The origin of the unusually high dibenzothiophene (DBT) concentrations in Lower Ordovician oils from the Tazhong Uplift,Tarim Basin was studied by Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR...The origin of the unusually high dibenzothiophene (DBT) concentrations in Lower Ordovician oils from the Tazhong Uplift,Tarim Basin was studied by Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS).The most abundant sulfur compounds in the oils are S 1 species with doublebond equivalent (DBE) values of 1-19 and 11-48 carbon atoms.The range of the number of carbon atoms in the sulfur compounds detected by the FT-ICR MS (S 1 species with DBE=9) is about ten times larger than that for sulfur compounds detected by GC/MS (DBTs).This suggests that FT-ICR MS is a much better approach than GC/MS for characterization of DBTs in crude oils.The abundance of S 1 species with DBE=1-8 decreased with increasing thermal maturity,while the abundance of S 1 species with DBE=9 (primarily DBTs) increased.Therefore,thermal maturity is an important factor in the formation of oils with high DBT concentrations.Unusually high abundances of S 1 species with low DBE values (1-8),which include sulfide,thiophene and benzothiophene,were observed in several oils,especially the TZ83 (O 1) oil with high or very high thermal maturity.Thermochemical sulfate reduction (TSR) was thought to be the reason for the high abundance of these low DBE compounds in deep reservoirs,and thermochemical sulfate reduction could affect the distribution and composition of DBTs in the oils.According to the results of FT-ICR MS analysis,there are no signs that TSR is occurring or has occurred recently for most of the Lower Ordovician oils.展开更多
The origin of the marine oils in the Tarim Basin has long been a disputed topic. A total of 58 DST (drill stem test) crude oil and 8 rock samples were investigated using a comprehensive geochemical method to charact...The origin of the marine oils in the Tarim Basin has long been a disputed topic. A total of 58 DST (drill stem test) crude oil and 8 rock samples were investigated using a comprehensive geochemical method to characterize and identify the origin of the Ordovician oils in the Tazhong Uplift, Tarim Basin, northwest China. Detailed oil–oil and oil–source rock correlations show that the majority of the oils have typical biomarker characteristics of the Middle-Upper Ordovician (O2+3) source rock and the related crude oil. These characteristics include a distinct "V-shaped" relative abundance of C27, C28 and C29 regular steranes, low abundance of dinosterane, 24-norcholestanes, triaromatic dinosteroids and gammacerane. Only a few oils display typical biomarker characteristics indicating the Cambrian–Lower Ordovician (∈-O1) genetic affinity, such as linear or anti "L" shape distribution of C27, C28 and C29 regular sterane, with relatively high concentrations of dinosterane, 24-norcholestanes, triaromatic dinosteroids and gammacerane. It appears that most of the Ordovician oils in the Tazhong Uplift were derived from the O2+3 intervals, as suggested by previous studies. However, the compound specific n-alkane stable carbon isotope data indicate that the Ordovician oils are mixtures from both the ∈-O1 and O2+3 source rocks rather than from the O2+3 strata alone. It was calculated that the proportion of the∈-O1 genetic affinity oils mixed is about 10.8%-74.1%, with an increasing trend with increasing burial depth. This new oil-mixing model is critical for understanding hydrocarbon generation and accumulation mechanisms in the region, and may have important implications for further hydrocarbon exploration in the Tarim Basin.展开更多
