Flexible carbon fiber cloth(CFC)is an important scaffold and/or current collector for active materials in the development of flexible self-supportive electrode materials(SSEMs),especially in lithium-ion batteries.Howe...Flexible carbon fiber cloth(CFC)is an important scaffold and/or current collector for active materials in the development of flexible self-supportive electrode materials(SSEMs),especially in lithium-ion batteries.However,during the intercalation of Li ions into the matrix of CFC(below 0.5 V vs.Li/Li+),the incompatibility in the capacity of the CFC,when used directly as an anode material or as a current collector for active materials,leads to difficulty in the estimation of its actual contribution.To address this issue,we prepared Ni_(5)P_(4)nanosheets on CFC(denoted CFC@Ni_(5)P_(4))and investigated the contribution of CFC in the CFC@Ni_(5)P_(4)by comparing to the powder Ni_(5)P_(4)nanosheets traditionally coated on a copper foil(CuF)(denoted P-Ni_(5)P_(4)).At a current density of 0.4 mA cm^(−2),the as-prepared CFC@Ni_(5)P_(4)showed an areal capacity of 7.38 mAh cm^(−2),which is significantly higher than that of the PNi_(5)P_(4)electrode.More importantly,theoretical studies revealed that the CFC has a high Li adsorption energy that contributes to the low Li-ion diffusion energy barrier of the Ni_(5)P_(4)due to the strong interaction between the CFC and Ni_(5)P_(4),leading to the superior Li-ion storage performance of the CFC@Ni_(5)P_(4)over the pristine Ni_(5)P_(4)sample.This present work unveils the underlying mechanism leading to the achievement of high performance in SSEMs.展开更多
Nickel molybdate(NiMoO_(4))attracts superior hydrogen desorption behavior but noticeably poor for efficiently driving the hydrogen evolution reaction(HER)in alkaline media due to the sluggish water dissociation step.H...Nickel molybdate(NiMoO_(4))attracts superior hydrogen desorption behavior but noticeably poor for efficiently driving the hydrogen evolution reaction(HER)in alkaline media due to the sluggish water dissociation step.Herein,we successfully accelerate the water dissociation kinetics of NiMoO_(4)for prominent HER catalytic properties via simultaneous in situ interfacial engineering with molybdenum dioxide(MoO_(2))and doping with phosphorus(P).The as-synthesized P-doped NiMoO_(4)/MoO_(2)heterostructure nanorods exhibit outstanding HER performance with an extraordinary low overpotential of-23 m V at a current density of 10 m A cm^(-2),which is highly comparable to the performance of the state-of-art Pt/C coated on nickel foam(NF)catalyst.The density functional theory(DFT)analysis reveals the enhanced performance is attributed to the formation of MoO_(2)during the in situ epitaxial growth that substantially reduces the energy barrier of the Volmer pathway,and the introduction of P that provides efficient hydrogen desorption of Ni MoO_(2).This present work creates valuable insight into the utilization of interfacial and doping systems for hydrogen evolution catalysis and beyond.展开更多
The microstructure,mechanical properties and flame resistance behavior of the AZ91−1Ce alloys with different Ca additions were firstly investigated.Then,the effect of processing parameters,including applied pressures ...The microstructure,mechanical properties and flame resistance behavior of the AZ91−1Ce alloys with different Ca additions were firstly investigated.Then,the effect of processing parameters,including applied pressures and rotation speeds,on the microstructure and mechanical properties of the rheo-squeeze casting AZ91−1Ce−2Ca alloy was studied.The results indicate that with the increase of Ca content,the microstructure is refined and the flame resistance of the AZ91−1Ce−xCa alloys increases.But when the Ca content exceeds 1 wt.%,with the Ca content increasing,the mechanical properties of the AZ91−1Ce−xCa alloys reduce rapidly.For rheo-squeeze casting process,the increase of applied pressure and rotation speed can both bring about significant refinement in the microstructure of the AZ91−1Ce−2Ca alloy and reduction of the porosity,so the mechanical properties increase.Compared to conventional casting,the AZ91−1Ce alloy with the addition of 2 wt.%Ca by rheo-squeeze casting not only guarantees the oxidation resistance(801℃),but also improves mechanical properties.展开更多
