This study explores the epitaxial relationship and electrical properties of α-Ga_(2)O_(3) thin films deposited on a-plane, mplane, and r-plane sapphire substrates. We characterize the thin films by X-ray diffraction ...This study explores the epitaxial relationship and electrical properties of α-Ga_(2)O_(3) thin films deposited on a-plane, mplane, and r-plane sapphire substrates. We characterize the thin films by X-ray diffraction and Raman spectroscopy, and elucidate thin film epitaxial relationships with the underlying sapphire substrates. The oxygen vacancy concentration of α-Ga_(2)O_(3) thin films on m-plane and r-plane sapphire substrates are higher than α-Ga_(2)O_(3) thin film on a-plane sapphire substrates. All three thin films have a high transmission of over 80% in the visible and near-ultraviolet regions, and their optical bandgaps stay around 5.02–5.16 eV. Hall measurements show that the α-Ga_(2)O_(3) thin film grown on r-plane sapphire has the highest conductivity of 2.71 S/cm, which is at least 90 times higher than the film on a-plane sapphire. A similar orientation-dependence is seen in their activation energy as revealed by temperature-dependent conductivity measurements, with 0.266, 0.079, and 0.075eV for the film on a-, m-, r-plane, respectively. The origin of the distinct transport behavior of films on differently oriented substrates is suggested to relate with the distinct evolution of oxygen vacancies at differently oriented substrates. This study provides insights for the substrate selection when growing α-Ga_(2)O_(3) films with tunable transport properties.展开更多
Di(2-ethylhexyl)phthalate(DEHP)is a widely used plasticizer known for its reproductive developmental and immune system toxicity,mainly through esophagal,dermal,and respiratory exposure^([1-3]).Maternal exposure to DEH...Di(2-ethylhexyl)phthalate(DEHP)is a widely used plasticizer known for its reproductive developmental and immune system toxicity,mainly through esophagal,dermal,and respiratory exposure^([1-3]).Maternal exposure to DEHP during pregnancy can lead to adverse birth outcomes in offspring,including impacts on the thyroid system of adolescent offspring^([2-4]).展开更多
为了缓解日益严重的能源危机和环境污染压力,需要开发相对高效和清洁的污泥利用技术。超临界水气化(Supercritical Water Gasification,SCWG)技术可以实现废弃生物质中能量的回收,并起到稳定重金属的作用,是一种清洁、有效的处理城市污...为了缓解日益严重的能源危机和环境污染压力,需要开发相对高效和清洁的污泥利用技术。超临界水气化(Supercritical Water Gasification,SCWG)技术可以实现废弃生物质中能量的回收,并起到稳定重金属的作用,是一种清洁、有效的处理城市污泥方法。介绍污泥处置的必要性和污泥SCWG反应参数优化的研究进展,阐述污泥及污泥与生物质共气化的技术优势及污泥SCWG制氢多联产系统的热力学分析和生命周期评价(Life Cycle Assessment,LCA)的相关研究进展,探讨污泥SCWG技术目前存在的一些问题,并展望该技术的发展前景。展开更多
During the process of thunderstorm in a county on June 23,2015,eight mobile base stations in the region were damaged.The reasons for the damage caused by the thunderstorm were discussed through on-the-spot investigati...During the process of thunderstorm in a county on June 23,2015,eight mobile base stations in the region were damaged.The reasons for the damage caused by the thunderstorm were discussed through on-the-spot investigation,and some countermeasures were proposed.展开更多
Significant progress has been made in the exploration and development of unconventional gas resources in China since the beginning of the 21st century.With a rapid increase in yield,the exploration and development of ...Significant progress has been made in the exploration and development of unconventional gas resources in China since the beginning of the 21st century.With a rapid increase in yield,the exploration and development of shale gas have been upgraded to a level of national strategy.Logging is one of the core technologies in gas exploration and development.However,logging technologies face the challenges of complex geological conditions and well casing environment,high temperature,high pressure,and strong heterogeneity.Despite the rich experience accumulated,unified understanding and implementation specifications are yet to be established for shale gas well logging.Given the analysis and comparison of the effectiveness and adaptability of logging technologies at different stages of shale gas exploration and development for the Sichuan Basin,this study optimizes the log suite to meet the demand for highefficiency exploration and development of shale gas.According to the adaptability analysis of shale gas log suite,the mandatory logging items of exploratory wells should include caliper log(CAL),natural gamma ray spectrometry(NGS)log,spontaneous potential(SP)log,directional survey,borehole compensated sonic log,litho-density log(LDL),compensated neutron log(CNL),dual laterologmicrospherically focused log/dual induction-laterolog log/array induction log,temperature log,elemental capture spectroscopy(ECS)log,formation microimager(FMI)log,and array sonic log.The log suite of appraisal wells is almost the same as that for exploratory wells,excluding the ECS log and microresistivity scanning imaging.Meanwhile,for the logging of horizontal/highly-deviated holes,the log suite of vertical wells should be referred to according to specific well conditions.展开更多
