期刊文献+
共找到54篇文章
< 1 2 3 >
每页显示 20 50 100
富含氧空位的由多金属氧簇辅助的银基异质结用于高效电催化固氮
1
作者 陈昕煜 赵聪聪 +8 位作者 任静 李波 刘倩倩 李葳 杨帆 陆思琦 赵宇飞 颜力楷 臧宏瑛 《Chinese Journal of Catalysis》 SCIE CAS CSCD 2024年第7期209-218,共10页
目前工业产氨主要依赖传统的Haber-Bosch工艺,然而该工艺条件苛刻,需要高温(350-550℃)和高压(150-250bar),每年消耗全球能源供应的2%,同时排放4.5亿吨二氧化碳(占全球总排放量的1.6%).近年来,科研工作者致力于开发高效率、高选择性的... 目前工业产氨主要依赖传统的Haber-Bosch工艺,然而该工艺条件苛刻,需要高温(350-550℃)和高压(150-250bar),每年消耗全球能源供应的2%,同时排放4.5亿吨二氧化碳(占全球总排放量的1.6%).近年来,科研工作者致力于开发高效率、高选择性的固氮电催化剂,但是由于析氢反应的强烈竞争,目前已报道的氮还原催化剂仍然受到低法拉第效率和低氨产率的限制.因此,开发活性位点丰富、氮气吸附能力强、催化性能优异的氮还原电催化剂成为当务之急.贵金属催化剂由于其纳米结构中富含活性位点,并且金属表界面处具有较好的导电性,因此表现出较高的法拉第效率.而分子催化剂因可调的电子结构和明确的构效关系引起了广泛关注.多金属氧簇是一种典型的金属聚阴离子团簇,由氧原子连接的含氧多面体组成,且具备优异的氧化还原性能.因此,本课题组尝试将多金属氧簇分子引入到氮还原催化剂中,并探究其催化机理.本文选取了一个多金属氧簇为前驱体,在溶剂、还原剂和诱导剂共存时,通过一锅法合成了富含氧空位的AgPW_(11)/Ag纳米方块电催化剂.实验结果表明,富含氧空位的AgPW_(11)/Ag异质结催化剂在-0.2 V(vs.RHE)电位时表现出高达46.02±1.03μg h^(-1)mg^(-1)_(cat).的氨产率和34.07±0.16%的法拉第效率,催化反应能够稳定运行32h且性能未见衰减,显著优于银催化剂.随后系统地研究了AgPW_(11)/Ag催化剂的氮还原活性位点,发现异质结中的银单质为催化反应提供了高导电性的支持,而催化剂中的银氧簇具有较好的电子得失能力,有利于促进氮还原反应中的六电子转移过程.丰富的氧空位利于吸附氮气,也能协同提升AgPW_(11)/Ag对电化学氮还原的催化活性.密度泛函理论计算结果表明,在还原后的银氧簇中,银原子d轨道与氮气π*轨道之间的强相互作用激活了吸附的氮气,促进了第一个质子化过程:*N_(2)向*N-NH的转化(电化学决速步).综上,本工作建立了异质结催化剂的催化性能与其分子结构之间的构效关系,为开发多金属氧簇及其衍生物作为电催化剂提供了依据和思路. 展开更多
关键词 多酸 金属氧簇 电催化 氮还原 氧空位 密度泛函理论 异质结
下载PDF
内建电场与偶极场协同增强SnNb_(2)O_(6)/富氮C_(3)N_(5)S型异质结光催化性能
2
作者 刘倩倩 杜兴 +2 位作者 李宛飞 戴维林 刘波 《物理化学学报》 SCIE CAS CSCD 北大核心 2024年第10期48-51,共4页
定向电荷转移是调控光生载流子分离动力学的一种极具吸引力的策略。本文通过在SnNb_(2)O_(6)纳米片上原位生长C_(3)N_(5)纳米棒,设计一种具有强内建电场(IEF)和偶极场(DF)的新型2D/1D SnNb_(2)O_(6)/富氮C_(3)N_(5)S型异质结。通过构筑... 定向电荷转移是调控光生载流子分离动力学的一种极具吸引力的策略。本文通过在SnNb_(2)O_(6)纳米片上原位生长C_(3)N_(5)纳米棒,设计一种具有强内建电场(IEF)和偶极场(DF)的新型2D/1D SnNb_(2)O_(6)/富氮C_(3)N_(5)S型异质结。通过构筑S型异质结,在界面处产生IEF,促进电荷从SnNb_(2)O_(6)向C_(3)N_(5)的定向迁移。与此同时,C_(3)N_(5)中的DF提供一种驱动力,将光生电子定向转移至活性位点。通过IEF和DF的协同效应,SnNb_(2)O_(6)/C_(3)N_(5)异质结实现了快速的定向电子转移,从而显著提高了电荷分离效率。研究结果表明,SnNb_(2)O_(6)/C_(3)N_(5)异质结的最佳产氢速率高达1090.0μmol·g^(-1)·h^(-1)(反应过程中持续释放H2气泡),分别是SnNb_(2)O_(6)和C_(3)N_(5)的38.8和10.7倍。此外,SnNb_(2)O_(6)/C_(3)N_(5)异质结在去除罗丹明B、四环素和Cr(Ⅵ)方面也表现出优异的光催化性能。通过电子顺磁共振(EPR)、时间分辨光致发光光谱(TPRL)和密度泛函理论(DFT)计算,本文系统探讨了SnNb_(2)O_(6)/C_(3)N_(5)异质结的定向电荷转移机制。这项研究为开发高效异质结光催化剂提供了一种可行的方法。 展开更多
关键词 SnNb_(2)O_(6)/C_(3)N_(5) 内建电场 偶极场 光催化性能 定向电荷转移
下载PDF
用于提升全水解性能的超低含量Ru掺杂NiMoO_(4)@Ni_(3)(PO_(4))_(2)核壳纳米结构
3
作者 Adel Al-Salihy 梁策 +5 位作者 Abdulwahab Salah Abdel-Basit Al-Odayni 卢子昂 陈孟新 刘倩倩 徐平 《Chinese Journal of Catalysis》 SCIE CAS CSCD 2024年第5期360-375,共16页
随着全球能源危机和环境污染日益加剧,开发可持续的绿色能源技术已经成为当务之急.其中,水分解制氢作为一种清洁能源的生产方式,因其零排放和高能量密度的特点,而受到广泛的研究和关注.析氢反应(HER)和析氧反应(OER)是水分解过程的关键... 随着全球能源危机和环境污染日益加剧,开发可持续的绿色能源技术已经成为当务之急.其中,水分解制氢作为一种清洁能源的生产方式,因其零排放和高能量密度的特点,而受到广泛的研究和关注.析氢反应(HER)和析氧反应(OER)是水分解过程的关键步骤,它们的反应效率直接影响整个制氢过程的能量转换效率.因此,开发高效的双功能电催化剂对于推动水分解技术的发展具有重要意义.本文制备了一种超低Ru掺杂的新型核壳纳米结构电催化剂,该催化剂生长在泡沫镍(NF)上,简称Ru-NiMoO_(4)@Ni_(3)(PO_(4))_(2)/NF.首先,通过水热法在NF上均匀生长了水合NiMoO_(4)纳米柱,并通过共价相互作用,确保其在垂直方向上有序排列.随后,采用超低浓度的RuCl_(3)对NiMoO_(4)纳米柱进行蚀刻,并通过磷酸化反应引入(PO_(4))^(3+)离子形成了Ni_(3)(PO_(4))_(2)壳层.这种设计克服了以往Ru易团聚的难题,保障了Ru的均匀分布,从而合成Ru-NiMoO_(4)@Ni_(3)(PO_(4))_(2)/NF催化剂.通过X-射线衍射、X-射线光电子能谱及透射电子显微镜等对催化剂的化学组分和微观结构进行了分析,证实其成功制备.元素分析结果表明,催化剂中Ru的含量仅为1.94 wt%,显著降低了其制备成本.电化学测试结果表明,该催化剂在HER和OER中均表现出较好的催化活性.在10和100 mA cm^(−2)电流密度下,HER的过电位分别为−14.8和−57.1 mV,Tafel斜率为35.8 mV dec^(-1),优于商业Pt/C催化剂;在100 mA cm^(−2)电流密度下,OER过电位为259.7 mV,Tafel斜率为21.6 mV dec^(−1),优于商业RuO_(2)催化剂.在全水解测试中,该催化剂在10和100 mA cm^(−2)时所需的电池电压分别为1.43和1.68 V,与其他自支撑材料相比表现出良好的性能.此外,该催化剂在150 h性能测试过程中表现出较好的稳定性.采用密度泛函理论计算研究了催化剂具有较好活性的内在机制.结果表明,其具有低水离解能垒(ΔGb=0.46 eV),接近零的HER自由吸附能(∆G*H=0.02 eV),低的OER自由吸附能量(ΔG*OOH−ΔG*OH=2.74 eV)和接近费米能级的高密度态.这些特性共同促进了电解水反应的高效进行.综上,本文研究开发的Ru-NiMoO_(4)@Ni_(3)(PO_(4))_(2)/NF双功能催化剂具有较好的催化活性、低电位需求和长期稳定性,为氢气生产开辟了新途径,也为优化双功能水分解催化剂提供了新视角,并为未来可持续能源应用发展提供一定的参考. 展开更多
