Hydrogeophysical and Structural Investigations Using VES: A Case Study of Dosso Region in the Southwestern Part of the Meso-Cenozoic Iullemmeden Basin (Southwestern Niger)

A regional study connecting geolelectrical surveys with geology and hydrogeology was carried out in the western part of the Iullemmeden basin, precisely in the Dosso region in Niger. One hundred and four (104) vertical electrical sounds have been realized, among them nineteen representative were thus be used as parametric surveys. The local resistivity values of the geological formations of Quaternary range from 100 Ω⋅m to 1000 Ω⋅m (sands and lateritic sandstones). The Oligo-Miocene formation of the Continental terminal (Ct) shows resistivity values ranging from 1 to 5 Ω⋅m (brackish groundwaters) to 1500 Ω⋅m (clay sandstones) while the Upper Cretaceous formation of the Continental “hamadien” (Ch) indicates values ranging from 20 Ω⋅m (sandy clay) to 5000 Ω⋅m (clayey sandstones). The geological formations of Paleocene have values from 2 Ω⋅m (marls) to 60 Ω⋅m (calcareous marl), while the Precambrian basement exhibits values of granite around 300 Ω⋅m to 60,000 Ω⋅m. The update of the structural settings reveals many faults in the study area which explain both the shape of the basin and the geometry of the aquifers. Tectonics is also consistent with the hydraulic characteristics of aquifers. In addition, brackish groundwaters were identified as perched aquifer groundwaters in different depths in Dosso region. They probably come from the marine brines during the regression of the Paleocene Sea.

Assessment of Groundwater Quality for Drinking and Irrigation Uses in the Samba Dia Area, Central West Senegal

In the Sahelian zone in Africa, groundwater is the main source of drinking water for domestic, industrial, and agricultural uses. The groundwater of the Samba Dia sandy aquifer was assessed for understanding processes controlling the hydrogeochemistry and its drinking and irrigation suitability, on the basis of various water quality parameters. For the present study, thirty-three groundwater samples were collected in wells of the study area during the dry season in March 2021 and subjected to analysis for chemical characteristics (major ions), pH, electrical conductivity (EC), and total dissolved solids (TDS). Gibbs plot depicts that the process of ionic exchange is mainly due to the dissolution of water-rock interaction. The Piper diagram indicates a largely dominant sodium chloride facies with 70% of the groundwater samples followed by calcium chloride facies (18%) than calcium bicarbonate facies (12%). Analytical results of hydrogeochemical parameters of groundwater samples reveal that the majority of samples are within the World Health Organization safety range for drinking water. TDS and electrical conductivity (EC) values of groundwater indicate that 70% and 61% are safe for drinking water, respectively. Sodium percentage (% Na), Sodium Adsorption Ratio (SAR) values, and Ca/Mg ratio were calculated and compared with the standard guideline values recommended by the World Health Organization and agricultural water standards. This study shows that the groundwater in the area is mostly chemically suitable for drinking and irrigation, although some wells at the edge of the area exhibit signs of progressive salinization and traces of pollution.

Recycling Tailings Seepage Water for Diogo Heavy Minerals Mine Sustainability (Northern Senegal)

The sandy Quaternary and the deep Maastrichtian aquifers located in the northern coastal zone of Senegal, from the locality of Kayar in the south to Saint-Louis in the north, constitute the main sources of water supply for urban and local needs as well as mining activities. The Quaternary aquifer that provides the water required for the irrigation of local farmlands, hosts a significant heavy mineral sands deposit currently being mined by the Grande Cote Operations (GCO). As a result of variable rainfall and increased water abstraction, this shallow aquifer has recorded a continuous water level decline since 1970, with potential negative effects on both the social and economic development of the region. The mining of heavy minerals (zircon, ilmenite, leucoxene and rutile) at GCO is realised through conventional dredging techniques that require large volumes of water (up to 60,000 m3/d). The water pumped by the dredge to enable the extraction of the heavy minerals, infiltrates into the shallow aquifer, runs-off into the dredge pond or evaporates. The objective of this study is to evaluate a water balance that enables the provision of a permanent water supply to the dredge pond, whilst minimising the risk of flooding of the cropping depressions adjacent to the mine site or drying out of the farming wells. The hydrodynamic model implemented for this purpose was calibrated and tested during the first year of operation. The Root Mean Squared Error (RMSE) obtained for the calibration is approximately 0.52 m. The predictions indicate a requirement for the system to recover part of the tailings infiltration through dewatering boreholes. The quantity of recycled water is estimated at 16,000 m3/d on average. The model simulations show an additional water requirement, extracted from the deep Maastrichtian aquifer, varying between 23,000 and 28,000 m3/d to achieve the optimum pond water level.

