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H_2O和CH_4在煤表面竞争吸附机理 被引量:6
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作者 林柏泉 李永 +2 位作者 杨凯 孔佳 张祥良 《西安科技大学学报》 CAS 北大核心 2018年第6期878-885,918,共9页
为从微观上探讨H_2O和CH_4在煤表面竞争吸附的机理,构建C30H14(9个苯环)代表煤局部表面,通过密度泛函理论分析甲烷分子,水分子和煤局部表面之间的相互作用。结果表明,水分子在煤表面的吸附比甲烷分子在煤表面的吸附更加稳定,二者以最稳... 为从微观上探讨H_2O和CH_4在煤表面竞争吸附的机理,构建C30H14(9个苯环)代表煤局部表面,通过密度泛函理论分析甲烷分子,水分子和煤局部表面之间的相互作用。结果表明,水分子在煤表面的吸附比甲烷分子在煤表面的吸附更加稳定,二者以最稳定吸附构型吸附时的吸附能分别为-13.23 kJ/mol和-10.13 kJ/mol.当甲烷分子与已吸附水分子的煤表面作用时,甲烷分子吸附能显著下降,吸附平衡距离增大,表明水分子能迫使甲烷吸附到不稳定位置。水分子和甲烷共存时,水分子处于吸附状态,甲烷分子处于脱附状态且总能量最低,进而从分子水平表明水和甲烷竞争吸附时水处于主导地位。 展开更多
关键词 密度泛函理论 竞争吸附 吸附位 吸附能
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管道内预混气体爆炸的波形演化特征及超压预测模型 被引量:1
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作者 朱传杰 孙豫敏 +1 位作者 林柏泉 江丙友 《消防科学与技术》 CAS 北大核心 2021年第12期1707-1710,共4页
综合采用数值模拟、理论建模和实验验证方法,开展了平直管道内气体爆炸超压的预测方法研究。研究分析发现:爆炸波可以分为三种类型,即爆轰波、高速爆燃波和缓燃波,而且爆炸波形能够反映火焰燃烧和爆炸超压之间的关系,典型的爆炸波包含... 综合采用数值模拟、理论建模和实验验证方法,开展了平直管道内气体爆炸超压的预测方法研究。研究分析发现:爆炸波可以分为三种类型,即爆轰波、高速爆燃波和缓燃波,而且爆炸波形能够反映火焰燃烧和爆炸超压之间的关系,典型的爆炸波包含前驱冲击波、火焰压缩波和稀疏波三个部分。前驱冲击波的超压随着爆炸的传播不断增大,其与距离的关系可以用线性函数表征,火焰压缩波形成的第二次峰值超压与传播距离的关系也可以用线性函数表征,但其波形可以用指数函数表征。最后,实验验证了本文提出的爆炸波形函数的正确性,其可以很好地预测爆炸超压演化,而且与数值模拟结论基本相同。研究成果可以为管道或巷道内可燃气体爆炸超压预测及破坏评估提供理论依据。 展开更多
关键词 气体爆炸 超压 爆炸波形 火焰 爆炸波
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各向异性和非均质性对煤层抽采钻孔瓦斯渗流的影响作用机制 被引量:8
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作者 宋浩然 林柏泉 +2 位作者 赵洋 孔佳 查伟 《西安科技大学学报》 CAS 北大核心 2019年第3期461-468,482,共9页
为提高深部煤层瓦斯抽采效率,研究抽采钻孔周围煤体的瓦斯渗流规律十分关键。文中基于煤体的各向异性和非均质性,考虑煤体应力变形场和瓦斯渗流场的交叉耦合作用,分析了煤层抽采中水力割缝钻孔周围瓦斯压力以及渗透率的时空演化规律。... 为提高深部煤层瓦斯抽采效率,研究抽采钻孔周围煤体的瓦斯渗流规律十分关键。文中基于煤体的各向异性和非均质性,考虑煤体应力变形场和瓦斯渗流场的交叉耦合作用,分析了煤层抽采中水力割缝钻孔周围瓦斯压力以及渗透率的时空演化规律。结果表明:煤体的各向异性和非均质性影响割缝钻孔周围的瓦斯渗流规律。对于瓦斯压力的变化,平行层理方向瓦斯压力降幅大于垂直层理方向,抽采影响范围分布呈现"椭圆形",煤体各向异性表征明显。对于渗透率的变化,平行层理方向的煤层渗透率高于垂直层理方向,抽采初期渗透率的增加幅度较快,随后逐渐减缓,渗透率变化曲线呈现不规则"锯齿形",煤体非均质性表征明显。将数值模拟结果与杨柳矿4~#钻场瓦斯抽采的实际监测情况相互对比,现场实测的瓦斯抽采情况与模拟得到情况基本吻合,从而验证了数值模拟的合理性及工程适用性。 展开更多
关键词 瓦斯抽采 非均质性 各向异性 多场耦合 数值模拟
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Numerical simulation and experiment analysis of improving permeability by deep-hole presplitting explosion in high gassy and low permeability coal seam 被引量:6
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作者 CAI Feng LIU Ze-gong +1 位作者 lin bai-quan LI Wei 《Journal of Coal Science & Engineering(China)》 2009年第2期175-180,共6页
Created a new damage model for explosive for LS-DYNA3D,taking advantageof the Taylor method aimed at the high gassy and low permeability coal seam,and numericallysimulated and analyzed the deep-hole presplitting explo... Created a new damage model for explosive for LS-DYNA3D,taking advantageof the Taylor method aimed at the high gassy and low permeability coal seam,and numericallysimulated and analyzed the deep-hole presplitting explosion.The entire processof explosion was represented,including cracks caused by dynamic pressure,transmissionand vibration superposition of stress waves,as well as cracks growth driven by gas generatedby explosion.The influence of the cracks generated in the process of explosion andthe performance of improving permeability caused by the difference of interval between.explosive holes were analyzed.A reasonable interval between explosive holes of deepholepresplitting explosions in high gassy and low permeability coal seams was proposed,and the resolution of gas drainage in high gassy and low permeability coal seam was putforward. 展开更多
关键词 High gassy and low permeability coal seam deep-hole presplitting explosion stress wave crack growth
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High-low-blasting technology and its application in methane dynamic disaster prevention 被引量:1
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作者 LI Xian-zhong lin bai-quan +2 位作者 YANG Wei NI Guan-hua LI Quan-gui 《Journal of Coal Science & Engineering(China)》 2011年第3期305-310,共6页
