The effect of Si content on the microstructures and growth kinetics of intermetallic compounds(IMCs)formed during the initial interfacial reaction(<10 s)between solid steel and liquid aluminum was investigated by a...The effect of Si content on the microstructures and growth kinetics of intermetallic compounds(IMCs)formed during the initial interfacial reaction(<10 s)between solid steel and liquid aluminum was investigated by a thermophysical simulation method.The influence of Si addition on interfacial mechanical properties was revealed by a high-frequency induction brazing.The results showed that IMCs layers mainly consisted ofη-Fe_(2)Al_(5)andθ-Fe_(4)Al_(13).The addition of Si reduced the thickness of the IMCs layer.The growth of theηphase was governed by the diffusion process when adding 2 wt.%Si to the aluminum melt.When 5 wt.%or 8 wt.%Si was added to aluminum,the growth was governed by both the diffusion process and interfacial reaction,and ternary phaseτ1/τ9-(Al,Si)_(5)Fe_(3)was formed in theηphase.The apparent activation energies of theηphase decreased gradually with increasing Si content.The joint with pure aluminum metal had the highest tensile strength and impact energy.展开更多
Organic low-dimensional crystals have garnered escalating interests in the realms of miniaturized optoelectronics and integrated photonics.The continual expansion of molecular systems and improvement in experimental c...Organic low-dimensional crystals have garnered escalating interests in the realms of miniaturized optoelectronics and integrated photonics.The continual expansion of molecular systems and improvement in experimental conditions have given rise to unconventional organic low-dimensional crystals,which showcase a variety of appealing structure-dependent properties in the realm of organic semiconductors,owing to their adaptable physicochemical characteristics and exceptional optoelectronics performance.Simultaneously,the development of unconventional low-dimensional crystals is filled with abundant possibilities due to their diverse application prospects.Herein,we present a comprehensive overview of advancements in research on representative cases of unconventional low-dimensional organic crystals,using a systematic and rational structural classification.Finally,we have also discussed the existing challenges and future directions,aspiring to deepen understanding and encourage further research exploration in this field.展开更多
Based on Kolmgorov-Johnson-Mehl-Avrami analysis, a new bainite kinetics of high strength low alloy steel in fast cooling process was developed by utilizing different experimental methods. Upper bainite transformation ...Based on Kolmgorov-Johnson-Mehl-Avrami analysis, a new bainite kinetics of high strength low alloy steel in fast cooling process was developed by utilizing different experimental methods. Upper bainite transformation morphological evolutions at a cooling rate of 8.3 K/s were directly observed by laser scanning confocal microscopy. This qualitative analysis suggests that bainite packet is more suitable to give a one-dimensional growth model if it is considered as a transformation unit. The nucleation rate of bainite packets in fast cooling process is assumed to give an a priori item. One-dimensional growth model with constant growth rate which is assumed as a function of cooling rate is adopted as well. Thus, the devel- oped new bainite kinetics is simple in expression and contains an adjustable parameter and an empirical pa rameter. Experimental results show upper bainite and lower bainite transformations in fast cooling processes. Their referential phase volume fractions are calculated by the expanded lever rule on the first derivative dilatometer curves. For the similar transformation mechanisms, upper bainite and lower bainite are considered to give the same kinetics. With considering the Nakamura's equation, the bainite kinetics is fitted with experimental data. Results show that bainite volume fractions and bainite transformation rates can be expressed precisely bY the newly developed bainite kinetics.展开更多
基金The authors are grateful for the financial supports from the National Natural Science Foundation of China(No.51875037)the Beijing Municipal Natural Science Foundation,China(No.3192021)the Fundamental Research Funds for the Central Universities,China(No.FRF-GF-18-004B).
文摘The effect of Si content on the microstructures and growth kinetics of intermetallic compounds(IMCs)formed during the initial interfacial reaction(<10 s)between solid steel and liquid aluminum was investigated by a thermophysical simulation method.The influence of Si addition on interfacial mechanical properties was revealed by a high-frequency induction brazing.The results showed that IMCs layers mainly consisted ofη-Fe_(2)Al_(5)andθ-Fe_(4)Al_(13).The addition of Si reduced the thickness of the IMCs layer.The growth of theηphase was governed by the diffusion process when adding 2 wt.%Si to the aluminum melt.When 5 wt.%or 8 wt.%Si was added to aluminum,the growth was governed by both the diffusion process and interfacial reaction,and ternary phaseτ1/τ9-(Al,Si)_(5)Fe_(3)was formed in theηphase.The apparent activation energies of theηphase decreased gradually with increasing Si content.The joint with pure aluminum metal had the highest tensile strength and impact energy.
基金financial support from the National Natural Science Foundation of China (grant nos.52173177,21703148,and 21971185)the Natural Science Foundation of Jiangsu Province (grant no.BK20230010)+1 种基金the Natural Science Foundation of Shandong Province (grant no.ZR2020MB054)the Collaborative Innovation Center of Suzhou Nano Science&Technology.
文摘Organic low-dimensional crystals have garnered escalating interests in the realms of miniaturized optoelectronics and integrated photonics.The continual expansion of molecular systems and improvement in experimental conditions have given rise to unconventional organic low-dimensional crystals,which showcase a variety of appealing structure-dependent properties in the realm of organic semiconductors,owing to their adaptable physicochemical characteristics and exceptional optoelectronics performance.Simultaneously,the development of unconventional low-dimensional crystals is filled with abundant possibilities due to their diverse application prospects.Herein,we present a comprehensive overview of advancements in research on representative cases of unconventional low-dimensional organic crystals,using a systematic and rational structural classification.Finally,we have also discussed the existing challenges and future directions,aspiring to deepen understanding and encourage further research exploration in this field.
文摘Based on Kolmgorov-Johnson-Mehl-Avrami analysis, a new bainite kinetics of high strength low alloy steel in fast cooling process was developed by utilizing different experimental methods. Upper bainite transformation morphological evolutions at a cooling rate of 8.3 K/s were directly observed by laser scanning confocal microscopy. This qualitative analysis suggests that bainite packet is more suitable to give a one-dimensional growth model if it is considered as a transformation unit. The nucleation rate of bainite packets in fast cooling process is assumed to give an a priori item. One-dimensional growth model with constant growth rate which is assumed as a function of cooling rate is adopted as well. Thus, the devel- oped new bainite kinetics is simple in expression and contains an adjustable parameter and an empirical pa rameter. Experimental results show upper bainite and lower bainite transformations in fast cooling processes. Their referential phase volume fractions are calculated by the expanded lever rule on the first derivative dilatometer curves. For the similar transformation mechanisms, upper bainite and lower bainite are considered to give the same kinetics. With considering the Nakamura's equation, the bainite kinetics is fitted with experimental data. Results show that bainite volume fractions and bainite transformation rates can be expressed precisely bY the newly developed bainite kinetics.