基金supported by the Zhejiang Provincial Natural Science Foundation under (Grant No. LZ21F040001)the Pioneer Hundred Talents Program of Chinese Academy of Sciencesthe Ningbo Yongjiang Talent Introduction Programme and the Ningbo Key Scientific and Technological Project (Grant No. 2022Z016)。
文摘This study explores the epitaxial relationship and electrical properties of α-Ga_(2)O_(3) thin films deposited on a-plane, mplane, and r-plane sapphire substrates. We characterize the thin films by X-ray diffraction and Raman spectroscopy, and elucidate thin film epitaxial relationships with the underlying sapphire substrates. The oxygen vacancy concentration of α-Ga_(2)O_(3) thin films on m-plane and r-plane sapphire substrates are higher than α-Ga_(2)O_(3) thin film on a-plane sapphire substrates. All three thin films have a high transmission of over 80% in the visible and near-ultraviolet regions, and their optical bandgaps stay around 5.02–5.16 eV. Hall measurements show that the α-Ga_(2)O_(3) thin film grown on r-plane sapphire has the highest conductivity of 2.71 S/cm, which is at least 90 times higher than the film on a-plane sapphire. A similar orientation-dependence is seen in their activation energy as revealed by temperature-dependent conductivity measurements, with 0.266, 0.079, and 0.075eV for the film on a-, m-, r-plane, respectively. The origin of the distinct transport behavior of films on differently oriented substrates is suggested to relate with the distinct evolution of oxygen vacancies at differently oriented substrates. This study provides insights for the substrate selection when growing α-Ga_(2)O_(3) films with tunable transport properties.
基金supported by the National Natural Science Foundation of China[82073593]the Scientific Research Projects in Colleges and Universities of Anhui Education Department[KJ2019A0281 and KJ2020A0666]+2 种基金Domestic Visiting and Training Project for Excellent Young Key Teachers of Colleges and Universities[gxgnfx2020115]Research level improvement program of Anhui Medical University[2021xkjT010]2022 Early Exposure to Research Training Program for Clinical Medicine(“5+3”Integration)Students(2022-ZQKY-84)。
文摘Di(2-ethylhexyl)phthalate(DEHP)is a widely used plasticizer known for its reproductive developmental and immune system toxicity,mainly through esophagal,dermal,and respiratory exposure^([1-3]).Maternal exposure to DEHP during pregnancy can lead to adverse birth outcomes in offspring,including impacts on the thyroid system of adolescent offspring^([2-4]).
文摘为了缓解日益严重的能源危机和环境污染压力,需要开发相对高效和清洁的污泥利用技术。超临界水气化(Supercritical Water Gasification,SCWG)技术可以实现废弃生物质中能量的回收,并起到稳定重金属的作用,是一种清洁、有效的处理城市污泥方法。介绍污泥处置的必要性和污泥SCWG反应参数优化的研究进展,阐述污泥及污泥与生物质共气化的技术优势及污泥SCWG制氢多联产系统的热力学分析和生命周期评价(Life Cycle Assessment,LCA)的相关研究进展,探讨污泥SCWG技术目前存在的一些问题,并展望该技术的发展前景。
文摘During the process of thunderstorm in a county on June 23,2015,eight mobile base stations in the region were damaged.The reasons for the damage caused by the thunderstorm were discussed through on-the-spot investigation,and some countermeasures were proposed.
文摘Significant progress has been made in the exploration and development of unconventional gas resources in China since the beginning of the 21st century.With a rapid increase in yield,the exploration and development of shale gas have been upgraded to a level of national strategy.Logging is one of the core technologies in gas exploration and development.However,logging technologies face the challenges of complex geological conditions and well casing environment,high temperature,high pressure,and strong heterogeneity.Despite the rich experience accumulated,unified understanding and implementation specifications are yet to be established for shale gas well logging.Given the analysis and comparison of the effectiveness and adaptability of logging technologies at different stages of shale gas exploration and development for the Sichuan Basin,this study optimizes the log suite to meet the demand for highefficiency exploration and development of shale gas.According to the adaptability analysis of shale gas log suite,the mandatory logging items of exploratory wells should include caliper log(CAL),natural gamma ray spectrometry(NGS)log,spontaneous potential(SP)log,directional survey,borehole compensated sonic log,litho-density log(LDL),compensated neutron log(CNL),dual laterologmicrospherically focused log/dual induction-laterolog log/array induction log,temperature log,elemental capture spectroscopy(ECS)log,formation microimager(FMI)log,and array sonic log.The log suite of appraisal wells is almost the same as that for exploratory wells,excluding the ECS log and microresistivity scanning imaging.Meanwhile,for the logging of horizontal/highly-deviated holes,the log suite of vertical wells should be referred to according to specific well conditions.