Role of Natural and Anthropogenic Influence on the Salinization of Groundwater from Basement Aquifers in the Middle Part of Mono River Basin, Togo

This study aimed to identify the role of natural and anthropogenic influence on geochemical processes controlling groundwater salinization in the middle portion of the Mono River basin, Togo. Multivariate statistical analysis, geochemical masse balance modeling, and conventional graphical methods were applied to the chemical dataset obtained from 110 groundwater samples collected during two campaigns (March-May 2011 and April 2014). The results showed that groundwater is predominantly fresh, acidic to circumneutral and mixed cations-HCO-3 water types. The proportion of ions (Na+, K+, Cl- and SO2-4) occurring ubiquitously in a saline environment increases substantially with TDS. Two factors, defined as natural and anthropogenic, account for 76.5% of the hydrochemical dataset variance. Based on the hierarchical cluster analysis, groundwater samples are classified into four clusters that corroborate the factor analysis results and illustrate different hydrochemical evolution stages along a topographically-driven groundwater flow path. The primary natural process contributing to cations and bicarbonate ions is the weathering of silicate minerals and possibly secondary carbonates by infiltrating water enriched with soil CO2 gas. Groundwater salinization indicators including Cl-, SO2-4 and NO-3, originate from potential sources such as human and animal wastes, agrochemicals, and deforestation. Thermodynamic equilibrium conditions ranged from saturation to oversaturation with respect to quartz, chalcedony, amorphous silica, calcite, dolomite, sepiolite, and talc. In conjunction with the lowering of CO2 partial pressure and evaporation, these conditions restrict acidic hydrolysis of primary silicates but magnify the groundwater salinization process in the lower elevation areas where soil crusts’ formation is favorable. This study showed the effective use of multivariate statistical analysis and complementary techniques in identifying the significant factors and processes controlling groundwater chemistry.

Salinization Processes in the Benichab Coastal Aquifer-Mauritania

A comprehensive and detailed study was conducted for the first time in the Benichab Region (western part of Mauritania) unique groundwater resource to identify the main process driving groundwater salinization using major and minor ions together with environmental isotopes. One hundred and nineteen samples were collected from 45 points (dug-wells and boreholes) during the period 2015 to 2017, where physico-chemical, chemical and isotope parameters were analyzed. pH values indicate circumneutral to basic (6.8 to 8.6) values while Electric Conductivity (EC) values show an increasing gradient from fresh groundwater lense (EC < 1 mS/cm) to highly saline groundwater in the vicinity of the Atlantic Ocean. In addition, TDS values range from 140 to 38,613 mg/l. Geogenic inputs reveal water rock interactions dominated by ion exchange, dissolution-precipitation processes and evaporation. Minor ions such as Br and B indicate that the salinization of groundwater in the study area comes from mixing between seawater through salt sea intrusion and fresh water where sea water represents a mean value of 8.42%. However, this marine source could increase with anthropogenic actions. According to δ-values, the mean values range for rainfall, from -3.8‰ and -25.04‰ for δ18O and δ2H, respectively;and for groundwater from -5.0‰ and -41.44‰ for δ18O and δ2H respectively. The isotopic characterization indicates fractionation processes such as evaporation and mixing of groundwater and seawater prevail in the unique source of potable water.

