A chemo-mechanical model is developed to investigate the effects on the stress development of the coating of polycrystalline Ni-rich LiNixMnyCo_(z)O_(2)(x≥0.8)(NMC)particles with poly(3,4-ethylenedioxythiophene)(PEDO...A chemo-mechanical model is developed to investigate the effects on the stress development of the coating of polycrystalline Ni-rich LiNixMnyCo_(z)O_(2)(x≥0.8)(NMC)particles with poly(3,4-ethylenedioxythiophene)(PEDOT).The simulation results show that the coating of primary NMC particles significantly reduces the stress generation by efficiently accommodating the volume change associated with the lithium diffusion,and the coating layer plays roles both as a cushion against the volume change and a channel for the lithium transport,promoting the lithium distribution across the secondary particles more homogeneously.Besides,the lower stiffness,higher ionic conductivity,and larger thickness of the coating layer improve the stress mitigation.This paper provides a mathematical framework for calculating the chemo-mechanical responses of anisotropic electrode materials and fundamental insights into how the coating of NMC active particles mitigates stress levels.展开更多
This investigative study is focused on the impact of wavelet on traditional forecasting time-series models,which significantly shows the usage of wavelet algorithms.Wavelet Decomposition(WD)algorithm has been combined...This investigative study is focused on the impact of wavelet on traditional forecasting time-series models,which significantly shows the usage of wavelet algorithms.Wavelet Decomposition(WD)algorithm has been combined with various traditional forecasting time-series models,such as Least Square Support Vector Machine(LSSVM),Artificial Neural Network(ANN)and Multivariate Adaptive Regression Splines(MARS)and their effects are examined in terms of the statistical estimations.The WD has been used as a mathematical application in traditional forecast modelling to collect periodically measured parameters,which has yielded tremendous constructive outcomes.Further,it is observed that the wavelet combined models are classy compared to the various time series models in terms of performance basis.Therefore,combining wavelet forecasting models has yielded much better results.展开更多
基金the National Research Foundation of Korea(Nos.2018R1A5A7023490 and 2022R1A2C1003003)。
文摘A chemo-mechanical model is developed to investigate the effects on the stress development of the coating of polycrystalline Ni-rich LiNixMnyCo_(z)O_(2)(x≥0.8)(NMC)particles with poly(3,4-ethylenedioxythiophene)(PEDOT).The simulation results show that the coating of primary NMC particles significantly reduces the stress generation by efficiently accommodating the volume change associated with the lithium diffusion,and the coating layer plays roles both as a cushion against the volume change and a channel for the lithium transport,promoting the lithium distribution across the secondary particles more homogeneously.Besides,the lower stiffness,higher ionic conductivity,and larger thickness of the coating layer improve the stress mitigation.This paper provides a mathematical framework for calculating the chemo-mechanical responses of anisotropic electrode materials and fundamental insights into how the coating of NMC active particles mitigates stress levels.
文摘This investigative study is focused on the impact of wavelet on traditional forecasting time-series models,which significantly shows the usage of wavelet algorithms.Wavelet Decomposition(WD)algorithm has been combined with various traditional forecasting time-series models,such as Least Square Support Vector Machine(LSSVM),Artificial Neural Network(ANN)and Multivariate Adaptive Regression Splines(MARS)and their effects are examined in terms of the statistical estimations.The WD has been used as a mathematical application in traditional forecast modelling to collect periodically measured parameters,which has yielded tremendous constructive outcomes.Further,it is observed that the wavelet combined models are classy compared to the various time series models in terms of performance basis.Therefore,combining wavelet forecasting models has yielded much better results.