关键词 电催化 核壳结构 掺杂 密度泛函理论 析氢反应 析氧反应 分解水
下载PDF
改革开放40年我国幼儿园、家庭、社区协同共育的发展与展望 被引量:63
4
作者 李晓巍 刘倩倩 郭媛芳 《学前教育研究》 CSSCI 北大核心 2019年第2期12-20,共9页
改革开放40年来,幼儿园、家庭、社区三方关系不断发展,历经服务性联结关系阶段(1978~1988年)、协同共育意识萌芽阶段(1989~1995年)、协同共育意识成熟阶段(1996~2005年)、协同共育初步发展阶段(2006年至今)四个时期。当前幼儿园、家... 改革开放40年来,幼儿园、家庭、社区三方关系不断发展,历经服务性联结关系阶段(1978~1988年)、协同共育意识萌芽阶段(1989~1995年)、协同共育意识成熟阶段(1996~2005年)、协同共育初步发展阶段(2006年至今)四个时期。当前幼儿园、家庭、社区协同共育缺乏专门的政策规章与监督机制,相关理论与实证研究亟待加强,实践中三方存在"不协同"现象。为有效实现幼儿园、家庭、社区协同共育,需完善相关政策,建立监督评价体系;开展理论与实证研究,并注重研究与实践的密切结合;运用多种方式扭转协同共育实践中的"不协同"现象。 展开更多
关键词 协同共育 幼儿园 家庭 社区
下载PDF
In-situ optimizing the valence configuration of vanadium sites in NiV-LDH nanosheet arrays for enhanced hydrogen evolution reaction 被引量:5
5
作者 Danyang He Liyun Cao +6 位作者 Jianfeng Huang Koji Kajiyoshi Jianpeng Wu Changcong Wang qianqian liu Dan Yang Liangliang Feng 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2020年第8期263-271,I0010,共10页
Developing the highly active, cost-effective, environmental-friendly, and ultra-stable nonprecious electrocatalysts for hydrogen evolution reaction(HER) is distinctly indispensable for the large-scale practical applic... Developing the highly active, cost-effective, environmental-friendly, and ultra-stable nonprecious electrocatalysts for hydrogen evolution reaction(HER) is distinctly indispensable for the large-scale practical applications of hydrolytic hydrogen production. Herein, we report the synthesis of well-integrated electrode, NiV layered double hydroxide nanosheet array grown in-situ on porous nickel foam(abbreviated as in-NiV-LDH/NF) via the facile one-step hydrothermal route. Interestingly, the valence configuration of vanadium(V) sites in such NiV-LDH are well dominated by the innovative use of NF as the reducing regulator, achieving the reassembled in-NiV-LDH/NF with a high proportion of trivalent V ions(V3+), and then an enhanced intrinsic electrocatalytic HER activity. The HER testing results show that the in-NiVLDH/NF drives the current densities of 10 and 100 mA cm-2 at extremely low overpotentials of 114 and 245 mV without iR-compensation respectively, even outperforms commercial 20 wt% Pt/C at the large current density of over 80 mA cm-2 in alkaline media, as well as gives robust catalytic durability of at least 100 h in both alkaline and neutral media. More importantly, this work provides a fresh perspective for designing bimetal(oxy) hydroxides electrocatalysts with efficient hydrogen generation. 展开更多
关键词 NiV-LDH V sites Valence configuration Stability Hydrogen evolution reaction
下载PDF
Sustained‑Release Nanocapsules Enable Long‑Lasting Stabilization of Li Anode for Practical Li‑Metal Batteries 被引量:5
6
作者 qianqian liu Yifei Xu +3 位作者 Jianghao Wang Bo Zhao Zijian Li Hao Bin Wu 《Nano-Micro Letters》 SCIE EI CAS CSCD 2020年第12期239-250,共12页
A robust solid-electrolyte interphase(SEI)enabled by electrolyte additive is a promising approach to stabilize Li anode and improve Li cycling efficiency.However,the self-sacrificial nature of SEI forming additives li... A robust solid-electrolyte interphase(SEI)enabled by electrolyte additive is a promising approach to stabilize Li anode and improve Li cycling efficiency.However,the self-sacrificial nature of SEI forming additives limits their capability to stabilize Li anode for long-term cycling.Herein,we demonstrate nanocapsules made from metal–organic frameworks for sustained release of