A hydrotalcite(layered double hydroxide, LDH) inhibitor which is suitable for the whole process of coal spontaneous combustion and a LDH inhibitor containing rare earth lanthanum elements were prepared. The inhibition...A hydrotalcite(layered double hydroxide, LDH) inhibitor which is suitable for the whole process of coal spontaneous combustion and a LDH inhibitor containing rare earth lanthanum elements were prepared. The inhibition effect and mechanism were analyzed by scanning electron microscopy(SEM),X-ray diffraction(XRD), thermal performance analysis, in-situ diffuse reflectance infrared spectroscopy and temperature-programmed experiment. The results have shown that the inhibitor containing lanthanum can play a good inhibitory role in every stage of coal oxidation. During the slow oxidation of coal samples, the inhibitor containing lanthanum ions can slow down the oxidation process of coal and increase the initial temperature of coal spontaneous combustion. At the same time, because the hydroxyl groups in LDHs are connected with-COO-groups on the coal surface through hydrogen bonds, the stability of coal is improved. With the increase of temperature, LDHs can remove interlayer water molecules and reduce the surface temperature of coal. CO release rate of coal samples decreases significantly after adding inhibitor containing lanthanum element, and the maximum inhibition rate of the inhibitor is 58.1%.展开更多
文摘以圆形截面桩为例,基于修正后的Loganathan公式,利用文克尔弹性地基梁模型、m法计算理论和荷载传递法,建立盾构隧道近接斜交侧穿既有桥梁桩基的变形计算方法.通过现场监测结果验证计算方法的工程适用性,并利用该方法分析侧穿桥梁桩基施工引起桩身水平挠曲变形的主要影响因素.结果表明:桩身水平位移和桩顶竖向位移的理论计算结果与监测结果之间的最大误差分别不超过14.6%和2.7%.与现有方法相比,所提方法的计算结果更接近实测值.入土段桩身水平挠曲程度与隧道轴心和桩基中心轴线之间的水平距离、隧道侧穿斜交角呈负相关;最大水平挠曲位移与隧道侧穿斜交角呈负相关.当水平侧穿距离为6.0 m时,最大水平挠曲变形为7.4 mm;当隧道盾构侧穿斜交角为70.0°时,入土段桩身最大水平挠曲位移为15.4 mm.
基金Funded by National Natural Science Foundation of China (No.52074218)。
文摘A hydrotalcite(layered double hydroxide, LDH) inhibitor which is suitable for the whole process of coal spontaneous combustion and a LDH inhibitor containing rare earth lanthanum elements were prepared. The inhibition effect and mechanism were analyzed by scanning electron microscopy(SEM),X-ray diffraction(XRD), thermal performance analysis, in-situ diffuse reflectance infrared spectroscopy and temperature-programmed experiment. The results have shown that the inhibitor containing lanthanum can play a good inhibitory role in every stage of coal oxidation. During the slow oxidation of coal samples, the inhibitor containing lanthanum ions can slow down the oxidation process of coal and increase the initial temperature of coal spontaneous combustion. At the same time, because the hydroxyl groups in LDHs are connected with-COO-groups on the coal surface through hydrogen bonds, the stability of coal is improved. With the increase of temperature, LDHs can remove interlayer water molecules and reduce the surface temperature of coal. CO release rate of coal samples decreases significantly after adding inhibitor containing lanthanum element, and the maximum inhibition rate of the inhibitor is 58.1%.
