In recent years diamonds and other unusual minerals (carbides, nitrides, metal alloys and native elements) have been recovered from mantle peridotites and chromitites (both high-Cr chromitites and high-Al chromiti...In recent years diamonds and other unusual minerals (carbides, nitrides, metal alloys and native elements) have been recovered from mantle peridotites and chromitites (both high-Cr chromitites and high-Al chromitites) from a number of ophiolites of different ages and tectonic settings. Here we report a similar assemblage of minerals from the Skenderbeu massif of the Mirdita zone ophiolite, west Albania. So far, more than 20 grains of microdiamonds and 30 grains of moissanites (SIC) have been separated from the podiform chromitite. The diamonds are mostly light yellow, transparent, euhedral crystals, 200-300μm across, with a range of morphologies; some are octahedral and cuboctahedron and others are elongate and irregular. Secondary electron images show that some grains have well-developed striations. All the diamond grains have been analyzed and yielded typical Raman spectra with a shift at -1325 cm^-1. The moissanite grains recovered from the Skenderben chromitites are mainly light blue to dark blue, but some are yellow to light yellow. All the analyzed grains have typical Raman spectra with shifts at 766 cm^-1, 787 cm^-1, and 967 cm^-1. The energy spectrums of the moissanites confirm that the grains are composed entirely of silicon and carbon. This investigation expands the occurrence of diamonds and moissanites to Mesozoic ophiolites in the Neo-Tethys. Our new findings suggest that diamonds and moissanites are present, and probably ubiquitous in the oceanic mantle and can provide new perspectives and avenues for research on the origin of ophiolites and podiform chromitites.展开更多
GRV 020175 is an Antarctic mesosiderite,containing about 43 vol%silicates and 57 vol% metal.Metal occurs in a variety of textures from irregular large masses,to veins penetrating silicates, and to matrix fine grains.T...GRV 020175 is an Antarctic mesosiderite,containing about 43 vol%silicates and 57 vol% metal.Metal occurs in a variety of textures from irregular large masses,to veins penetrating silicates, and to matrix fine grains.The metallic portion contains kamacite,troilite and minor taenite.Terrestrial weathering is evident as partial replacement of the metal and troilite veins by Fe oxides.Silicate phases exhibit a porphyritic texture with pyroxene,plagioclase,minor silica and rare olivine phenocrysts embedded in a fine-grained groundmass.The matrix is ophitic and consists mainly of pyroxene and plagioclase grains.Some orthopyroxene phenocrysts occur as euhedral crystals with chemical zoning from a magnesian core to a ferroan overgrowth;others are characterized by many fine inclusions of plagioclase composition.Pigeonite has almost inverted to its orthopyroxene host with augite lamellae, enclosed by more magnesian rims.Olivine occurs as subhedral crystals,surrounded by a necklace of tiny chromite grains(about 2-3μm).Plagioclase has a heterogeneous composition without zoning. Pyroxene geothermometry of GRV 020175 gives a peak metamorphic temperature(~1000℃) and a closure temperature(~875℃).Molar Fe/Mn ratios(19-32) of pyroxenes are consistent with mesosiderite pyroxenes(16-35) and most plagioclase compositions(An_(87.5_96.6)) are within the range of mesosiderite plagioclase grains(An_(88-95)).Olivine composition(Fo_(53.8)) is only slightly lower than the range of olivine compositions in mesosiderites(Fo_(55-90)).All petrographic characteristics and chemical compositions of GRV 020175 are consistent with those of mesosiderite and based on its matrix texture and relatively abundant plagioclase,it can be further classified as a type 3A mesosiderite.Mineralogical, penological,and geochemical studies of GRV 020175 imply a complex formation history starting as rapid crystallization from a magma in a lava flow on the surface or as a shallow intrusion.Following primary igneous crystallization,the silicate underwent varying degrees of reheating.It was reheated to 1000℃,followed by rapid cooling to 875℃.Subsequently,metal mixed with silicate,during or after which,reduction of silicates occurred;the reducing agent is likely to have been sulfur.After redox reaction,the sample underwent thermal metamorphism,which produced the corona on the olivine, rims on the inverted pigeonite phenocrysts and overgrowths on the orthopyroxene phenocrysts,and homogenized matrix pyroxenes.Nevertheless,metamorphism was not extensive enough to completely reequilibrate the GRV 020175 materials.展开更多
1 Introduction The Wulong glomerophyric diorite porphyry has an extremely peculiar texture with plagioclase phenocrysts clustered as flower-like glomerocrysts(Figs.1a&b),which is never discovered elsewhere of the ...1 Introduction The Wulong glomerophyric diorite porphyry has an extremely peculiar texture with plagioclase phenocrysts clustered as flower-like glomerocrysts(Figs.1a&b),which is never discovered elsewhere of the world.The展开更多
