Transmission electron microscopy (TEM) observations were carried out for examining the precipitation behavior in a Cu-Sn-Ni-Zn-P lead frame material. TEM observations revealed that the precipitate is hexagonal Ni5P2 a...Transmission electron microscopy (TEM) observations were carried out for examining the precipitation behavior in a Cu-Sn-Ni-Zn-P lead frame material. TEM observations revealed that the precipitate is hexagonal Ni5P2 and the orientation relationship between the Cu matrix and Ni$Pi precipitate is (111)fcc//(0001)hcp, [101]fcc//[1120]hcp, where the suffix fcc denotes the Cu matrix and hep denotes the hexagonal Ni5P2 precipitate. The Ni5P2 precipitate is ovoidal in shape at the beginning of aging at lower temperature. By prolonging the aging time or increasing the aging temperature, Ni5P2 precipitate grows and shows a rod-like shape. The Ni added Cu based lead frame material has a comparative mechanical properties with that of TAMAC15 which has been developed and used in electrical industry.展开更多
The Co3 Ti phase hardens appreciably by the fine precipitation of disordered fcc Co-rich phase upon aging after quenching from solution annealing temperature. Transmission electron microscope (TEM)observations reveale...The Co3 Ti phase hardens appreciably by the fine precipitation of disordered fcc Co-rich phase upon aging after quenching from solution annealing temperature. Transmission electron microscope (TEM)observations revealed that the precipitates are platelet in shape, lying nearly parallel to the {100} planes of the L12-ordered matrix, and perfectly coherent with the matrix lattice at the beginning of aging. The high temperature strength increases appreciably with the fine precipitation of disondered Co-rich phase over the whole temperature range investigated. TEM observations of the deformed alloys after underaging revealed that saperdislocations are pinned by precipitates indicating an attractive interaction between dislocations and precipitates.展开更多
基金support of the National Natural Science Foundation of China(Grant No.59971008).
文摘Transmission electron microscopy (TEM) observations were carried out for examining the precipitation behavior in a Cu-Sn-Ni-Zn-P lead frame material. TEM observations revealed that the precipitate is hexagonal Ni5P2 and the orientation relationship between the Cu matrix and Ni$Pi precipitate is (111)fcc//(0001)hcp, [101]fcc//[1120]hcp, where the suffix fcc denotes the Cu matrix and hep denotes the hexagonal Ni5P2 precipitate. The Ni5P2 precipitate is ovoidal in shape at the beginning of aging at lower temperature. By prolonging the aging time or increasing the aging temperature, Ni5P2 precipitate grows and shows a rod-like shape. The Ni added Cu based lead frame material has a comparative mechanical properties with that of TAMAC15 which has been developed and used in electrical industry.
文摘The Co3 Ti phase hardens appreciably by the fine precipitation of disordered fcc Co-rich phase upon aging after quenching from solution annealing temperature. Transmission electron microscope (TEM)observations revealed that the precipitates are platelet in shape, lying nearly parallel to the {100} planes of the L12-ordered matrix, and perfectly coherent with the matrix lattice at the beginning of aging. The high temperature strength increases appreciably with the fine precipitation of disondered Co-rich phase over the whole temperature range investigated. TEM observations of the deformed alloys after underaging revealed that saperdislocations are pinned by precipitates indicating an attractive interaction between dislocations and precipitates.