The gas cooperative control model combined local pressure-relief with regional pressure-reliet was estaonsnea, based on the theory of multi-parameters cooperative. For the status of high gas contents, high in-situ str... The gas cooperative control model combined local pressure-relief with regional pressure-reliet was estaonsnea, based on the theory of multi-parameters cooperative. For the status of high gas contents, high in-situ stress and low-permeability of Ji-15 seam of No.12 coal mine in Pingmei Group. The law of detonation wave propagation and ground-stress change distribution were simulated by means of the finite element analysis software. The technology of high-low-blasting, composed of high blasting(deep crossing hole controlled hydraulic blasting) and low blasting (special roadway deep hole controlled blasting) were developed. The research shows that around control hole produce maximum tension fracture failure, and result in directional and controlled Masting, when the distance between control hole and blasting hole is 1.2 m. The theory makes blasting force and hydraulic force advantage superimpose, which raises the effect of pressure relief and permeability enhancements compared with general blasting. High blasting influence radius and low blasting influence radius superimposed with each other, that prevents methane dynamic disaster. The result of type approval test shows that the technology can increase gas permeability as high as 22.7-36.2 ratio, decrease gas pressure from 2.85 MPa to 0.30 MPa, increase drilling influence radius to about 9 m. The technology realizes regional overall permeability improvement, that provides a new technical measure for methane dynamic disaster prevention. 展开更多
关键词 high-low-blasting multi-parameters cooperative numerical simulation methane dynamic disaster
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Experimental study and theoretical analysis on the effect of electric field on gas explosion and its propagation
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作者 YE Qing lin bai-quan +1 位作者 JIAN Cong-guang JIA Zhen-zhen 《Journal of Coal Science & Engineering(China)》 2011年第2期147-151,共5页
The effect of the electric field with different intensity on explosion wave pressure and flame propagation velocity of gas explosion was experimentally studied, and the effect of electric field on gas explosion and it... The effect of the electric field with different intensity on explosion wave pressure and flame propagation velocity of gas explosion was experimentally studied, and the effect of electric field on gas explosion and its propagation was theoretically analyzed from heat transportation, mass transportation, and reaction process of gas explosion. The results show that the electric field can affect gas explosion by enhancing explosion intensity and explosion pressure, thus increasing flame velocity. The electric field can offer energy to the gas explosion reaction; the effect of the electric field on gas explosion increases with the increase of electric field intensity. The electric field can increase mass transfer action, heat transfer action, convection effects, diffusion coefficient, and the reaction system entropy, which make the turbulence of gas explosion in electric field increase; therefore, the electric field can improve flame combustion velocity and flame propagation velocity, release more energy, increase shock wave energy, and then promote the gas explosion and its propagation. 展开更多
关键词 electric field gas explosion explosion wave pressure flame propagation reaction process
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高温热源特性对木粉阴燃传播特性影响 被引量:2
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作者 查伟 林柏泉 刘统 《工程热物理学报》 EI CAS CSCD 北大核心 2019年第11期2664-2671,共8页
为了探究高温热源特性对阴燃传播的影响,本文基于高温氮化硅点火装置建立了阴燃传播速度实验测试平台,并以红棕木粉为实验材料,结合木粉的热重分析开展了不同引燃温度和时间作用下木粉阴燃传播特性实验研究,结果表明:在实验条件下,木粉... 为了探究高温热源特性对阴燃传播的影响,本文基于高温氮化硅点火装置建立了阴燃传播速度实验测试平台,并以红棕木粉为实验材料,结合木粉的热重分析开展了不同引燃温度和时间作用下木粉阴燃传播特性实验研究,结果表明:在实验条件下,木粉堆在6种不同适宜热源引燃温度下所能达到的最高温度几乎一致约490℃,且三个热电偶位置距离阴燃初始点越近其升温到最高温度越慢;在640℃到675℃之间存在一个最佳热源热通量使木粉堆析出挥发分与内部氧气含量为适宜比例,且在这个比例下木粉阴燃初期的传播速度最快,约4.4×10^-2 cm/s;相同高温热源温度下,木分堆持续引燃时间越长,热源提供的总热量越大,阴燃初期的传播速度越快。所得结果可为木材加工企业防控阴燃火灾提供实验依据。 展开更多
关键词 阴燃速度 木粉 热源特性 热重曲线
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