Valence electronic engineering of superhydrophilic Dy-evoked Ni-MOF outperforming RuO_(2) for highly efficient electrocatalytic oxygen evolution

Tackling the problem of poor conductivity and catalytic stability of pristine metal-organic frameworks(MOFs) is crucial to improve their oxygen evolution reaction(OER) performance.Herein,we introduce a novel strategy of dysprosium(Dy) doping,using the unique 4f orbitals of this rare earth element to enhance electrocatalytic activity of MOFs.Our method involves constructing Dy-doped Ni-MOF(Dy@Ni-MOF) nanoneedles on carbon cloth via a Dy-induced valence electronic perturbation approach.Experiments and density functional theory(DFT) calculations reveal that Dy doping can effectively modify the electronic structure of the Ni active centers and foster a strong electronic interaction between Ni and Dy.The resulting benefits include a reduced work function and a closer proximity of the d-band center to the Fermi level,which is conducive to improving electrical conductivity and promoting the adsorption of oxygen-containing intermediates.Furthermore,the Dy@Ni-MOF achieves superhydrophilicity,ensuring effective electrolyte contact and thus accelerating reaction kinetics,Ex-situ and in-situ analysis results manifest Dy_(2)O_(3)/NiOOH as the actual active species.Therefore,Dy@Ni-MOF shows impressive OER performance,significantly surpassing Ni-MOF.Besides,the overall water splitting device with Dy@NiMOF as an anode delivers a low cell voltage of 1.51 V at 10 mA cm^(-2) and demonstrates long-term stability for 100 h,positioning it as a promising substitute for precious metal catalysts.

Teaching Reform Based on the Competency Model for Software Engineering-related Courses

This paper explores the reform and practice of software engineering-related courses based on the competency model of the Computing Curricula,and proposes some measures of teaching reform and talent cultivation in software engineering.The teaching reform emphasizes student-centered education,and focuses on the cultivation and enhancement of students’knowledge,skills,and dispositions.Based on the three elements of the competency model,specific measures of teaching reform are proposed for some professional courses in software engineering,to strengthen course relevance,improve knowledge systems,reform practical modes with a focus on skill development,and cultivate good dispositions through student-centered education.The teaching reform’s attempts and practice are conducted in some courses such as Advanced Web Technologies,Software Engineering,and Intelligent Terminal Systems and Application Development.Through the analysis and comparison of the implementation effects,significant improvements are observed in teaching effectiveness,students’mastery of knowledge and skills are noticeably improved,and the expected goals of the teaching reform are achieved.