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基于文化自信的中外合作办学学科基础课“General Chemistry”课程思政建设探索与实践
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作者 段金伟 王莹 +6 位作者 崔林 郑华宇 王康 王英辉 王珊珊 李佳佳 王其召 《大学化学》 CAS 2024年第4期227-237,共11页
“General Chemistry”是面向中外合作办学工科专业学生开设的一门学科基础课。为了提升教学质量,课程引入国外经典教材,在教学过程中面临外来文化的冲击和文化自信缺失的风险。因此,必须通过“General Chemistry”课程思政教学提升学... “General Chemistry”是面向中外合作办学工科专业学生开设的一门学科基础课。为了提升教学质量,课程引入国外经典教材,在教学过程中面临外来文化的冲击和文化自信缺失的风险。因此,必须通过“General Chemistry”课程思政教学提升学生对自身文化的深度认同。本文中,“General Chemistry”课程思政建设坚持文化自信理念,积极挖掘中国思政元素,将中外思政元素合理融入到教学的每一个环节,不断助推课程思政教学内涵式发展,打造课程思政高效课堂,取得了较好的育人成效。 展开更多
关键词 中外合作办学 课程思政 文化自信 普通化学 三维评价
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Monitoring seismicity in the southern Sichuan Basin using a machine learning workflow 被引量:1
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作者 kang wang Jie Zhang +2 位作者 Ji Zhang Zhangyu wang Huiyu Zhu 《Earthquake Research Advances》 CSCD 2024年第1期59-66,共8页
Monitoring seismicity in real time provides significant benefits for timely earthquake warning and analyses.In this study,we propose an automatic workflow based on machine learning(ML)to monitor seismicity in the sout... Monitoring seismicity in real time provides significant benefits for timely earthquake warning and analyses.In this study,we propose an automatic workflow based on machine learning(ML)to monitor seismicity in the southern Sichuan Basin of China.This workflow includes coherent event detection,phase picking,and earthquake location using three-component data from a seismic network.By combining Phase Net,we develop an ML-based earthquake location model called Phase Loc,to conduct real-time monitoring of the local seismicity.The approach allows us to use synthetic samples covering the entire study area to train Phase Loc,addressing the problems of insufficient data samples,imbalanced data distribution,and unreliable labels when training with observed data.We apply the trained model to observed data recorded in the southern Sichuan Basin,China,between September 2018 and March 2019.The results show that the average differences in latitude,longitude,and depth are 5.7 km,6.1 km,and 2 km,respectively,compared to the reference catalog.Phase Loc combines all available phase information to make fast and reliable predictions,even if only a few phases are detected and picked.The proposed workflow may help real-time seismic monitoring in other regions as well. 展开更多
关键词 Earthquake monitoring Machine learning Local seismicity Gaussian waveform Sparse stations
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瓦斯隧道气密性机制砂混凝土的配制与研究
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作者 赵宇翔 康旺 +4 位作者 张海龙 黄天勇 李扬 赵文静 边学俊 《新型建筑材料》 2024年第8期94-97,共4页
通过掺入气密剂,配制适用于瓦斯隧道的气密性机制砂混凝土,并研究其对水泥水化的影响,运用等温量热仪、X射线衍射仪、热重分析仪、扫描电镜和压汞法对水泥水化放热及水化产物进行分析。结果表明:相较未掺时,掺入气密剂混凝土表观渗透率... 通过掺入气密剂,配制适用于瓦斯隧道的气密性机制砂混凝土,并研究其对水泥水化的影响,运用等温量热仪、X射线衍射仪、热重分析仪、扫描电镜和压汞法对水泥水化放热及水化产物进行分析。结果表明:相较未掺时,掺入气密剂混凝土表观渗透率由497.50×10^(-18) m^(2)减小为29.16×10^(-18) m^(2),抗氯离子渗透系数减小了54.96%,56 d干燥收缩减小了8.63%,56 d抗压强度提高了11.2%。掺加气密剂对水泥净浆水化产物的生成无不利影响,同时明显减少了水泥净浆水化产物内部的大毛细孔(100~1000 nm)数量,使水化产物更密实,并改善了混凝土界面过渡区结构,从而提高了混凝土的强度、气密性及耐久性。 展开更多
关键词 瓦斯隧道 气密性混凝土 气密剂 孔隙结构
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Fracture behavior and mechanism of highly fragmented steel cylindrical shell under explosive loading
