Production of Light Fraction-Based Pyrolytic Fuel from Spirulina platensis Microalgae Using Various Low-Cost Natural Catalysts and Insertion

The use of catalysts has significantly enhanced the yield and quality of in-situ pyrolysis products.However,there is a lack of understanding regarding pyrolysis approaches that utilize several low-cost natural catalysts(LCC)and their placement within the reactor.Therefore,this study aims to examine the effects of various LCC on the insitu pyrolysis of spirulina platensis microalgae(SPM)and investigate the impact of different types of catalysts.We employed LCCsuch as zeolite,dolomite,kaolin,and activated carbon,with both layered and uniformlymixed LCCSPM placements.Each experiment was conducted at a constant temperature of 500℃for 60 min.The resulting pyrolytic liquids(bio-oil)and syngas were analyzed using a Gas Chromatography Mass Spectrometry(GC-MS)analyzer to determine the distribution of hydrocarbon compounds.The experimental results indicated that the presence of catalysts significantly influenced the mass yield productivity of liquid fuels and syngas.Activated carbon and zeolite were preferred among the four catalysts for producing liquid fuels(22.4 and 18.6 wt%)when layered and uniformly mixed,respectively.Kaolin with a layered mixture with SPM was more suitable for the production of light fractions(C_(5)–C_(12)),achieving approximately 95.7%peak area,while zeolite with a uniform mixture produced the highest light fraction at about 86.3%peak area.All catalysts except kaolin significantly increased the aromatic compounds in the liquid fuels.Although the amount of oxygenated hydrocarbons in the bio-oil remained relatively high,the final hydrocarbon composition was highly comparable to conventional fuels such as gasoline-88,which has a C_(5)–C_(12)hydrocarbon distribution of approximately 88.1%peak area.Regarding the syngas products,all catalysts except activated carbon successfully converted nitromethane compounds into tetranitromethane hydrocarbons,with activated carbon predominantly yielding nitromethane compounds.

Mitigating Carbon Emissions:A Comprehensive Analysis of Transitioning to Hydrogen-Powered Plants in Japan’s Energy Landscape Post-Fukushima

One of the impacts of the Fukushima disaster was the shutdown of all nuclear power plants in Japan,reaching zero production in 2015.In response,the country started importing more fossil energy including coal,oil,and natural gas to fill the energy gap.However,this led to a significant increase in carbon emissions,hindering the efforts to reduce its carbon footprint.In the current situation,Japan is actively working to balance its energy requirements with environmental considerations,including the utilization of hydrogen fuel.Therefore,this paper aims to explore the feasibility and implications of using hydrogen power plants as a means to reduce emissions,and this analysis will be conducted using the energy modeling of the MARKAL-TIMES Japan framework.The hydrogen scenario(HS)is assumed with the extensive integration of hydrogen into the power generation sector,supported by a hydrogen import scheme.Additionally,this scenario will be compared with the Business as Usual(BAU)scenario.The results showed that the generation capacities of the BAU and HS scenarios have significantly different primary energy supplies.The BAU scenario is highly dependent on fossil fuels,while the HS scenario integrates hydrogen contribution along with an increase in renewable energy,reaching a peak contribution of 2,160 PJ in 2050.In the HS scenario,the target of reducing CO_(2) emissions by 80%is achieved through significant hydrogen penetration.By 2050,the total CO_(2) emissions are estimated to be 939 million tons for the BAU scenario and 261 million tons for the Hydrogen scenario.In addition,the contribution of hydrogen to electricity generation is expected to be 153 TWh,smaller than PV and wind power.

The Use of Single-Phase Immersion Cooling by Using Two Types of Dielectric Fluid for Data Center Energy Savings

Data centers are recognized as one of the most important aspects of the fourth industrial revolution since conventional data centers are inefficient and have dependency on high energy consumption,in which the cooling is responsible for 40%of the usage.Therefore,this research proposes the immersion cooling method to solving the high energy consumption of data centers by cooling its component using two types of dielectric fluids.Four stages of experimentalmethods are used,such as fluid types,cooling effectiveness,optimization,and durability.Furthermore,benchmark software is used to measure the CPU maximum work with the temperature data performed for 24 h.The results of this study show that the immersion cooling reduces 13℃ lower temperature than the conventional cooling method which means it saves more energy consumption in the data center.The most optimum variable used to decrease the temperature is 1.5 lpm of flow rate and 800 rpm of fan rotation.Furthermore,the cooling performance of the dielectric fluids shows that the mineral oil(MO)is better than the virgin coconut oil(VCO).In durability experiment,there are no components damage after five months immersed in the fluid.

Engine Performance Using Blended Fuels of Biodiesel and Eco Diesel

Diesel engines is an internal combustion engine with high thermal efficiency,which also uses biodiesel fuel,an environmentally friendly,non-toxic,and low sulfur content.Biodiesel has been around for a long time due to its similar characteristics to diesel fuels which has limited availability.However,several disadvantages are associated with biodiesel,such as poor volatility and high viscosity,which reduces engine performance.Therefore,this study was carried out to improve the diesel engine performance by mixing biodiesel with ecodiesel(ED),an additive produced from natural ingredients that is dissolvable in biodiesel.The biodiesel fuel properties used are density 860 kg/m3,dynamic viscosity 4.50E-06 m2/s,cetane number 45,and flashpoint 52°C.The results showed that biodiesel-ED mixture could improve engine performance and the optimum performance was at a speed of 3000 rpm on 43.30(kW),124.93(N.m)of the engine torque,and 2.45E–5(kg/kW.s)of the specific fuel consumption.According to paired sample t-test,the difference in the engine performance is only experienced in the torque,which has a significant increase in the composition of the biodiesel+ED by 0.07 gr mixture.

