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All-optical driven soft crawler with complexmotion capabilities
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作者 Chenchu Zhang Jin Wang +9 位作者 Linhan zhao Renfei Chen qiangqiang zhao Jie zhao Fating Liu Yucheng Bian Heng Zhang Yisen Wang Chaowei Wang Ying Hu 《International Journal of Smart and Nano Materials》 SCIE EI 2024年第2期348-364,共17页
The emergence of millimeter-scale soft actuators has signifi-cantly expanded the potential applications in areas such as search and rescue,drug delivery,and human assistance,due to their high flexibility.Despite these... The emergence of millimeter-scale soft actuators has signifi-cantly expanded the potential applications in areas such as search and rescue,drug delivery,and human assistance,due to their high flexibility.Despite these advancements,achieving precise control over the intricate movements of soft crawlers poses a significant challenge.In this study,we have developed an all-optical approach that enables manipulation of propul-sive forces by simultaneously modifying the magnitude and direction of friction forces,thereby enabling complex motions of soft actuators.Importantly,the approach is not constrained by specific actuator shapes,and theoretically,any elongated photothermal actuator can be employed.The actuator was designed with an isosceles trapezoid shape,featuring a top width of 2mm,a bottom width of 4 mm,and a length of 8 mm.Through our,manipulation approach,we showcase a proof-of-concept for complex soft robotic motions,including crawling(achieving speeds of up to 2.25 body lengths per minute),turning,avoiding obstacles,handling and trans-ferring objects approximately twice its own weight,and navi-gating narrow spaces along programmed paths.Our results showcasethis all-optical manipulationapproach as a promising,yet unexplored tool for the precision and wireless control for the development of advanced soft actuators. 展开更多
关键词 Light driven soft actuator all-optical manipulation laser manipulation
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硼酸提升钙钛矿太阳能电池前驱体溶液的稳定性 被引量:1
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作者 刘大昌 范颖平 +7 位作者 王啸 赵强强 李志鹏 王莉 邵志鹏 张秉乾 崔光磊 逄淑平 《中国科学:化学》 CAS CSCD 北大核心 2022年第2期355-361,共7页
钙钛矿前驱体溶液的稳定性是一个长期被忽视的问题,其对器件效率、稳定性和一致性至关重要.在甲胺甲脒复合钙钛矿体系中,溶液的不稳定性主要是由碘化甲胺的去质子化及其衍生的转亚胺基副反应造成的.在本文中,我们系统研究了不同的酸添... 钙钛矿前驱体溶液的稳定性是一个长期被忽视的问题,其对器件效率、稳定性和一致性至关重要.在甲胺甲脒复合钙钛矿体系中,溶液的不稳定性主要是由碘化甲胺的去质子化及其衍生的转亚胺基副反应造成的.在本文中,我们系统研究了不同的酸添加剂对去质子化和转亚胺基反应平衡的影响规律,发现不易于升华的硼酸具有更好的稳定效果.硼酸作为一种路易斯酸,具有sp^(2)杂化的硼原子,硼原子中未杂化的p轨道易接受一对孤对电子,从而形成配位键.在混合有机阳离子钙钛矿溶液中,B原子与I^(-)离子之间存在强的配位相互作用,可以有效抑制碘化甲胺的去质子化反应以及甲胺与碘化甲脒的转亚胺基反应,使生成副产物的含量降低了97.9%.加入硼酸稳定剂的钙钛矿前驱体溶液在老化不同时间后制备的钙钛矿薄膜和器件具有良好的重复性和一致性,这对推动钙钛矿电池的商业化进程具有重要意义. 展开更多
关键词 钙钛矿太阳能电池 溶液化学 硼酸 转亚胺基反应 去质子化
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