water clarity and trophic state,and the findings are mostly consistent with the results from related literature.All in all,it might be a feasible way to roughly assess inland water quality by FU index in large region and over long time period.展开更多
Three-dimensional (3D) porous carbon-based materials with tunable composition and microstructure are of great interest for the development of oxygen involved electrocatalytic reactions. Here, we report the synthesis o...Three-dimensional (3D) porous carbon-based materials with tunable composition and microstructure are of great interest for the development of oxygen involved electrocatalytic reactions. Here, we report the synthesis of 3D porous carbon-based electrocatalyst by self-assembling Co-metal organic frameworks (MOF) building blocks on graphene via a layer-by-layer technique. Precise control of the structure and morphology is achieved by varying the MOF layer to tune the electrocatalytic properties. The as-produced electrocatalyst exhibits an excellent catalytic activity for the oxygen reduction reaction in 0.1molL^-1 KOH, showing a high onset potential of 0.963V vs. reversible hydrogen electrode (RHE) and a low tafel slope of 54mVdec^-1, compared to Pt/C (0.934V and 52mVdec^-1, respectively). Additionally, it shows a slightly lower potential vs. RHE (1.72V) than RuO2 (1.75V) at 10mAcm^-2 in an alkaline electrolyte. A rechargeable Zn-air battery based on the as-produced 3D porous catalyst demonstrates a high peak power density of 119mWcm^-2 at a cell voltage of 0.578V while retaining an excellent stability over 250 charge-discharge cycles.展开更多
基金Supported by the International Partnership Program of Chinese Academy of Sciences(No.313GJHZ2022085 FN)the Dragon 5 Cooperation(No.59193)。
文摘Rapidly monitoring regional water quality and the changing trend is of great practical and scientific significance,especially for the Beijing-Tianjin-Hebei(BTH)region of China where water resources are relatively scarce and inland water bodies are generally small.The remote sensing data of the GF 1 satellite launched in 2013 have characteristics of high spatial and temporal resolution,which can be used for the dynamic monitoring of the water environment in small lakes and reservoirs.However,the water quality remote sensing monitoring model based on the GF 1 satellite data for lakes and reservoirs in BTH is still lacking because of the considerable differences in the optical characteristics of the lakes and reservoirs.In this paper,the typical reservoirs in BTH-Guanting Reservoir,Yuqiao Reservoir,Panjiakou Reservoir,and Daheiting Reservoir are taken as the study areas.In the atmospheric correction of GF 1-WFV,the relative radiation normalized atmospheric correction was adopted after comparing it with other methods,such as 6 S and FLAASH.In the water clarity retrieval,a water color hue angle based model was proposed and outperformed other available published models,with the R 2 of 0.74 and MRE of 31.7%.The clarity products of the four typical reservoirs in the BTH region in 2013-2019 were produced using the GF 1-WFV data.Based on the products,temporal and spatial changes in clarity were analyzed,and the main influencing factors for each water body were discussed.It was found that the clarity of Guanting,Daheiting,and Panjiakou reservoirs showed an upward trend during this period,while that of Yuqiao Reservoir showed a downward trend.In the influencing factors,the water level of the water bodies can be an important factor related to the water clarity changes in this region.
基金Supported by the National Key Research and Development Program of China(No.2017YFC0405804)the National Natural Science Foundation of China(Nos.41971318,41701402,41901272)the Science and Technology Service Network Initiative,Chinese Academy of Sciences(No.KFJ-STS-ZDTP-077)。
文摘The Moderate Resolution Imaging Spectroradiometer(MODIS)surface reflectance data were used to analyze the temporal and spatial distribution characteristics of water clarity(Z_(sd))in the Jiaozhou Bay,Qingdao,China,in the Yellow Sea from 2000 to 2018.Z_(sd)retrieval models were regionally optimized using in-situ data with coincident MODIS images,and then were used to retrieve the Z_(sd) products in Jiaozhou Bay from 2000-2018.The analysis of the Z_(sd) results suggests that the spatial distribution of relative Z_(sd) spatial characteristics in Jiaozhou Bay was stable,being higher Z_(sd) in the southeast and a lower Z_(sd) in the northwest.The annual mean Z_(sd) in Jiaozhou Bay showed a significant upward trend,with an annual increase of approximately 0.02 m.Water depth and wind speed were important factors affecting the spatial distribution and annual variation of Z_(sd) in Jiaozhou Bay,respectively.
