外加物理场调控二维材料的HER和OER性能

长期以来,氢燃料一直被认为是一种有前途和可行的传统化石燃料的替代品,可以支撑我们未来的能源格局。电催化水分解是一种可用于大规模高效生产高纯度氢气的可持续和环保的技术。该技术的工业化需要我们不断地提高两个电极上的析氢反应(HER)和析氧反应(OER)的反应动力学。此外,催化剂催化活性和结构稳定性的持续优化对于该技术的实际实施同样关键。因此,合适的催化剂的选取是影响电催化水分解的关键因素之一。二维(2D)纳米材料由于其独特的物理化学性质和丰富的活性位点成为了电解水领域的热点。此外,2D材料独特的物理化学特性能与外加物理场之间高度契合,可以产生一些独特的效果来增强电催化性能。因此,近些年,外加物理场在辅助改善HER和OER方面的作用和机制越来越受到关注。外加物理场,如电场,磁场,应变,光,温度和超声波,可以应用于催化剂合成和电催化过程。本文首先总结了物理场辅助电解水催化剂合成的研究。随后,根据外场在电催化过程中作用机制的不同,对外场辅助HER和OER的研究进行了分类。最后,本文指出了本领域快速发展所面临的主要挑战和前景。

Construction of Dynamic Alloy Interfaces for Uniform Li Deposition in Li-Metal Batteries

It is well accepted that a lithiophilic interface can effectively regulate Li deposition behaviors,but the influence of the lithiophilic interface is gradually diminished upon continuous Li deposition that completely isolates Li from the lithiophilic metals.Herein,we perform in-depth studies on the creation of dynamic alloy interfaces upon Li deposition,arising from the exceptionally high diffusion coefficient of Hg in the amalgam solid solution.As a comparison,other metals such as Au,Ag,and Zn have typical diffusion coefficients of 10-20 orders of magnitude lower than that of Hg in the similar solid solution phases.This difference induces compact Li deposition pattern with an amalgam substrate even with a high areal capacity of 55 mAh cm^(-2).This finding provides new insight into the rational design of Li anode substrate for the stable cycling of Li metal batteries.

Hydrogel-based catalysts for hydrogen generation by the hydrolysis of B–H compounds under external physical fields

Hydrogen is a popular clean high-energy-density fuel.However,its utilization is limited by the challenges toward low-cost hydrogen production and safe hydrogen storage.Fortunately,these issues can be addressed using promising hydrogen storage materials such as B–H compounds.Hydrogen stored in B–H compounds can be released by hydrolysis at room temperature,which requires catalysts to increase the rate of the reaction.Recently,several effective approaches have been developed for hydrogen generation by catalyzing the hydrolysis of B–H compounds.This review summarizes the existing research on the use of nanoparticles loaded on hydrogels as catalysts for the hydrolysis of B–H compounds.First,the factors affecting the hydrolysis rate,such as temperature,p H,reactant concentration,and type of nano particles,were investigated.Further,the preparation methods(in situ reduction,one-pot method,template adsorption,etc.)for the hydrogel catalysts and the types of loaded catalysts were determined.Additionally,the hydrogel catalysts that can respond to magnetic fields,ultrasound fields,optical fields,and other physical fields are introduced.Finally,the issues and future developments of hydrogel-based catalysts are discussed.This review can inspire deeper investigations and provide guidance for the study of hydrogel catalysts in the field of hydrogen production via hydrolysis.

聚合物基复合固态电解质中锂枝晶生长的相场模拟研究

固态锂金属电池是最具潜力的下一代高能量密度储能技术,但其面临的一个最迫切问题是锂枝晶的不均匀生长.目前低模量复合固态电解质,特别是低模量多相复合固态电解质,抑制锂枝晶生长的机制还没有被完全明确.因此,本文通过相场法构建了力学-化学模型,研究了复合固态电解质不同弹性模量对于锂枝晶生长的影响,结果表明电解质模量越高,锂金属的应力越大,易使锂枝晶发生塑性形变,从而抑制锂枝晶的生长.本文的研究加深理解了低模量多相复合固态电解质抑制锂枝晶的机制,并为复合固态电解质的设计提供了指导.

Strain engineering in electrocatalysis:Strategies,characterization,and insights

Strain engineering,as a cutting-edge method for modulating the electronic structure of catalysts,plays a crucial role in regulating the interaction between the catalytic surface and the adsorbed molecules.The electrocatalytic performance is influenced by the electronic structure,which can be achieved by introducing the external forces or stresses to adjust interatomic spacing between surface atoms.The challenges in strain engineering research lie in accurately understanding the mechanical impact of strain on performance.This paper first introduces the basic strategy for generating the strain,summarizes the different strain generation forms and their advantages and disadvantages.The progress in researching the characterization means for the lattice strains and their applications in the field of electrocatalysis is also emphasized.Finally,the challenges of strain engineering are introduced,and an outlook on the future research directions is provided.

基于等效电路模型理解机械应变对电催化反应的作用

电催化的应变工程被认为是提高材料电催化性能最有效的策略之一.然而,目前还缺乏数学模型来深入理解这些有趣的科学现象.本文基于等效电路理论研究了应变对电极反应中法拉第过程的影响.根据基尔霍夫定律,获得了应变影响电极响应电流的数学表达式,研究了法拉第过程逐渐成为电催化反应的主导作用时,由应变导致的响应电流参数的变化趋势和峰值的变化规律,并深入探索电催化反应中不同因素相互作用的复杂机制.