LiNO3 as surface passivation additive in commercial carbonate-based electrolyte.The nanocapsules can offer over 10 times more LiNO3 than the solubility of LiNO3.Continuous supply of LiNO3 by nanocapsules forms a nitride-rich SEI layer on Li anode and persistently remedies SEI during prolonged cycling.As a result,lifespan of thin Li anode in 50μm,which experiences drastic volume change and repeated SEI formation during cycling,has been notably improved.By pairing with an industry-level thick LiCoO2 cathode,practical Li-metal full cell demonstrates a remarkable capacity retention of 90%after 240 cycles,in contrast to fast capacity drop after 60 cycles in LiNO3 saturated electrolyte. 展开更多
关键词 Metal–organic frameworks LiNO3 NANOCAPSULES Lithium-metal anode Lithium-metal batteries
下载PDF
Partitioning tree water usage into storage and transpiration in a mixed forest 被引量:4
7
作者 Ziqiang liu qianqian liu +3 位作者 Zijun Wei Xinxiao Yu Guodong Jia Jiang Jiang 《Forest Ecosystems》 SCIE CSCD 2021年第4期961-973,共13页
Background:Water migration and use are important processes in trees.However,it is possible to overestimate transpiration by equating the water absorbed through the plant roots to that diffused back to the atmosphere t... Background:Water migration and use are important processes in trees.However,it is possible to overestimate transpiration by equating the water absorbed through the plant roots to that diffused back to the atmosphere through stomatal transpiration.Therefore,it is necessary to quantify the water transpired and stored in plants.Method:The δ^(2)H/δ^(18)O technique and heat ratio method were used to explore the water usage of coniferous and broad-leaved tree species,including the proportions of water used for transpiration and water storage.Results:Platycladus orientalis and Quercus variabilis had strong plasticity in their water usage from different sources.Platycladus orientalis primarily used groundwater(30.5%)and the 60-100-cm soil layer(21.6%)throughout the experimental period and was sensitive to precipitation,absorbing water from the 0-20-cm layer(26.6%)during the rainy season.Quercus variabilis absorbed water from all sources(15.7%-36.5%)except from the 40-60-cm soil layer during the dry season.In addition,it did not change its water source but increased its groundwater uptake during the rainy season.The annual mean water fluxes of P.orientalis and Q.variabilis were 374.69 and 469.50 mm·year−1,with 93.49% and 93.91% of the water used for transpiration,respectively.However,nocturnal sap flow in P.orientalis and Q.variabilis was mainly used for water storage in the trunk rather than transpiration,which effectively alleviated drought stress and facilitated the transport of nutrients.Conclusions:The water stored in both species comprised 6%-7% of the total water fluxes and,therefore,should be considered in water balance models. 展开更多
关键词 Water migration Water uptake Nocturnal sap flow TRANSPIRATION
下载PDF
Superhydrophobic modification of ceramic membranes for vacuum membrane distillation 被引量:11
8
作者 Yanhui Yang qianqian liu +4 位作者 Haizhi Wang Fusheng Ding Guoshan Jin Chunxi Li Hong Meng 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2017年第10期1395-1401,共7页
