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原油沥青质含量对纳米颗粒-十二烷基硫酸钠发泡二氧化碳泡沫稳定性的影响
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作者 SADEGHI Hossein khaz'ali ali reza MOHAMMADI Mohsen 《石油勘探与开发》 EI CSCD 北大核心 2024年第1期212-222,共11页
采用十二烷基硫酸钠(SDS)表面活性剂和SiO_(2)纳米颗粒作为发泡体系,在不同原油沥青质含量下进行泡沫稳定性实验,测量CO_(2)泡沫半衰期;采用扫描电子显微图像、紫外分光光度法测试和Zeta电位测量,分析沥青质降低CO_(2)泡沫稳定性的机理... 采用十二烷基硫酸钠(SDS)表面活性剂和SiO_(2)纳米颗粒作为发泡体系,在不同原油沥青质含量下进行泡沫稳定性实验,测量CO_(2)泡沫半衰期;采用扫描电子显微图像、紫外分光光度法测试和Zeta电位测量,分析沥青质降低CO_(2)泡沫稳定性的机理。研究表明:当合成油与发泡体系质量比为1∶9时,合成油沥青质质量分数从0增至15%,SDS稳定泡沫半衰期从751 s减少至239 s,SDS-SiO_(2)稳定泡沫半衰期从912 s缩短至298 s;当合成油与发泡体系质量比为2∶8时,随着沥青质质量分数增大,SDS稳定泡沫半衰期从526 s缩短至171 s,SDS-SiO_(2)稳定泡沫半衰期从660 s缩短至205 s。由于沥青质与SDS和SiO_(2)纳米颗粒在水相中的相互作用,Zeta电位绝对值减小,颗粒表面电荷降低,导致薄液膜两侧界面之间的排斥力减小,从而破坏泡沫稳定性。 展开更多
关键词 CO_(2)泡沫 泡沫稳定性 沥青质 二氧化硅纳米颗粒 十二烷基硫酸钠(SDS) 排斥力 表面电荷 ZETA电位
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Experimental investigation of the effects of oil asphaltene content on CO_(2) foam stability in the presence of nanoparticles and sodium dodecyl sulfate
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作者 SADEGHI Hossein khaz'ali ali reza MOHAMMADI Mohsen 《Petroleum Exploration and Development》 SCIE 2024年第1期239-250,共12页
Foam stability tests were performed using sodium dodecyl sulfate(SDS)surfactant and SiO2 nanoparticles as foaming system at different asphaltene concentrations,and the half-life of CO_(2) foam was measured.The mechani... Foam stability tests were performed using sodium dodecyl sulfate(SDS)surfactant and SiO2 nanoparticles as foaming system at different asphaltene concentrations,and the half-life of CO_(2) foam was measured.The mechanism of foam stability reduction in the presence of asphaltene was analyzed by scanning electron microscope(SEM),UV adsorption spectrophotometric concentration measurement and Zeta potential measurement.When the mass ratio of synthetic oil to foam-formation suspension was 1:9 and the asphaltene mass fraction increased from 0 to 15%,the half-life of SDS-stabilized foams decreased from 751 s to 239 s,and the half-life of SDS/silica-stabilized foams decreased from 912 s to 298 s.When the mass ratio of synthetic oil to foam-formation suspension was 2:8 and the asphaltene mass fraction increased from 0 to 15%,the half-life of SDS-stabilized foams decreased from 526 s to 171 s,and the half-life of SDS/silica-stabilized foams decreased from 660 s to 205 s.In addition,due to asphaltene-SDS/silica interaction in the aqueous phase,the absolute value of Zeta potential decreases,and the surface charges of particles reduce,leading to the reduction of repulsive forces between two interfaces of thin liquid film,which in turn,damages the foam stability. 展开更多
关键词 CO_(2)foam foam stability ASPHALTENE silica nanoparticle sodium dodecyl sulfate(SDS) repulsive forces surface charges Zeta potential
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