The low-energy muon facility at PSI provides nearly fully polarized positive muons with tunable energies in the ke V range to carry out muon spin rotation(LE-μSR)experiments with nanometer depth resolution on thin fi...The low-energy muon facility at PSI provides nearly fully polarized positive muons with tunable energies in the ke V range to carry out muon spin rotation(LE-μSR)experiments with nanometer depth resolution on thin films,heterostructures, and near-surface regions. The low-energy muon beam is focused and transported to the sample by electrostatic lenses. In order to achieve a minimum beam spot size at the sample position and to enable the steering of the beam in the horizontal and vertical direction, a special electrostatic device has been implemented close to the sample position. It consists of a cylinder at ground potential followed by four conically shaped electrodes,which can be operated at different electric potential. In LE-μSR experiments, an electric field at the sample along the beam direction can be applied to accelerate/decelerate muons to different energies(0.5–30 keV). Additionally, a horizontal or vertical magnetic field can be superimposed for transverse or longitudinal field μSR experiments. The focusing properties of the conical lens in the presence of these additional electric and magnetic fields have been investigated and optimized by Geant4 simulations. Some experimental tests were also performed and show that the simulation well describes the experimental setup.展开更多
A novel surface muon capture system with a large acceptance was proposed based on the China spallation neutron source(CSNS).This system was designed using a superconducting solenoid where a long graphite target was pu...A novel surface muon capture system with a large acceptance was proposed based on the China spallation neutron source(CSNS).This system was designed using a superconducting solenoid where a long graphite target was put inside it.Firstly,the spin polarization evolution was studied in a constant uniform magnetic field.As the magnetic field can interact with the spin of the surface muon,both the spin polarization and production rate of the surface muons collected by the new capture system were calculated by the G4beamline.Simulation results showed that the surface muons could still keep a high spin polarization([90%)with different magnetic fields(0–10 T),and the larger magnetic field is,the more surface muons can be captured.Finally,the proton phase space,Courant–Snyder parameters,and intensities of surface muons of different beam fractions were given with magnetic fields of 0 and 5T.The solenoid capture system can focus proton and surface muon beams and collect p?and l?particles.It can also provide an intense energetic positron source.展开更多
Organic inputs are key to increasing soil organic carbon in agricultural soils.This study aimed to unravel the process of mineralization and humification of chicken manure(CM)and composted kitchen waste(KW)using an in...Organic inputs are key to increasing soil organic carbon in agricultural soils.This study aimed to unravel the process of mineralization and humification of chicken manure(CM)and composted kitchen waste(KW)using an in situ litter-bag incubation experiment.The results indicated that over 50%,64%to 72%,and 62%to 85%of the initial mass,carbon and nitrogen,respectively,were lost through incubation with a marked loss occurring during the first 28 days.Increased humic acids(HAs),humus(Hs)and degree of humification,along with a decrease in the level of fulvic acids and precursors for humic substances were observed through incubation.By comparison,CM demonstrated higher carbon and nitrogen conservation efficiencies and greater humification compared to KW.Additionally,a higher degree of humifaction and larger quantities of HAs and HS were not favorable for carbon and nitrogen conservation.Further structural equation modeling indicated that microbial community had a strong effect on carbon loss and nitrogen release,while stoichiometric properties of organic inputs were the main determinant of the mineralization and humification processes.These findings will enhance understanding of litter decomposition in soils and provide valuable references for soil carbon sequestration with organic inputs.展开更多