文摘Objective: Accurate staging of patients with pancreatic cancer is crucial to clarify whether meaningful resection is indeed possible. Staging laparoscopy has been suggested as a tool for staging which may spare up to two-fifth of these patients from undergoing nontherapeutic laparotomy. A controversy exists, however, as to whether the procedure should be used routinely or selectively in these patients with no evidence of metastasis on noninvasive staging. This review aims to evaluate the available literature critically, identify its limitations and address the existing controversies. Methods: The current available English literature was reviewed on this topic. Results: A direct and conclusive comparison of the controversial literature is difficult because of inconsistent use of high-quality CT scans, different study designs and dissimilarity of judgment for non-resectability among patients staged by laparoscopy. However, recent studies reveal that not more than 14% of the patients benefit from diagnostic laparoscopy when a dual-contrast thin cut and 3-D digital reformatting CT scan has been performed previously. Conclusion: We conclude that routine use of diagnostic laparoscopy does not appear warranted in all patients with pancreatic cancer, especially for patients with early-staged pancreatic cancer or non-pancreatic periampullary cancers, because diagnostic laparoscopy is costly and ultrasonography is largely operator-dependent. Rather, selective use is appropriate, especially in patients with a large primary tumor, a tumor in the body or tail of the pancreas, equivocal findings of metastasis on CT, the presence of ascites, severe weight loss, hypoalbuminemia, and a markedly elevated CA 19–9.
基金supported by the International Research Centre of Big Data for Sustainable Development Goals(CBAS)[grant no CBASYX0906]the National Natural Science Foundation of China[grant no 42271363,41971318]the Dragon 5 Cooperation[grant no 59193]..
文摘Cyanobacterial harmful algal blooms(CyanoHABs)in inland waters are now among the most pressing environmental issues worldwide,especially in China.Satellite remote sensing has limitations in monitoring CyanoHABs in small water bodies due to spatial and temporal resolution limitations.While literature and news media have the potential to supplement satellite remote sensing in monitoring CyanoHABs,they have currently not received sufficient attention.In this study,we combined information on the distributions of CyanoHABs from literature and media for the first time to comprehensively assess the spatiotemporal variation in CyanoHABs in China.We collected,cleaned,validated,and organized data from literature and media on CyanoHABs in China,resulting in the establishment of a comprehensive database on CyanoHABs in China's inland waters(ChinaCyanoDB)covering 198 water bodies,525 records for 1950-2021.The majority of water bodies with CyanoHABs(CyanoWaters)are located in the eastern China,mainly concentrated in the middle and lower Yangtze region,with a clear upward trend in their number over the last four decades.The ChinaCyanoDB and analytical results can provide valuable data support for monitoring and managing CyanoHABs in China while the database construction method may also be applied to other countries and regions.
基金supported by the Project of Nature Scientific Foundation of Heilongjiang Province (No. C2017037)the National Natural Science Foundation of China (No. 31501839)
文摘The effects of tourmaline on nitrogen removal performance and biofilm structures were comparatively investigated in two identical laboratory-scale sequencing batch biofilm reactors(SBBRs)(denoted SBBR1 and SBBR2) at different nitrogen loading rates(NLRs) varying from(0.24 ± 0.01) to(1.26 ± 0.02) g N/(L·day). SBBR1 was operated in parallel with SBBR2, but SBBR1 was filled with polyurethane foam loaded tourmaline(TPU) carriers and another(SBBR2) filled with polyurethane foam(PU) carriers. Results obtained from this study showed that the excellent and stable performance of SBBR1 was obtained. Ammonia nitrogen removal and total nitrogen removal were higher in SBBR1 than that in SBBR2 with increase of NLR. At an NLR of(0.24 ± 0.01) g N/(L·day), the majority of the spherical and elliptical bacteria were surrounded by the extracellular polymeric substance(EPS) and bacillus or filamentous bacteria in two SBBRs biofilms. When NLR increased to(1.26 ± 0.02) g N/(L·day), the clusters were more obvious in the SBBR1 biofilm than that in the SBBR2 biofilm. Bacteria in SBBR1 were inclined to synthesis more EPS, and the formed EPS could protect the bacteria from free ammonia(FA) under extreme condition NLR(1.26 ± 0.02) g N/(L·day). The results of polymerase chain reaction-denaturing gradient gel electrophoresis analysis showed that the microbial community similarity in SBBR2 decreased more obviously than that in SBBR1 with the increase of NLR, which the microbial community in SBBR1 was relatively stable.