The Silurian stratum in the Tazhong uplift is an important horizon for exploration because it preserves some features of the hydrocarbons produced from multi-stage tectonic evolution. For this reason, the study of the...The Silurian stratum in the Tazhong uplift is an important horizon for exploration because it preserves some features of the hydrocarbons produced from multi-stage tectonic evolution. For this reason, the study of the origin of the Silurian oils and their formation characteristics constitutes a major part in revealing the mechanisms for the composite hydrocarbon accumulation zone in the Tazhong area. Geochemical investigations indicate that the physical properties of the Silurian oils in Tazhong vary with belts and blocks, i.e., heavy oils are distributed in the TZ47-15 well-block in the North Slope while normal and light oils in the No. I fault belt and the TZ16 well-block, which means that the oil properties are controlled by structural patterns. Most biomarkers in the Silurian oils are similar to that of the Mid-Upper Ordovician source rocks, suggesting a good genetic relationship. However, the compound specific isotope of n-alkanes in the oils and the chemical components of the hydrocarbons in fluid inclusions indicate that these oils are mixed oils derived from both the Mid- Upper Ordovician and the Cambrian-Lower Ordovician source rocks. Most Silurian oils have a record of secondary alterations like earlier biodegradation, including the occurrence of "UCM" humps in the total ion current (TIC) chromatogram of saturated and aromatic hydrocarbons and 25-norhopane in saturated hydrocarbons of the crude oils, and regular changes in the abundances of light and heavy components from the structural low to the structural high. The fact that the Silurian oils are enriched in chain alkanes, e.g., n-alkanes and 25-norhopane, suggests that they were mixed oils of the earlier degraded oils with the later normal oils. It is suggested that the Silurian oils experienced at least three episodes of petroleum charging according to the composition and distribution as well as the maturity of reservoir crude oils and the oils in fluid inclusions. The migration and accumulation models of these oils in the TZ47-15 well-blocks, the No. I fault belt and the TZ16 well-block are different from but related to each other. The investigation of the origin of the mixed oils and the hydrocarbon migration and accumulation mechanisms in different charging periods is of great significance to petroleum exploration in this area.展开更多
A large number of crude oil and rock samples from various oil pools of the Central Uplift in Dongying Depression were investigated to reveal the origin and accumulation of hydrocarbons. The results showed that the com...A large number of crude oil and rock samples from various oil pools of the Central Uplift in Dongying Depression were investigated to reveal the origin and accumulation of hydrocarbons. The results showed that the composition and areal distribution of hydrocarbons vary with the location of the oil pools. An increasing trend of gammacerane/C30-hopane and steranes/hopanes but a decreasing trend of prystane/phytane (Pr/Ph) and 18(H)-/17(H)- trisnorhopane (Ts/Tm) ratios were observed from southwest to northeast. This indicates a variation of source rocks and hydrocarbon properties. An increasing trend of water salinity with much more input of algae-rich microorganisms in the deposition environment of the source rock was observed from southwest to northeast. However, the thermal maturity of the source rocks showed a decreasing trend in the same direction. Oil-to-oil and oil-to-source rock correlations showed that most oils were sourced from Es3 and Es4 members with a burial depth of more than 3,000-3,150 m and 2,700 m respectively. The oils in the Shinan and Ying 11 sand bodies, which were generally mixed with the Es4 sourced oils, came mostly from Es3 mudstones. It is quite significant that the Es4 derived oils migrated vertically for hundreds of meters and accumulated in an overlying lithologic pool of the Es3^m, i.e., Ying 11 synclinal lithologic pool, which suggests that the mechanisms of migration and accumulation for subtle oil pools in the Dongying Depression are more complex than that of the previously expected.展开更多
