Zinc-air batteries(ZABs)hold tremendous promise for clean and efficient energy storage with the merits of high theoretical energy density and environmental friendliness.However,the performance of practical ZABs is sti...Zinc-air batteries(ZABs)hold tremendous promise for clean and efficient energy storage with the merits of high theoretical energy density and environmental friendliness.However,the performance of practical ZABs is still unsatisfactory because of the inevitably decreased activity of electrocatalysts when assembly into a thick electrode with high mass loading.Herein,we report a hierarchical electrocatalyst based on carbon microtube@nanotube core-shell nanostructure(CMT@CNT),which demonstrates superior electrocatalytic activity for oxygen reduction reaction and oxygen evolution reaction with a small potential gap of 0.678 V.Remarkably,when being employed as air-cathode in ZAB,the CMT@CNT presents an excellent performance with a high power density(160.6 mW cm^−2),specific capacity(781.7 mAhgZn^−1)as well as long cycle stability(117 h,351 cycles).Moreover,the ZAB performance of CMT@CNT is maintained well even under high mass loading(3 mg cm−2,three times as much as traditional usage),which could afford high power density and energy density for advanced electronic equipment.We believe that this work is promising for the rational design of hierarchical structured electrocatalysts for advanced metal-air batteries.展开更多
Interferometric phase filtering is one of the key steps in interferometricsynthetic aperture radar (InSAR/SAR). However, the ideal filtering results are difficult toobtain due to dense fringe and low coherence regions...Interferometric phase filtering is one of the key steps in interferometricsynthetic aperture radar (InSAR/SAR). However, the ideal filtering results are difficult toobtain due to dense fringe and low coherence regions. Moreover, the InSAR/SAR datarange is relatively large, so the efficiency of interferential phase filtering is one of themajor problems. In this letter, we proposed an interferometric phase filtering methodbased on an amended matrix pencil and linear window mean filter. The combination ofthe matrix pencil and the linear mean filter are introduced to the interferometric phasefiltering for the first time. First, the interferometric signal is analyzed, and theinterferometric phase filtering is transformed into a local frequency estimation problem.Then, the local frequency is estimated using an amended matrix pencil at a window. Thelocal frequency can represent terrain changes, thus suggesting that the frequency can beaccurately estimated even in dense fringe regions. Finally, the local frequency is filteredby using a linear window mean filter, and the filtered phase is recovered. The proposedmethod is calculated by some matrices. Therefore, the computational complexity isreduced, and the efficiency of the interferometric phase filtering is improved.Experiments are conducted with simulated and real InSAR data. The proposed methodexhibits a better filtering effect and an ideal efficiency as compared with the traditionalfiltering method.展开更多
Layered double hydroxides(LDHs), as a class of typical two-dimensional materials, have sparked increasing interest in the field of energy storage and conversion. In the last few years, the research about LDHs as elect...Layered double hydroxides(LDHs), as a class of typical two-dimensional materials, have sparked increasing interest in the field of energy storage and conversion. In the last few years, the research about LDHs as electrode active materials has seen much progress in terms of structure designing, material synthesis, properties tailoring, and applications. In this review, we focus on the integrated nanostructural electrodes(INEs) construction using LDH materials, including pristine LDH-INEs, hybrid LDH-INEs, and LDH derivativeINEs, as well as the performance advantages and applications of LDH-INEs.Moreover, in the final section, the insights about challenges and prospective in this promising research field were concluded, especially in regulation of intrinsic activity and uncovering of structure–activity relationship, which would push forward the development of this fast-growing field.展开更多
基金supported by the National Natural Science Foundation of China(21922501,21871021 and 21521005)the Beijing Natural Science Foundation(2192040)+1 种基金the National Key Research and Development Programme(2017YFA0206804)the Fundamental Research Funds for the Central Universities(XK1802-6 and 479 XK1803-05).
文摘Zinc-air batteries(ZABs)hold tremendous promise for clean and efficient energy storage with the merits of high theoretical energy density and environmental friendliness.However,the performance of practical ZABs is still unsatisfactory because of the inevitably decreased activity of electrocatalysts when assembly into a thick electrode with high mass loading.Herein,we report a hierarchical electrocatalyst based on carbon microtube@nanotube core-shell nanostructure(CMT@CNT),which demonstrates superior electrocatalytic activity for oxygen reduction reaction and oxygen evolution reaction with a small potential gap of 0.678 V.Remarkably,when being employed as air-cathode in ZAB,the CMT@CNT presents an excellent performance with a high power density(160.6 mW cm^−2),specific capacity(781.7 mAhgZn^−1)as well as long cycle stability(117 h,351 cycles).Moreover,the ZAB performance of CMT@CNT is maintained well even under high mass loading(3 mg cm−2,three times as much as traditional usage),which could afford high power density and energy density for advanced electronic equipment.We believe that this work is promising for the rational design of hierarchical structured electrocatalysts for advanced metal-air batteries.
基金The authors would like to thank the support by the State Key Program of National Natural Science Foundation of China under Grant[Number 41774026]the Satellite Mapping Technology and Application,National Administration of Surveying,Mapping and Geoinformation Key Laboratory under Grant[Number KLSMTA-201708].
文摘Interferometric phase filtering is one of the key steps in interferometricsynthetic aperture radar (InSAR/SAR). However, the ideal filtering results are difficult toobtain due to dense fringe and low coherence regions. Moreover, the InSAR/SAR datarange is relatively large, so the efficiency of interferential phase filtering is one of themajor problems. In this letter, we proposed an interferometric phase filtering methodbased on an amended matrix pencil and linear window mean filter. The combination ofthe matrix pencil and the linear mean filter are introduced to the interferometric phasefiltering for the first time. First, the interferometric signal is analyzed, and theinterferometric phase filtering is transformed into a local frequency estimation problem.Then, the local frequency is estimated using an amended matrix pencil at a window. Thelocal frequency can represent terrain changes, thus suggesting that the frequency can beaccurately estimated even in dense fringe regions. Finally, the local frequency is filteredby using a linear window mean filter, and the filtered phase is recovered. The proposedmethod is calculated by some matrices. Therefore, the computational complexity isreduced, and the efficiency of the interferometric phase filtering is improved.Experiments are conducted with simulated and real InSAR data. The proposed methodexhibits a better filtering effect and an ideal efficiency as compared with the traditionalfiltering method.
基金supported by the National Natural Science Foundation of China(21601011 and 21521005)the National Key Research and Development Programme(2017YFA0206804)+1 种基金the Fundamental Research Funds for the Central Universities(buctrc201506 and buctylkxj01)the Higher Education and HighQuality and World-Class Universities(PY201610)
文摘Layered double hydroxides(LDHs), as a class of typical two-dimensional materials, have sparked increasing interest in the field of energy storage and conversion. In the last few years, the research about LDHs as electrode active materials has seen much progress in terms of structure designing, material synthesis, properties tailoring, and applications. In this review, we focus on the integrated nanostructural electrodes(INEs) construction using LDH materials, including pristine LDH-INEs, hybrid LDH-INEs, and LDH derivativeINEs, as well as the performance advantages and applications of LDH-INEs.Moreover, in the final section, the insights about challenges and prospective in this promising research field were concluded, especially in regulation of intrinsic activity and uncovering of structure–activity relationship, which would push forward the development of this fast-growing field.