There is a general consensus that most ophiolites formed above subduction zones(Pearce,2003),particularly during forearc extension at subduction initiation(Shervais,2001;Stern,2004;Whattam and Stern,2011).'Supra-S...There is a general consensus that most ophiolites formed above subduction zones(Pearce,2003),particularly during forearc extension at subduction initiation(Shervais,2001;Stern,2004;Whattam and Stern,2011).'Supra-Subduction zone'(SSZ)ophiolites such as the well-studied Tethyan ophiolites,generally display a characteristic sequential evolution from mid-oceanic ridge basalts(MORBs)to island arc tholeiities(IATs)or bonites(BONs)(Pearce,2003;Dilek and Furnes,2009,2011),which were generated in sequence from the decompression melting of asthenospheric mantle and partial melting of subduction-metasomatized depleted mantle(Stern and Bloomer,1992;Dilek and Furnes,2009;Whattam and Stern,2011).However,ophiolites with MORB and/or oceanic-island basalt(OIB)affinities are rare,and their origin and tectonic nature are poorly understood(Boedo et al.,2013;Saccani et al.,2013).It is interesting that the composition of these ophiolites from the central Tibetan Plateau(CTP)is dominated by MORBs and minor OIBs and a distinct lack of IATs and BONs,which is inconsistent with most ophiolites worldwide(Robinson and Zhou,2008;Zhang et al.,2008).But the generation and tectonic nature of these ophiolites are still controversial.*In this study,we present new geochronological,mineralogical and Sr-Nd isotopic data for the Chayong and Xiewu mafic complexes in the western Garzê-Litang suture zone(GLS),a typical Paleo-Tethyan suture crossing the CTP(Fig.1).The Triassic ophiolite in the western GLS has been described by Li et al.(2009),who foundthat it mainly consists of gabbros,diabases,pillow basalts and a few metamorphic peridotites.The ophiolite has been tectonically dismembered and crops out in Triassic clastic rocks and limestones as tectonic blocks.The Chayong and Xiewu mafic complexes are generally regarded as important fragments of the Triassic ophiolites(e.g.,Jin,2006;Li et al.,2009).Zircon LA-ICP-MS U-Pb ages of234±3 Ma and 236±2 Ma can be interpreted as formation times of the Chayong and Xiewu mafic complexes,respectively.The basalts and gabbros of the Chayong complexexhibitenrichedMORB(E-MORB)compositional affinities except for a weak depletion of Nb,Ta and Ti relative to the primitive mantle,whereas the basalts and gabbros of the Xiewu complex display distinct E-MORB and OIB affinities.The geochemical features suggest a probable fractionation of olivine±clinopyroxene±plagioclase as well as insignificant crustal contamination.The geochemical and Sr-Nd isotopic data reveal that the Chayong mafic rocks may have been derived from depleted MORB-type mantle metasomatized by crustal components and Xiewu mafic rocks from enriched lithosphericmantlemetasomatizedbyOIB-like components.The ratios of Zn/Fet,La/Yb and Sm/Yb indicate that these mafic melts were produced by the partial melting of garnet+minor spinel-bearing peridotite or spinel±minor garnet-bearing peridotite.We propose thatback-arcbasinspreadingassociated with OIB/seamount recycling had occurred in the western GLS at least since the Middle Triassic times,and the decompression melting of the depleted MORB-type asthenospheremantleandpartialmeltingof sub-continental lithosphere were metasomatized by plume-related melts,such as OIBs,which led to the generation of the Chayong and Xiewu mafic melts.展开更多
1 Introduction Scientific study of the geology and mineral resources in Sudan is rather limited.Jebel Dumbier is the first identified carbonatite-bearing alkaline complex in Sudanby El Sharkawi&El Raba’a in 1973....1 Introduction Scientific study of the geology and mineral resources in Sudan is rather limited.Jebel Dumbier is the first identified carbonatite-bearing alkaline complex in Sudanby El Sharkawi&El Raba’a in 1973.It is located in Northern Kordofan Province on the northeastern margin of the Nuba Mountains.The complex exposed as small展开更多
There is a general consensus that most ophiolites on the earth formed above a subduction zone and they often display a characteristic, sequential evolution of MORB to island arc tholeiities (IAT) to bonnites (Dilek...There is a general consensus that most ophiolites on the earth formed above a subduction zone and they often display a characteristic, sequential evolution of MORB to island arc tholeiities (IAT) to bonnites (Dilek et al., 2010, 2009; Pearce et al., 2003). However, ophiolites occurred in a continental margin are very rare and usually have more complicated, irregular components, such as N-MORB,展开更多
