Stress-corrosion coupled damage localization induced by secondary phases in bio-degradable Mg alloys:phase-field modeling

In this study,a phase-field scheme that rigorously obeys conservation laws and irreversible thermodynamics is developed for modeling stress-corrosion coupled damage(SCCD).The coupling constitutive relationships of the deformation,phase-field damage,mass transfer,and electrostatic field are derived from the entropy inequality.The SCCD localization induced by secondary phases in Mg is numerically simulated using the implicit iterative algorithm of the self-defined finite elements.The quantitative evaluation of the SCCD of a C-ring is in good agreement with the experimental results.To capture the damage localization,a micro-galvanic corrosion domain is defined,and the buffering effect on charge migration is explored.Three cases are investigated to reveal the effect of localization on corrosion acceleration and provide guidance for the design for resistance to SCCD at the crystal scale.

Fully Recyclable Liquid Metal-Based Ultra-St retch able Electronics Enabled by Water-Modulation-Degradation-Reconstruction Polymer-Gel

The rapid development of stretchable electronics made by circuits,microchips,and encapsulation elastomers has caused the production of a large amount of electronic waste(e-waste).The degradation of elastomers can highly minimize the negative effects of e-wastes.However,chemicals that included acid,alkali,and organics were repeatedly used during the recycling process,which were environmentally unfriendly.Here,a water-modulation-degradation-reconstruction(WDR)polyvinylpyrrolidone(PVP)-honey composite(PHC)polymer-gel was developed and could be regarded as encapsulation elastomers to realize a fully recyclable water-degradable stretchable(WS)electronics with multi-functions.The stretchability of the PHC polymer-gel could be modulated by the change of its water retention.The Chip-integrated liquid metal(LM)circuits encapsulated with the modulated PHC encapsulation elastomer could withstand a strain value of~3000%.Moreover,we developed a WS biomedical sensor composed of PHC encapsulation elastomer,LM circuits,and microchips,which could be fully recycled by biodegrading it in water to reconstruct a new one.As before,the reconstructed WS biomedical sensor could still simultaneously realize the combination of ultra-stretchability,recycling,self-healing,self-adhesive,and self-conformal abilities.The results revealed that this study exercises a profound influence on the rational design of multi-functional WS electronics.

CAS-ESM2.0 Successfully Reproduces Historical Atmospheric CO_(2) in a Coupled Carbon−Climate Simulation

The atmospheric carbon dioxide(CO_(2))concentration has been increasing rapidly since the Industrial Revolution,which has led to unequivocal global warming and crucial environmental change.It is extremely important to investigate the interactions among atmospheric CO_(2),the physical climate system,and the carbon cycle of the underlying surface for a better understanding of the Earth system.Earth system models are widely used to investigate these interactions via coupled carbon-climate simulations.The Chinese Academy of Sciences Earth System Model version 2(CAS-ESM2.0)has successfully fixed a two-way coupling of atmospheric CO_(2)with the climate and carbon cycle on land and in the ocean.Using CAS-ESM2.0,we conducted a coupled carbon-climate simulation by following the CMIP6 proposal of a historical emissions-driven experiment.This paper examines the modeled CO_(2)by comparison with observed CO_(2)at the sites of Mauna Loa and Barrow,and the Greenhouse Gases Observing Satellite(GOSAT)CO_(2)product.The results showed that CAS-ESM2.0 agrees very well with observations in reproducing the increasing trend of annual CO_(2)during the period 1850-2014,and in capturing the seasonal cycle of CO_(2)at the two baseline sites,as well as over northern high latitudes.These agreements illustrate a good ability of CAS-ESM2.0 in simulating carbon-climate interactions,even though uncertainties remain in the processes involved.This paper reports an important stage of the development of CAS-ESM with the coupling of carbon and climate,which will provide significant scientific support for climate research and China’s goal of carbon neutrality.