The hydrophobically modi fied ceramic membranes have great potential for energy-ef ficient membrane distillation.In this work,flat-sheet ceramic membranes with a superhydrophobic surface were fabricated by grafting 1H... The hydrophobically modi fied ceramic membranes have great potential for energy-ef ficient membrane distillation.In this work,flat-sheet ceramic membranes with a superhydrophobic surface were fabricated by grafting 1H,1H,2H,2H-per fluorooctyltrichlorosilane or 1H,1H,2H,2H-per fluorodecyltriethoxysilane and followed by ultraviolet irradiation.The surface water contact angle was improved from 46° of original ceramic membrane to 159°,which exhibited a stable and excellent superhydrophobic effect.The modi fied membranes showed a high flux of 27.28 kg·m^(-2)·h^(-1) and simultaneously maintained an excellent retention rate of 99.99%,when used in vacuum membrane distillation process for treatment of a 1 wt% NaCl(75 °C) aqueous solution.These results suggested that superhydrophobic modi fication of ceramic surface is a facile and cost-effective way to achieve higher membrane distillation performance.The superhydrophobically-modi fied ceramic membrane with an excellent desalination capacity would show considerable potential in practical membrane distillation utilizations. 展开更多
关键词 Superhydrophobic modification Fluoroalkylsilane Ultraviolet irradiation Ceramic membrane Vacuum membrane distillation
下载PDF
WiFi CSI Gesture Recognition Based on Parallel LSTM-FCN Deep Space-Time Neural Network 被引量:2
9
作者 Zhiling Tang qianqian liu +2 位作者 Minjie Wu Wenjing Chen Jingwen Huang 《China Communications》 SCIE CSCD 2021年第3期205-215,共11页
In this study,we developed a system based on deep space–time neural networks for gesture recognition.When users change or the number of gesture categories increases,the accuracy of gesture recognition decreases consi... In this study,we developed a system based on deep space–time neural networks for gesture recognition.When users change or the number of gesture categories increases,the accuracy of gesture recognition decreases considerably because most gesture recognition systems cannot accommodate both user differentiation and gesture diversity.To overcome the limitations of existing methods,we designed a onedimensional parallel long short-term memory–fully convolutional network(LSTM–FCN)model to extract gesture features of different dimensions.LSTM can learn complex time dynamic information,whereas FCN can predict gestures efficiently by extracting the deep,abstract features of gestures in the spatial dimension.In the experiment,50 types of gestures of five users were collected and evaluated.The experimental results demonstrate the effectiveness of this system and robustness to various gestures and individual changes.Statistical analysis of the recognition results indicated that an average accuracy of approximately 98.9% was achieved. 展开更多
关键词 signal and information processing parallel LSTM-FCN neural network deep learning gesture recognition wireless channel state information
下载PDF
Universal memory based on phase-change materials:From phase-change random access memory to optoelectronic hybrid storage 被引量:2
10
作者 Bo liu Tao Wei +5 位作者 Jing Hu Wanfei Li Yun Ling qianqian liu Miao Cheng Zhitang Song 《Chinese Physics B》 SCIE EI CAS CSCD 2021年第5期128-149,共22页