基金supported by the Environmental Protection Public Service Project of China(201209031)
文摘Priority Areas of Biodiversity Conservation(PABCs) are the key areas for future biodiversity conservation in China. In this study, we used 5 dynamic global vegetation models(DGVMs) to simulate the ecosystem function changes under future climate change scenario in the 32 terrestrial PABCs. We selected vegetation coverage,vegetation productivity, and ecosystem carbon balance as the indicators to describe the ecosystem function changes.The results indicate that woody vegetation coverage will greatly increase in the Loess Plateau Region, the North China Plain, and the Lower Hilly Region of South China.The future climate change will have great impact on the original vegetation in alpine meadow and arid and semiarid regions. The vegetation productivity of most PABCs will enhance in the coming 100 years. The largest increment will take place in the southwestern regions with high elevation. The PABCs in the Desert Region of InnerMongolia-Xinjiang Plateau are with fastest productivity climbing, and these areas are also with more carbon sink accumulation in the future. DGVM will be a new efficient tool for evaluating ecosystem function changes in future in large scale. This study is expected to provide technical support for the future ecosystem management and biodiversity conservation under climate change.
基金supported by the Big Earth Data Science Engineering Program of the Chinese Academy of Sciences Strategic Priority Research Program(XDA19090000 and XDA19030000)。
文摘The United Nations 2030 Agenda for Sustainable Development provides an important framework for economic,social,and environmental action.A comprehensive indicator system to aid in the systematic implementation and monitoring of progress toward the Sustainable Development Goals(SDGs)is unfortunately limited in many countries due to lack of data.The availability of a growing amount of multi-source data and rapid advancements in big data methods and infrastructure provide unique opportunities to mitigate these data shortages and develop innovative methodologies for comparatively monitoring SDGs.Big Earth Data,a special class of big data with spatial attributes,holds tremendous potential to facilitate science,technology,and innovation toward implementing SDGs around the world.Several programs and initiatives in China have invested in Big Earth Data infrastructure and capabilities,and have successfully carried out case studies to demonstrate their utility in sustainability science.This paper presents implementations of Big Earth Data in evaluating SDG indicators,including the development of new algorithms,indicator expansion(for SDG 11.4.1)and indicator extension(for SDG 11.3.1),introduction of a biodiversity risk index as a more effective analysis method for SDG 15.5.1,and several new high-quality data products,such as global net ecosystem productivity,high-resolution global mountain green cover index,and endangered species richness.These innovations are used to present a comprehensive analysis of SDGs 2,6,11,13,14,and 15 from 2010 to 2020 in China utilizing Big Earth Data,concluding that all six SDGs are on schedule to be achieved by 2030.
基金This research has been jointly sponsored by the National Natural Science Foundation of China(Grant Numbers:41471308,41325004,41571361)Youth Innovation Promotion Association of Chinese Academy of Sciences,and China Scholarship Council.
文摘Forel-Ule(FU)index of water color is an important parameter in traditional water quality investigations.We retrieved the FU index of the largest 10 lakes in China during 2000-2012 from MODerate-resolution Imaging Spectroradiometer surface reflectance product(MOD09)images.Since FU index is an optical parameter,it can be derived from optical remote sensing data by direct formulas,which is invariant with region and season.Based on validation by in situ measured reflectance data,the FU index products are reliable,with average relative error of 7.7%.FU index can be used to roughly assess water clarity:the clearer a water body is,and the bluer it is in color,the smaller its FU index is.FU index can also be used to roughly classify trophic state into three classes:oligotrophic,mesotrophic,and eutrophic.We analyzed the spatial,interannual,and seasonal variations of the FU index and its implications for water clarity and trophic state,and the findings are mostly consistent with the results from related literature.All in all,it might be a feasible way to roughly assess inland water quality by FU index in large region and over long time period.
基金supported by the National Natural Science Foundation of China (51472187)
文摘Three-dimensional (3D) porous carbon-based materials with tunable composition and microstructure are of great interest for the development of oxygen involved electrocatalytic reactions. Here, we report the synthesis of 3D porous carbon-based electrocatalyst by self-assembling Co-metal organic frameworks (MOF) building blocks on graphene via a layer-by-layer technique. Precise control of the structure and morphology is achieved by varying the MOF layer to tune the electrocatalytic properties. The as-produced electrocatalyst exhibits an excellent catalytic activity for the oxygen reduction reaction in 0.1molL^-1 KOH, showing a high onset potential of 0.963V vs. reversible hydrogen electrode (RHE) and a low tafel slope of 54mVdec^-1, compared to Pt/C (0.934V and 52mVdec^-1, respectively). Additionally, it shows a slightly lower potential vs. RHE (1.72V) than RuO2 (1.75V) at 10mAcm^-2 in an alkaline electrolyte. A rechargeable Zn-air battery based on the as-produced 3D porous catalyst demonstrates a high peak power density of 119mWcm^-2 at a cell voltage of 0.578V while retaining an excellent stability over 250 charge-discharge cycles.