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作者 kang wang Peng Chen +5 位作者 Xingyun Sun Yufeng Liu Jiayu Meng Xiaoyuan Li Xiongwei Zheng Chuan Xiao 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2024年第6期122-132,共11页
An in-depth understanding of the fracture behavior and mechanism of metallic shells under internal explosive loading can help develop material designs for warheads and regulate the quantity and mass distribution of th... An in-depth understanding of the fracture behavior and mechanism of metallic shells under internal explosive loading can help develop material designs for warheads and regulate the quantity and mass distribution of the fragments formed.This study investigated the fragmentation performance of a new high-carbon silicon-manganese(HCSiMn)steel cylindrical shell through fragment recovery experiments.Compared with the conventional 45Cr steel shell,the number of small mass fragments produced by the HCSi Mn steel shell was significantly increased with a scale parameter of 0.57 g fitted by the Weibull distribution model.The fragmentation process of the HCSi Mn shell exhibited more brittle tensile fracture characteristics,with the microcrack damage zone on the outer surface being the direct cause of its high fragmentation.On the one hand,the doping of alloy elements resulted in grain refinement by forming metallographic structure of tempered sorbite,so that microscopic intergranular fracture reduces the characteristic mass of the fragments;on the other hand,the distribution of alloy carbides can exert a"pinning"effect on the substrate grains,causing more initial cracks to form and propagate along the brittle carbides,further improving the shell fragmentation.Although the killing power radius for light armored vehicles was slightly reduced by about 6%,the dense killing radius of HCSiMn steel projectile against personnel can be significantly increased by about 26%based on theoretical assessment.These results provided an experimental basis for high fragmentation warhead design,and to some extent,revealed the correlation mechanism between metallographic structure and shell fragmentation. 展开更多
关键词 Projectile fragmentation Fragment mass distribution Fracture mode Metallographic structure Damage power
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African Bison Optimization Algorithm:A New Bio-Inspired Optimizer with Engineering Applications
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作者 Jian Zhao kang wang +2 位作者 Jiacun wang Xiwang Guo Liang Qi 《Computers, Materials & Continua》 SCIE EI 2024年第10期603-623,共21页
This paper introduces the African Bison Optimization(ABO)algorithm,which is based on biological population.ABO is inspired by the survival behaviors of the African bison,including foraging,bathing,jousting,mating,and ... This paper introduces the African Bison Optimization(ABO)algorithm,which is based on biological population.ABO is inspired by the survival behaviors of the African bison,including foraging,bathing,jousting,mating,and eliminating.The foraging behavior prompts the bison to seek a richer food source for survival.When bison find a food source,they stick around for a while by bathing behavior.The jousting behavior makes bison stand out in the population,then the winner gets the chance to produce offspring in the mating behavior.The eliminating behavior causes the old or injured bison to be weeded out from the herd,thus maintaining the excellent