Carbon fiber confined mixed Ni-based crystal phases with interfacial charge redistribution induced by high bond polarity for electrochemical urea-assisted hydrogen generation

Interfacial electronic structure modulation of nickel-based electrocata-lysts is significant in boosting energy-conversion-relevant urea oxidation reaction(UOR).Herein,porous carbon nanofibers confined mixed Ni-based crystal phases of Ni_(2)P and NiF_(2) are developed via fluorination and phosphorization of Ni coated carbon nanofiber(Ni_(2)P/NiF_(2)/PCNF),which possess sufficient mesoporous and optimized Gibbs adsorption free energy by mixed phase-induced charge redistribution.This novel system further reduces the reaction energy barrier and improves the reaction activity by addressing the challenges of low intrinsic activity,difficulty in active site formation,and insufficient synergism.A considerably high current density of 254.29 mA cm^(-2) is reached at 1.54 V versus reversible hydrogen electrode on a glass carbon electrode,and the cell voltage requires 1.39 V to get 10 mA cm^(-2) in hydrogen generation,with very good stability,about 190 mV less than that of the traditional water electrolysis.The facile active phase formation and high charge transfer ability induced by asymmetric charge redistribution are found in the interface,where the urea molecules tend to bond with Ni atoms on the surface of heterojunction,and the rate-determining step is changed from CO_(2) desorption to the fourth H-atom deprotonation.The work reveals a novel catalyst system by interfacial charge redistribution induced by high bond polarity for energy-relevant catalysis reactions.

美国、欧盟、德国、法国和俄罗斯教育数字化转型分析

数字经济的快速发展推动了世界科技革命和产业变革。随着新一代信息技术在教育领域中的规模化应用,教育数字化转型成为大势所趋,世界各国纷纷制定与教育数字化转型相关的发展战略。文章采用案例研究与内容分析法,对美国、欧盟、德国、法国、俄罗斯的教育数字化转型政策进行梳理,总结出国际教育数字化转型的四个特征:注重战略层面的组织结构变革,指向公平、包容和安全的教育,强调新型基础设施与标准体系建设,关注多边参与的数字合作机制,以期为我国教育数字化转型提供参考。

High valence state of Ni and Mo synergism in NiS_(2);MoS_(2)hetero-nanorods catalyst with layered surface structure for urea electrocatalysis

High valence state species are significant in the energy-relevant electrochemical oxidation reactions.Herein,the high active state of Ni^(3+)formation induced by Mo^(6+)and their efficient synergism in NiS_(2)-MoS_(2)hetero-nanorods powder catalyst with the rough layered structure are demonstrated,as proof of concept,for the urea-assisted water electrolysis.This catalyst can be derived from the sulfidation of NiMoO_(4) nanorods that can realize individual metal sulfides sufficiently mixing at a domain size in the nanoscale which creates lots of active sites and nanointerfaces.The high valence state of Mo^(6+)and Ni^(3+)formation and increased conductive phase of 1 T MoS_(2)in the hetero-nanorods compared to the counterpart pure phases are revealed by spectral study and microscopic analysis;high electrochemical surface area and active site exposure are found due to the nano-interface formation and layered rough nanosheets over the surface of nanorods.They show much higher catalytic performance than their pure phases for urea oxidation,including high catalytic activity,stability,charge transfer ability and catalytic kinetics resulting from more active Ni^(3+)species formation and electronic synergism of high valence metals.Transformation of 1 T MoS_(2)to Mo^(6+)and increased amount of Mo^(6+)and Ni^(3+)after stability test indicate their involvement and synergism for the catalysis reaction.The current work offers a novel understanding of the synergistic effect based on the high valence state synergism for heterogeneous catalysts in electrocatalysis.

Surfactant Surface Tension Effects on Promoting Hydrate Formation: An Experimental Study Using Fluorocarbon Surfactant (Intechem-01) + SDS Composite Surfactant

The investigation of surface tension is a very important task for gas hydrate studying. Surfactants can effectively reduce the surface tension, improve the gas storage capability of hydrate and increase the formation rate, shorten the induction time. The objective of this study were to obtain a better understanding of the role of surface tension on hydrate formation and build gas hydrate models involve surfactant. In this study it was highlighted that the surface tension of Intechem-01 + SDS composite surfactants in natural gas hydrate promotion system and the change rules at different temperatures, concentration and proportion. According to the results of experiment, the surface tension of composite surfactants decreased with the increase of Intechem-01. The best cooperating effect was observed in proportion (Intechem-01 content) of 0.6 - 0.7, where the surface tension was the lowest. In this proportion range, the composite surfactants showed the same effect to pure fluorine carbon surfactant. The study shown the surface tension of composite surfactants decreased with the rise of temperature, and they were in a linear relationship within a certain range. Surface tension of composite surfactants decreased with the increase of surfactant concentration, however, it was no longer decreased above critical micelle concentration (CMC). The fitting equation of surface tension with various factors has been obtained.