The era of information explosion is coming and information need to be continuously stored and randomly accessed over long-term periods,which constitute an insurmountable challenge for existing data centers.At present,... The era of information explosion is coming and information need to be continuously stored and randomly accessed over long-term periods,which constitute an insurmountable challenge for existing data centers.At present,computing devices use the von Neumann architecture with separate computing and memory units,which exposes the shortcomings of“memory bottleneck”.Nonvolatile memristor can realize data storage and in-memory computing at the same time and promises to overcome this bottleneck.Phase-change random access memory(PCRAM)is called one of the best solutions for next generation non-volatile memory.Due to its high speed,good data retention,high density,low power consumption,PCRAM has the broad commercial prospects in the in-memory computing application.In this review,the research progress of phase-change materials and device structures for PCRAM,as well as the most critical performances for a universal memory,such as speed,capacity,and power consumption,are reviewed.By comparing the advantages and disadvantages of phase-change optical disk and PCRAM,a new concept of optoelectronic hybrid storage based on phase-change material is proposed.Furthermore,its feasibility to replace existing memory technologies as a universal memory is also discussed as well. 展开更多
关键词 universal memory optoelectronic hybrid storage phase-change material phase-change random access memory
下载PDF
Quasi-solid electrolyte membranes with percolated metal–organic frameworks for practical lithium-metal batteries 被引量:1
11
作者 Zijian Li qianqian liu +6 位作者 Lina Gao Yifei Xu Xueqian Kong Yang Luo Huaxin Peng Yurong Ren Hao Bin Wu 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2021年第1期354-360,I0012,共8页
High-energy Li-metal batteries (LMBs) suffer from short cycle life and safety issues due to severe parasitic reactions and dendrite growth of Li metal anode (LMA) in liquid electrolytes [1–3].It is generally believed... High-energy Li-metal batteries (LMBs) suffer from short cycle life and safety issues due to severe parasitic reactions and dendrite growth of Li metal anode (LMA) in liquid electrolytes [1–3].It is generally believed that replacing liquid electrolytes with solidstate electrolytes (SSEs) would be a feasible approach for practical LMBs [4,5]. Conventional SSEs including ceramic and polymer electrolytes have been studied for decades. 展开更多
关键词 Solid electrolyte Composite membrane Metal-organic framework Lithium metal anode Lithium-metal battery
下载PDF
化妆品中防腐剂的应用现状及检测技术研究进展 被引量:1
12
作者 朱海荣 孙胜敏 +3 位作者 张娟 刘爽 刘倩倩 邹惠玲 《日用化学工业(中英文)》 CAS 北大核心 2023年第6期679-685,共7页
化妆品中的防腐剂在抑制微生物生长、延长产品保质期方面发挥了重要作用,但其使用不当会损害人体健康并对环境和生态安全造成潜在危害。随着化妆品安全事件的频发,居民消费安全意识的提升和行业监管法规趋严,防腐剂的添加状况成为社会... 化妆品中的防腐剂在抑制微生物生长、延长产品保质期方面发挥了重要作用,但其使用不当会损害人体健康并对环境和生态安全造成潜在危害。随着化妆品安全事件的频发,居民消费安全意识的提升和行业监管法规趋严,防腐剂的添加状况成为社会各界的关注焦点。文章总结了当前化妆品中防腐剂的使用现状,梳理了近年来常规检测技术在化妆品中防腐剂领域的最新应用,介绍了高效液相色谱-电感耦合等离子体质谱法和激光解吸附离子化质谱等新型检测手段。分析了化妆品中防腐剂的市场发展前景和检测技术发展方向,为今后化妆品中防腐剂的监管和高通量快速检测提供借鉴。 展开更多
关键词 化妆品 防腐剂 应用 检测技术
下载PDF
Pharmacological Activity and Application of Roots, Stems and Leaves of Scutellaria baicalensis Georgi 被引量:1
13
作者 Xinyang liu Yuanyuan YE +2 位作者 qianqian liu Shengkai DING Yazhen SHANG 《Medicinal Plant》 CAS 2019年第6期4-5,共2页
The root of Scutellaria baicalensis Georgi is traditionally used as medicine,and it has been confirmed that S.baicalensis Georgi has flavonoid chemical constituents,pharmacological activity and cosmetic efficacy.With ... The root of Scutellaria baicalensis Georgi is traditionally used as medicine,and it has been confirmed that S.baicalensis Georgi has flavonoid chemical constituents,pharmacological activity and cosmetic efficacy.With the extensive application of S.baicalensis Georgi roots,the resource of S.baicalensis Georgi has been increasingly short.The above-ground part of stems and leaves of S.baicalensis Georgi has also been gradually recognized and developed.Studies have found that the chemical constituents from stems and leaves of S.baicalensis Georgi are also a group of flavonoids with a lot of pharmacological activity and have a great application value.Based on this,the present review will be reported on the chemical constituents and application of the roots,stems and leaves of S.baicalensis Georgi. 展开更多