The rapid increase in the proportion of cash crops and livestock production in the Yangtze River Basin has led to commensurate increases in fertilizer and pesticide inputs. Excessive application of chemical fertilizer...The rapid increase in the proportion of cash crops and livestock production in the Yangtze River Basin has led to commensurate increases in fertilizer and pesticide inputs. Excessive application of chemical fertilizer, organophosphorus pesticides and inappropriate disposal of agricultural waste induced water pollution and potentially threaten Agriculture Green Development(AGD). To ensure food security and the food supply capacity of the Yangtze River Basin, it is important to balance green and development, while ensuring the quality of water bodies. Multiple pollutants affect the transfer, adsorption, photolysis and degradation of each other throughout the soil-plant-water system. This paper considers the impact of multi-pollutants on the nitrogen and phosphorus cycles especially for crops, which are related to achieving food security and AGD. It presents prospective on theory, modeling and multi-pollutant control in the Yangtze River Basin for AGD that are of potential value for other developing regions.展开更多
Shaanxi is a leading province in animal husbandry(AH)in China.However,the lack of provincial information on the characteristics and utilization potential of livestock manure(LM)hinders crucial management decisions.The...Shaanxi is a leading province in animal husbandry(AH)in China.However,the lack of provincial information on the characteristics and utilization potential of livestock manure(LM)hinders crucial management decisions.Therefore,we investigated the spatiotemporal distribution,availability and biogas potential of LM in Shaanxi,and examine the carbon emission reduction potential of AH.There has been a 1.26-fold increase in LM quantities in Shaanxi over the past 35 years,reaching 4635.6×10^(4)t by 2021.LM was mainly concentrated in northern Shaanxi and the eastern part of Hanzhong.Cattle and pig manure were the primary sources of LM,with the average LM land-load of 14.57 t·ha^(−1)in 2021.While the overall AH in Shaanxi has not exceeded the environmental capacity,the actual scales of AH in Ankang and Hanzhong have already surpassed the respective environmental capacities,posing a higher risk of N and P pollutions.In 2021,the estimated biogas energy potential of LM was 1.2×10^(11)MJ.From 2012 to 2021,the average carbon emission reduction potential in Shaanxi was 22%,with an average potential scale of 10%.The results of this research provide valuable data and policy recommendations for promoting the intensive use of LM and reducing carbon emissions in Shaanxi.展开更多
基金National Natural Science Foundation of China,Grant/Award Numbers:21875292,21902188National Key Research and Development Program of China,Grant/Award Number:2019YFA0705702+2 种基金Hunan Provincial Natural Science Foundation,Grant/Award Number:2021JJ30087Natural Science Foundation of Guangdong Province,Grant/Award Number:2020A1515010798Hunan Joint International Laboratory of Advanced Materials and Technology for Clean Energy,Grant/Award Number:2020CB1007。
文摘Flexible carbon fiber cloth(CFC)is an important scaffold and/or current collector for active materials in the development of flexible self-supportive electrode materials(SSEMs),especially in lithium-ion batteries.However,during the intercalation of Li ions into the matrix of CFC(below 0.5 V vs.Li/Li+),the incompatibility in the capacity of the CFC,when used directly as an anode material or as a current collector for active materials,leads to difficulty in the estimation of its actual contribution.To address this issue,we prepared Ni_(5)P_(4)nanosheets on CFC(denoted CFC@Ni_(5)P_(4))and investigated the contribution of CFC in the CFC@Ni_(5)P_(4)by comparing to the powder Ni_(5)P_(4)nanosheets traditionally coated on a copper foil(CuF)(denoted P-Ni_(5)P_(4)).At a current density of 0.4 mA cm^(−2),the as-prepared CFC@Ni_(5)P_(4)showed an areal capacity of 7.38 mAh cm^(−2),which is significantly higher than that of the PNi_(5)P_(4)electrode.More importantly,theoretical studies revealed that the CFC has a high Li adsorption energy that contributes to the low Li-ion diffusion energy barrier of the Ni_(5)P_(4)due to the strong interaction between the CFC and Ni_(5)P_(4),leading to the superior Li-ion storage performance of the CFC@Ni_(5)P_(4)over the pristine Ni_(5)P_(4)sample.This present work unveils the underlying mechanism leading to the achievement of high performance in SSEMs.