以中国矿业大学图书馆开展的ESI学科评估工作实践为例,阐述基于ESI和InCites数据库,用进入全球1%的学科、学者、高被引论文、热点论文等指标,对中国矿业大学的学科建设现状进行宏观分析,从文献分析的角度得出其学科发展现状,评价学科的...以中国矿业大学图书馆开展的ESI学科评估工作实践为例,阐述基于ESI和InCites数据库,用进入全球1%的学科、学者、高被引论文、热点论文等指标,对中国矿业大学的学科建设现状进行宏观分析,从文献分析的角度得出其学科发展现状,评价学科的优势与不足。首先是针对无法深入研究众多文献间的关联问题,建议将Histcite、Citespace以及Web of Science平台自带的引文分析工具作为ESI学科评估工具的辅助工具结合使用,以达到更深入全面的对学科建设进行分析,进而为高校的学科发展政策的制定提供可靠的依据,更为后期学科建设与发展提供参考,其次是对参与学科评估工作人员能力的要求,建议从加强培训方面给出相应的对策,并在提高学科评估工作人员能力的同时,根据各高校学科发展的情况与教师之间建立关系,为其日常的科学研究提供与学科相关的服务;最后是对以理工科为主的高校在学科建设发展中存在的弱势学科在文献资源缺乏的问题上提出应对措施。展开更多
基金funded by the Natural Science FundingCouncil of China(Grant No.#40973031)the Foundationof State Key Laboratory of Petroleum Resources and Prospecting,China University of Petroleum(No.PRPJC2008-02)Natural Science Research Council of China(China 973 National Key Research and Development Program 2011CB201102)
文摘The origin of the unusually high dibenzothiophene (DBT) concentrations in Lower Ordovician oils from the Tazhong Uplift,Tarim Basin was studied by Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS).The most abundant sulfur compounds in the oils are S 1 species with doublebond equivalent (DBE) values of 1-19 and 11-48 carbon atoms.The range of the number of carbon atoms in the sulfur compounds detected by the FT-ICR MS (S 1 species with DBE=9) is about ten times larger than that for sulfur compounds detected by GC/MS (DBTs).This suggests that FT-ICR MS is a much better approach than GC/MS for characterization of DBTs in crude oils.The abundance of S 1 species with DBE=1-8 decreased with increasing thermal maturity,while the abundance of S 1 species with DBE=9 (primarily DBTs) increased.Therefore,thermal maturity is an important factor in the formation of oils with high DBT concentrations.Unusually high abundances of S 1 species with low DBE values (1-8),which include sulfide,thiophene and benzothiophene,were observed in several oils,especially the TZ83 (O 1) oil with high or very high thermal maturity.Thermochemical sulfate reduction (TSR) was thought to be the reason for the high abundance of these low DBE compounds in deep reservoirs,and thermochemical sulfate reduction could affect the distribution and composition of DBTs in the oils.According to the results of FT-ICR MS analysis,there are no signs that TSR is occurring or has occurred recently for most of the Lower Ordovician oils.
基金This study is funded by the Natural Science Research Council of China (973 State Key Research and Development Program 2006CB202308)National Natural Science Foundation of China (Grant No.40973031)
文摘The origin of the marine oils in the Tarim Basin has long been a disputed topic. A total of 58 DST (drill stem test) crude oil and 8 rock samples were investigated using a comprehensive geochemical method to characterize and identify the origin of the Ordovician oils in the Tazhong Uplift, Tarim Basin, northwest China. Detailed oil–oil and oil–source rock correlations show that the majority of the oils have typical biomarker characteristics of the Middle-Upper Ordovician (O2+3) source rock and the related crude oil. These characteristics include a distinct "V-shaped" relative abundance of C27, C28 and C29 regular steranes, low abundance of dinosterane, 24-norcholestanes, triaromatic dinosteroids and gammacerane. Only a few oils display typical biomarker characteristics indicating the Cambrian–Lower Ordovician (∈-O1) genetic affinity, such as linear or anti "L" shape distribution of C27, C28 and C29 regular sterane, with relatively high concentrations of dinosterane, 24-norcholestanes, triaromatic dinosteroids and gammacerane. It appears that most of the Ordovician oils in the Tazhong Uplift were derived from the O2+3 intervals, as suggested by previous studies. However, the compound specific n-alkane stable carbon isotope data indicate that the Ordovician oils are mixtures from both the ∈-O1 and O2+3 source rocks rather than from the O2+3 strata alone. It was calculated that the proportion of the∈-O1 genetic affinity oils mixed is about 10.8%-74.1%, with an increasing trend with increasing burial depth. This new oil-mixing model is critical for understanding hydrocarbon generation and accumulation mechanisms in the region, and may have important implications for further hydrocarbon exploration in the Tarim Basin.