关键词 ROOTS STEMS LEAVES SCUTELLARIA baicalensis Georgi Chemical constituents PHARMACOLOGICAL ACTIVITY
下载PDF
A Brief Discussion on the Toxicity of Traditional Chinese Medicine 被引量:1
14
作者 Shengkai DING Qing GUO +3 位作者 qianqian liu Xinyang liu Yuanyuan YE Yazhen SHANG 《Medicinal Plant》 CAS 2020年第3期15-17,共3页
With the wide application of traditional Chinese medicine in the world,the related reports on the toxicity of traditional Chinese medicine are increasing,which makes the safety of traditional Chinese medicine receive ... With the wide application of traditional Chinese medicine in the world,the related reports on the toxicity of traditional Chinese medicine are increasing,which makes the safety of traditional Chinese medicine receive wide attention.This paper analyzes the toxicity of traditional Chinese medicine with a fair and scientific attitude,in order to promote the benign and sustainable development of traditional Chinese medicine. 展开更多
关键词 Traditional Chinese medicine TOXICITY
下载PDF
Facile oxalic acid-assisted construction of laminated porous N-deficient graphitic carbon nitride: Highly efficient visible-light-driven hydrogen evolution photocatalyst
15
作者 Fengli Yang Jia Ren +3 位作者 qianqian liu Lu Zhang Yuanyuan Chai Wei-Lin Dai 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2019年第6期1-8,共8页
The laminated porous N-deficient g-C3N4(CN–H)is successfully synthesized by a facile two-step hydrothermal calcination method using oxalic acid-assisted melamine as the precursor.Compared with pristine g-C3N4(224μmo... The laminated porous N-deficient g-C3N4(CN–H)is successfully synthesized by a facile two-step hydrothermal calcination method using oxalic acid-assisted melamine as the precursor.Compared with pristine g-C3N4(224μmol g-1h-1),the CN–H shows superior photocatalytic hydrogen production activity(up to 728μmol g-1h-1),which is three times higher than the unmodified counterpart.To draw out the multifaceted influences of oxalic acid modification on the visible-light-induced photocatalytic activity,various techniques are utilized to investigate the formation mechanism,structural characteristics and photoelectrical properties of CN–H.The results indicate that the addition of a trace amount of oxalic acid to the precursor melamine results in a g-C3N4 structure possessing the advantage of both nitrogen defects and laminated porosity.These properties can enlarge specific surface areas of g-C3N4,enhance an efficient separating of photogenerated electron-hole pairs and extend the range of spectral response,all contributing to the enhancement of the visible-light-induced photocatalytic activity. 展开更多
关键词 Oxalic acid MELAMINE LAMINATED POROUS N-deficient g-C3N4 Visible-light-induced photocatalytic activity for H2 generation
下载PDF
Multilevel optoelectronic hybrid memory based on N-doped Ge_(2)Sb_(2)Te_(5)film with low resistance drift and ultrafast speed
16
作者 吴奔 魏涛 +6 位作者 胡敬 王瑞瑞 刘倩倩 程淼 李宛飞 凌云 刘波 《Chinese Physics B》 SCIE EI CAS CSCD 2023年第10期724-730,共7页
