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表面活性聚合物驱油剂的合成及性能研究 被引量:9
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作者 李义 刘平德 张松 《石油与天然气化工》 CAS CSCD 北大核心 2021年第6期81-86,共6页
针对聚合物/表面活性剂复合驱中聚合物与表面活性剂黏度差异导致其在地层中运移不同步而发生的色谱分离,以及常规驱油用聚合物无表面活性的问题,利用可聚合表面活性单体(YCM)、丙烯酰胺(AM),借助于复合引发体系,控制低温聚合的方法,合... 针对聚合物/表面活性剂复合驱中聚合物与表面活性剂黏度差异导致其在地层中运移不同步而发生的色谱分离,以及常规驱油用聚合物无表面活性的问题,利用可聚合表面活性单体(YCM)、丙烯酰胺(AM),借助于复合引发体系,控制低温聚合的方法,合成了具有增黏性与界面活性的驱油用表面活性聚合物。红外光谱表征表明表面活性聚合物分子结构中含有磺酸基团(SO_(3)^(-))、苯环、长链亚甲基疏水基团,目标产物与分子结构设计吻合。优化出表面活性单体YCM质量分数为1.5%~2.5%,引发剂质量分数为0.04%~0.06%。表面活性聚合物在大庆模拟盐水中具有较好的溶解性(溶解时间为85 min)、增黏性(表观黏度>40 mPa·s,7.34 s^(-1))及降低油水界面张力的能力(10^(-2) mN/m数量级)。岩心驱替实验结果表明,表面活性聚合物比常规聚合物/石油磺酸盐提高采收率2.5%,表面活性聚合物起到了聚合物与表面活性剂二元复合驱的作用,抑制了二元复合驱的色谱分离,实现了表面活性聚合物既能扩大波及体积又能提高洗油效率的功能,对高含水油田提高采收率具有重要意义。 展开更多
关键词 表面活性聚合物 复合驱 界面张力 色谱分离 采收率
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气/液介质对泡沫液膜渗透性的影响规律 被引量:4
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作者 魏发林 张松 +3 位作者 丁彬 熊春明 刘平德 王典林 《油田化学》 CAS CSCD 北大核心 2022年第4期663-667,共5页
为了构建适用于泡沫驱的高稳定泡沫,从液膜渗透率角度阐明气/液介质对泡沫稳定性的影响机制。以氮气和二氧化碳为气体介质,利用气泡缩减法,测定了7种起泡体系的泡沫液膜渗透率以及起泡性能、析液半衰期和泡沫半衰期。研究结果表明,对于... 为了构建适用于泡沫驱的高稳定泡沫,从液膜渗透率角度阐明气/液介质对泡沫稳定性的影响机制。以氮气和二氧化碳为气体介质,利用气泡缩减法,测定了7种起泡体系的泡沫液膜渗透率以及起泡性能、析液半衰期和泡沫半衰期。研究结果表明,对于同一种气体介质,表面活性剂分子疏水碳链数目越多,液膜上表面活性剂分子之间相互作用越强,泡沫液膜渗透率越小;CO_(2)泡沫的液膜渗透率是N泡沫的1~3倍,CO_(2)泡沫稳定性比N泡沫的低;泡沫液膜渗透率与泡沫半衰期呈现出良好的相关性,随着液膜渗透率升高,CO_(2)泡沫半衰期快速递减。 展开更多
关键词 泡沫液膜渗透性 气体类型 泡沫半衰期 失稳机理
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A bull-heading water control technique of thermo-sensitive temporary plugging agent 被引量:4
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作者 liu pingde WEI Falin +3 位作者 ZHANG Song ZHU Xiuyu WANG Longfei XIONG Chunming 《Petroleum Exploration and Development》 2018年第3期536-543,共8页
Aimed at the disadvantages of secondary damage to oil layers caused by the conventional bull-heading water control technique, a thermo-sensitive temporary plugging agent for water control was synthesized by water solu... Aimed at the disadvantages of secondary damage to oil layers caused by the conventional bull-heading water control technique, a thermo-sensitive temporary plugging agent for water control was synthesized by water solution polymerization and applied in the field with a new secondary temporary plugging technique. The optimization and performance evaluation of thermo-sensitive temporary plugging agent were carried out through laboratory experiments. The optimized formula is as follows:(6%-8%) acrylamide +(0.08%-0.12%) ammonium persulfate +(1.5%-2.0%) sepiolite +(0.5%-0.8%) polyethylene glycol diacrylate. The thermo-sensitive temporary plugging agent is suitable for formation temperatures of 70-90 ?C, it has high temporary plugging strength(5-40 k Pa), controllable degradation time(1-15 d), the apparent viscosity after degradation of less than 100 m Pa?S and the permeability recovery value of simulated cores of more than 95%. Based on the research results, secondary temporary plugging technique was used in a horizontal well in the Jidong Oilfield. After treatment, the well saw a drop of water cut to 27%, and now it has a water cut of 67%, its daily increased oil production was 4.8 t, and the cumulative oil increment was 750 t, demonstrating that the technique worked well in controlling water production and increasing oil production. 展开更多
关键词 bull-heading water control TECHNIQUE THERMO-SENSITIVE TEMPORARY plugging agent secondary TEMPORARY plugging TECHNIQUE thermal degradation property RESERVOIR protection
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