Black shales are important products of material cycling and energy exchange among the lithosphere,atmosphere,hydrosphere,and biosphere.They are widely distributed throughout geological history and provide essential en...Black shales are important products of material cycling and energy exchange among the lithosphere,atmosphere,hydrosphere,and biosphere.They are widely distributed throughout geological history and provide essential energy and mineral resources for the development of human society.They also record the evolution process of the earth and improve the understanding of the earth.This review focuses on the diagenesis and formation mechanisms of black shales sedimentation,composition,evolution,and reconstruction,which have had a significant impact on the formation and enrichment of shale oil and gas.In terms of sedimentary environment,black shales can be classified into three types:Marine,terrestrial,and marine-terrestrial transitional facies.The formation processes include mechanisms such as eolian input,hypopycnal flow,gravity-driven and offshore bottom currents.From a geological perspective,the formation of black shales is often closely related to global or regional major geological events.The enrichment of organic matter is generally the result of the interaction and coupling of several factors such as primary productivity,water redox condition,and sedimentation rate.In terms of evolution,black shales have undergone diagenetic evolution of inorganic minerals,thermal evolution of organic matter and hydrocarbon generation,interactions between organic matter and inorganic minerals,and pore evolution.In terms of reconstruction,the effects of fold deformation,uplift and erosion,and fracturing have changed the stress state of black shale reservoirs,thereby having a significant impact on the pore structure.Fluid activity promotes the formation of veins,and have changed the material composition,stress structure,and reservoir properties of black shales.Regarding resource effects,the deposition of black shales is fundamental for shale oil and gas resources,the evolution of black shales promotes the shale oil and gas formation and storage,and the reconstruction of black shales would have caused the heterogeneous distribution of oil and gas in shales.Exploring the formation mechanisms and interactions of black shales at different scales is a key to in-depth research on shale formation and evolution,as well as the key to revealing the mechanism controlling shale oil and gas accumulation.The present records can reveal how these processes worked in geological history,and improve our understanding of the coupling mechanisms among regional geological events,black shales evolution,and shale oil and gas formation and enrichment.展开更多
The shale gas resources in China have great potential and the geological resources of shale gas is over 100×10^(12)m^(3),which includes about 20×10^(12)m^(3) of recoverable resources.Organic-rich shales can ...The shale gas resources in China have great potential and the geological resources of shale gas is over 100×10^(12)m^(3),which includes about 20×10^(12)m^(3) of recoverable resources.Organic-rich shales can be divided into three types according to their sedimentary environments,namely marine,marine-continental transitional,and continental shales,which are distributed in 13 stratigraphic systems from the Mesoproterozoic to the Cenozoic.The Sichuan Basin and its surrounding areas have the highest geological resources of shale gas,and the commercial development of shale gas has been achieved in the Upper Ordovician Wufeng Formation-Lower Silurian Longmaxi Formation in these areas,with a shale gas production of up to 20×10^(9)m^(3) in 2020.China has seen rapid shale gas exploration and development over the last five years,successively achieving breakthroughs and important findings in many areas and strata.The details are as follows.(1)Large-scale development of middle-shallow shale gas(burial depth:less than 3500 m)has been realized,with the productivity having rapidly increased;(2)breakthroughs have been constantly made in the development of deep shale gas(burial depth:3500-4500 m),and the ultradeep shale gas(burial depth:greater than 4500 m)is under testing;(3)breakthroughs have been made in the development of normal-pressure shale gas,and the assessment of the shale gas in complex tectonic areas is being accelerated;(4)shale gas has been frequently discovered in new areas and new strata,exhibiting a great prospect.Based on the exploration and development practice,three aspects of consensus have been gradually reached on the research progress in the geological theories of shale gas achieved in China.(1)in terms of deep-water fine-grained sediments,organic-rich shales are the base for the formation of shale gas;(2)in terms of high-quality reservoirs,the development of micro-nano organic matter-hosted pores serves as the core of shale gas accumulation;(3)in terms of preservation conditions,weak structural transformation,a moderate degree of thermal evolution,and a high pressure coefficient are the key to shale gas enrichment.As a type of important low-carbon fossil energy,shale gas will play an increasingly important role in achieving the strategic goals of peak carbon dioxide emissions and carbon neutrality.Based on the in-depth study of shale gas geological conditions and current exploration progress,three important directions for shale gas exploration in China in the next five years are put forward.展开更多
