Generally,layered Ni-rich cathode materials exhibit the morphology of polycrystalline secondary sphere composed of numerous primary particles.While the arrangement of primary particles plays a very important role in t...Generally,layered Ni-rich cathode materials exhibit the morphology of polycrystalline secondary sphere composed of numerous primary particles.While the arrangement of primary particles plays a very important role in the properties of Ni-rich cathodes.The disordered particle arrangement is harmful to the cyclic performance and structural stability,yet the fundamental understanding of disordered structure on the structural degradation behavior is unclarified.Herein,we have designed three kinds of LiNi_(0.83)Co_(0.06)Mn_(0.11)O_(2) cathode materials with different primary particle orientations by regulating the precursor coprecipitation process.Combining finite element simulation and in-situ characterization,the Li^(+)transport and structure evolution behaviors of different materials are unraveled.Specifically,the smooth Li^(+)diffusion minimizes the reaction heterogeneity,homogenizes the phase transition within grains,and mitigates the anisotropic microstructural change,thereby modulating the crack evolution behavior.Meanwhile,the optimized structure evolution ensures radial tight junctions of the primary particles,enabling enhanced Li^(+)diffusion during dynamic processes.Closed-loop bidirectional enhancement mechanism becomes critical for grain orientation regulation to stabilize the cyclic performance.This precursor engineering with particle orientation regulation provides the useful guidance for the structural design and feature enhancement of Ni-rich layered cathodes.展开更多
[ Objective ] The aim was to explore the relation between culture diversity and biodiversity of the Zhuang people. [ Method ] Botany in minority ethnic groups was researched based on information searching, interviewin...[ Objective ] The aim was to explore the relation between culture diversity and biodiversity of the Zhuang people. [ Method ] Botany in minority ethnic groups was researched based on information searching, interviewing and surveying with consideration of the importance of cultural and biological diversity. [ Result] The Zhuang culture, involving color, cuisine, geography and song, is closely related to biodiversity, and worship culture, involving plants, animals, and folk cus- tom, plays an important role in protection of biodiversity. However, biodiversity is significantly affected by some factors, including natural condition, population quality, traditional culture, wrong policies, negative effect of modern ecological culture, natural and environmental resources. [ Conclusion] It is suggested that lo- cal education should be enhanced to absorb modem science＆technology, to promote the concept of confirming to nature and of harmonious development and to achieve sustainable development in western of Guangxi.展开更多
基金supported by National Natural Science Foundation of China (52070194,52073309)Natural Science Foundation of Hunan Province (2022JJ20069)。
文摘Generally,layered Ni-rich cathode materials exhibit the morphology of polycrystalline secondary sphere composed of numerous primary particles.While the arrangement of primary particles plays a very important role in the properties of Ni-rich cathodes.The disordered particle arrangement is harmful to the cyclic performance and structural stability,yet the fundamental understanding of disordered structure on the structural degradation behavior is unclarified.Herein,we have designed three kinds of LiNi_(0.83)Co_(0.06)Mn_(0.11)O_(2) cathode materials with different primary particle orientations by regulating the precursor coprecipitation process.Combining finite element simulation and in-situ characterization,the Li^(+)transport and structure evolution behaviors of different materials are unraveled.Specifically,the smooth Li^(+)diffusion minimizes the reaction heterogeneity,homogenizes the phase transition within grains,and mitigates the anisotropic microstructural change,thereby modulating the crack evolution behavior.Meanwhile,the optimized structure evolution ensures radial tight junctions of the primary particles,enabling enhanced Li^(+)diffusion during dynamic processes.Closed-loop bidirectional enhancement mechanism becomes critical for grain orientation regulation to stabilize the cyclic performance.This precursor engineering with particle orientation regulation provides the useful guidance for the structural design and feature enhancement of Ni-rich layered cathodes.
基金Supported by Scientific Research of Guangxi Education Department(201012MS190)Integration Establishment of Characteristic Majors and Subjects of Guangxi Higher Education Institutions(GXTSZY224)
文摘[ Objective ] The aim was to explore the relation between culture diversity and biodiversity of the Zhuang people. [ Method ] Botany in minority ethnic groups was researched based on information searching, interviewing and surveying with consideration of the importance of cultural and biological diversity. [ Result] The Zhuang culture, involving color, cuisine, geography and song, is closely related to biodiversity, and worship culture, involving plants, animals, and folk cus- tom, plays an important role in protection of biodiversity. However, biodiversity is significantly affected by some factors, including natural condition, population quality, traditional culture, wrong policies, negative effect of modern ecological culture, natural and environmental resources. [ Conclusion] It is suggested that lo- cal education should be enhanced to absorb modem science＆technology, to promote the concept of confirming to nature and of harmonious development and to achieve sustainable development in western of Guangxi.