Zircon U-Pb ages of 163.8-100.4 Ma and 146.6-134.5 Ma are obtained for the granitoids from the Pearl River mouth basin, and from southern Guangdong Province, respectively. These new dating data accord well with the cr...Zircon U-Pb ages of 163.8-100.4 Ma and 146.6-134.5 Ma are obtained for the granitoids from the Pearl River mouth basin, and from southern Guangdong Province, respectively. These new dating data accord well with the crystallization ages of Yanshanian granitoids broadly in the Nanling. The active continental margin of South China, as revealed by a combination of zircon U-Pb data, underwent a key granitoid-dominated magmatism in 165-100 Ma. Its evolution varied temporally, and spatially, registering under control of the paleo-Pacific slab subduction. The granitoids that occurred in 165-150 Ma broadly from the South China Sea to the Nanling are preferably related to two settings from volcanic-arc to back-arc extension, respectively. The activities of Cretaceous granitoids migrated from the southeastern Guangdong (148-130 Ma) to the Pearl River Mouth basin (127-112 Ma), corresponding to the model of a retreating subduction. The subduction-related granitoid magmatism in South China continued until 108-97 Ma. A tectonic transformation from slab-subduction to extension should occur at -100 Ma.展开更多
Five Paleogene volcanics sampled from the northern South China Sea were analyzed via LA-ICP-MS zircon U-Pb dating, including basalt and andesite from Borehole SCSVI and volcanic agglomerate from Borehole SCSV2, respec...Five Paleogene volcanics sampled from the northern South China Sea were analyzed via LA-ICP-MS zircon U-Pb dating, including basalt and andesite from Borehole SCSVI and volcanic agglomerate from Borehole SCSV2, respectively. A total of 162 zircon U-Pb dates for them cover an age range from Neoarchean to Eocene, in which the pre-Paleocene data dominate. The Paleogene dates of 62.5±2.2 Ma and 42.1±2.9 Ma are associated with two igneous episodes prior to opening of South China Sea basin. Those pre-Paleocene zircons are inherited zircons mostly with magmatogenic oscillatory zones, and have REE features of crustal zircon. Zircon U-Pb dates of 2518-2481 Ma, 1933- 1724 Ma, and 1094-1040 Ma from the SCSV1 volcanics, and 2810-2718 Ma, 2458-2421 Ma, and 1850-993.4 Ma from the SCSV2 volcanics reveal part of Precambrian evolution of the northern South China Sea, well comparable with age records dated from the Cathaysia block. The data of 927.0±6.9 Ma and 781±38 Ma dated from the SCSV2 coincide with amalgamation between Yangtze and Cathaysia blocks and breakup of the Rodinia, respectively. The age records of Caledonian orogeny from the Cathaysia block are widely found from our volcanic samples with concordant mean ages of 432.0±5.8 Ma from the SCSV1 and of 437±15 Ma from the SCSV2. The part of the northern South China Sea resembling the Cathaysia underwent Indosinian and Yanshannian tectonothermal events. Their age signatures from the SCSV1 cover 266.5±3.5 Ma, 241.1±6.0 Ma, 184.0±4.2 Ma, 160.9±4.2 Ma and 102.8±2.6 Ma, and from the SCSV2 are 244±15 Ma, 158.1±3.5 Ma, 141±13 Ma and 96.3±2.1 Ma. Our pre-Paleogene U-Pb age spectra of zircons from the borehole volcanics indicate that the northern South China Sea underwent an evolution from formation of Precambrian basement, Caledonian orogeny, and Indosinian orogeny to Yanshannian magmatism. This process can be well comparable with the tectonic evolution of South China, largely supporting the areas of the northern South China Sea as part of southward extension of the Cathaysia.展开更多
Ophiolites are fragments of upper mantle and oceanic crust (Dewey and Bird, 1971; Coleman, 1977; Nicolas, 1989) that were consisting of mantle peridotites and a suite of magmatic rocks. Importantly,
Peridotites are an important part of ophiolites: they not only record plate tectonic settings and events, but also offer help to interpret the composition of the mantle and the effect of the deep mantle. The Yarlung-...Peridotites are an important part of ophiolites: they not only record plate tectonic settings and events, but also offer help to interpret the composition of the mantle and the effect of the deep mantle. The Yarlung-Zangbo suture zone extends more than 2000 km along southern Tibet,展开更多
The Huashanguan rapakivi pluton in Zhongxiang,Hubei Province,China,is the first discovered Proterozoic rapakivi pluton in the Yangtze block.Based on field and petrographical observations,a typical rapakivi texture was...The Huashanguan rapakivi pluton in Zhongxiang,Hubei Province,China,is the first discovered Proterozoic rapakivi pluton in the Yangtze block.Based on field and petrographical observations,a typical rapakivi texture was found in the northern portion of the Huashanguan granitic pluton.Almost all the K-feldspar phenocrysts were round to oval in shape and most had plagioclase coatings known as rapakivi phenocrysts.Alkali feldspars and quartz had two or more generations.Petrochemically,the Huashanguan rapakivi granites were characterized as having high values of Si,K,Fe,Th,U,La,Ga,Ce,Sm and LREE,low values of Ca,Mg,Sr,Nb,Y and HREE,and a negative Eu anomaly.These geochemical characteristics of the Huashanguan granites were concordant with typical rapakivi granites,and had an affinity to A-type granites.LA-ICP-MS U-Pb zircon dating also was conducted.The dating yielded a 207Pb/206Pb weighted mean age of 1851±18 Ma (MSWD =1.2),which represents the age of the pluton emplacement.The age of 803±170 Ma at the lower intercept in the concordia diagram corresponds to the age of a later deformation event which affected the pluton,and suggests that the Huashanguan pluton was influenced by Neoproterozoic thermo-tectonic events after its formation.The discovery of Paleoproterozoic Huashanguan rapakivi granites indicates continental rifting or a post-orogenic extensional event that took place in the Paleoproterozoic in the Yangtze block.These events may be related to the breakup of the Paleoproterozoic Columbia supercontinent.展开更多