The sequence stratigraphic framework of Shanxi Formation in the northeast Zhoukou Depression was established based on detailed sequence stratigraphical and sedimentological analysis by utilizing the logging and core d...The sequence stratigraphic framework of Shanxi Formation in the northeast Zhoukou Depression was established based on detailed sequence stratigraphical and sedimentological analysis by utilizing the logging and core data of six wells drilled in the eastern tectonic unit of Zhoukou Depression.It was divided into three third-order sequences,namely SQs1,SQs2,and SQs3 from bottom to top.Each sequence can be divided into a transgressive system tract(TST)and a highstand system tract(HST).Furthermore,four sequence boundaries and three maximum flooding surfaces were identified,and they are the bottom interface SBs and maximum flooding surface mfss1 of SQs1,the bottom interface SBs1 and maximum flooding surface mfss2 of SQs2,the bottom interface SBs3 and maximum flooding surface mfss3 of SQs3,and the top interface SBx from bottom to top.Carbonate tidal flat–clastic tidal flat sedimentary system developed in Shanxi Formation in the northeast Zhoukou Depression(also referred to as the study area)under the control of regression.Meanwhile,four sedimentary microfacies were identified in the sedimentary system,which are lime-mud flats,sand flats,mixed flats,and mud flats.The transgression in the study area occurred from the southeast to the northwest.Therefore,the northwestern part is the seaward side,and the southeastern part is the landward side.As revealed by relevant drilling data,SQs1 of the Shanxi Formation is characterized by the development of limestone and carbonaceous mudstone,with limestone,dark mudstone,and carbonaceous mudstone mainly developing.Meanwhile,lime-mud flats were mainly deposited in it.During the periods of SQs2 and SQs3,the sedimentary environment of the study area changed from the carbonate tidal flats to clastic tidal flats as the coastline migrated towards the sea.In these periods,sand flats mainly developed near the maximum flooding surfaces and were relatively continuous in the eastern and southern parts of the transgressive system tract;mixed flats were relatively continuous in the western and northern parts of the transgressive system tract as well as the eastern and southern parts of the highstand system tract;mud flats widely developed in the highstand system tract.Peat flats mainly developed in the period of HSTs2,with coal seams relatively developing in the southeastern part of the study area as revealed by drilling data.The peat flats in SQs2 are favorable hydrocarbon source layers,the lime-mud flats in SQs1 and sand flats formed in the transgression periods of SQs2 and SQs3 constitute favorable hydrocarbon reservoirs,and the mud flats form in the transgressions periods serve as favorable cap rocks.Therefore,the study area features a reservoir-cap assemblage for self-generating and self-storing of hydrocarbon,and the southeastern part of the study area can be taken as a favorable exploration area.展开更多
基金supported by the projects of the China Geological Survey(DD20230043,DD20240048)the project of the National Natural Science Foundation of China(42102123)。
文摘Black shales are important products of material cycling and energy exchange among the lithosphere,atmosphere,hydrosphere,and biosphere.They are widely distributed throughout geological history and provide essential energy and mineral resources for the development of human society.They also record the evolution process of the earth and improve the understanding of the earth.This review focuses on the diagenesis and formation mechanisms of black shales sedimentation,composition,evolution,and reconstruction,which have had a significant impact on the formation and enrichment of shale oil and gas.In terms of sedimentary environment,black shales can be classified into three types:Marine,terrestrial,and marine-terrestrial transitional facies.The formation processes include mechanisms such as eolian input,hypopycnal flow,gravity-driven and offshore bottom currents.From a geological perspective,the formation of black shales is often closely related to global or regional major geological events.The enrichment of organic matter is generally the result of the interaction and coupling of several factors such as primary productivity,water redox condition,and sedimentation rate.In terms of evolution,black shales have undergone diagenetic evolution of inorganic minerals,thermal evolution of organic matter and hydrocarbon generation,interactions between organic matter and inorganic minerals,and pore evolution.In terms of reconstruction,the effects of fold deformation,uplift and erosion,and fracturing have changed the stress state of black shale reservoirs,thereby having a significant impact on the pore structure.Fluid activity promotes the formation of veins,and have changed the material composition,stress structure,and reservoir properties of black shales.Regarding resource effects,the deposition of black shales is fundamental for shale oil and gas resources,the evolution of black shales promotes the shale oil and gas formation and storage,and the reconstruction of black shales would have caused the heterogeneous distribution of oil and gas in shales.Exploring the formation mechanisms and interactions of black shales at different scales is a key to in-depth research on shale formation and evolution,as well as the key to revealing the mechanism controlling shale oil and gas accumulation.The present records can reveal how these processes worked in geological history,and improve our understanding of the coupling mechanisms among regional geological events,black shales evolution,and shale oil and gas formation and enrichment.
