Boosting High-Voltage Dynamics Towards High-Energy-Density Lithium-Ion Capacitors

Lithium-ion capacitors(LICs)are becoming important electrochemical energy storage systems due to their great potential to bridge the gap between supercapacitors and lithium-ion batteries.However,capacity lopsidedness and low output voltage greatly hinder the realization of high-energy-density LICs.Herein,a strategy of balancing capacity towards fastest dynamics is proposed to enable high-voltage LICs.Through electrochemical prelithiation of Nb_(2)C to be 1.1 V with 165 mAh g^(-1),Nb_(2)C//LiFePO_(4) LICs show a broadened potential window from 3.0 to 4.2 V and an according high energy density of 420 Wh kg^(-1).Moreover,the underlying mechanism between prelithiation and high voltage is disclosed by electrochemical dynamic analysis.Prelithiation declines the Nb_(2)C anode potential that facilitates electron transmission in the interlayer of two-dimensional Nb_(2)C MXene.This effect induces small drive force for Li^(+)ions deposition and hence weakens the repulsive force from adsorbed ions on the electrode surface.Benefiting from even more Li^(+)ions deposition,a higher voltage is eventually delivered.In addition,prelithiation significantly increases Coulomb efficiency of the 1st cycle from 74%to 90%,which is crucial to commercial application of LICs.

Seed-Oriented Local Community Detection Based on Influence Spreading

In recent years,local community detection algorithms have developed rapidly because of their nearly linear computing time and the convenience of obtaining the local information of real-world networks.However,there are still some issues that need to be further studied.First,there is no local community detection algorithm dedicated to detecting a seed-oriented local community,that is,the local community with the seed as the core.The second and third issues are that the quality of local communities detected by the previous local community detection algorithms are largely dependent on the position of the seed and predefined parameters,respectively.To solve the existing problems,we propose a seed-oriented local community detection algorithm,named SOLCD,that is based on influence spreading.First,we propose a novel measure of node influence named k-core centrality that is based on the k-core value of adjacent nodes.Second,we obtain the seed-oriented local community,which is composed of the may-members and the must-member chain of the seed,by detecting the influence scope of the seed.The may-members and the must-members of the seed are determined by judging the influence relationship between the node and the seed.Five state-of-art algorithms are compared to SOLCD on six real-world networks and three groups of artificial networks.The experimental results show that SOLCD can achieve a high-quality seed-oriented local community for various real-world networks and artificial networks with different parameters.In addition,when taking nodes with different influence as seeds,SOLCD can stably obtain high-quality seed-oriented local communities.

Tertiary orientation structures enhance the piezoelectricity of MXene/PVDF nanocomposite

With the increasing demand for flexible piezoelectric sensor components,research on polyvinylidene fluoride(PVDF)based piezoelectric polymers is mounting up.However,the low dipole polarization and disordered polarization direction presented in PVDF hinder further improvement of piezoelectric properties.Here,we constructed an oriented tertiary structure,consisting of molecular chains,crystalline region,and MXene sheets,in MXene/PVDF nanocomposite via a temperature-pressure dual-field regulation method.The highly oriented PVDF molecular chains form approximately 90%of theβphase.In addition,the crystalline region structure with long-range orientation achieves out of plane polarization orientation.The parallel orientation arrangement of MXene effectively enhances the piezoelectric performances of the nanocomposite,and the current output of the device increases by nearly 23 times.This high output device is used to monitor exercise action,exploring the potential applications in wearable electronics.

Erratum to:Tertiary orientation structures enhance the piezoelectricity of MXene/PVDF nanocomposite

In the first page of the original version of this paper,the Received date should be“10 October 2023”instead of“10 October 2013”.

Body-area sensor network featuring micropyramids for sports healthcare

Monitoring physiological signals of the human body can provide extremely important information for sports healthcare,preventing injuries and providing efficient guidance for individual sports.However,the signals related to human healthcare involve both subtle and vigorous signals,making it difficult for a sensor to satisfy the full-scale monitoring at the same time.Here,a novel conductive elastomer featuring homogeneously micropyramid-structured PDMS/CNT composite is used to fabricate highperformance piezoresistive sensors by a drop-casting method.Benefiting from the significant increase in the contact area of microstructure during deformation,the flexible sensor presents a broad detection range(up to 185.5 kPa),fast response/recovery time(44/13 ms),ultrahigh sensitivity(242.4 kPa–1)and excellent durability over 8,000 cycles.As a proof of concept,the as-fabricated pressure sensor can be used for body-area sports healthcare,and enable the detection of full-scale pressure distribution.Considering the fabulous sensing performance,the sensor may potentially become promising in personal sports healthcare and telemedicine monitoring.

Gradient CNT/PVDF piezoelectric composite with enhanced force-electric coupling for soccer training

Real-time monitoring of ball–shoe interactions can provide essential information for high-quality instruction in personalized soccer training,yet existing monitoring systems struggle to reflect specific forces,loci,and durations of action.Here,we design a self-powered piezoelectric sensor constructed by the gradient carbon nanotube/polyvinylidene fluoride(CNT/PVDF)composite to monitor the interactions between the ball and the shoe.Two-dimensional Raman mapping demonstrates the gradient structure of CNT/PVDF prepared by programmable electrospinning combined with a hot pressing.Benefitting from the synergistic effect of local polarization caused by the enrichment of CNT and the reduced diffusion of silver patterns in gradient structure,the as-prepared composite exhibits enhanced force-electric coupling with an excellent sensitivity of 80 mV/N and durability over 15,000 cycles.On this basis,we conformally attach a 3×3 sensor array to a soccer shoe,enabling real-time acquisition of kick position and contact force,which could provide quantitative assessment and personalize guidance for the training of soccer players.This self-powered piezoelectric sensor network system offers a promising paradigm for wearable monitoring under strong impact forces.