The Ningzhen region in Jiangsu Province represents the easternmost magmatic region in the middle-lower Yangtze River belt.The formation of the polymetallic deposits has close genetic relationships with Early Cretaceou...The Ningzhen region in Jiangsu Province represents the easternmost magmatic region in the middle-lower Yangtze River belt.The formation of the polymetallic deposits has close genetic relationships with Early Cretaceous intermediate-acid intrusions.In this study,LA-ICP-MS zircon geochronology of two Mesozoic intermediate-acid intrusive rocks(including the Shima porphyritic granodiorite and Gaozi quartz diorite porphyry)in the Ningzhen region were systematically investigated.These new geochronological data demonstrate that the intermediate-acid magmatism in the Ningzhen region dates to approximately between 109 and101 Ma.We present new40Ar-39Ar phlogopite ages for the Cishantou skarn iron deposits that constrain the timing of the mineralisation in the Ningzhen region.The phlogopite in the Cishantou skarn deposits yielded a40Ar-39Ar plateau age of 104±1 Ma.This result coincides with the ages of the Anjishan and Tongshan Cu(Mo)deposits in the Ningzhen region.Our high-precision geochronological data together with recent high-precision geochronological studies(such as zircon LA-ICP-MS U-Pb,zircon SHRIMP U-Pb,molybdenite Re-Os and single-mineral40Ar-39Ar dates)reveal that there were four periods(152-135 Ma,135-127 Ma,127-121 Ma,109-101 Ma)of magmatism and ore formation in the middle-lower Yangtze River metallogenic belt.The Mesozoic intermediate-acid magmatism and mineralisation in the Ningzhen region belong to the latest episode in the middle-lower Yangtze River metallogenic belt.展开更多
SHRIMP U-Pb dating on magmatic zircons extracted from a riebeckite quartz syenite in the Huangyangshan pluton in Suizhou,the southern margin of Tongbai-Dabieshan yielded an age of 439±6Ma.According to the morphol...SHRIMP U-Pb dating on magmatic zircons extracted from a riebeckite quartz syenite in the Huangyangshan pluton in Suizhou,the southern margin of Tongbai-Dabieshan yielded an age of 439±6Ma.According to the morphology and high Th/U ratios of the zircons,the age is interpreted as crystallization timing of the pluton.The Huangyangshan pluton is composed of peralkaline quartz syenite,alkaline granite and syenite.All of the rocks are characterized by high agpaitic index(A.I.=(Na+K)/Al,molar ratio)and Fe-number[FeO_(T)/(FeO_(T)+MgO)],low CaO and MgO contents,enrichment of high field strength elements(i.e.Nb,Zr,Ga,Y,Hf)and light REEs,evidently negative Eu anomalies and high Ga/Al ratios,which are consistent with anorogenic A-type granitoids.Being part of the South Qinling-South Dabieshan Paleozoic alkaline rock belt,the Huangyangshan A-type granitoid pluton results from the Paleozoic extension-initial rifting in the northern margin of the Yangtze Craton related to the opening of the eastern Paleo-Tethyan Ocean.展开更多
Foliated garnet-bearing granite,usually associated with high pressure and ultrahigh-pressure(UHP) metamophic rocks,is a particular rock-type extensively exposed in the Mesozoic Dabie-Sulu orogenic belt of China.This s...Foliated garnet-bearing granite,usually associated with high pressure and ultrahigh-pressure(UHP) metamophic rocks,is a particular rock-type extensively exposed in the Mesozoic Dabie-Sulu orogenic belt of China.This study focuses on deformation features and SHRIMP zircon dating of foliated garnet granite in a high-pressure metamorphic unit from Huwan,western Dabie Mountains in order to resolve discrepancies in current versions of its petrogenesis and structural evolution.SHRIMP dating reveals a zircon age of 762 ± 15 Ma(MSWD=1.7) for Huwan granites,representing the Middle to Late Neoproterozoic age of intrusion and crystallization.Field and microstructural studies show that the Huwan granite body underwent multiple-stage deformation.The deformation was manifested by an early stage of rootless folding and imposition of relict foliation(S1);an Indosinian main stage marked by imposition of north-dipping penetrative gneissosity(S2) and development of ductile shear zones under NNE-SSW directed compression;and a final Indosinian stage of southward thrusting of the Huwan high-pressure unit.Shallow level extension prevailed after the Late Triassic,giving rise to south-dipping thrust faults and north-dipping normal faults.展开更多