基金supported by a project of shale gas in Southern China(DD20190561)initiated by the China Geological Surveythe project for High-level Innovative Talents in Science and Technology,Ministry of Natural Resources(12110600000018003918)。
文摘The shale gas resources in China have great potential and the geological resources of shale gas is over 100×10^(12)m^(3),which includes about 20×10^(12)m^(3) of recoverable resources.Organic-rich shales can be divided into three types according to their sedimentary environments,namely marine,marine-continental transitional,and continental shales,which are distributed in 13 stratigraphic systems from the Mesoproterozoic to the Cenozoic.The Sichuan Basin and its surrounding areas have the highest geological resources of shale gas,and the commercial development of shale gas has been achieved in the Upper Ordovician Wufeng Formation-Lower Silurian Longmaxi Formation in these areas,with a shale gas production of up to 20×10^(9)m^(3) in 2020.China has seen rapid shale gas exploration and development over the last five years,successively achieving breakthroughs and important findings in many areas and strata.The details are as follows.(1)Large-scale development of middle-shallow shale gas(burial depth:less than 3500 m)has been realized,with the productivity having rapidly increased;(2)breakthroughs have been constantly made in the development of deep shale gas(burial depth:3500-4500 m),and the ultradeep shale gas(burial depth:greater than 4500 m)is under testing;(3)breakthroughs have been made in the development of normal-pressure shale gas,and the assessment of the shale gas in complex tectonic areas is being accelerated;(4)shale gas has been frequently discovered in new areas and new strata,exhibiting a great prospect.Based on the exploration and development practice,three aspects of consensus have been gradually reached on the research progress in the geological theories of shale gas achieved in China.(1)in terms of deep-water fine-grained sediments,organic-rich shales are the base for the formation of shale gas;(2)in terms of high-quality reservoirs,the development of micro-nano organic matter-hosted pores serves as the core of shale gas accumulation;(3)in terms of preservation conditions,weak structural transformation,a moderate degree of thermal evolution,and a high pressure coefficient are the key to shale gas enrichment.As a type of important low-carbon fossil energy,shale gas will play an increasingly important role in achieving the strategic goals of peak carbon dioxide emissions and carbon neutrality.Based on the in-depth study of shale gas geological conditions and current exploration progress,three important directions for shale gas exploration in China in the next five years are put forward.
基金This research was supported by project of China Geological Survey(DD20190725)Innovative Special Project of Sino-US Intergovernmental Cooperation in Science and Technology(2017YFE0106300)。
文摘The sequence stratigraphic framework of Shanxi Formation in the northeast Zhoukou Depression was established based on detailed sequence stratigraphical and sedimentological analysis by utilizing the logging and core data of six wells drilled in the eastern tectonic unit of Zhoukou Depression.It was divided into three third-order sequences,namely SQs1,SQs2,and SQs3 from bottom to top.Each sequence can be divided into a transgressive system tract(TST)and a highstand system tract(HST).Furthermore,four sequence boundaries and three maximum flooding surfaces were identified,and they are the bottom interface SBs and maximum flooding surface mfss1 of SQs1,the bottom interface SBs1 and maximum flooding surface mfss2 of SQs2,the bottom interface SBs3 and maximum flooding surface mfss3 of SQs3,and the top interface SBx from bottom to top.Carbonate tidal flat–clastic tidal flat sedimentary system developed in Shanxi Formation in the northeast Zhoukou Depression(also referred to as the study area)under the control of regression.Meanwhile,four sedimentary microfacies were identified in the sedimentary system,which are lime-mud flats,sand flats,mixed flats,and mud flats.The transgression in the study area occurred from the southeast to the northwest.Therefore,the northwestern part is the seaward side,and the southeastern part is the landward side.As revealed by relevant drilling data,SQs1 of the Shanxi Formation is characterized by the development of limestone and carbonaceous mudstone,with limestone,dark mudstone,and carbonaceous mudstone mainly developing.Meanwhile,lime-mud flats were mainly deposited in it.During the periods of SQs2 and SQs3,the sedimentary environment of the study area changed from the carbonate tidal flats to clastic tidal flats as the coastline migrated towards the sea.In these periods,sand flats mainly developed near the maximum flooding surfaces and were relatively continuous in the eastern and southern parts of the transgressive system tract;mixed flats were relatively continuous in the western and northern parts of the transgressive system tract as well as the eastern and southern parts of the highstand system tract;mud flats widely developed in the highstand system tract.Peat flats mainly developed in the period of HSTs2,with coal seams relatively developing in the southeastern part of the study area as revealed by drilling data.The peat flats in SQs2 are favorable hydrocarbon source layers,the lime-mud flats in SQs1 and sand flats formed in the transgression periods of SQs2 and SQs3 constitute favorable hydrocarbon reservoirs,and the mud flats form in the transgressions periods serve as favorable cap rocks.Therefore,the study area features a reservoir-cap assemblage for self-generating and self-storing of hydrocarbon,and the southeastern part of the study area can be taken as a favorable exploration area.