基金supported by the National Natural Science Foundation of China(21875292 and 51902103)Hunan Provincial Natural Science Foundation(2019JJ50037 and 2021JJ30087)+1 种基金Natural Science Foundation of Guangdong Province(2020A1515010798)the Hunan Joint International Laboratory of Advanced Materials and Technology for Clean Energy(2020CB1007)。
文摘Nickel molybdate(NiMoO_(4))attracts superior hydrogen desorption behavior but noticeably poor for efficiently driving the hydrogen evolution reaction(HER)in alkaline media due to the sluggish water dissociation step.Herein,we successfully accelerate the water dissociation kinetics of NiMoO_(4)for prominent HER catalytic properties via simultaneous in situ interfacial engineering with molybdenum dioxide(MoO_(2))and doping with phosphorus(P).The as-synthesized P-doped NiMoO_(4)/MoO_(2)heterostructure nanorods exhibit outstanding HER performance with an extraordinary low overpotential of-23 m V at a current density of 10 m A cm^(-2),which is highly comparable to the performance of the state-of-art Pt/C coated on nickel foam(NF)catalyst.The density functional theory(DFT)analysis reveals the enhanced performance is attributed to the formation of MoO_(2)during the in situ epitaxial growth that substantially reduces the energy barrier of the Volmer pathway,and the introduction of P that provides efficient hydrogen desorption of Ni MoO_(2).This present work creates valuable insight into the utilization of interfacial and doping systems for hydrogen evolution catalysis and beyond.
基金financial supports from National Natural Science Foundation of China(Nos.51775334,51771115,U2037601)Research Program of Joint Research Center of Advanced Spaceflight Technologies,China(No.USCAST2020-14)。
文摘The microstructure,mechanical properties and flame resistance behavior of the AZ91−1Ce alloys with different Ca additions were firstly investigated.Then,the effect of processing parameters,including applied pressures and rotation speeds,on the microstructure and mechanical properties of the rheo-squeeze casting AZ91−1Ce−2Ca alloy was studied.The results indicate that with the increase of Ca content,the microstructure is refined and the flame resistance of the AZ91−1Ce−xCa alloys increases.But when the Ca content exceeds 1 wt.%,with the Ca content increasing,the mechanical properties of the AZ91−1Ce−xCa alloys reduce rapidly.For rheo-squeeze casting process,the increase of applied pressure and rotation speed can both bring about significant refinement in the microstructure of the AZ91−1Ce−2Ca alloy and reduction of the porosity,so the mechanical properties increase.Compared to conventional casting,the AZ91−1Ce alloy with the addition of 2 wt.%Ca by rheo-squeeze casting not only guarantees the oxidation resistance(801℃),but also improves mechanical properties.
基金a scholarship from the China Scholarship Council (CSC)financial support from PSI for her stay at PSI
文摘The low-energy muon facility at PSI provides nearly fully polarized positive muons with tunable energies in the ke V range to carry out muon spin rotation(LE-μSR)experiments with nanometer depth resolution on thin films,heterostructures, and near-surface regions. The low-energy muon beam is focused and transported to the sample by electrostatic lenses. In order to achieve a minimum beam spot size at the sample position and to enable the steering of the beam in the horizontal and vertical direction, a special electrostatic device has been implemented close to the sample position. It consists of a cylinder at ground potential followed by four conically shaped electrodes,which can be operated at different electric potential. In LE-μSR experiments, an electric field at the sample along the beam direction can be applied to accelerate/decelerate muons to different energies(0.5–30 keV). Additionally, a horizontal or vertical magnetic field can be superimposed for transverse or longitudinal field μSR experiments. The focusing properties of the conical lens in the presence of these additional electric and magnetic fields have been investigated and optimized by Geant4 simulations. Some experimental tests were also performed and show that the simulation well describes the experimental setup.
基金supported by the National Natural Science Foundation of China(No.11527811)
文摘A novel surface muon capture system with a large acceptance was proposed based on the China spallation neutron source(CSNS).This system was designed using a superconducting solenoid where a long graphite target was put inside it.Firstly,the spin polarization evolution was studied in a constant uniform magnetic field.As the magnetic field can interact with the spin of the surface muon,both the spin polarization and production rate of the surface muons collected by the new capture system were calculated by the G4beamline.Simulation results showed that the surface muons could still keep a high spin polarization([90%)with different magnetic fields(0–10 T),and the larger magnetic field is,the more surface muons can be captured.Finally,the proton phase space,Courant–Snyder parameters,and intensities of surface muons of different beam fractions were given with magnetic fields of 0 and 5T.The solenoid capture system can focus proton and surface muon beams and collect p?and l?particles.It can also provide an intense energetic positron source.