基金funded by grants from the International Geoscicence Programme (IGCP 649,2015-2020)the National Natural Science Foundation of China(41541017,41641015)+2 种基金the Ministry of Science and Technology of China(2014DFR21270)China Geological Survey(12120115026801,12120115027201, 201511022,DD20160023-01)the Fund from the State Key Laboratory of Continental Tectonics and Dynamics (Z1301-a20 and K201502)
文摘In recent years diamonds and other unusual minerals (carbides, nitrides, metal alloys and native elements) have been recovered from mantle peridotites and chromitites (both high-Cr chromitites and high-Al chromitites) from a number of ophiolites of different ages and tectonic settings. Here we report a similar assemblage of minerals from the Skenderbeu massif of the Mirdita zone ophiolite, west Albania. So far, more than 20 grains of microdiamonds and 30 grains of moissanites (SIC) have been separated from the podiform chromitite. The diamonds are mostly light yellow, transparent, euhedral crystals, 200-300μm across, with a range of morphologies; some are octahedral and cuboctahedron and others are elongate and irregular. Secondary electron images show that some grains have well-developed striations. All the diamond grains have been analyzed and yielded typical Raman spectra with a shift at -1325 cm^-1. The moissanite grains recovered from the Skenderben chromitites are mainly light blue to dark blue, but some are yellow to light yellow. All the analyzed grains have typical Raman spectra with shifts at 766 cm^-1, 787 cm^-1, and 967 cm^-1. The energy spectrums of the moissanites confirm that the grains are composed entirely of silicon and carbon. This investigation expands the occurrence of diamonds and moissanites to Mesozoic ophiolites in the Neo-Tethys. Our new findings suggest that diamonds and moissanites are present, and probably ubiquitous in the oceanic mantle and can provide new perspectives and avenues for research on the origin of ophiolites and podiform chromitites.
基金The sample of GRV 020175 was provided by the Polar Research Institute of Chinasupported by China Ministry of Science and Technology(Grant No. 2005DKA21406)+1 种基金the National Natural Science Foundation of China(Grant Nos.10621303 and 40773046)the Minor Planet Foundation of China.
文摘GRV 020175 is an Antarctic mesosiderite,containing about 43 vol%silicates and 57 vol% metal.Metal occurs in a variety of textures from irregular large masses,to veins penetrating silicates, and to matrix fine grains.The metallic portion contains kamacite,troilite and minor taenite.Terrestrial weathering is evident as partial replacement of the metal and troilite veins by Fe oxides.Silicate phases exhibit a porphyritic texture with pyroxene,plagioclase,minor silica and rare olivine phenocrysts embedded in a fine-grained groundmass.The matrix is ophitic and consists mainly of pyroxene and plagioclase grains.Some orthopyroxene phenocrysts occur as euhedral crystals with chemical zoning from a magnesian core to a ferroan overgrowth;others are characterized by many fine inclusions of plagioclase composition.Pigeonite has almost inverted to its orthopyroxene host with augite lamellae, enclosed by more magnesian rims.Olivine occurs as subhedral crystals,surrounded by a necklace of tiny chromite grains(about 2-3μm).Plagioclase has a heterogeneous composition without zoning. Pyroxene geothermometry of GRV 020175 gives a peak metamorphic temperature(~1000℃) and a closure temperature(~875℃).Molar Fe/Mn ratios(19-32) of pyroxenes are consistent with mesosiderite pyroxenes(16-35) and most plagioclase compositions(An_(87.5_96.6)) are within the range of mesosiderite plagioclase grains(An_(88-95)).Olivine composition(Fo_(53.8)) is only slightly lower than the range of olivine compositions in mesosiderites(Fo_(55-90)).All petrographic characteristics and chemical compositions of GRV 020175 are consistent with those of mesosiderite and based on its matrix texture and relatively abundant plagioclase,it can be further classified as a type 3A mesosiderite.Mineralogical, penological,and geochemical studies of GRV 020175 imply a complex formation history starting as rapid crystallization from a magma in a lava flow on the surface or as a shallow intrusion.Following primary igneous crystallization,the silicate underwent varying degrees of reheating.It was reheated to 1000℃,followed by rapid cooling to 875℃.Subsequently,metal mixed with silicate,during or after which,reduction of silicates occurred;the reducing agent is likely to have been sulfur.After redox reaction,the sample underwent thermal metamorphism,which produced the corona on the olivine, rims on the inverted pigeonite phenocrysts and overgrowths on the orthopyroxene phenocrysts,and homogenized matrix pyroxenes.Nevertheless,metamorphism was not extensive enough to completely reequilibrate the GRV 020175 materials.