Electronic Transport Properties of Transition-Metal Terminated Trigonal Graphene Nanoribbons

With the non-equilibrium Green’s function method and density functional theory, we have studied the electronic properties of trigonal graphene nanoribbons, with Fe terminal and H terminal, coupled to gold electrodes. Rectification behavior can be observed when the electrode-molecule contact distance is larger than 2.2 &Aring. The electronic transport is greatly improved in case of Fe terminal which is analyzed in terms of transmission spectra and density of states.

双亲性聚合物稠油降黏剂的合成及降黏性能

采用具有疏水结构的丁苯烯(PB)和具有亲水结构的丙烯酰胺(AM)、丙烯酸(AA)、2-丙烯酰胺-2甲基丙磺酸(AMPS)合成双亲性聚合物。聚合物链中的苯环结构可嵌进稠油沥青质的板结结构中,进入稠油内部聚合物链上的亲水基团可促进O/W乳状液的形成,进而降低稠油黏度。聚合物的红外光谱、热重分析、凝胶渗透色谱结果表明,单体AM,AA,AMPS和PB均参与了共聚,较高的热解温度(250℃)保证了降黏剂的热稳定性,较低的相对分子质量(8×10^4~10×10^4)之间有利于降黏剂进入到稠油的“内部”。以绥中36-1脱气稠油(SZ)和江汉油区八面河稠油(BMH)为降黏处理对象,降黏剂在一定条件下(70℃,质量分数为0.5%和0.6%),降黏率分别为86.14%和83.85%,表明双亲性聚合物具有优良的降黏效果,且在一定条件下(70℃,质量分数0.5%),降低油水体积比(低于6∶4)可有效提高降黏效果。

基于不同水溶性聚合物制备的绒囊流体的性能特征

为揭示采用不同水溶性聚合物制备的绒囊流体性能特征,制备出具有优良耐酸性的高性能绒囊工作液。分别采用羟乙基纤维素(HEC)、羧甲基纤维素(CMC)、羟乙基淀粉(HES)、羧甲基淀粉(CMS)与非离子型表面活性剂制备了一系列绒囊流体,并研究所得绒囊流体的流变性能,考察了氯化钠、盐酸和温度对绒囊流体性能的影响。通过六速旋转黏度计测定绒囊流体流变性能可知,采用不同水溶性聚合物制备的绒囊流体的几种性能有明显差异。不同水溶性聚合物制备的绒囊流体表观黏度大小顺序为HEC>CMC>CMS>HES,剪切稀释能力大小顺序为HES>CMS>HEC>CMC;不同水溶性聚合物制备的绒囊流体抗盐性能顺序为HEC>HES>CMS>CMC;不同绒囊流体相应耐酸性顺序为HEC>HES>CMC>CMS;采用旋转流变仪测定绒囊流体的黏度与温度的变化关系可知,不同绒囊流体的黏度与温度之间呈现各自特有的变化关系,绒囊流体耐温性能顺序为HEC>HES>CMS>CMC;对比来看,采用HEC可制备出具有优良耐温耐酸抗盐性能的绒囊流体。

CAS FGOALS-f3-L Model Datasets for CMIP6 Historical Atmospheric Model Intercomparison Project Simulation

The outputs of the Chinese Academy of Sciences(CAS) Flexible Global Ocean–Atmosphere–Land System(FGOALS-f3-L) model for the baseline experiment of the Atmospheric Model Intercomparison Project simulation in the Diagnostic,Evaluation and Characterization of Klima common experiments of phase 6 of the Coupled Model Intercomparison Project(CMIP6) are described in this paper. The CAS FGOALS-f3-L model, experiment settings, and outputs are all given. In total,there are three ensemble experiments over the period 1979–2014, which are performed with different initial states. The model outputs contain a total of 37 variables and include the required three-hourly mean, six-hourly transient, daily and monthly mean datasets. The baseline performances of the model are validated at different time scales. The preliminary evaluation suggests that the CAS FGOALS-f3-L model can capture the basic patterns of atmospheric circulation and precipitation well, including the propagation of the Madden–Julian Oscillation, activities of tropical cyclones, and the characterization of extreme precipitation. These datasets contribute to the benchmark of current model behaviors for the desired continuity of CMIP.