individuals.The above behaviors are translated into ABO by mathematical modeling.To assess the reliability and performance of ABO,it is evaluated on a diverse set of 23 benchmark functions and applied to solve five practical engineering problems with constraints.The findings from the simulation demonstrate that ABO exhibits superior and more competitive performance by effectively managing the trade-off between exploration and exploitation when compared with the other nine popular metaheuristics algorithms. 展开更多
关键词 OPTIMIZATION metaheuristics African bison optimization engineering problems
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An envelope-based machine learning workflow for locating earthquakes in the southern Sichuan Basin
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作者 kang wang Jie Zhang +2 位作者 Ji Zhang Zhangyu wang Ziyu Li 《Earthquake Research Advances》 CSCD 2024年第2期45-54,共10页
The development of machine learning technology enables more robust real-time earthquake monitoring through automated implementations. However, the application of machine learning to earthquake location problems faces ... The development of machine learning technology enables more robust real-time earthquake monitoring through automated implementations. However, the application of machine learning to earthquake location problems faces challenges in regions with limited available training data. To address the issues of sparse event distribution and inaccurate ground truth in historical seismic datasets, we expand the training dataset by using a large number of synthetic envelopes that closely resemble real data and build an earthquake location model named ENVloc. We propose an envelope-based machine learning workflow for simultaneously determining earthquake location and origin time. The method eliminates the need for phase picking and avoids the accumulation of location errors resulting from inaccurate picking results. In practical application, ENVloc is applied to several data intercepted at different starting points. We take the starting point of the time window corresponding to the highest prediction probability value as the origin time and save the predicted result as the earthquake location. We apply ENVloc to observed data acquired in the southern Sichuan Basin, China, between September 2018 and March 2019. The results show that the average difference with the catalog in latitude, longitude, depth, and origin time is 0.02°,0.02°, 2 km, and 1.25 s, respectively. These suggest that our envelope-based method provides an efficient and robust way to locate earthquakes without phase picking, and can be used in earthquake monitoring in near-real time. 展开更多
关键词 Waveform envelope Earthquake location Local seismicity Synthetic data Sparse stations
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通州区副中心城市绿心(原东方化工厂及周边区域)更新实践
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作者 林海燕 于润东 +2 位作者 王康 宋春雨 侯启 《城市设计》 2024年第3期108-111,共4页
本文探讨了通州区副中心城市绿心(原东方化工厂及周边区域)的更新实践。城市绿心位于副中心核心区域,占地约11.2 km~2,原为工业区和村庄。2016年,北投集团启动城市绿心改造工作,旨在构建绿色生态本底,实现工业区向生态公园的转变。改造... 本文探讨了通州区副中心城市绿心(原东方化工厂及周边区域)的更新实践。城市绿心位于副中心核心区域,占地约11.2 km~2,原为工业区和村庄。2016年,北投集团启动城市绿心改造工作,旨在构建绿色生态本底,实现工业区向生态公园的转变。改造工作包括生态治理、文化传承和功能融合,通过科学更新,打造了绿色可持续的生态样板。该项目不仅提升了生态环境,还丰富了生物多样性,成为市民休闲体验的新目的地。创新经验包括生态重塑、利旧更新、赋能重构等策略,并通过全周期管理,实现了从工业文明到生态文明的转变。 展开更多
关键词 区域综合性更新 城市绿心 工业区再利用 城市再生策略 功能融合 绿色基础设施