异质结构NiSe_(2)/MoSe_(2)用于高效尿素辅助电解水制氢

电催化水分解是实现绿色制氢的理想方法之一.然而,阳极析氧反应(OER)固有的缓慢动力学和高理论电压(1.23V),使得电解水制氢的能效受到严重限制.采用理论电位更低和热力学更有利的小分子氧化反应替代OER过程,可以在降低电能耗的同时降解污染物或生成有附加值的产物,能够带来多重效益.尿素氧化反应(UOR)具有较低的理论电压(0.37V),是替代OER的潜在反应之一.然而,UOR中复杂的六电子转移严重阻碍了尿素电解的整体效率.因此,设计经济且高效的电催化剂来促进UOR固有的缓慢动力学过程非常必要.硒化镍具有电子构型多样和结构调控灵活等优点,被认为是有效的UOR催化剂.然而,UOR过程涉及催化剂表面多种反应中间体的吸附/解吸,单相催化剂要同时满足多种反应中间的吸附/解吸是一项艰巨的挑战.众所周知,非均相电催化涉及电子转移以及电催化剂表面反应物和产物的吸附和解吸.因此,催化剂的电催化性能在很大程度上取决于材料表面的电子特性.通过构建异质结构是一种有效策略,可以调节电催化剂的电子结构,优化反应中间体的化学吸附行为,实现不同组份高效协同电催化.研究表明,通过界面工程优化结构和电子特性可进一步促进UOR的动力学.MoSe_(2)具有良好的稳定性和导电性,与镍基催化剂组合构建异质结构能够改善电催化反应中的催化动力学.本文通过简单的水热和低温硒化方法构建了异质NiSe_(2)/MoSe_(2)微球作为UOR的电催化剂.差分电荷密度和Mulliken电荷分析结果表明,MoSe_(2)与NiSe_(2)的耦合引起界面处的电荷重新分布,促使电子从NiSe_(2)向MoSe_(2)转移,更容易形成高价态Ni(NiOOH)活性物种.另外,异质界面的构建优化了催化剂表面的电子结构并调节d带中心,改变反应途径,降低反应能垒,从而提高UOR的反应活性.异质结NiSe_(2)/MoSe_(2)微球由于其独特的结构特征、强的协同耦合作用、增加的活性中心和高含量的高价Ni3+物种的综合优势而具有高效的催化性能.当负载在玻碳电极上时,仅需1.33 V的电压就能驱动10 m Acm^(-2)的电流密度,该活性优于大多数已报道的非贵金属UOR催化剂.将NiSe_(2)/MoSe_(2)催化剂组装到UOR//HER电解槽中时,NiSe_(2)/MoSe_(2)|Pt/C具有较低的操作电压和长期稳定性,在1.47 V的电池电压下电流密度达到10 m Acm^(-2),比单纯的水电解降低了约220 m V.与OER相比,热力学上有利的UOR可以作为阳极OER替代反应.综上,本文为能源/环境相关的催化反应提供了一个有效的催化剂体系,对构建高效异质结催化系统具有借鉴意义.

A review of Ni based powder catalyst for urea oxidation in assisting water splitting reaction