基金funded by the Key Research and Development Project for the Xizang Autonomous Region(XZ202101ZD003N,XZ202201ZY0003N)the National Key Research and Development Program of China(2022YFD1901402)the Key Basic Research Foundation of Chongqing Academy of Agricultural Sciences(cqaas2023siczzd003).
文摘Organic inputs are key to increasing soil organic carbon in agricultural soils.This study aimed to unravel the process of mineralization and humification of chicken manure(CM)and composted kitchen waste(KW)using an in situ litter-bag incubation experiment.The results indicated that over 50%,64%to 72%,and 62%to 85%of the initial mass,carbon and nitrogen,respectively,were lost through incubation with a marked loss occurring during the first 28 days.Increased humic acids(HAs),humus(Hs)and degree of humification,along with a decrease in the level of fulvic acids and precursors for humic substances were observed through incubation.By comparison,CM demonstrated higher carbon and nitrogen conservation efficiencies and greater humification compared to KW.Additionally,a higher degree of humifaction and larger quantities of HAs and HS were not favorable for carbon and nitrogen conservation.Further structural equation modeling indicated that microbial community had a strong effect on carbon loss and nitrogen release,while stoichiometric properties of organic inputs were the main determinant of the mineralization and humification processes.These findings will enhance understanding of litter decomposition in soils and provide valuable references for soil carbon sequestration with organic inputs.
基金financially supported by the National Natural Science Foundation of China (U20A2047 and 42107056)the Key Laboratory of Low-carbon Green Agriculture (Ministry of Agriculture and Rural Affairs)the State Cultivation Base of Eco-agriculture for Southwest Mountainous Land (Southwest University)。
文摘The rapid increase in the proportion of cash crops and livestock production in the Yangtze River Basin has led to commensurate increases in fertilizer and pesticide inputs. Excessive application of chemical fertilizer, organophosphorus pesticides and inappropriate disposal of agricultural waste induced water pollution and potentially threaten Agriculture Green Development(AGD). To ensure food security and the food supply capacity of the Yangtze River Basin, it is important to balance green and development, while ensuring the quality of water bodies. Multiple pollutants affect the transfer, adsorption, photolysis and degradation of each other throughout the soil-plant-water system. This paper considers the impact of multi-pollutants on the nitrogen and phosphorus cycles especially for crops, which are related to achieving food security and AGD. It presents prospective on theory, modeling and multi-pollutant control in the Yangtze River Basin for AGD that are of potential value for other developing regions.
基金supported by the National Natural Science Foundation of China(32172679 and 31902122).
文摘Shaanxi is a leading province in animal husbandry(AH)in China.However,the lack of provincial information on the characteristics and utilization potential of livestock manure(LM)hinders crucial management decisions.Therefore,we investigated the spatiotemporal distribution,availability and biogas potential of LM in Shaanxi,and examine the carbon emission reduction potential of AH.There has been a 1.26-fold increase in LM quantities in Shaanxi over the past 35 years,reaching 4635.6×10^(4)t by 2021.LM was mainly concentrated in northern Shaanxi and the eastern part of Hanzhong.Cattle and pig manure were the primary sources of LM,with the average LM land-load of 14.57 t·ha^(−1)in 2021.While the overall AH in Shaanxi has not exceeded the environmental capacity,the actual scales of AH in Ankang and Hanzhong have already surpassed the respective environmental capacities,posing a higher risk of N and P pollutions.In 2021,the estimated biogas energy potential of LM was 1.2×10^(11)MJ.From 2012 to 2021,the average carbon emission reduction potential in Shaanxi was 22%,with an average potential scale of 10%.The results of this research provide valuable data and policy recommendations for promoting the intensive use of LM and reducing carbon emissions in Shaanxi.