Evaluation of the New Dynamic Global Vegetation Model in CAS-ESM

In the past several decades, dynamic global vegetation models（DGVMs） have been the most widely used and appropriate tool at the global scale to investigate vegetation-climate interactions. At the Institute of Atmospheric Physics, a new version of DGVM（IAP-DGVM） has been developed and coupled to the Common Land Model（CoLM） within the framework of the Chinese Academy of Sciences＇ Earth System Model（CAS-ESM）. This work reports the performance of IAP-DGVM through comparisons with that of the default DGVM of CoLM（CoLM-DGVM） and observations. With respect to CoLMDGVM, IAP-DGVM simulated fewer tropical trees, more ＂needleleaf evergreen boreal tree＂ and ＂broadleaf deciduous boreal shrub＂, and a better representation of grasses. These contributed to a more realistic vegetation distribution in IAP-DGVM,including spatial patterns, total areas, and compositions. Moreover, IAP-DGVM also produced more accurate carbon fluxes than CoLM-DGVM when compared with observational estimates. Gross primary productivity and net primary production in IAP-DGVM were in better agreement with observations than those of CoLM-DGVM, and the tropical pattern of fire carbon emissions in IAP-DGVM was much more consistent with the observation than that in CoLM-DGVM. The leaf area index simulated by IAP-DGVM was closer to the observation than that of CoLM-DGVM; however, both simulated values about twice as large as in the observation. This evaluation provides valuable information for the application of CAS-ESM, as well as for other model communities in terms of a comparative benchmark.

Agricultural pesticide use and food safety:California's model

Pesticides have been an essential part of agriculture to protect crops and livestock from pest infestations and yield reduction for many decades. Despite their usefulness, pesticides could pose potential risks to food safety and the environment as well as human health. This paper reviews the positive benefits of agricultural pesticide use as well as some potential negative impacts on the environment and food safety. In addition, using the case of California, we discuss the need for both residue monitoring and effective pest management to promote food safety. Twenty years＇ pesticide residue data from California＇s pesticide residue monitoring program were analyzed. Results showed that more than 95% of food samples were in compliance with US pesticide residue standards （tolerances）. However, certain commodities from certain sources had high percentages of residues above tolerance levels. Even when residues above tolerance levels were detected, most were at levels well below 1 mg kg^-1, and most posed negligible acute health risk. However, a few detected residues had the potential to cause health effects. Therefore, establishing an effective food residue monitoring program is important to ensure food quality throughout the marketplace.

Deep placement of nitrogen fertilizer increases rice yield and nitrogen use efficiency with fewer greenhouse gas emissions in a mechanical direct-seeded cropping system

Deep placement of nitrogen fertilizer is a key strategy for improving nitrogen use efficiency. A two-year field experiment was conducted during the early rice growing seasons(March–July) of 2016 and 2017.The experimental treatments comprised two rice cultivars: Wufengyou 615(WFY 615) and Yuxiangyouzhan(YXYZ), and three N treatments: mechanical deep placement of all fertilizers as basal dose at 10 cm soil depth(one-time deep-placement fertilization, namely OTDP fertilization);manual surface broadcast(the common farmer practice) of 40% N fertilizer at one day before sowing(basal fertilizer)followed by broadcast application of 30% each at tillering and panicle initiation stages;and no fertilizer application at any growth stage as a control. One-time deep-placement fertilization increased grain yield of both rice cultivars by 11.8%–19.6%, total nitrogen accumulation by 10.3%–13.1%, nitrogen grain production efficiency by 29.7%–31.5%, nitrogen harvest index by 27.8%–30.0%, nitrogen agronomic efficiency by 71.3%–77.2%, and nitrogen recovery efficiency by 42.4%–56.7% for both rice cultivars, compared with the multiple-broadcast treatment. One-time deep-placement fertilization reduced CH4-induced global warming potential(GWP) by 20.7%–25.3%, N2O-induced GWP by 7.2%–12.3%, and total GWP by 14.7%–22.9% for both rice cultivars relative to the multiple-broadcast treatment. The activities of glutamine synthetase and nitrate reductase were increased at both panicle-initiation and heading stages in both rice cultivars following one-time deep-placement fertilization treatment. Larger leaf area index at heading stage and more favorable root morphological traits expressed as larger total root length, mean root diameter, and total root volume per hill were also observed. One-time deep-placement fertilization could be an effective strategy for increasing grain yield and nitrogen use efficiency and lowering greenhouse-gas emissions under mechanical direct-seeded cropping systems.