基金financially supported by the National Natural Science Foundation of China(No.41502046,41530211 and 41272079)
文摘1 Introduction The Wulong glomerophyric diorite porphyry has an extremely peculiar texture with plagioclase phenocrysts clustered as flower-like glomerocrysts(Figs.1a&b),which is never discovered elsewhere of the world.The
基金financially supported by the National Nature Science Foundation of China (Grant 41272079)
文摘There is a general consensus that most ophiolites formed above subduction zones(Pearce,2003),particularly during forearc extension at subduction initiation(Shervais,2001;Stern,2004;Whattam and Stern,2011).'Supra-Subduction zone'(SSZ)ophiolites such as the well-studied Tethyan ophiolites,generally display a characteristic sequential evolution from mid-oceanic ridge basalts(MORBs)to island arc tholeiities(IATs)or bonites(BONs)(Pearce,2003;Dilek and Furnes,2009,2011),which were generated in sequence from the decompression melting of asthenospheric mantle and partial melting of subduction-metasomatized depleted mantle(Stern and Bloomer,1992;Dilek and Furnes,2009;Whattam and Stern,2011).However,ophiolites with MORB and/or oceanic-island basalt(OIB)affinities are rare,and their origin and tectonic nature are poorly understood(Boedo et al.,2013;Saccani et al.,2013).It is interesting that the composition of these ophiolites from the central Tibetan Plateau(CTP)is dominated by MORBs and minor OIBs and a distinct lack of IATs and BONs,which is inconsistent with most ophiolites worldwide(Robinson and Zhou,2008;Zhang et al.,2008).But the generation and tectonic nature of these ophiolites are still controversial.*In this study,we present new geochronological,mineralogical and Sr-Nd isotopic data for the Chayong and Xiewu mafic complexes in the western Garzê-Litang suture zone(GLS),a typical Paleo-Tethyan suture crossing the CTP(Fig.1).The Triassic ophiolite in the western GLS has been described by Li et al.(2009),who foundthat it mainly consists of gabbros,diabases,pillow basalts and a few metamorphic peridotites.The ophiolite has been tectonically dismembered and crops out in Triassic clastic rocks and limestones as tectonic blocks.The Chayong and Xiewu mafic complexes are generally regarded as important fragments of the Triassic ophiolites(e.g.,Jin,2006;Li et al.,2009).Zircon LA-ICP-MS U-Pb ages of234±3 Ma and 236±2 Ma can be interpreted as formation times of the Chayong and Xiewu mafic complexes,respectively.The basalts and gabbros of the Chayong complexexhibitenrichedMORB(E-MORB)compositional affinities except for a weak depletion of Nb,Ta and Ti relative to the primitive mantle,whereas the basalts and gabbros of the Xiewu complex display distinct E-MORB and OIB affinities.The geochemical features suggest a probable fractionation of olivine±clinopyroxene±plagioclase as well as insignificant crustal contamination.The geochemical and Sr-Nd isotopic data reveal that the Chayong mafic rocks may have been derived from depleted MORB-type mantle metasomatized by crustal components and Xiewu mafic rocks from enriched lithosphericmantlemetasomatizedbyOIB-like components.The ratios of Zn/Fet,La/Yb and Sm/Yb indicate that these mafic melts were produced by the partial melting of garnet+minor spinel-bearing peridotite or spinel±minor garnet-bearing peridotite.We propose thatback-arcbasinspreadingassociated with OIB/seamount recycling had occurred in the western GLS at least since the Middle Triassic times,and the decompression melting of the depleted MORB-type asthenospheremantleandpartialmeltingof sub-continental lithosphere were metasomatized by plume-related melts,such as OIBs,which led to the generation of the Chayong and Xiewu mafic melts.
基金The National Natural Science Foundation of China (41502046, 41272081,41530211)the Fundamental Research Funds for the Central Universities (CUG150611) are acknowledged for financial support
文摘1 Introduction Scientific study of the geology and mineral resources in Sudan is rather limited.Jebel Dumbier is the first identified carbonatite-bearing alkaline complex in Sudanby El Sharkawi&El Raba’a in 1973.It is located in Northern Kordofan Province on the northeastern margin of the Nuba Mountains.The complex exposed as small
文摘There is a general consensus that most ophiolites on the earth formed above a subduction zone and they often display a characteristic, sequential evolution of MORB to island arc tholeiities (IAT) to bonnites (Dilek et al., 2010, 2009; Pearce et al., 2003). However, ophiolites occurred in a continental margin are very rare and usually have more complicated, irregular components, such as N-MORB,
基金supported by the State Key Program of the National Natural Science of China(grant no2008ZX05023-003)the project of the State Key Laboratory of Marine Geology(grant noMG200904)the National Natural Science Foundation of China (grant no40872138)
文摘Zircon U-Pb ages of 163.8-100.4 Ma and 146.6-134.5 Ma are obtained for the granitoids from the Pearl River mouth basin, and from southern Guangdong Province, respectively. These new dating data accord well with the crystallization ages of Yanshanian granitoids broadly in the Nanling. The active continental margin of South China, as revealed by a combination of zircon U-Pb data, underwent a key granitoid-dominated magmatism in 165-100 Ma. Its evolution varied temporally, and spatially, registering under control of the paleo-Pacific slab subduction. The granitoids that occurred in 165-150 Ma broadly from the South China Sea to the Nanling are preferably related to two settings from volcanic-arc to back-arc extension, respectively. The activities of Cretaceous granitoids migrated from the southeastern Guangdong (148-130 Ma) to the Pearl River Mouth basin (127-112 Ma), corresponding to the model of a retreating subduction. The subduction-related granitoid magmatism in South China continued until 108-97 Ma. A tectonic transformation from slab-subduction to extension should occur at -100 Ma.
