Ribbon-like Cu doped V6O(13) was synthesized via a simple solvothermal approach followed by heat treatment in air.As an cathode material for lithium ion battery,the ribbon-like Cu doped V6O(13 )electrode exhibited...Ribbon-like Cu doped V6O(13) was synthesized via a simple solvothermal approach followed by heat treatment in air.As an cathode material for lithium ion battery,the ribbon-like Cu doped V6O(13 )electrode exhibited good capacity retention with a reversible capacity of over 313 m Ah·g^-1 for up to 50 cycles at 0.1C,as well as a high charge capacity of 306 m Ah·g^-1 at a high current rate of 1 C,in comparison to undoped V6O(13 )electrode(267 m Ah·g^-1 at 0.1C and 273 m Ah·g^-1 at 1 C).The high rate capability and better cycleability of the doped electrode can be attributed to the influence of the Cu ions on the mophology and the electronic conductivity of V6O(13) during the lithiation and delithiation process.展开更多
Series Bi3NbO7/Bi2Zn(2/3)Nb(4/3)O7 (BN/BZN) composites were synthesized through a facile solid state reaction method. The products were characterized by X-ray diffraction(XRD), field emission scanning electron...Series Bi3NbO7/Bi2Zn(2/3)Nb(4/3)O7 (BN/BZN) composites were synthesized through a facile solid state reaction method. The products were characterized by X-ray diffraction(XRD), field emission scanning electron microscopy(FE-SEM) and UV-vis diffuse reflectance spectroscopy(DRS). When BN: BZN=0.1 mole ratio, the BN/BZN composite showed the best visible-light-driven photocatalytic performance, which decomposed nearly 100% of Rh B(10 ppm, p H=3-4) within 40 min. The results demonstrated that in-situ solid state synthesis of BN/BZN composites could be an efficient strategy to develop new photocatalyst for environmental remediation.展开更多
基金Funded by the Program for New Century Excellent Talents in University of Ministry of Education,(No.NCET-12-0655)the Guangxi Natural Science Foundation(No.2014GXNSFFA118004)
文摘Ribbon-like Cu doped V6O(13) was synthesized via a simple solvothermal approach followed by heat treatment in air.As an cathode material for lithium ion battery,the ribbon-like Cu doped V6O(13 )electrode exhibited good capacity retention with a reversible capacity of over 313 m Ah·g^-1 for up to 50 cycles at 0.1C,as well as a high charge capacity of 306 m Ah·g^-1 at a high current rate of 1 C,in comparison to undoped V6O(13 )electrode(267 m Ah·g^-1 at 0.1C and 273 m Ah·g^-1 at 1 C).The high rate capability and better cycleability of the doped electrode can be attributed to the influence of the Cu ions on the mophology and the electronic conductivity of V6O(13) during the lithiation and delithiation process.
基金Funded by the National Natural Science Foundation of China(No.51662005)the Guangxi Natural Science Foundation(No.2014GXNSFFA118004)
文摘Series Bi3NbO7/Bi2Zn(2/3)Nb(4/3)O7 (BN/BZN) composites were synthesized through a facile solid state reaction method. The products were characterized by X-ray diffraction(XRD), field emission scanning electron microscopy(FE-SEM) and UV-vis diffuse reflectance spectroscopy(DRS). When BN: BZN=0.1 mole ratio, the BN/BZN composite showed the best visible-light-driven photocatalytic performance, which decomposed nearly 100% of Rh B(10 ppm, p H=3-4) within 40 min. The results demonstrated that in-situ solid state synthesis of BN/BZN composites could be an efficient strategy to develop new photocatalyst for environmental remediation.