CAS-ESM2.0 Model Datasets for the CMIP6 Ocean Model Intercomparison Project Phase 1 (OMIP1)

As a member of the Chinese modeling groups,the coupled ocean-ice component of the Chinese Academy of Sciences’Earth System Model,version 2.0(CAS-ESM2.0),is taking part in the Ocean Model Intercomparison Project Phase 1(OMIP1)experiment of phase 6 of the Coupled Model Intercomparison Project(CMIP6).The simulation was conducted,and monthly outputs have been published on the ESGF(Earth System Grid Federation)data server.In this paper,the experimental dataset is introduced,and the preliminary performances of the ocean model in simulating the global ocean temperature,salinity,sea surface temperature,sea surface salinity,sea surface height,sea ice,and Atlantic Meridional Overturning Circulation(AMOC)are evaluated.The results show that the model is at quasi-equilibrium during the integration of 372 years,and performances of the model are reasonable compared with observations.This dataset is ready to be downloaded and used by the community in related research,e.g.,multi-ocean-sea-ice model performance evaluation and interannual variation in oceans driven by prescribed atmospheric forcing.

CAS-ESM2.0 Model Datasets for the CMIP6 Flux-Anomaly-Forced Model Intercomparison Project (FAFMIP)

The second version of the Chinese Academy of Sciences Earth System Model(CAS-ESM2.0)is participating in the Flux-Anomaly-Forced Model Intercomparison Project(FAFMIP)experiments in phase 6 of the Coupled Model Intercomparison Project(CMIP6).The purpose of FAFMIP is to understand and reduce the uncertainty of ocean climate changes in response to increased CO2 forcing in atmosphere-ocean general circulation models(AOGCMs),including the simulations of ocean heat content(OHC)change,ocean circulation change,and sea level rise due to thermal expansion.FAFMIP experiments(including faf-heat,faf-stress,faf-water,faf-all,faf-passiveheat,faf-heat-NA50pct and faf-heat-NA0pct)have been conducted.All of the experiments were integrated over a 70-year period and the corresponding data have been uploaded to the Earth System Grid Federation data server for CMIP6 users to download.This paper describes the experimental design and model datasets and evaluates the preliminary results of CAS-ESM2.0 simulations of ocean climate changes in the FAFMIP experiments.The simulations of the changes in global ocean temperature,Atlantic Meridional Overturning Circulation(AMOC),OHC,and dynamic sea level(DSL),are all reasonably reproduced.

Changes in Global Vegetation Distribution and Carbon Fluxes in Response to Global Warming:Simulated Results from IAP-DGVM in CAS-ESM2

