Green technology innovation is an important driving force and source to promote my country’s high-quality development,and it is the core path to achieve sustainable development.This paper uses my country’s provincia...Green technology innovation is an important driving force and source to promote my country’s high-quality development,and it is the core path to achieve sustainable development.This paper uses my country’s provincial panel data from 2016 to 2019 to study the impact mechanism of R&D investment on green technology innovation,and introduces the level of digitization,using the panel threshold model to discuss its role in the impact mechanism of R&D investment on green technology innovation.The study found that when the level of digitalization in a region is low,increasing R&D investment does not necessarily improve the ability of green technology innovation;when the level of digitalization is relatively high,R&D investment has a positive role in promoting green technology innovation.Therefore,it is necessary to improve policies to encourage enterprises to increase investment in research and development;at the same time,it is necessary to promote the coordinated development of digital foundation,digital investment,digital literacy,digital economy and digital application,and promote the deep integration of digitalization and green technology innovation.展开更多
The effect of Li(2.0 wt%)addition on mechanical properties and ageing precipitation behavior of Al-3.0 Mg 0.5 Si was investigated by tensile test,dynamic elasticity modulus test,scanning electron microscopy(SEM),trans...The effect of Li(2.0 wt%)addition on mechanical properties and ageing precipitation behavior of Al-3.0 Mg 0.5 Si was investigated by tensile test,dynamic elasticity modulus test,scanning electron microscopy(SEM),transmission electron microscopy(TEM)and high-resolution transmission electron microscopy(HRTEM)images.The results show that the tensile strength of the Li-containing alloy can be significantly improved;however,the ductility is sharply decreased and the fracture mechanism changes from ductile fracture to intergranular fracture.The elasticity modulus of the Li-containing alloy increases by 11.6%compared with the base alloy.The microstructure observation shows that the Li addition can absolutely change the precipitation behavior of the base alloy,andδ′-Al_(3)Li phase becomes the main precipitates.Besides,β′′-Mg_(2)Si andδ′-Al_(3)Li dual phases precipitation can be visibly observed at 170℃ ageing for 100 h,although the quantity ofδ′-Al_(3)Li phase is more thanβ′′-Mg_(2)Si phase.The width of the precipitate-free zone(PFZ)of the Li-containing alloy is much wider at the over-ageing state than the base alloy,which has a negative impact on the ductile and results in the decrease of elongation.展开更多
In the industrial production, the dynamic cooling pre-aging treatment was employed to replace the isothermal pre-aging during the continuous heat treatment production of Al-Mg-Si alloy automotive sheets. The effects o...In the industrial production, the dynamic cooling pre-aging treatment was employed to replace the isothermal pre-aging during the continuous heat treatment production of Al-Mg-Si alloy automotive sheets. The effects of dynamic cooling pre-aging treatment on mechanical properties and paint-bake hardening behavior of an Al-Mg-Si alloy sheet are proposed in this study. The scanning electron microscopy, transmission electron microscopy, tensile test, Vickers hardness test, and differential scanning calorimetry were conducted for the purpose. It was found that the dynamic cooling pre-aging treatment at low temperature region led to the decreasing of cluster II, resulting in the deterioration of the ability of the paint-bake hardening. With the increase of the cooling pre-aging temperature, the increasing of cluster II effectively improved the stability against natural aging and the paint-bake hardening ability. The optimized dynamic cooling pre-aging temperature was ~150 ℃. In this condition, the hardness increase of the alloy sheet with pre-aging treatment is low during storage at room temperature. The high yield strength increment is obtained after paint-bake hardening.展开更多
The simulation of blast furnace slag was prepared by pure chemical reagents.Test methods like DSC,XRD and SEM were used to study the effect of Al2O3 and MgO content on crystallization of blast furnace slag during fibe...The simulation of blast furnace slag was prepared by pure chemical reagents.Test methods like DSC,XRD and SEM were used to study the effect of Al2O3 and MgO content on crystallization of blast furnace slag during fiber formation.The results show that as Al2O3 and MgO contents in the sample changed,blast furnace slag was crystallized at the average temperature below 1232 K.When the ratio of Mg/Al in the samples is 0.6 calculated by Kissinger equation,crystallization activation energy is at the maximum value and the system is in the most stable condition.The sample crystallization phases are mainly calcium akermanite(2CaO?MgO?2SiO2)and gehlenite(2CaO?Al2O3?SiO2).Secondary crystallization phases are anorthite(CaAl2Si2O8),wollastonite minerals(WOLLA)and pyroxene minerals(cPyrA).Meanwhile,the principal crystallization phases of the samples are different types and have different contents,and the microstructures of the sample sections are different due to the difference between MgO/Al2O3 ratio.展开更多
文摘Green technology innovation is an important driving force and source to promote my country’s high-quality development,and it is the core path to achieve sustainable development.This paper uses my country’s provincial panel data from 2016 to 2019 to study the impact mechanism of R&D investment on green technology innovation,and introduces the level of digitization,using the panel threshold model to discuss its role in the impact mechanism of R&D investment on green technology innovation.The study found that when the level of digitalization in a region is low,increasing R&D investment does not necessarily improve the ability of green technology innovation;when the level of digitalization is relatively high,R&D investment has a positive role in promoting green technology innovation.Therefore,it is necessary to improve policies to encourage enterprises to increase investment in research and development;at the same time,it is necessary to promote the coordinated development of digital foundation,digital investment,digital literacy,digital economy and digital application,and promote the deep integration of digitalization and green technology innovation.