Water splitting has been regarded as a sustainable and environmentally-friendly technique to realize green hydrogen generation,while more energy is consumed due to the high overpotentials required for the anode oxygen evolution reaction.Urea electrooxidation,an ideal substitute,is thus received increasing attention in assisting water-splitting reactions.Note that highly efficient catalysts are still required to drive urea oxidation,and the facile generation of high valence state species is significant in the reaction based on the electrochemicalchemical mechanisms.The high cost and rareness make the noble metal catalysts impossible for further consideration in large-scale application.Ni-based catalysts are very promising due to their cheap price,facile structure tuning,good compatibility,and easy active phase formation.In the light of the significant advances made recently,herein,we reviewed the recent advances of Ni-based powder catalysts for urea oxidation in assisting water-splitting reaction.The fundamental of urea oxidation is firstly presented to clarify the mechanism of urea-assisted water splitting,and then the prevailing evaluation indicators are briefly expressed based on the electrochemical measurements.The catalyst design principle including synergistic effect,electronic effect,defect construction and surface reconstruction as well as the main fabrication approaches are presented and the advances of various Ni-based powder catalysts for urea assisted water splitting are summarized and discussed.The problems and challenges are also concluded for the Ni-based powder catalysts fabrication,the performance evaluation,and their application.Considering the key influencing factors for catalytic process and their application,attention should be given to structure-property relationship deciphering,novel Ni-based powder catalysts development and their construction in the real device;specifically,the effort should be directed to the Ni-based powder catalyst with multi-functions to simultaneously promote the fundamental steps and high anti-corrosion ability by revealing the local structure reconstruction as well as the integration in the practical application.We believe the current summarization will be instructive and helpful for the Ni-based powder catalysts development and understanding their catalytic action for urea-assisted hydrogen generation via water splitting technique.

An Improved Deadbeat Predictive Current Control Method for SPMSM Drives with a Novel Adaptive Disturbance Observer

To improve the dynamic performance of conventional deadbeat predictive current control(DPCC)under parameter mismatch,especially eliminate the current overshoot and oscillation during torque mutation,it is necessary to enhance the robustness of DPCC against various working conditions.However,the disturbance from parameter mismatch can deteriorate the dynamic performance.To deal with the above problem,firstly,traditional DPCC and the parameter sensitivity of DPCC are introduced and analyzed.Secondly,an extended state observer(ESO)combined with DPCC method is proposed,which can observe and suppress the disturbance due to various parameter mismatch.Thirdly,to improve the accuracy and stability of ESO,an adaptive extended state observer(AESO)using fuzzy controller based on ESO,is presented,and combined with DPCC method.The improved DPCC-AESO can switch the value of gain coefficients with fuzzy control,accelerating the current response speed and avoid the overshoot and oscillation,which improves the robustness and stability performance of SPMSM.Finally,the three methods,as well as conventional DPCC method,DPCC-ESO method,DPCC-AESO method,are comparatively analyzed in this paper.The effectiveness of the proposed two methods are verified by simulation and experimental results.

Experiment of New Additives Effect on Gas Hydrate Formation

Natural gas hydrate has tremendous gas storage capacity;natural gas hydrate can be used to store and transport energy. The current problem faced is how to improve the hydrate formation rate and storage capacity, and form continuously. Compared to the pure water and SDBS solution, the ionic solution [HMIPS]OTs made by the team was the excellent additive and ensured the best reaction concentration range. Specific effects of different additives on hydrate formation were summarized;hydrate formation mechanism of additives was expounded. Considering the investment cost, operation cost, simple and stable operation of different surfactants, it is thought that the study of different additives mechanisms and developing the new efficient additive have the important value.

Break of thermal equilibrium between optical and acoustic phonon branches of CsPbI_(3)under continuous-wave light excitation and cryogenic temperature

The kinetic of low-temperature carrier and lattice of lead-halide perovskite is yet to be fully understood.In this work,we investigate the steady-state photoluminescences(PLs)of CsPbI_(3)at the environmental temperature(Te)ranging from 20 K to 300 K,and observed anomalous behaviors at cryogenic temperatures:The carrier temperature(Tc)of pure CsPbI_(3)exhibits a negative correlation with Te,accompanied by an expansion in Urbach tails of absorption spectra(Abs.)and excessive red-shifts at peak energy of PLs.These phenomena are also observed in those samples containing a certain amount of Cs_(4)PbI_(6),but to a lesser extent and occurs at lower temperatures.It is attributed to the intensified hot phonon bottleneck effect(HPB)in CsPbI_(3)at cryogenic Te,which hinders the energy transfer from hot carriers,via longitudinal optics(LO)phonons to longitudinal acoustic(LA)phonons,to the ambient.For samples under continuous-wave laser excitation,in specific,the barrier induced by the enhanced HPB at low Teprevents the effective thermalization among carriers,LO and LA phonons,which,therefore,form thermally isolated ensembles with different temperatures.At cryogenic Terange,the elevated temperatures of carrier and LO phonon expand the high-energy side of PLs and the low-energy tail of Abs.,respectively.For those samples in which the CsPbI_(3)is mixed with Cs_(4)PbI_(6),the interfacial LO-LO interaction across them provides a bypass for heat dissipation,mitigating the heat accumulation in LO-phonons of CsPbI_(3).The results suggest that a strong HPB effect may break the thermal equilibrium among different branches of phonons in the lattice under certain extreme conditions.