Multilevel phase-change memory is an attractive technology to increase storage capacity and density owing to its high-speed,scalable and non-volatile characteristics.However,the contradiction between thermal stability... Multilevel phase-change memory is an attractive technology to increase storage capacity and density owing to its high-speed,scalable and non-volatile characteristics.However,the contradiction between thermal stability and operation speed is one of key factors to restrain the development of phase-change memory.Here,N-doped Ge_(2)Sb_(2)Te_(5)-based optoelectronic hybrid memory is proposed to simultaneously implement high thermal stability and ultrafast operation speed.The picosecond laser is adopted to write/erase information based on reversible phase transition characteristics whereas the resistance is detected to perform information readout.Results show that when N content is 27.4 at.%,N-doped Ge_(2)Sb_(2)Te_(5)film possesses high ten-year data retention temperature of 175℃and low resistance drift coefficient of 0.00024 at 85℃,0.00170 at 120℃,and 0.00249 at 150℃,respectively,owing to the formation of Ge–N,Sb–N,and Te–N bonds.The SET/RESET operation speeds of the film reach 520 ps/13 ps.In parallel,the reversible switching cycle of the corresponding device is realized with the resistance ratio of three orders of magnitude.Four-level reversible resistance states induced by various crystallization degrees are also obtained together with low resistance drift coefficients.Therefore,the N-doped Ge_(2)Sb_(2)Te_(5)thin film is a promising phase-change material for ultrafast multilevel optoelectronic hybrid storage. 展开更多
关键词 multilevel optoelectronic hybrid memory N-doped Ge_(2)Sb_(2)Te_(5)thin film low resistance drift ultrafast speed
下载PDF
Application of Six Sigma Theory in Process Reengineering of Food Safety Monitoring Laboratory
17
作者 Suzhen ZHU qianqian liu +2 位作者 Chao LIN Lei WANG Yun MA 《Asian Agricultural Research》 2014年第3期53-54,59,共3页
Based on the survey of customer satisfaction,the authors found existing problems in inspection process of the food safety monitoring laboratory A( including the whole process from receiving samples to issue of inspect... Based on the survey of customer satisfaction,the authors found existing problems in inspection process of the food safety monitoring laboratory A( including the whole process from receiving samples to issue of inspection report),and determined solutions using flow chart supplied by sig sigma( 6σ) theory. Through comparing overall effect before and after improvement of the inspection process,it is proved that 6σmanagement theory is a new effective management tool for eliminating errors,simplifying process,and meeting requirements of customers to the maximal extent. 展开更多
关键词 SIX sigma(6σ) FOOD safety LABORATORY INSPECTION pr
下载PDF
A Brief Discussion on the Safety of Famous Region Herb
18
作者 qianqian liu Qing GUO +3 位作者 Shengkai DING Xinyang liu Yuanyuan YE Yazhen SHANG 《Medicinal Plant》 CAS 2020年第4期1-2,9,共3页
With the vigorous development of the Chinese herbal medicine market in China,the production of high-quality authentic medicinal materials must not only ensure its unique authentic properties,but also ensure its qualit... With the vigorous development of the Chinese herbal medicine market in China,the production of high-quality authentic medicinal materials must not only ensure its unique authentic properties,but also ensure its quality and safety.This article elaborates the challenges faced by the authentic Chinese medicinal materials and gives suggestions to improve the quality system of Chinese medicinal materials. 展开更多
