Mn2＋-doped zinc borosilicate （ZBSM） glass thin films were first synthesized by sol-gel method. In the experiment, a thin gel film was depos-ited onto quartz glass substrates by dip-coating method and then heat-trea...Mn2＋-doped zinc borosilicate （ZBSM） glass thin films were first synthesized by sol-gel method. In the experiment, a thin gel film was depos-ited onto quartz glass substrates by dip-coating method and then heat-treated to form a Mn2＋-doped zinc borosilicate glass thin film. Long lasting phosphorescence （LLP） and photo-stimulated long lasting phosphorescence （PSLLP） were found in the film sample. According to fluorescence spectra, LLP emission spectra, and PSLLP emission spectra, both LLP and PSLLP emissions are attributed to the energy level transition of 4Eg→4A1g from Mn2＋. Both the phosphorescence intensity decay curves contain a fast decay component and another slow decay one. The thermoluminescence （TL） spectra show that the sample has two kinds of traps at least and their energy level values are about 0.8 eV and 1.02 eV, which could be estimated by the Randall and Willcins formula. The infrared absorption spectra （IR） consist of characteristic vi-bration bands of Si-O-Si, Si-O-Zn, B-O in [BO3], B-O group, and Zn-O in [ZnO4]. Moreover, image storage and logical operation of the ZBSM film were carried out successfully through an experiment analogues of optical storage.展开更多
The transformation mechanism of muddy carbonate rock by the coupling of bioturbation and diagenesis was stud-ied based on core,cast thin section and physical property data of Cretaceous strata in the Mesopotamia Basin...The transformation mechanism of muddy carbonate rock by the coupling of bioturbation and diagenesis was stud-ied based on core,cast thin section and physical property data of Cretaceous strata in the Mesopotamia Basin,the Middle East.There are 3 ways of biological transformation of rocks:(1)The living creatures transformed formations mechanically to make the rocks looser and intergranular pores increase.(2)After formation,burrows were backfilled with coarse-grained debris,and then unsaturated fluid infiltrated into the burrows during the penecontemporaneous period,resulting in dissolution.(3)Chemical alteration occurred in abandoned burrows and dolomitization produced a large number of intercrystalline pores.The·coupling of bioturbation and dissolution occurred mainly in the penecontemporaneous phase,and was controlled by rock type,sea level decline,burrow abundance,infillings,and water environment etc.As the burrows had better physical properties than the matrix,unsaturated fluid preferentially migrated along the burrows,leading to dissolution and expansion of the burrows first and then dissolution of the matrix.The coupling of bioturbation and dolomitization occurred mainly in the burial phase.The rich organic matter and reducing bacteria in the burrow provided material basis,reducing conditions and alkaline envi-ronment for dolomitization.The metasomatism in the penecontemporaneous period had little effect on the physical properties of the burrows.When the burrows were se parated from the deposition interface,equimolar metasomatism occurred in the burrows in a closed environment,forming euhedral fine-crystalline dolomite with intercrystalline pores.The transformation degree of bioturbation to muddy carbonate reservoir depends on rock type,density,connectivity,infillings and structure of the burrows.With the increase of the carbonate mud content,the im provement to rock physical properties by bioturbation be-comes more prominent.When the burrows are filled with coarse-grained debris or fine-crystalline dolomite,the greater the density,the higher the connectivity,and the lower the tortuosity of burrows,the better the physical properties of the muddy carbonate rocks are.展开更多
Based on the waterflooding development in carbonate reservoirs in the Middle East,in order to solve the problem of the poor development effects caused by commingled injection and production,taking the thick bioclastic...Based on the waterflooding development in carbonate reservoirs in the Middle East,in order to solve the problem of the poor development effects caused by commingled injection and production,taking the thick bioclastic limestone reservoirs of Cretaceous in Iran-Iraq as an example,this paper proposes a balanced waterflooding development technology for thick and complex carbonate reservoirs.This technology includes the fine division of development units by concealed baffles and barriers,the combination of multi well type and multi well pattern,and the construction of balanced water injection and recovery system.Thick carbonate reservoirs in Iran-Iraq are characterized by extremely vertical heterogeneity,development of multi-genesis ultra-high permeability zones,and highly concealed baffles and barriers.Based on the technologies of identification,characterization,and sealing evaluation for concealed baffles and barriers,the balanced waterflooding development technology is proposed,and three types of balanced waterflooding development modes/techniques are formed,namely,conventional stratigraphic framework,fine stratigraphic framework,and deepened stratigraphic framework.Numerical simulations show that this technology is able to realize a fine and efficient waterflooding development to recover,in a balanced manner,the reserves of thick and complex carbonate reservoirs in Iran and Iraq.The proposed technology provides a reference for the development optimization of similar reservoirs.展开更多