基金supported by the National Natural Science Foundation of China (grant no. 41272218)the Fundamental Research Funds for the Central Universitiesthe State Key Program of the National Natural Science of China (grant no. 2011ZX05023-003)
文摘Five Paleogene volcanics sampled from the northern South China Sea were analyzed via LA-ICP-MS zircon U-Pb dating, including basalt and andesite from Borehole SCSVI and volcanic agglomerate from Borehole SCSV2, respectively. A total of 162 zircon U-Pb dates for them cover an age range from Neoarchean to Eocene, in which the pre-Paleocene data dominate. The Paleogene dates of 62.5±2.2 Ma and 42.1±2.9 Ma are associated with two igneous episodes prior to opening of South China Sea basin. Those pre-Paleocene zircons are inherited zircons mostly with magmatogenic oscillatory zones, and have REE features of crustal zircon. Zircon U-Pb dates of 2518-2481 Ma, 1933- 1724 Ma, and 1094-1040 Ma from the SCSV1 volcanics, and 2810-2718 Ma, 2458-2421 Ma, and 1850-993.4 Ma from the SCSV2 volcanics reveal part of Precambrian evolution of the northern South China Sea, well comparable with age records dated from the Cathaysia block. The data of 927.0±6.9 Ma and 781±38 Ma dated from the SCSV2 coincide with amalgamation between Yangtze and Cathaysia blocks and breakup of the Rodinia, respectively. The age records of Caledonian orogeny from the Cathaysia block are widely found from our volcanic samples with concordant mean ages of 432.0±5.8 Ma from the SCSV1 and of 437±15 Ma from the SCSV2. The part of the northern South China Sea resembling the Cathaysia underwent Indosinian and Yanshannian tectonothermal events. Their age signatures from the SCSV1 cover 266.5±3.5 Ma, 241.1±6.0 Ma, 184.0±4.2 Ma, 160.9±4.2 Ma and 102.8±2.6 Ma, and from the SCSV2 are 244±15 Ma, 158.1±3.5 Ma, 141±13 Ma and 96.3±2.1 Ma. Our pre-Paleogene U-Pb age spectra of zircons from the borehole volcanics indicate that the northern South China Sea underwent an evolution from formation of Precambrian basement, Caledonian orogeny, and Indosinian orogeny to Yanshannian magmatism. This process can be well comparable with the tectonic evolution of South China, largely supporting the areas of the northern South China Sea as part of southward extension of the Cathaysia.
文摘Ophiolites are fragments of upper mantle and oceanic crust (Dewey and Bird, 1971; Coleman, 1977; Nicolas, 1989) that were consisting of mantle peridotites and a suite of magmatic rocks. Importantly,
基金supported by grants from the Ministry of Science and Technology of China (2014DFR21270)China Geological Survey (12120115026801, 12120115027201, 201511022)the Fund from the State Key Laboratory of Continental Tectonics and Dynamics (Z1301-a20)
文摘Peridotites are an important part of ophiolites: they not only record plate tectonic settings and events, but also offer help to interpret the composition of the mantle and the effect of the deep mantle. The Yarlung-Zangbo suture zone extends more than 2000 km along southern Tibet,
基金supported by the International Cooperation Project of the Ministry of Science and Technology of China (2007DFA21230)the Natural Science Foundation of Hubei Province (2009CDA004)+2 种基金the National Training Foundation of Geological Science Base (J083520)the National Innovation Experiment Program for University Students (1320311009)part of a Higher Education Key Project of Hubei Province (2009108)
文摘The Huashanguan rapakivi pluton in Zhongxiang,Hubei Province,China,is the first discovered Proterozoic rapakivi pluton in the Yangtze block.Based on field and petrographical observations,a typical rapakivi texture was found in the northern portion of the Huashanguan granitic pluton.Almost all the K-feldspar phenocrysts were round to oval in shape and most had plagioclase coatings known as rapakivi phenocrysts.Alkali feldspars and quartz had two or more generations.Petrochemically,the Huashanguan rapakivi granites were characterized as having high values of Si,K,Fe,Th,U,La,Ga,Ce,Sm and LREE,low values of Ca,Mg,Sr,Nb,Y and HREE,and a negative Eu anomaly.These geochemical characteristics of the Huashanguan granites were concordant with typical rapakivi granites,and had an affinity to A-type granites.LA-ICP-MS U-Pb zircon dating also was conducted.The dating yielded a 207Pb/206Pb weighted mean age of 1851±18 Ma (MSWD =1.2),which represents the age of the pluton emplacement.The age of 803±170 Ma at the lower intercept in the concordia diagram corresponds to the age of a later deformation event which affected the pluton,and suggests that the Huashanguan pluton was influenced by Neoproterozoic thermo-tectonic events after its formation.The discovery of Paleoproterozoic Huashanguan rapakivi granites indicates continental rifting or a post-orogenic extensional event that took place in the Paleoproterozoic in the Yangtze block.These events may be related to the breakup of the Paleoproterozoic Columbia supercontinent.