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Magnetism Measurements of Two-Dimensional van der Waals Antiferromagnet CrPS_(4)Using Dynamic Cantilever Magnetometry
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作者 Qi Li Weili Zhen +10 位作者 Ning wang Meng Shi Yang Yu Senyang Pan Lin Deng Jiaqiang Cai kang wang Lvkuan Zou Zhongming Zeng Zhaosheng wang Jinglei Zhang 《Chinese Physics Letters》 SCIE EI CAS CSCD 2024年第10期123-128,共6页
Recent experimental and theoretical work has focused on two-dimensional van der Waals(2D vdW)magnets due to their potential applications in sensing and spintronics devises.In measurements of these emerging materials,c... Recent experimental and theoretical work has focused on two-dimensional van der Waals(2D vdW)magnets due to their potential applications in sensing and spintronics devises.In measurements of these emerging materials,conventional magnetometry often encounters challenges in characterizing the magnetic properties of small-sized vdW materials,especially for antiferromagnets with nearly compensated magnetic moments.Here,we investigate the magnetism of 2D antiferromagnet CrPS_(4)with a thickness of 8nm by using dynamic cantilever magnetometry(DCM). 展开更多
关键词 MAGNETS Magnet
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数控机床工作台定位精度测试与动态补偿研究(英文) 被引量:5
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作者 张中明 吴晓苏 +2 位作者 童逸杰 王康 高庆云 《机床与液压》 北大核心 2019年第6期82-91,137,共11页
为了进一步提高基于半闭环原理的数控机床在金属零件加工上的精度,减少在电气和机械传动过程中反向间隙和螺距误差引起的定位精度误差,这里提出了一种新的定位精度测量方法。在这项研究中,通过安装一套高分辨率光栅传感器和相应的显示... 为了进一步提高基于半闭环原理的数控机床在金属零件加工上的精度,减少在电气和机械传动过程中反向间隙和螺距误差引起的定位精度误差,这里提出了一种新的定位精度测量方法。在这项研究中,通过安装一套高分辨率光栅传感器和相应的显示仪表来测量工作台的实际位置,其目的是将光栅传感器的数据与数控单元中的数据进行比较并形成偏差矩阵。以高阶拟合曲线形式来建立一个初始的数学模型,其趋势是振荡和发散的。为了有效改善原有不合理的情形,这里导出了一种一般形式的非等距插补公式并投入运用。根据新推导出的抛物线插值计算方法,通过修改位于反向间隙分段螺距控制单元中的参数可以调高定位精度。与传统的静态测试方法相比,新方法可以用于测试和调整处于运动状态中的工作台定位精度。 展开更多
关键词 数控机床 工作台 定位精度 补偿 多项式拟合 插补
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人力资源服务专业人才队伍的建设与培养
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作者 王康 刘慨 崔岩 《管理科学与研究(中英文版)》 2024年第8期56-59,共4页
本研究聚焦于人力资源服务专业人才队伍的建设问题。通过分析行业现状,发现存在巨大人才缺口、结构性失衡、培养体系不完善等问题。研究指出,行业快速变化、知识更新加快、理论实践结合困难、复合型人才需求增加、评估激励机制不健全等... 本研究聚焦于人力资源服务专业人才队伍的建设问题。通过分析行业现状,发现存在巨大人才缺口、结构性失衡、培养体系不完善等问题。研究指出,行业快速变化、知识更新加快、理论实践结合困难、复合型人才需求增加、评估激励机制不健全等是人才队伍建设面临的主要挑战。针对这些挑战,本文提出了完善人才培养体系、强化实践能力、培养复合型人才、建立科学评估体系、完善激励机制、加强行业标准和职业认证等策略。这些策略旨在提高人才队伍的专业能力和综合素质,促进行业的可持续发展。 展开更多
关键词 人力资源服务 专业人才 培养策略 实践能力 复合型人才 评估机制 激励机制
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关于新职业青年的就业倾向和发展诉求浅析——以青岛西海岸新区新职业青年(大学生)为例
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作者 刘慨 王康 崔岩 《经济管理学刊(中英文版)》 2024年第3期78-82,共5页
近年来,伴随着信息技术的发展,催生出各种新兴职业,成为就业的重要渠道,对城市的人才、就业等领域的管理服务和政策提出新挑战。通过对青岛西海岸新区新职业青年(大学生)现状分析,旨在通过完善政策、优化管理举措,持续吸引青年人才流入... 近年来,伴随着信息技术的发展,催生出各种新兴职业,成为就业的重要渠道,对城市的人才、就业等领域的管理服务和政策提出新挑战。通过对青岛西海岸新区新职业青年(大学生)现状分析,旨在通过完善政策、优化管理举措,持续吸引青年人才流入,为城市未来发展奠定坚实基础。 展开更多
关键词 新职业 发展诉求 政策
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ESM/MIL-100(Fe)复合纤维膜的制备及可见光催化性能 被引量:1
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作者 常梦洁 柴晓娇 +5 位作者 邱磊 王康 崔雯娜 杨建业 彭龙贵 刘俊 《高分子材料科学与工程》 EI CAS CSCD 北大核心 2019年第2期131-135,共5页
以鸡蛋膜(ESM)为载体,采用层层自组装制备了ESM/MIL-100(Fe)复合纤维膜。扫描电子显微镜结果表明,MIL-100(Fe)均匀地组装到ESM纤维表面,MIL-100(Fe)的负载量可通过自组装的循环次数调节。红外光谱结果表明,组装过程不会明显破坏ESM的组... 以鸡蛋膜(ESM)为载体,采用层层自组装制备了ESM/MIL-100(Fe)复合纤维膜。扫描电子显微镜结果表明,MIL-100(Fe)均匀地组装到ESM纤维表面,MIL-100(Fe)的负载量可通过自组装的循环次数调节。红外光谱结果表明,组装过程不会明显破坏ESM的组成。在H_2O_2存在下,层层自组装10次、20次和30次的ESM/MIL-100(Fe)在1 h可见光照射后,对RhB的光催化效率均高于98%。在ESM载体上负载MIL-100(Fe)的过程易于操作,制备的ESM/MIL-100(Fe)便于回收。 展开更多