Phase and chemical state tuning of FeNi oxides for oxygen evolution reaction

Advancing and deploying the Fe Ni-based catalyst,the state-of-the-art pre-electrocatalysts,for oxygen evolution reactions(OER)still suffer from unclear chemical state correlation to the catalytic ability,as evidenced by the variedly reported performance for the different Fe Ni structures.Herein,we contributed the phase and redox chemical states tuning of Fe Ni oxides by the surface microenvironment regulation for the OER catalysis that was realized by the urea-assisted pyrolysis and molybdenum-doping technique by integrating molybdenum into the iron–nickel metal-organic precursor.Driven by the complicated and compromised atmosphere,namely,the oxidation state driven by the Mo doping and reduction ability induced by the urea-assisted pyrolysis,could transfer confined Fe Ni oxides to hybrid phases of Fe_(2)O_(3)and FeNi_(3)alloy,and the resultant compromised chemical states by the charge redistribution imparted very high electrocatalytic performance for OER compared with the control samples.The insitu Raman spectroscopy and post-XPS analysis confirmed the facile Fe/Ni oxyhydroxide active phase formation resulting from the proper phase and chemical states,and theoretical analysis disclosed the microenvironment regulation resulting in the charge redistribution forming the electron accumulation and depletion sites to accelerate the oxygen-species to oxyhydroxide-species transformation and enhance the electronic state density near the Fermi level by significantly reducing the energy barrier.The work not only showed the importance of surface chemical state tunning that can basically answer the varied performance of Fe Ni catalysts but also revealed an effective approach for fine-tuning their catalytic properties.

Microfluidic-based isolation of circulating tumor cells with high-efficiency and high-purity

The isolation of circulating tumor cells(CTCs)from complex biological samples is of paramount signifi-cance for advancing cancer diagnosis,prognosis,and treatment.However,the low concentration of CTCs and nonspecific adhesion of white blood cells(WBCs)present challenges that hinder the efficiency and purity of captured CTCs.Microfluidic-based strategies utilize precise fluid control at the micron level to incorporate specific micro/nanostructures or recognition molecules,enabling effective CTCs separation.Moreover,by employing surface modification designs that exhibit exceptional anti-adhesion properties against WBCs,the purity of isolated CTCs can be further enhanced.This review offers an in-depth explo-ration of recent advancements,challenges,and opportunities associated with microfluidic-based CTCs iso-lation from biological samples.Firstly,we will comprehensively introduce the microfluidic-based strate-gies for achieving high-efficiency CTCs isolation,which includes the morphological design of microchan-nels for physical force-based CTCs isolation and the specific modification of microchannel surfaces for affinity-based CTCs isolation.Subsequently,a review of recent research advances in microfluidic-based high-purity CTCs isolation is presented,focusing on strategies that decrease the nonspecific adhesion of WBCs through surface micro-/nanostructure construction or chemical and biological modification.Finally,we will summarize the article by providing the prospective opportunities and challenges for the future development of microfluidic-based CTCs isolation.

Green Synthesized Liquid-like Dynamic Polymer Chains with Decreased Nonspecific Adhesivity for High-Purity Capture of Circulating Tumor Cells

The capture of circulating tumor cells(CTCs)is of great significance in reducing cancer mortality and complications.However,the nonspecific binding of proteins and white blood cells(WBCs)weakens the targeting capabilities of the capture surfaces,which critically hampers the efficiency and purity of the captured CTCs.Herein,we propose a liquid-like interface design strategy that consists of liquid-like polymer chains and anti-EpCAM modification processes for high-purity and high-efficiency capture of CTCs.The dynamic flexible feature of the liquid-like chains endows the modified surfaces with excellent antiadhesion property for proteins and blood cells.The liquid-like surfaces can capture the target CTCs and show high cell viability due to the environmentfriendly surface modification processes.When liquid-like surface designs were introduced in the deterministic lateral displacement(DLD)-patterned microfluidic chip,the nonspecific adhesion rate of WBCs was reduced by more than fivefold compared to that in the DLD chip without liquid-like interface design,while maintaining comparable capture efficiency.Overall,this strategy provides a novel perspective on surface design for achieving high purity and efficient capture of CTCs.