基金Project(2016YFB0300802)supported by the National Key Research and Development Program of China。
文摘The effect of Li(2.0 wt%)addition on mechanical properties and ageing precipitation behavior of Al-3.0 Mg 0.5 Si was investigated by tensile test,dynamic elasticity modulus test,scanning electron microscopy(SEM),transmission electron microscopy(TEM)and high-resolution transmission electron microscopy(HRTEM)images.The results show that the tensile strength of the Li-containing alloy can be significantly improved;however,the ductility is sharply decreased and the fracture mechanism changes from ductile fracture to intergranular fracture.The elasticity modulus of the Li-containing alloy increases by 11.6%compared with the base alloy.The microstructure observation shows that the Li addition can absolutely change the precipitation behavior of the base alloy,andδ′-Al_(3)Li phase becomes the main precipitates.Besides,β′′-Mg_(2)Si andδ′-Al_(3)Li dual phases precipitation can be visibly observed at 170℃ ageing for 100 h,although the quantity ofδ′-Al_(3)Li phase is more thanβ′′-Mg_(2)Si phase.The width of the precipitate-free zone(PFZ)of the Li-containing alloy is much wider at the over-ageing state than the base alloy,which has a negative impact on the ductile and results in the decrease of elongation.
基金Project(2020YFF0218200) supported by the National Key R&D Program of China。
文摘In the industrial production, the dynamic cooling pre-aging treatment was employed to replace the isothermal pre-aging during the continuous heat treatment production of Al-Mg-Si alloy automotive sheets. The effects of dynamic cooling pre-aging treatment on mechanical properties and paint-bake hardening behavior of an Al-Mg-Si alloy sheet are proposed in this study. The scanning electron microscopy, transmission electron microscopy, tensile test, Vickers hardness test, and differential scanning calorimetry were conducted for the purpose. It was found that the dynamic cooling pre-aging treatment at low temperature region led to the decreasing of cluster II, resulting in the deterioration of the ability of the paint-bake hardening. With the increase of the cooling pre-aging temperature, the increasing of cluster II effectively improved the stability against natural aging and the paint-bake hardening ability. The optimized dynamic cooling pre-aging temperature was ~150 ℃. In this condition, the hardness increase of the alloy sheet with pre-aging treatment is low during storage at room temperature. The high yield strength increment is obtained after paint-bake hardening.
基金Project(51474090)supported by the National Natural Science Foundation of China
文摘The simulation of blast furnace slag was prepared by pure chemical reagents.Test methods like DSC,XRD and SEM were used to study the effect of Al2O3 and MgO content on crystallization of blast furnace slag during fiber formation.The results show that as Al2O3 and MgO contents in the sample changed,blast furnace slag was crystallized at the average temperature below 1232 K.When the ratio of Mg/Al in the samples is 0.6 calculated by Kissinger equation,crystallization activation energy is at the maximum value and the system is in the most stable condition.The sample crystallization phases are mainly calcium akermanite(2CaO?MgO?2SiO2)and gehlenite(2CaO?Al2O3?SiO2).Secondary crystallization phases are anorthite(CaAl2Si2O8),wollastonite minerals(WOLLA)and pyroxene minerals(cPyrA).Meanwhile,the principal crystallization phases of the samples are different types and have different contents,and the microstructures of the sample sections are different due to the difference between MgO/Al2O3 ratio.