关键词 金属有机骨架 鸡蛋膜 层层自组装 可见光催化
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Characterizations and Analysis of the Mold from Animal Specimens in Shenzhen Museum
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作者 Rui Zhang kang wang +7 位作者 Meirong Sun Bo Zhang Honglian Zhang Sidong Li Hui Du Yanlin Lu Yang Ye Xiaoqiang Yu 《Journal of Environmental Protection》 2016年第7期1033-1040,共8页
Biological specimens play an important role in cultural exchange, science popularization, scientific research and economic window, but the preparation and preservation technology system of biological specimens is rela... Biological specimens play an important role in cultural exchange, science popularization, scientific research and economic window, but the preparation and preservation technology system of biological specimens is relatively unsafe and inefficient. Mold grows seriously on animal specimens, which is not only harmful to human beings’ health and environment, but also is one of the factors that restricts the development of the natural history museums where these specimens are kept. This paper identified the mold species of animal specimens by PCR with ITS primers, bio-micro-scopic observation, sequencing and phylogenetic tree analysis. The results showed the mold of animal specimens mainly belonged to Aspergillus and Neurospora. This study established the foundations of controlling and restoring the mold that infected animal specimens and guided a new methodology of preparation and environmental friendly exhibition for animal specimens. 展开更多
关键词 Animal Specimens Mold Identification PCR SEQUENCING Phylogenetic Tree Analysis
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基于光声技术的椎弓根螺钉穿刺路径上骨组织特性研究
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作者 刘洋洋 王康 +1 位作者 钱志余 李韪韬 《生命科学仪器》 2020年第2期40-44,共5页
在脊柱内固定术中,实现PS的准确植入是一个难题。该文基于光声技术研究PS穿刺路径上骨组织的差异,将为光声技术的术中应用提供一个重要的支撑。具体地,分析研究骨组织的光学特性差异,然后研究骨膜、骨松质、骨密质对于特定光的光声参数... 在脊柱内固定术中,实现PS的准确植入是一个难题。该文基于光声技术研究PS穿刺路径上骨组织的差异,将为光声技术的术中应用提供一个重要的支撑。具体地,分析研究骨组织的光学特性差异,然后研究骨膜、骨松质、骨密质对于特定光的光声参数差异。研究表明,基于光声技术可以实现不同骨组织的区分。 展开更多
关键词 光声信号 椎骨 椎弓根螺钉
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斯格明子电子学的研究进展 被引量:2
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作者 赵巍胜 黄阳棋 +3 位作者 张学莹 康旺 雷娜 张有光 《物理学报》 SCIE EI CAS CSCD 北大核心 2018年第13期81-104,共24页
在过去的半个世纪中,微电子技术一直沿着著名的摩尔定律快速发展,当前已经达到单芯片可集成上百亿晶体管.然而随着晶体管尺寸的缩小,因量子效应所产生的漏电流及其所导致的热效应使得这一定律遇到瓶颈.自旋电子技术由于引入了电子自旋... 在过去的半个世纪中,微电子技术一直沿着著名的摩尔定律快速发展,当前已经达到单芯片可集成上百亿晶体管.然而随着晶体管尺寸的缩小,因量子效应所产生的漏电流及其所导致的热效应使得这一定律遇到瓶颈.自旋电子技术由于引入了电子自旋这一全新的自由度,将有望大幅度降低器件功耗,突破热效应枷锁.斯格明子是一种具有拓扑保护的类粒子自旋结构,有望成为下一代自旋电子信息载体,引起了从物理到电子领域的广泛关注.由于其特殊的拓扑性质,斯格明子具备尺寸小、结构稳定、驱动阈值电流小等诸多优点,室温下斯格明子的成核、输运及探测进一步验证了其广泛的应用潜力,由此诞生了研究相关器件及应用的斯格明子电子学.本综述从电子学角度首先介绍斯格明子的基础概念及发展现状、理论及实验研究方法,重点阐述斯格明子器件的写入、调控及读取功能,介绍了一系列具有代表性的新型信息器件;最后,结合斯格明子电子学现状分析了目前所面临的发展瓶颈以及未来的应用前景. 展开更多
关键词 斯格明子 自旋电子学 赛道存储 类脑计算器件
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双极纳米电极阵列实现单个铂纳米颗粒上氢气析出反应的电致化学发光成像 被引量:1
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作者 秦祥 李仲秋 +3 位作者 潘建斌 李剑 王康 夏兴华 《电化学》 CAS CSCD 北大核心 2021年第2期157-167,共11页
