Synthetic polymers:A review of applications in drilling fluids

With the growth of deep drilling and the complexity of the well profile,the requirements for a more complete and efficient exploitation of productive formations increase,which increases the risk of various complications.Currently,reagents based on modified natural polymers(which are naturally occurring compounds)and synthetic polymers(SPs)which are polymeric compounds created industrially,are widely used to prevent emerging complications in the drilling process.However,compared to modified natural polymers,SPs form a family of high-molecular-weight compounds that are fully synthesized by undergoing chemical polymerization reactions.SPs provide substantial flexibility in their design.Moreover,their size and chemical composition can be adjusted to provide properties for nearly all the functional objectives of drilling fluids.They can be classified based on chemical ingredients,type of reaction,and their responses to heating.However,some of SPs,due to their structural characteristics,have a high cost,a poor temperature and salt resistance in drilling fluids,and degradation begins when the temperature reaches 130℃.These drawbacks prevent SP use in some medium and deep wells.Thus,this review addresses the historical development,the characteristics,manufacturing methods,classification,and the applications of SPs in drilling fluids.The contributions of SPs as additives to drilling fluids to enhance rheology,filtrate generation,carrying of cuttings,fluid lubricity,and clay/shale stability are explained in detail.The mechanisms,impacts,and advances achieved when SPs are added to drilling fluids are also described.The typical challenges encountered by SPs when deployed in drilling fluids and their advantages and drawbacks are also discussed.Economic issues also impact the applications of SPs in drilling fluids.Consequently,the cost of the most relevant SPs,and the monomers used in their synthesis,are assessed.Environmental impacts of SPs when deployed in drilling fluids,and their manufacturing processes are identified,together with advances in SP-treatment methods aimed at reducing those impacts.Recommendations for required future research addressing SP property and performance gaps are provided.

Impacts of interactions with low-mineralized water on permeability and pore behavior of carbonate reservoirs

Laboratory filtration experiments are employed to investigate effective well killing while minimizing its impacts on surrounding rocks.The novelty of this experimental study lies in the prolonged exposure of rock samples to the killing fluid for seven days,corresponding to the average duration of well workovers in the oilfields in Perm Krai,Russia.Our findings indicate that critical factors influencing the interactions between rocks and the killing fluid include the chemical composition of the killing fluid,the mineralogical composition of the carbonate rocks,reservoir pressure and temperature,and the contact time.Petrophysical analyses using multi-scale X-ray computed tomography,field emission scanning electron microscopy,and X-ray diffraction were conducted on samples both before and after the well killing simulation.The experiments were performed using real samples of cores,crude oil,and the killing fluid.The results from this study indicate that low-mineralized water(practically fresh water)is a carbonate rock solvent.Such water causes the dissolution of rock components,the formation of new calcite crystals and amoeba-like secretions,and the migration of small particles(clay,quartz,and carbonates).The formation of deep channels was also recorded.The assessment reveals that the change in the pH of the killing fluid indicates that the observed mineral reactions were caused by carbonate dissolution.These combined phenomena led to a decrease in the total number of voids in the core samples,which was 25%on average,predominantly among voids measuring between 45 and 70μm in size.The change in the pore distribution in the bulk of the samples resulted in decreases in porosity of 1.8%and permeability of 67.0%in the studied core samples.The results from this study indicate the unsuitability of low-mineralized water as a well killing fluid in carbonate reservoirs.The composition of the killing fluid should be optimized,for example,in terms of the ionic composition of water,which we intend to investigate in future research.

A critical review of self-diverting acid treatments applied to carbonate oil and gas reservoirs

Carbonate reservoirs generally achieved relatively low primary resource recovery rates.It is therefore often necessary to clean those reservoirs up and/or stimulate them post drilling and later in their production life.A common and basic carbonate reservoir cleanup technique to remove contaminating material from the wellbore is acidizing.The efficiency of acid treatments is determined by many factors,including:the type and quantity of the acid used;the number of repeated treatments performed,heterogeneity of the reservoir,water cut of the reservoir fluids,and presence of idle zones and interlayers.Post-treatment production performance of such reservoirs frequently does not meet design expectations.There is therefore much scope to improve acidizing technologies and treatment designs to make them more reliable and effective.This review considers acid treatment technologies applied to carbonate reservoirs at the laboratory scale and in field-scale applications.The range of acid treatment techniques commonly applied are compared.Differences between specific acid treatments,such as foamed acids,acid emulsions,gelled and thickened acid systems,targeted acid treatments,and acid hydraulic fracturing are described in terms of the positive and negative influences they have on carbonate oil production rates and recovery.Opportunities to improve acid treatment techniques are identified,particularly those involving the deployment of nanoparticles(NPs).Due consideration is also given to the potential environmental impacts associated with carbonate reservoir acid treatment.Recommendations are made regarding the future research required to overcome the remaining challenges pertaining to acid treatment applications.