关键词 Famous region herb Hebei Province Chinese medicine safety
下载PDF
Extraction Technology and Content Determination of Total Flavonoids from Traditional Chinese Medicine Yipichou
19
作者 qianqian liu Wen ZHONG +5 位作者 Zongxi SUN Xiumei MA Xinli LU Yusheng HUANG Jingrong LU Jiangcun WEI 《Medicinal Plant》 CAS 2021年第1期47-50,55,共5页
[Objectives]The research aimed to optimize extraction technology of total flavonoids from traditional Chinese medicine Yipichou,and establish methods of extraction and content determination of its medicinal materials.... [Objectives]The research aimed to optimize extraction technology of total flavonoids from traditional Chinese medicine Yipichou,and establish methods of extraction and content determination of its medicinal materials.[Methods]Using reflux extraction method,total flavonoids of Yipichou were extracted.Via single-factor test,influence of extraction method,extraction solvent concentration,extraction volume and extraction time on content of total flavonoids from Yipichou was inspected.Using orthogonal test,extraction conditions were optimized,and optimal extraction technology of total flavonoids from Yipichou was obtained.[Results]The optimal extraction process of total flavonoids from Yipichou was as below:70%of methanol,1∶40 of solid-liquid ratio,and 1.0 h of reflux extraction time.[Conclusions]In the test,total flavonoids were extracted from Yipichou,with better repeatability,and stable and feasible method,which could provide certain scientific basis for studying quality standard of this medicinal material. 展开更多
关键词 Yipichou Total flavonoids Extraction process Ultraviolet-visible spectrophotometry
下载PDF
Examining urban-rural differences in the impact of Internet use on older adults’ depression: evidence from China
20
作者 Kai Sun Yuxiang Chris Zhao +2 位作者 Xiaofeng Tao Junjie Zhou qianqian liu 《Data Science and Management》 2022年第1期13-20,共8页
Both Internet use’s impact on depression and urban-rural disparities related to information and communication technologies(ICTs)are crucial topics in the information systems discipline.So far,limited studies have exp... Both Internet use’s impact on depression and urban-rural disparities related to information and communication technologies(ICTs)are crucial topics in the information systems discipline.So far,limited studies have explored these topics in a comprehensive way.This study aims to explore the impact of Internet use on urban and rural older adults’depression and provide insights into how ICTs play positive roles in human behaviors.Based on data from the China Health and Retirement Longitudinal Study,we used the panel-data regression approach to examine the relationships between older adults’Internet use and depression,and adopted the propensity score matching and the difference-in-difference approach to test the robustness of our findings.We found that the influencing mechanisms behind Internet use’s impact on urban and rural older adults’depression are different.Internet use not only directly reduces rural older adults’depression but also indirectly reduces it via the mediation of social activity,while the impact of Internet use on urban older adults’depression is fully mediated by social activity.We found that Internet use exerts different impacts on urban and rural older adults’depression,and rural older adults can receive a greater benefit. 展开更多
关键词 DEPRESSION Older adult WELL-BEING Internet use Quantitative research methods China
下载PDF
上一页 1 2 3 下一页 到第
使用帮助 返回顶部