Hydrodynamics and Recharge of the Aioune Sandstone Aquifer in the Taoudenni Transboundary Basin in Mauritania

In Mauritanian, 4/5 of the territory is subject to an arid climate, where groundwater resources are the main sources of drinking water for populations and livestock. The study area is located in south-eastern Mauritania and in the western part of the Taoudenni Transboundary Basin. A better knowledge of the hydrogeological system to ensure a sustainable and rational management is necessary for this vulnerable water resource. This pioneering study, based on the compilation of hydrogeological, geochemical and isotopic data, aims to characterize the hydrodynamics and recharge of this one layer aquifer system, composed of Aioune infracambrian sandstone. The piezometric surface exhibits relatively the same morphology of the soil topography, and computed effective velocity is 94 m/yr (Northeast area), and the direction of flow is generally from cliff to plains area. The chemical data show water types evolving between two poles namely the HCO3-Ca/Mg pole (low mineralized), and the Cl-Ca/Na pole;these waters are characterized by a high vulnerability to pollution, especially at shallow depth area (Douerare, Aioune). The dissolution of bicarbonate and evaporate minerals is likely the main source of mineralization. The isotopic tool used to support comprehension of the system functioning, evidences a local indirect recharge water localized at the cliff or Wadi zones. The age of the waters ranges from the present to 1060 year. The recharge rate calculated by 14C and the chloride masse balance is respectively 0.4 to 5 mm/year. This recharge compared to the water pumping rate is lower and hence this imbalance is likely the cause of water shortages particularly during summer season period.

Evaluation of Groundwater Quality in the Deep Maastrichtian Aquifer of Senegal Using Multivariate Statistics and Water Quality Index-Based GIS

A regional groundwater quality evaluation was conducted in the deep Maastrichtian aquifer of Senegal through multivariate statistical analysis and a GIS-based water quality index using physicochemical data from 232 boreholes distributed over the whole country. The aim was to 1) identify the water types and likely factors influencing the hydrochemistry, and 2) determine the suitability of groundwater for drinking and irrigation. Results showed that sodium, chloride, and fluoride are highly correlated with electrical conductivity (EC) reflecting the significant contribution of these elements to groundwater mineralization. The principal component analysis evidenced: 1) salinization processes (loaded by Na+, K+, EC, Cl-, F- and HCO3-) controlled by water/rock interaction, seawater intrusion and cation exchange reactions;2) dolomite dissolution loaded by the couple Ca2+ and Mg2+ and 3) localized mixing with upper aquifers and gypsum dissolution respectively loaded by NO3- and SO42-. The hierarchical clustering analysis distinguished four clusters: 1) freshwater (EC = 594 μs/cm) with mixed-HCO3 water type and ionic contents below WHO standard;2) brackish (Na-mixed) water type with moderate mineralization content (1310 μs/cm), 3) brackish (Na-Cl) water type depicted by high EC values (3292 μs/cm) and ionic contents above WHO and 4) saline water with Na-Cl water type and very high mineralization contents (5953 μs/cm). The mapping of the groundwater quality index indicated suitable zones for drinking accounting for 54% of the entire area. The occurrence of a central brackish band and its vicinity, which were characterized by high mineralization, yielded unsuitable groundwater for drinking and agricultural uses. The approach used in this study was valuable for assessing groundwater quality for drinking and irrigation, and it can be used for regional studies in other locations, particularly in shallow and vulnerable aquifers.

Groundwater Geochemistry and Saltwater Intrusion in the Dakar Coastal Area, Senegal

Groundwater levels and water samples were collected from 20 drinking water pumping and piezometer wells in the urban area of Dakar coastal region in the year 2019. The pH-value, electrical conductivity, as well as calcium, magnesium, sodium, potassium, chloride, sulfate, bicarbonate, and nitrate concentrations were measured to assess the hydrochemical quality of the infrabasaltic aquifer in the area. The present work carried out a hydrochemical analysis to interpret the groundwater chemistry of the aquifer. The results of this chemical analysis indicate that Na+ > Mg2+ > Ca2+ > K+ was the most dominant cation sequence in the groundwater, while Cl- > HCO3- > SO42- > NO3- was the most dominant one for anions. The chemical analysis of our samples showed, that the Cl-Ca-Mg facies was dominant in the aquifer, while Cl-Na-K and HCO3-Na-K facies represent 20% and 10% of the groundwater sampled, respectively. A comparison of the measured groundwater quality in relation to WHO drinking water quality standards revealed that 80% of the water samples are suitable for drinking purposes. Ca enrichment, Simpson ratio, ratio of sodium chloride, and calculating Base Exchange (BEX) indices for the samples revealed that the groundwater is mainly affected by three factors: seawater intrusion due to aquifer overexploitation on one hand, and freshening processes and nitrate pollution, on the other, mainly caused by the groundwater flow from the unconfined aquifer.