Toward understanding the microstructure characteristics,phase selection and magnetic properties of laser additive manufactured Nd-Fe-B permanent magnets

Nd-Fe-B permanent magnets play a crucial role in energy conversion and electronic devices.The essential magnetic properties of Nd-Fe-B magnets,particularly coercivity and remanent magnetization,are significantly infuenced by the phase characteristics and microstructure.In this work,Nd-Fe-B magnets were manufactured using vacuum induction melting(VIM),laser directed energy deposition(LDED)and laser powder bed fusion(LPBF)technologies.Themicrostructure evolution and phase selection of Nd-Fe-B magnets were then clarified in detail.The results indicated that the solidification velocity(V)and cooling rate(R)are key factors in the phase selection.In terms of the VIM-casting Nd-Fe-B magnet,a large volume fraction of theα-Fe soft magnetic phase(39.7 vol.%)and Nd2Fe17Bxmetastable phase(34.7 vol.%)areformed due to the low R(2.3×10-1?C s-1),whereas only a minor fraction of the Nd2Fe14B hard magnetic phase(5.15 vol.%)is presented.For the LDED-processed Nd-Fe-B deposit,although the Nd2Fe14B hard magnetic phase also had a low value(3.4 vol.%)as the values of V(<10-2m s-1)and R(5.06×103?C s-1)increased,part of theα-Fe soft magnetic phase(31.7vol.%)is suppressed,and a higher volume of Nd2Fe17Bxmetastable phases(47.5 vol.%)areformed.As a result,both the VIM-casting and LDED-processed Nd-Fe-B deposits exhibited poor magnetic properties.In contrast,employing the high values of V(>10-2m s-1)and R(1.45×106?C s-1)in the LPBF process resulted in the substantial formation of the Nd2Fe14B hard magnetic phase(55.8 vol.%)directly from the liquid,while theα-Fe soft magnetic phase and Nd2Fe17Bxmetastable phase precipitation are suppressed in the LPBF-processed Nd-Fe-B magnet.Additionally,crystallographic texture analysis reveals that the LPBF-processedNd-Fe-B magnets exhibit isotropic magnetic characteristics.Consequently,the LPBF-processed Nd-Fe-B deposit,exhibiting a coercivity of 656 k A m-1,remanence of 0.79 T and maximum energy product of 71.5 k J m-3,achieved an acceptable magnetic performance,comparable to other additive manufacturing processed Nd-Fe-B magnets from MQP(Nd-lean)Nd-Fe-Bpowder.

A review on the multi-scaled structures and mechanical/thermal properties of tool steels fabricated by laser powder bed fusion additive manufacturing

The laser powder bed fusion(LPBF) process can integrally form geometrically complex and high-performance metallic parts that have attracted much interest,especially in the molds industry.The appearance of the LPBF makes it possible to design and produce complex conformal cooling channel systems in molds.Thus,LPBF-processed tool steels have attracted more and more attention.The complex thermal history in the LPBF process makes the microstructural characteristics and properties different from those of conventional manufactured tool steels.This paper provides an overview of LPBF-processed tool steels by describing the physical phenomena,the microstructural characteristics,and the mechanical/thermal properties,including tensile properties,wear resistance,and thermal properties.The microstructural characteristics are presented through a multiscale perspective,ranging from densification,meso-structure,microstructure,substructure in grains,to nanoprecipitates.Finally,a summary of tool steels and their challenges and outlooks are introduced.

Laser powder bed fusion of a novel high strength quasicrystalline Al–Fe–Cr reinforced Al matrix composite

Quasicrystal(QC)-reinforced metal matrix composites fabricated by rapid solidification present promising new opportunities to develop high-strength alloys with multiple functions.In this research,specially designed Al–Fe–Cr samples possessing an Al–Fe–Cr quasicrystal-reinforced Al matrix structure were manufactured using a laser powder bed fusion(LPBF)process.Based on the optimized process parameters of laser scanning speed and hatch distance,an almost dense(99.8%)free-crack sample was obtained with the multiscaled heterogenous structure induced by the nonuniform rapid solidification in a single molten pool.The results show that nanosized Al–Fe–Cr quasicrystalline particles of different sizes are heterogeneously distributed in theα-Al columnar grain structure.In detail,the coarseflower-like and spherical QC particles can be observed at the molten pool boundary,and thefine spherical Al–Fe–Cr QC is located inside the laser fusion zone.The orientation relationship between the Al matrix and the icosahedral Al–Fe–Cr QC is as follows:Al[
112]||i5 with a semicoherency feature.The novel designed LPBF-processed Al–Fe–Cr alloy exhibits high mechanical strength due to the ultrafine multireinforced microstructure-induced Orowan strengthening effect.For instance,the ultimate tensile strength,yield strength and elongation of the sample processed with LPBF are 530.803.19 MPa,395.066.44 MPa,and 4.16%0.38%,respectively.The fractographic analysis shows that the fracture mechanism presents a combination of ductile‒brittle fracture.

Laser Powder Bed Fusion Processing of Soft Magnetic Fe–Ni–Si Alloys: Effect of Hot Isostatic Pressing Treatment

Laser powder bed fusion(L-PBF)-processed high-silicon steel has great advantages in freely designed electric engines,and various studies have been conducted in this field.However,the analysis of both the mechanical and magnetic properties,focusing on the multiscale microstructure under as-fabricated and heat-treated conditions,which is indispensable for industrial applications,has not been performed.In this study,an Fe–Ni–Si sample was fabricated using the L-PBF process.Subsequently,the following hot isotropic pressing(HIPing)process was employed as a post heat treatment step for the Fe–Ni–Si alloys.The effects of HIPing on the microstructure were investigated,focusing on the metastable stable phase transformation in the Fe–Ni–Si system.X-ray diffraction results showed single-phase fccγ(Fe,Ni)in the L-PBF-processed samples before and after HIPing.Moreover,the acicular Ni/Si-rich structure(formed in the as-fabricated L-PBF sample because of its high cooling rates)transformed to the equilibrium austenite,Ni3Si,and FeNi3 phases during HIPing.After HIP,the compressive modulus and strength increased from 11 GPa and 650 MPa to approximately 18 GPa and 900 MPa,respectively.The magnetic properties were evaluated via a hysteresis loop,and the coercivity increased from 1.8 kA/m and to 2.9 kA/m after the HIPing process.