Based on the analysis of a large number of core samples, logging results, logging interpretation data and dynamic data in the study area, the characteristics of Chang 6 reservoir in Zhouguan area of Baihe area are stu...Based on the analysis of a large number of core samples, logging results, logging interpretation data and dynamic data in the study area, the characteristics of Chang 6 reservoir in Zhouguan area of Baihe area are studied, and the favorable reservoir areas in the study area are predicted. The results show that the lithology of Chang 6 reservoir is mainly light gray and gray fine-grained to very fine-grained feldspar lithic sandstone. The pore types are mainly residual intergranular pores and feldspar dissolved pores, including debris dissolved pores and microfractures. The porosity and permeability values are low, which belongs to low porosity-low permeability and ultra-low permeability reservoirs. According to the reservoir distribution characteristics and related data, the Chang 6 reservoir in the study area is divided into two types, mainly Class II and Class III reservoirs. The comprehensive evaluation predicts that the spatial distribution of the favorable area of Chang 6 reservoir is not uniform, but the distribution area is large, which has broad exploration and development value, and provides the necessary conditions for the distribution study of the favorable oil-bearing zone in this area and the preparation for the next exploration and development.展开更多
A 3D mixed-valence Co（Ⅲ）-Co（Ⅱ） compound [Co9（bta）10（Hbta）2（H2O）10]n·[22（H2O）]n （1） （H2bta=N,N-bis（1H-tetrazole-5- yl）-amine） was hydrothermally synthesized by reaction of Co（NO3）2·6H2O ...A 3D mixed-valence Co（Ⅲ）-Co（Ⅱ） compound [Co9（bta）10（Hbta）2（H2O）10]n·[22（H2O）]n （1） （H2bta=N,N-bis（1H-tetrazole-5- yl）-amine） was hydrothermally synthesized by reaction of Co（NO3）2·6H2O with H2bta·H2O. Compound 1 consists of three kinds of distorted-octahedral [CoⅡ（N4O2）] paramagnetic nodes which are separated by [CoⅢ（bta）2（Hbta）]2-/[CoⅢ（bta）3]3- dia- magnetic linkers to generate a 3D porous metal-organic framework （MOF） with alternative …Co（Ⅲ）…Co（II）… array and channels incorporating water molecules. Under an applied magnetic field of 4000 Oe, compound 1 exhibits slow relaxation of magnetization at low temperatures, giving AE/kB=30.O0 K and ι0=2.0×10^-8 s.展开更多
The solubility properties of ZnCl\-2/ZnAc\-2/ZnSO\-4MetH\-2O systems at 25℃ in the whole cocentration range have been investigated by phase equilibrium method. The results indicate that ZnAc\-2 and ZnSO\-4 systems ar...The solubility properties of ZnCl\-2/ZnAc\-2/ZnSO\-4MetH\-2O systems at 25℃ in the whole cocentration range have been investigated by phase equilibrium method. The results indicate that ZnAc\-2 and ZnSO\-4 systems are both simple systems, which do not exist any compound; there are 2 complexes formed in ZnCl\-2 system: Zn（Met）Cl\-2 and Zn（Met）\-2Cl\-2·2H\-2O. Under the direction of phase equilibrium result, 2 solid complexes have been prepared in water and characterized by chemical analysis, IR, Xray diffraction. Their combustion energies have also been determined by means of a RBCtype1 rotatingbomb calorimeter, and their standard enthalpies of formation, Δ f, coor（s）H O-, have been calculated which are （-828.32±3.00） kJ·mol -1 and （-1 117.08±6.15） kJ·mol -1, respectively.展开更多
文摘Based on the analysis of a large number of core samples, logging results, logging interpretation data and dynamic data in the study area, the characteristics of Chang 6 reservoir in Zhouguan area of Baihe area are studied, and the favorable reservoir areas in the study area are predicted. The results show that the lithology of Chang 6 reservoir is mainly light gray and gray fine-grained to very fine-grained feldspar lithic sandstone. The pore types are mainly residual intergranular pores and feldspar dissolved pores, including debris dissolved pores and microfractures. The porosity and permeability values are low, which belongs to low porosity-low permeability and ultra-low permeability reservoirs. According to the reservoir distribution characteristics and related data, the Chang 6 reservoir in the study area is divided into two types, mainly Class II and Class III reservoirs. The comprehensive evaluation predicts that the spatial distribution of the favorable area of Chang 6 reservoir is not uniform, but the distribution area is large, which has broad exploration and development value, and provides the necessary conditions for the distribution study of the favorable oil-bearing zone in this area and the preparation for the next exploration and development.
基金supported by the National Natural Science Foundation of China(21373162,21127004,21173168,21203149,21463020)the Natural Science Foundation of Shaanxi Province(11JS110,FF10091,SJ08B09)
文摘A 3D mixed-valence Co（Ⅲ）-Co（Ⅱ） compound [Co9（bta）10（Hbta）2（H2O）10]n·[22（H2O）]n （1） （H2bta=N,N-bis（1H-tetrazole-5- yl）-amine） was hydrothermally synthesized by reaction of Co（NO3）2·6H2O with H2bta·H2O. Compound 1 consists of three kinds of distorted-octahedral [CoⅡ（N4O2）] paramagnetic nodes which are separated by [CoⅢ（bta）2（Hbta）]2-/[CoⅢ（bta）3]3- dia- magnetic linkers to generate a 3D porous metal-organic framework （MOF） with alternative …Co（Ⅲ）…Co（II）… array and channels incorporating water molecules. Under an applied magnetic field of 4000 Oe, compound 1 exhibits slow relaxation of magnetization at low temperatures, giving AE/kB=30.O0 K and ι0=2.0×10^-8 s.
文摘The solubility properties of ZnCl\-2/ZnAc\-2/ZnSO\-4MetH\-2O systems at 25℃ in the whole cocentration range have been investigated by phase equilibrium method. The results indicate that ZnAc\-2 and ZnSO\-4 systems are both simple systems, which do not exist any compound; there are 2 complexes formed in ZnCl\-2 system: Zn（Met）Cl\-2 and Zn（Met）\-2Cl\-2·2H\-2O. Under the direction of phase equilibrium result, 2 solid complexes have been prepared in water and characterized by chemical analysis, IR, Xray diffraction. Their combustion energies have also been determined by means of a RBCtype1 rotatingbomb calorimeter, and their standard enthalpies of formation, Δ f, coor（s）H O-, have been calculated which are （-828.32±3.00） kJ·mol -1 and （-1 117.08±6.15） kJ·mol -1, respectively.