基金supported by the National Natural Science Foundation of China (No.50872030)the National Natural Science Foundation of Hebei Province (No.E2006000372)+1 种基金Scientific Research Starting Foundation of Returned Overseas Chinese Scholars,the Ministry of Education,ChinaScience Foundation of the College of Light Industry, Hebei Polytechnic University (No. qz201001)
文摘Mn2＋-doped zinc borosilicate （ZBSM） glass thin films were first synthesized by sol-gel method. In the experiment, a thin gel film was depos-ited onto quartz glass substrates by dip-coating method and then heat-treated to form a Mn2＋-doped zinc borosilicate glass thin film. Long lasting phosphorescence （LLP） and photo-stimulated long lasting phosphorescence （PSLLP） were found in the film sample. According to fluorescence spectra, LLP emission spectra, and PSLLP emission spectra, both LLP and PSLLP emissions are attributed to the energy level transition of 4Eg→4A1g from Mn2＋. Both the phosphorescence intensity decay curves contain a fast decay component and another slow decay one. The thermoluminescence （TL） spectra show that the sample has two kinds of traps at least and their energy level values are about 0.8 eV and 1.02 eV, which could be estimated by the Randall and Willcins formula. The infrared absorption spectra （IR） consist of characteristic vi-bration bands of Si-O-Si, Si-O-Zn, B-O in [BO3], B-O group, and Zn-O in [ZnO4]. Moreover, image storage and logical operation of the ZBSM film were carried out successfully through an experiment analogues of optical storage.
基金Supported by the China National Science and Technology Major Project(2017ZX05030-001)。
文摘The transformation mechanism of muddy carbonate rock by the coupling of bioturbation and diagenesis was stud-ied based on core,cast thin section and physical property data of Cretaceous strata in the Mesopotamia Basin,the Middle East.There are 3 ways of biological transformation of rocks:(1)The living creatures transformed formations mechanically to make the rocks looser and intergranular pores increase.(2)After formation,burrows were backfilled with coarse-grained debris,and then unsaturated fluid infiltrated into the burrows during the penecontemporaneous period,resulting in dissolution.(3)Chemical alteration occurred in abandoned burrows and dolomitization produced a large number of intercrystalline pores.The·coupling of bioturbation and dissolution occurred mainly in the penecontemporaneous phase,and was controlled by rock type,sea level decline,burrow abundance,infillings,and water environment etc.As the burrows had better physical properties than the matrix,unsaturated fluid preferentially migrated along the burrows,leading to dissolution and expansion of the burrows first and then dissolution of the matrix.The coupling of bioturbation and dolomitization occurred mainly in the burial phase.The rich organic matter and reducing bacteria in the burrow provided material basis,reducing conditions and alkaline envi-ronment for dolomitization.The metasomatism in the penecontemporaneous period had little effect on the physical properties of the burrows.When the burrows were se parated from the deposition interface,equimolar metasomatism occurred in the burrows in a closed environment,forming euhedral fine-crystalline dolomite with intercrystalline pores.The transformation degree of bioturbation to muddy carbonate reservoir depends on rock type,density,connectivity,infillings and structure of the burrows.With the increase of the carbonate mud content,the im provement to rock physical properties by bioturbation be-comes more prominent.When the burrows are filled with coarse-grained debris or fine-crystalline dolomite,the greater the density,the higher the connectivity,and the lower the tortuosity of burrows,the better the physical properties of the muddy carbonate rocks are.
基金Supported by the Major Science and Technology Project of CNPC(2023ZZ19-01).
文摘Based on the waterflooding development in carbonate reservoirs in the Middle East,in order to solve the problem of the poor development effects caused by commingled injection and production,taking the thick bioclastic limestone reservoirs of Cretaceous in Iran-Iraq as an example,this paper proposes a balanced waterflooding development technology for thick and complex carbonate reservoirs.This technology includes the fine division of development units by concealed baffles and barriers,the combination of multi well type and multi well pattern,and the construction of balanced water injection and recovery system.Thick carbonate reservoirs in Iran-Iraq are characterized by extremely vertical heterogeneity,development of multi-genesis ultra-high permeability zones,and highly concealed baffles and barriers.Based on the technologies of identification,characterization,and sealing evaluation for concealed baffles and barriers,the balanced waterflooding development technology is proposed,and three types of balanced waterflooding development modes/techniques are formed,namely,conventional stratigraphic framework,fine stratigraphic framework,and deepened stratigraphic framework.Numerical simulations show that this technology is able to realize a fine and efficient waterflooding development to recover,in a balanced manner,the reserves of thick and complex carbonate reservoirs in Iran and Iraq.The proposed technology provides a reference for the development optimization of similar reservoirs.