本文制备了嵌于多孔阳极氧化铝(AAO)膜中直径为200 nm,间距为450 nm的高密度(5.7×10^(8)cm^(-2))的金纳米电极阵列,纳米电极分布规则,尺寸高度均一。我们将该金纳米电极阵列作为双极电极阵列,可将电极一侧的电化学法拉第信号在另... 本文制备了嵌于多孔阳极氧化铝(AAO)膜中直径为200 nm,间距为450 nm的高密度(5.7×10^(8)cm^(-2))的金纳米电极阵列,纳米电极分布规则,尺寸高度均一。我们将该金纳米电极阵列作为双极电极阵列,可将电极一侧的电化学法拉第信号在另一侧电极上转化成电致化学发光(ECL)信号,从而实现对单个铂纳米颗粒上氢气析出反应(HER)进行亚微米空间分辨率的电化学成像。本文介绍的方法为高空间分辨率成像电催化材料、能源材料以及细胞过程的局部电化学活性提供了一个良好的平台。 展开更多
关键词 纳米电极阵列 双极电极 电致化学发光成像 电化学成像 单个铂纳米颗粒 氢气析出反应
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PLC-RF无线传输网络中的能效最优设计方法 被引量:1
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作者 蒋跃宇 承昊新 +2 位作者 王康 戴文骏 刘笑宇 《电信科学》 2023年第4期111-119,共9页
针对电力线通信(PLC)和射频(RF)无线通信混合传输的室内通信场景,提出了一种基于角度信息的信道状态信息(AI-CSI)的能效优先传输方案。首先,Wi-Fi无线网络和PLC网络分别作为主网络和次级网络,并且采用认知无线电技术来提高频谱效率的情... 针对电力线通信(PLC)和射频(RF)无线通信混合传输的室内通信场景,提出了一种基于角度信息的信道状态信息(AI-CSI)的能效优先传输方案。首先,Wi-Fi无线网络和PLC网络分别作为主网络和次级网络,并且采用认知无线电技术来提高频谱效率的情况下,建立次级网络总能效最大化为目标函数的优化问题。其次,为了求解该问题,通过基于AI-CSI的迫零波束成形方法,获得波束成形权矢量,并进一步提出Dinkelbach与拉格朗日乘子法相结合的优化方法,进行最优的功率分配。最后,计算机仿真结果不仅验证了所提方案的有效性和优越性,而且分析了中继天线数和用户个数等典型参数对系统能效带来的影响,从而为实际系统设计提供了参考和依据。 展开更多
关键词 电力线通信 射频无线通信 认知无线电 统计信道信息 能量效率
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Prognostic value of systemic immune.inflammation index in patients with gastric cancer 被引量:31
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作者 kang wang Feiyu Diao +8 位作者 Zhijun Ye Xinhua Zhang Ertao Zhai Hui Ren Tong Li Hui Wu Yulong He Shirong Cai Jianhui Chen 《Chinese Journal of Cancer》 SCIE CAS CSCD 2017年第9期420-426,共7页
Background:Inflammation-based indexes have been used to predict survival and recurrence in cancer patients.Systemic immune-inflammation index(Sll) was reported to be associated with prognosis in some malignant tumors.... Background:Inflammation-based indexes have been used to predict survival and recurrence in cancer patients.Systemic immune-inflammation index(Sll) was reported to be associated with prognosis in some malignant tumors.In the present study,we aimed to explore the association between Sll and the prognosis of patients with gastric cancer.Methods:We retrospectively analyzed data from 444 gastric cancer patients who underwent gastrectomy at the First Affiliated Hospital of Sun Yat-sen University between January 1994 and December 2005.Preoperative Sll was calculated.The Chi square test or Fisher's exact test was used to determine the relationship between preoperative Sll and clinicopathologic characteristics.Overall survival(OS) rates were estimated using the Kaplan-Meier method,and the effect of Sll on OS was analyzed using the Cox proportional hazards model.Receiver operating characteristic(ROC)curves were used to compare the predictive ability of Sll,NLR,and PLR.Results:Sll equal to or higher than 660 was significantly associated with old age,large tumor size,unfavorable Borrmann classification,advanced tumor invasion,lymph node metastasis,distant metastasis,advanced TNM stage,and high carcino-embryonic antigen level,high neutrophil-lymphocyte ratio,and high platelet-lymphocyte ratio(all P<0.05).High Sll was significantly associated with unfavorable prognosis(P<0.001) and Sll was an independent predictor for OS(P=0.015).Subgroups analysis further showed significant associations between high Sll and short OS in stage Ⅰ,Ⅱ,Ⅲ subgroups(all P<0.05).Sll was superior to NLR and PLR for predicting OS in patients with gastric cancer.Conclusion:Preoperative Sll level is an independent prognostic factor for OS in patients with gastric cancer. 展开更多
关键词 GASTRIC cancer PREOPERATIVE SYSTEMIC IMMUNE-INFLAMMATION INDEX Prognosis