Terrestrial ecosystems are an important part of Earth systems,and they are undergoing remarkable changes in response to global warming.This study investigates the response of the terrestrial vegetation distribution and carbon fluxes to global warming by using the new dynamic global vegetation model in the second version of the Chinese Academy of Sciences(CAS)Earth System Model(CAS-ESM2).We conducted two sets of simulations,a present-day simulation and a future simulation,which were forced by the present-day climate during 1981-2000 and the future climate during 2081-2100,respectively,as derived from RCP8.5 outputs in CMIP5.CO_(2)concentration is kept constant in all simulations to isolate CO_(2)-fertilization effects.The results show an overall increase in vegetation coverage in response to global warming,which is the net result of the greening in the mid-high latitudes and the browning in the tropics.The results also show an enhancement in carbon fluxes in response to global warming,including gross primary productivity,net primary productivity,and autotrophic respiration.We found that the changes in vegetation coverage were significantly correlated with changes in surface air temperature,reflecting the dominant role of temperature,while the changes in carbon fluxes were caused by the combined effects of leaf area index,temperature,and precipitation.This study applies the CAS-ESM2 to investigate the response of terrestrial ecosystems to climate warming.Even though the interpretation of the results is limited by isolating CO_(2)-fertilization effects,this application is still beneficial for adding to our understanding of vegetation processes and to further improve upon model parameterizations.

Ocean Response to a Climate Change Heat-Flux Perturbation in an Ocean Model and Its Corresponding Coupled Model

State-of-the-art coupled general circulation models(CGCMs)are used to predict ocean heat uptake(OHU)and sealevel change under global warming.However,the projections of different models vary,resulting in high uncertainty.Much of the inter-model spread is driven by responses to surface heat perturbations.This study mainly focuses on the response of the ocean to a surface heat flux perturbation F,as prescribed by the Flux-Anomaly-Forced Model Intercomparison Project(FAFMIP).The results of ocean model were compared with those of a CGCM with the same ocean component.On the global scale,the changes in global mean temperature,ocean heat content(OHC),and steric sea level(SSL)simulated in the OGCM are generally consistent with CGCM simulations.Differences in changes in ocean temperature,OHC,and SSL between the two models primarily occur in the Arctic and Atlantic Oceans(AA)and the Southern Ocean(SO)basins.In addition to the differences in surface heat flux anomalies between the two models,differences in heat exchange between basins also play an important role in the inconsistencies in ocean climate changes in the AA and SO basins.These discrepancies are largely due to both the larger initial value and the greater weakening change of the Atlantic meridional overturning circulation(AMOC)in CGCM.The greater weakening of the AMOC in the CGCM is associated with the atmosphere–ocean feedback and the lack of a restoring salinity boundary condition.Furthermore,differences in surface salinity boundary conditions between the two models contribute to discrepancies in SSL changes.

A high-top version of IAP-AGCM:Preliminary assessment and sensitivity IAP-AGCM

Extending the atmospheric model top to high altitude is important for simulation of upper atmospheric phenomena,such as the stratospheric quasi-biennial oscillation.The high-top version of the Institute of Atmospheric Physics Atmospheric General Circulation Model with 91 vertical layers(IAP-AGCML91)extends to the mesopause at about 0.01 hPa(~80 km).The high-top model with a fully resolved stratosphere is found to simulate a warmer stratosphere than the low-top version,except near the South Pole,thus reducing its overall cold bias in the stratosphere,and significantly in the upper stratosphere.This sensitivity is shown to be consistent with two separate mechanisms:larger shortwave heating and larger poleward stratospheric meridional eddy heat flux in the hightop model than in the low-top model.Results indicate a significant influence of vertical resolution and model top on climate simulations in IAP-AGCM.

Specificity Screening of Potential Active Components from Moutan Cortex for Rat Mesangial Cells HBZY-1 by Cell Membrane Immobilized Chromatography

Moutan Cortex (MC) has been demonstrated to have an inhibitive effect on inflammation and oxidative stress responses in mesangial cells in our previous study. However, little is known about the components of MC contributing to this benefit. In the present study, cell membrane immobilized chromatography (CMC), a fast and useful method, was presented for screening potential active components of MC. HBZY-1 cells were incubated with MC (200 μg/mL) at the optimal incubation time (90 min). HPLC-DAD analysis and LC/ESI/MS/MS were performed to distinguish the active components and identify its structural ion fragments. The results showed that eight components binding to HBZY-1 cells were mudanoside B, paeoniflorin sulfonate, paeoniflorin, tetragalloyl glucose (isomeride), hexagalloyl glucose, mudanopiside A, and paeonol. In conclusion, our established CMC might be a useful method for screening potential active components in complicated traditional Chinese medicines. These components might be associated with the efficacy of MC on prevention and treatment of diabetic nephropathy.