基金supported by the National Key Basic Research Program of China(2012CB416800)the Key International Science and Technology Cooperation project(2007DFA21230)
文摘The Ningzhen region in Jiangsu Province represents the easternmost magmatic region in the middle-lower Yangtze River belt.The formation of the polymetallic deposits has close genetic relationships with Early Cretaceous intermediate-acid intrusions.In this study,LA-ICP-MS zircon geochronology of two Mesozoic intermediate-acid intrusive rocks(including the Shima porphyritic granodiorite and Gaozi quartz diorite porphyry)in the Ningzhen region were systematically investigated.These new geochronological data demonstrate that the intermediate-acid magmatism in the Ningzhen region dates to approximately between 109 and101 Ma.We present new40Ar-39Ar phlogopite ages for the Cishantou skarn iron deposits that constrain the timing of the mineralisation in the Ningzhen region.The phlogopite in the Cishantou skarn deposits yielded a40Ar-39Ar plateau age of 104±1 Ma.This result coincides with the ages of the Anjishan and Tongshan Cu(Mo)deposits in the Ningzhen region.Our high-precision geochronological data together with recent high-precision geochronological studies(such as zircon LA-ICP-MS U-Pb,zircon SHRIMP U-Pb,molybdenite Re-Os and single-mineral40Ar-39Ar dates)reveal that there were four periods(152-135 Ma,135-127 Ma,127-121 Ma,109-101 Ma)of magmatism and ore formation in the middle-lower Yangtze River metallogenic belt.The Mesozoic intermediate-acid magmatism and mineralisation in the Ningzhen region belong to the latest episode in the middle-lower Yangtze River metallogenic belt.
基金the National Natural Science Foundation of China(Grant No.40334037)the Besearch Fumd for the Doctoral Program of Higher Education(Grant No.20010491018).
文摘SHRIMP U-Pb dating on magmatic zircons extracted from a riebeckite quartz syenite in the Huangyangshan pluton in Suizhou,the southern margin of Tongbai-Dabieshan yielded an age of 439±6Ma.According to the morphology and high Th/U ratios of the zircons,the age is interpreted as crystallization timing of the pluton.The Huangyangshan pluton is composed of peralkaline quartz syenite,alkaline granite and syenite.All of the rocks are characterized by high agpaitic index(A.I.=(Na+K)/Al,molar ratio)and Fe-number[FeO_(T)/(FeO_(T)+MgO)],low CaO and MgO contents,enrichment of high field strength elements(i.e.Nb,Zr,Ga,Y,Hf)and light REEs,evidently negative Eu anomalies and high Ga/Al ratios,which are consistent with anorogenic A-type granitoids.Being part of the South Qinling-South Dabieshan Paleozoic alkaline rock belt,the Huangyangshan A-type granitoid pluton results from the Paleozoic extension-initial rifting in the northern margin of the Yangtze Craton related to the opening of the eastern Paleo-Tethyan Ocean.
基金Supported by the National Natural Science Foundation of China (Grant Nos.40802046 and 40334037)the Project of Science & Technology Research and Development from Sinopec (Grant No.P02009)
文摘Foliated garnet-bearing granite,usually associated with high pressure and ultrahigh-pressure(UHP) metamophic rocks,is a particular rock-type extensively exposed in the Mesozoic Dabie-Sulu orogenic belt of China.This study focuses on deformation features and SHRIMP zircon dating of foliated garnet granite in a high-pressure metamorphic unit from Huwan,western Dabie Mountains in order to resolve discrepancies in current versions of its petrogenesis and structural evolution.SHRIMP dating reveals a zircon age of 762 ± 15 Ma(MSWD=1.7) for Huwan granites,representing the Middle to Late Neoproterozoic age of intrusion and crystallization.Field and microstructural studies show that the Huwan granite body underwent multiple-stage deformation.The deformation was manifested by an early stage of rootless folding and imposition of relict foliation(S1);an Indosinian main stage marked by imposition of north-dipping penetrative gneissosity(S2) and development of ductile shear zones under NNE-SSW directed compression;and a final Indosinian stage of southward thrusting of the Huwan high-pressure unit.Shallow level extension prevailed after the Late Triassic,giving rise to south-dipping thrust faults and north-dipping normal faults.