利用四乙基溴化铵与H 4PMo 11 VO 40反应,制备了磷钼钒有机盐催化剂(TEAB-HPMV),并以苯酚氧化溴代反应为探针反应,评价催化剂的催化性能。结果表明,TEAB-HPMV仍保留了磷钼钒酸的Keggin结构,具有较好的热稳定性,在苯酚的氧化溴代反应中...利用四乙基溴化铵与H 4PMo 11 VO 40反应,制备了磷钼钒有机盐催化剂(TEAB-HPMV),并以苯酚氧化溴代反应为探针反应,评价催化剂的催化性能。结果表明,TEAB-HPMV仍保留了磷钼钒酸的Keggin结构,具有较好的热稳定性,在苯酚的氧化溴代反应中表现出优良的催化性能,在优化条件下苯酚溴代转化率达到95.8%,其中对溴苯酚选择性为84.6%。TEAB-HPMV具有较好的重复利用性,通过过滤可回收,在4次使用时仍具有较高的催化活性。展开更多
A novel process was proposed for the utilization of potash feldspar by roasting in the presence of sodium carbonate. The effects of roasting temperature, granularity, molar ratio of sodium carbonate to potash feldspar...A novel process was proposed for the utilization of potash feldspar by roasting in the presence of sodium carbonate. The effects of roasting temperature, granularity, molar ratio of sodium carbonate to potash feldspar and roasting time on the silica extraction rate were investigated. Under the optimal roasting conditions, the silica extraction rate was 98%. The optimal conditions, determined using an orthogonal experiment, were found to be roasting temperature of 875 A degrees C, potash feldspar granularity of 74-89 mu m, molar ratio of sodium carbonate to potash feldspar of 1.2:1, and roasting time of 80 min. The kinetics of potash feldspar roasting in the presence of sodium carbonate was described by the shrinking core model and the reaction rate was found to be controlled by the chemical reaction at the particle surface. According to the Arrhenius expression, the activation energy was 164.99 kJ/mol, and the process could be expressed as [1-(1-alpha)(1/3)]=2.66x10(5) exp[-164990/(RT)] t.展开更多
文摘利用四乙基溴化铵与H 4PMo 11 VO 40反应,制备了磷钼钒有机盐催化剂(TEAB-HPMV),并以苯酚氧化溴代反应为探针反应,评价催化剂的催化性能。结果表明,TEAB-HPMV仍保留了磷钼钒酸的Keggin结构,具有较好的热稳定性,在苯酚的氧化溴代反应中表现出优良的催化性能,在优化条件下苯酚溴代转化率达到95.8%,其中对溴苯酚选择性为84.6%。TEAB-HPMV具有较好的重复利用性,通过过滤可回收,在4次使用时仍具有较高的催化活性。
基金Project(51204054)supported by the National Natural Science Foundation of ChinaProject(2007CB613603)supported by the National Basic Research Program of ChinaProject(N140204011)supported by the Ministry of Education Basic Scientific Research Business Expenses,China
文摘A novel process was proposed for the utilization of potash feldspar by roasting in the presence of sodium carbonate. The effects of roasting temperature, granularity, molar ratio of sodium carbonate to potash feldspar and roasting time on the silica extraction rate were investigated. Under the optimal roasting conditions, the silica extraction rate was 98%. The optimal conditions, determined using an orthogonal experiment, were found to be roasting temperature of 875 A degrees C, potash feldspar granularity of 74-89 mu m, molar ratio of sodium carbonate to potash feldspar of 1.2:1, and roasting time of 80 min. The kinetics of potash feldspar roasting in the presence of sodium carbonate was described by the shrinking core model and the reaction rate was found to be controlled by the chemical reaction at the particle surface. According to the Arrhenius expression, the activation energy was 164.99 kJ/mol, and the process could be expressed as [1-(1-alpha)(1/3)]=2.66x10(5) exp[-164990/(RT)] t.