食源和景观管理中对地下水硝酸盐污染的评估

最近50年来,加利福尼亚州图莱里县地下水中硝酸盐浓度增加,有时超出公共卫生标准,那里的生态健康和农业生产力受到威胁。本项研究解释了地下水硝酸盐浓度的一些空间变化与土壤的潜在淋滤,农业土地利用和地下水抬升的空间一致性。凡土壤中存在过量氮负荷最大、土壤受潜在淋滤影响最大、而且地下水位也较高的地方,地下水中硝酸盐浓度就增高。高风险的硝酸盐淋滤和污染地点,大部分是在粗质结构土壤上种植柑橘、胡桃果园及葡萄园的乡镇。评估所利用数据的空间尺度与设置管理解决方案相适应,所用的地图能有效地传递信息。农民和规划人员能够利用该信息调整农场管理实践与土地利用对策,使地下水中硝酸盐污染的危险性降至最低。

Earthquake fault framework and seismotectonics of the Songpan-Garze region since 1900

Based on 4 781 observed faults （〉2 km length） from a 1：200 000 scale digital geologic map and 5 220 recorded seismic events since the year 1900, 993 earthquake faults are identified within the triangular Songpan-Garze study region. The study area is delineated by the nearly EW-trending East Kunlun fault zone to the north, the NW-trending Xianshuihe fault to the south and the NE-trending Longmenshan thrust belt to the east. Seismicity changes along these earthquake faults, spanning four 10-year intervals since 1970, show that following a strong earthquake swarm, which occurred in the Huya area in the mid-1970s, seismic activity increased from north to south, and migrated eastward along each major strike-slip fault zone. GPS observation data before 2008 indicate a displacement rate across the Xianshuihe fault zone to the south of -6.5- 8.6 mm/a, whereas across the East Kunlun fault zone to the north it was -1.8- 2.2 mm/a. The May 12, 2008 Ms8.0 Wenchuan earthquake, which occurred in the southeast corner of the study region, was the result of stable, high-speed left-lateral displacement along the Xianshuihe fault zone, and a sharp eastward bend of the fault trend in response to the presence of crystalline rocks in the Kangding area. Therefore, the 110-year established seismotectonic framework of the Songpan-Garze region can be defined by a network of various earthquake faults and the structural relations of the local earthquake activities.

Simulation of the QBO in IAP-AGCM:Analysis of momentum budget

The quasi-biennial oscillation(QBO),a dominant mode of the equatorial stratospheric(~100–1 hPa)variability,is known to impact tropospheric circulation in the middle and high latitudes.Yet,its realistic simulation in general circulation models remains a challenge.The authors examine the simulated QBO in the 69-layer version of the Institute of Atmospheric Physics Atmospheric General Circulation Model(IAP-AGCML69)and analyze its momentum budget.The authors find that the QBO is primarily caused by parameterized gravity-wave forcing due to tropospheric convection,but the downward propagation of the momentum source is significantly offset by the upward advection of zonal wind by the equatorial upwelling in the stratosphere.Resolved-scale waves act as a positive contribution to the total zonal wind tendency of the QBO over the equator with comparable magnitude to the gravity-wave forcing in the upper stratosphere.Results provide insights into the mechanism of the QBO and possible causes of differences in models.

Advances in Research on Drought Resistance in Rice

Rice is the main grain crop in China. With global warming, drought and water shortage have become one of the important factors limiting rice production. Improving the drought resistance of rice can effectively alleviate the loss of rice yield caused by drought. In this paper, the research progress on rice drought resistance and its evaluation methods, mapping of QTLs for drought resistance-related traits, and mining for drought resistance genes were reviewed, and molecular breeding for drought resistance in rice was prospected.