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Facile preparation of N-doped corncob-derived carbon nanofiber efficiently encapsulating Fe2O3 nanocrystals towards high ORR electrocatalytic activity 被引量:7
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作者 Wei Yan Yanling Wu +6 位作者 Yanli Chen Qi Liu kang wang Ning Cao Fangna Dai Xiyou Li Jianzhuang Jiang 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2020年第5期121-130,共10页
Facile preparation of cost-effective and durable porous carbon-supported non-precious-metal/nitrogen electrocatalysts for oxygen reduction reaction(ORR)is extremely important for promoting the commercialized applicati... Facile preparation of cost-effective and durable porous carbon-supported non-precious-metal/nitrogen electrocatalysts for oxygen reduction reaction(ORR)is extremely important for promoting the commercialized applications of such catalysts.In this work,the FeCl3-containing porphyrinato iron-based covalent porous polymer(FeCl3·FeP or-CPP)was fabricated in-situ onto porous corncob biomass supports via a simple one-pot method.Subsequent thermal-reduction pyrolysis at 700℃-900℃with CO2 gas as an activating agent resulted in Fe2O3-decorated and N-doped graphitic carbon composite Fe2O3@NC&bio-C with a high degree of graphitization of Fe-involved promotion during pyrolysis(Fe2O3=FeCl3·FePor-CPP derived Fe2O3;NC=N-doped graphene analog;bio-C=the corncob-derived hierarchically porous graphitic biomass carbon framework).The derivedα-Fe2O3 andγ-Fe2O3 nanocrystals(5-10 nm particle diameter)were all immobilized on the N-doped bio-C micro/nanofibers.Notably,the Fe2O3@NC&bio-C obtained at the pyrolysis temperature of 800℃(Fe2O3@NC&bio-C-800),exhibited unusual ORR catalytic efficiency via a 4-electron pathway with the onset and half-wave potentials of 0.96 V and 0.85 V vs.RHE,respectively.In addition,Fe2O3@NC&bio-C-800 also exhibited a high and stable limiting current density of-6.0 mA cm-2,remarkably stability(larger than 91%retention after 10000 s),and good methanol tolerance.The present work represents one of the best results for iron-based biomass material ORR catalysts reported to date.The high ORR activity is attributed to the uniformly distributedα-Fe2O3 andγ-Fe2O3 nanoparticles on the N-enriched carbon matrix with a large specific surface area of 772.6 m^2 g^-1.This facilitates favor faster electron movement and better adsorption of oxygen molecules on the surface of the catalyst.Nevertheless,comparative studies on the structure and ORR catalytic activity of Fe2O3@NC&bioC-800 with Fe2O3@bio-C-800 and NC&bio-C-800 clearly highlight the synergistic effect of the coexisting Fe2O3 nanocrystals,NC,and bio-C on the ORR performance. 展开更多
关键词 PORPHYRIN iron polymer CORNCOB FE2O3 Biomass carbon Oxygen reduction reaction
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卡巴他赛结构确证的波谱学研究 被引量:6
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作者 余大海 康旺 +1 位作者 郝福 李志刚 《波谱学杂志》 CAS CSCD 北大核心 2017年第2期191-199,共9页
用红外吸收光谱、紫外吸收光谱、核磁共振(NMR)波谱(包含~1H NMR、^(13)C NMR、DEPT-135、COSY、HSQC和HMBC)、质谱、差示扫描量热分析、X-射线粉末衍射和元素分析等方法对卡巴他赛原料药精制品进行了结构确证,对其所有的~1H和^(13)C NM... 用红外吸收光谱、紫外吸收光谱、核磁共振(NMR)波谱(包含~1H NMR、^(13)C NMR、DEPT-135、COSY、HSQC和HMBC)、质谱、差示扫描量热分析、X-射线粉末衍射和元素分析等方法对卡巴他赛原料药精制品进行了结构确证,对其所有的~1H和^(13)C NMR信号进行了归属,同时讨论了质谱主要碎片离子可能的裂解方式和红外特征吸收峰所对应的官能团的振动形式,通过多种波谱技术结合确证了卡巴他赛的结构. 展开更多
关键词 卡巴他赛 核磁共振(NMR) 红外吸收光谱 质谱 结构确证
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