Stepwise Pyrolysis by LBCR Downstream to Enhance of Gasoline Fraction of Liquid Fuel from MMSW

Pyrolysis is one of the thermal cracking methods to convert hydrocarbon to liquid fuel.The quantity and quality of the process are dependent on several condition including temperature,reaction time,catalyst,and the type of reactor.Meanwhile,a gasoline fraction was maximum product to be considered in the pyrolisis process.Therefore,this study aims to increase the gasoline fraction in liquid fuel using stepwise pyrolysis with a long bed catalytic reactor downstream(LBCR).The LBCR downstream was equipped with the top and bottom outlet and the fed source was mixed municipal solid waste(MMSW).The activated natural dolomite at 500℃ was used to allow the repetition of the secondary cracking.Also,the reactor temperature was setup at around 200℃-300℃ and the pyrolizer was 400℃.To analyze the gasoline fraction and physical properties of liquid fuel,Gas Chromatography-Mass Spectroscopy(GC-MS)and ASTM standard were employed.The experimental results showed there was a significant increase in the gasoline fraction of liquid fuels compared to using direct catalytic cracking and absence of catalysts.By using a LBCR at 250℃,the liquid fuel obtained at top outlet(TO)and bottom outlet(BO)have 84.08 and 56.94 percent peak area of gasoline fraction(C5-C12),respectively.The average value(TO and BO)of the fraction at 250℃ by LBCR was 70.51 percent peak area and it was increased by about 93.6%and 51.14%compared to without catalyst and direct catalytic,respectively.Furthermore,pyrolytic liquid oils were found to have kinematic viscosity of 2.979 and 0.789 cSt,density of 0.781 and 0.782 g/cm^(3),and flash point<−5℃ for BO-250 and TO-250 liquid fuel,respectively.These results showed BO liquid fuel was comparable to diesel conventional fuel while TO liquid fuel was comparable to gasoline.Evidently,the presence of LBCR made a major contribution to generate multi secondary cracking and to produce more gasoline fraction from mixed MMSW feedstock,as well as to increase the physical properties of liquid fuel.

Experimental Investigation of Organic Rankine Cycle (ORC) for Low Temperature Geothermal Fluid: Effect of Pump Rotation and R-134 Working Fluid in Scroll-Expander

Organic Rankine Cycle(ORC)is one of the solutions to utilize a low temperature geothermal fluid for power generation.The ORC system can be placed at the exit of the separator to extract energy from brine.Furthermore,one of the main components of the system and very important is the pump.Therefore,in this research,the pump rotation is examined to investigate the effect on power output and energy efficiency for low temperature geothermal fluid.The rotation is determined by using an inverter with the following frequencies:7.5,10,12.5,15 and 17.5 Hz,respectively.R-134 working fluid is employed with 373.15 K evaporator temperature in relation to the low temperature of the geothermal fluid.Furthermore,the condenser temperature and fluid pressure were set up to 293.15 K and 5×10^(5) Pa,respectively.This research uses a DC generator with a maximum power of 750 Watt and the piping system is made from copper alloy C12200 ASTM B280 with size 1.905×10^(−2) m and a thickness of 8×10^(−4) m.The results showed that there is an increase in mass flow rate,enthalpy and generator power output along with increasing pump rotation.In addition,it showed that the maximum generator output power was 377.31 Watt at the highest pump rotation with a frequency of 17.5 Hz.

Prospects and Challenges of Utilizing Solar Energy for the COVID-19 Vaccine Cold Storage in Remote Clinics of Tropical Countries:Review

The rapid spread of COVID-19 pandemic has forced several countries in the world to store vaccines in cold storage towards ensuring their protection from being damaged and to maintain their stability.However,most remote clinics,especially those in the equator and islands,are faced with the challenges of hot climates and the inability to afford electricity resources needed to power the cold storage facility.Meanwhile,the hot equatorial region has abundant solar energy to power the vaccine cold storage but previous studies showed that several field workers do not have the ability to maintain the vaccine storage temperature as indicated by the manufacturer’s recommendations.Therefore,this literature review study examines the prospects and challenges of implementing solar-powered cold storage to provide cooling space for remote clinics.This is expected to contribute significantly to cold chain vaccine management technology.The findings showed that four technology integration schemes including Cold Storage Ice Maker,Cold Storage Ice Maker-PCM,Refrigerator-Ice Maker and,Absorbing Cooling-PV-Ice Maker have the potential to be applied in clinics situated in certain tropical regions.

Upgrading the Quality of Solid Fuel Made from Nyamplung (Calophyllum inophyllum) Wastes Using Hydrothermal Carbonization Treatment

One of the major problems faced in managing biomass waste to higher quality products is choosing the right technology.Wastes are used as an alternative fuel,with increase in the calorific value.Hydrothermal carbonization(HTC)is a biomass conversion technology,used to obtain solid fuel.This study aims to utilize of Calophyllum inophyllum as an alternative solid fuel through HTC.The calorific value and proximate of the hydrochar will be determined and analyzed to find out its quality.The experiments were carried out at temperature variations of 160℃,190℃,and 220℃ and holding times of 30 and 60 minutes.The results show that an increase in temperature and holding time causes a decline in the moisture content 1.87%,volatile matter 54.03%,and ash content 12.35%,respectively,leading to elevations in the fixed carbon at 31.75%.In addition,the highest calorific value of 4149 Kcal/Kg was produced at a temperature of 220℃,within a holding time of 60 minutes.The results showed a significant increase in the quality of solid fuels between 3500–4611 Kcal/Kg in accordance with the American Standard Testing and Materials(ASTM).Therefore,this research leads to an important finding that Calophyllum inophyllum waste through the HTC process can be used as an alternative fuel to substitute lignite coal,which is environmentally friendly.