基金supported by the China National 973 Key Research and Development Project(Grant No. 2006CB202308)the National Natural Science Foundation of China(Grant No.40973031 and 40772077/ D0206)
文摘The Silurian stratum in the Tazhong uplift is an important horizon for exploration because it preserves some features of the hydrocarbons produced from multi-stage tectonic evolution. For this reason, the study of the origin of the Silurian oils and their formation characteristics constitutes a major part in revealing the mechanisms for the composite hydrocarbon accumulation zone in the Tazhong area. Geochemical investigations indicate that the physical properties of the Silurian oils in Tazhong vary with belts and blocks, i.e., heavy oils are distributed in the TZ47-15 well-block in the North Slope while normal and light oils in the No. I fault belt and the TZ16 well-block, which means that the oil properties are controlled by structural patterns. Most biomarkers in the Silurian oils are similar to that of the Mid-Upper Ordovician source rocks, suggesting a good genetic relationship. However, the compound specific isotope of n-alkanes in the oils and the chemical components of the hydrocarbons in fluid inclusions indicate that these oils are mixed oils derived from both the Mid- Upper Ordovician and the Cambrian-Lower Ordovician source rocks. Most Silurian oils have a record of secondary alterations like earlier biodegradation, including the occurrence of "UCM" humps in the total ion current (TIC) chromatogram of saturated and aromatic hydrocarbons and 25-norhopane in saturated hydrocarbons of the crude oils, and regular changes in the abundances of light and heavy components from the structural low to the structural high. The fact that the Silurian oils are enriched in chain alkanes, e.g., n-alkanes and 25-norhopane, suggests that they were mixed oils of the earlier degraded oils with the later normal oils. It is suggested that the Silurian oils experienced at least three episodes of petroleum charging according to the composition and distribution as well as the maturity of reservoir crude oils and the oils in fluid inclusions. The migration and accumulation models of these oils in the TZ47-15 well-blocks, the No. I fault belt and the TZ16 well-block are different from but related to each other. The investigation of the origin of the mixed oils and the hydrocarbon migration and accumulation mechanisms in different charging periods is of great significance to petroleum exploration in this area.
文摘A large number of crude oil and rock samples from various oil pools of the Central Uplift in Dongying Depression were investigated to reveal the origin and accumulation of hydrocarbons. The results showed that the composition and areal distribution of hydrocarbons vary with the location of the oil pools. An increasing trend of gammacerane/C30-hopane and steranes/hopanes but a decreasing trend of prystane/phytane (Pr/Ph) and 18(H)-/17(H)- trisnorhopane (Ts/Tm) ratios were observed from southwest to northeast. This indicates a variation of source rocks and hydrocarbon properties. An increasing trend of water salinity with much more input of algae-rich microorganisms in the deposition environment of the source rock was observed from southwest to northeast. However, the thermal maturity of the source rocks showed a decreasing trend in the same direction. Oil-to-oil and oil-to-source rock correlations showed that most oils were sourced from Es3 and Es4 members with a burial depth of more than 3,000-3,150 m and 2,700 m respectively. The oils in the Shinan and Ying 11 sand bodies, which were generally mixed with the Es4 sourced oils, came mostly from Es3 mudstones. It is quite significant that the Es4 derived oils migrated vertically for hundreds of meters and accumulated in an overlying lithologic pool of the Es3^m, i.e., Ying 11 synclinal lithologic pool, which suggests that the mechanisms of migration and accumulation for subtle oil pools in the Dongying Depression are more complex than that of the previously expected.
文摘以中国矿业大学图书馆开展的ESI学科评估工作实践为例,阐述基于ESI和InCites数据库,用进入全球1%的学科、学者、高被引论文、热点论文等指标,对中国矿业大学的学科建设现状进行宏观分析,从文献分析的角度得出其学科发展现状,评价学科的优势与不足。首先是针对无法深入研究众多文献间的关联问题,建议将Histcite、Citespace以及Web of Science平台自带的引文分析工具作为ESI学科评估工具的辅助工具结合使用,以达到更深入全面的对学科建设进行分析,进而为高校的学科发展政策的制定提供可靠的依据,更为后期学科建设与发展提供参考,其次是对参与学科评估工作人员能力的要求,建议从加强培训方面给出相应的对策,并在提高学科评估工作人员能力的同时,根据各高校学科发展的情况与教师之间建立关系,为其日常的科学研究提供与学科相关的服务;最后是对以理工科为主的高校在学科建设发展中存在的弱势学科在文献资源缺乏的问题上提出应对措施。