智慧教育驱动的教育系统革新

教育系统是一个充满不确定性的动态复杂系统。当前教育系统中不同程度地存在着改革对象规划较为局限、挟制于要素式的局部成功、革新进度滞后于时代脚步、未能回应社会发展需求等问题,以新一代数字技术与智能技术为支撑的智慧教育能够为破解教育系统发展难题、引领教育系统革新提供有效解决方案。本研究在认识论上厘清智慧教育破解教育系统革新相关难题的作用机制,分析智慧教育驱动教育系统革新的目标体系,认为智慧教育能够促使教育系统激发新活力与新动能、助力教育系统提升适应能力与韧性、带动教育系统发展自我进化能力、引领教育系统革新整体层次与结构;提出以智慧教育拓展教育系统革新的格局与版图、赋能教育系统内部要素优化升级、推动教育信息化并引领教育现代化、回应新时代社会人才培养目标;给出了实施路径,即从教育理念革新、多学科交叉与融合、信息技术融合创新、教与学的空间重塑、数智技术赋能增效、教育公共服务生态构建、教育治理方式升级、终身学习体系建立八大方面驱动教育系统革新。

仿生多孔膜材料研究进展

近些年来,仿生多孔膜材料已经成为膜材料领域研究热点之一.与传统多孔膜材料相比,受生物膜独特孔道结构和分离特性启发的仿生多孔膜具有优异选择分离性、智能门控性和智能响应性等优点,实现了多孔膜材料性能的突破并拓展其应用领域.首先,本文从生物膜的多尺度孔道结构出发,讨论生物膜的孔道结构与其选择分离性、门控性和响应性的关系,并系统介绍受生物膜启发的仿生纳/微尺度多孔膜材料的构建思路、结构及性能.其次,介绍仿生多孔膜在水处理、能源、生物医学及物质检测等主要应用领域的最新研究进展.最后,讨论了仿生多孔膜材料在发展过程中所面临的挑战,并展望了其发展趋势.

Microwave-assisted hydrothermal synthesis of NiMoO_(4) nanorods for high-performance urea electrooxidation

A large surface area with high active site exposure is desired for the nano-scaled electrocatalysts fabrica-tion.Herein,taking NiMoO_(4)nanorods for example,we demonstrated the advantages of the microwave-assisted hydrothermal synthesis method compared to the traditional hydrothermal approaches.Both monoclinic structured NiMoO_(4)in the nanorods morphology are found for these samples but it is more time-saving and efficient in the Ni-Mo synergism for the catalyst obtained by microwave-assisted hydrothermal syntheses method.When evaluated for urea oxidation,the current density can reach 130.79 mA/cm^(2)at 1.54 V,about 2.4 times higher than that of the counterpart catalyst(54.08 mA/cm^(2)).Moreover,largely improved catalytic stability,catalytic kinetics and rapid charge transfer ability are found on the catalyst obtained by the microwave-assisted approach.The high catalytic performance can be at-tributed to the high surface area and active site exposure of NiMoO_(4)nanorods formed by microwave irradiation.Considering the less time,facile synthesis condition and efficient components synergism,the microwave-assisted hydrothermal synthesis method might work better for the nanostructure electrocata-lysts fabrication.

美国推进教师信息技术能力发展策略及启示

教师是国家教育信息化发展中的关键要素之一。相较于我国主要关注中小学教师的信息技术能力,美国在教师信息技术能力发展,特别是职前教师信息技术能力培养方面的政策规划和举措值得我国借鉴。本文重点分析了自2016年美国发布第五个国家教育技术计划(NETP16)以来美国国家政策规划、教师信息技术能力标准建设以及在职和职前教师信息技术能力发展方面的典型实践动态,探究了美国教师信息技术能力发展策略以及对我国当前教师信息技术能力发展的重要启示。研究结果表明,转变教师角色,鼓励其利用信息技术支持学生的学习已成为教师信息技术能力发展的方向。此外,为在职教师提供持续、嵌入式的信息技术能力发展支持,重视职前教师信息技术能力培养并改革职前教师培养的课程体系,加强高校与中小学校的合作,职前职后培养一体化以及不断提升和更新高校教师的信息技术能力,都是我国促进教师信息技术能力持续发展可以借鉴的重要策略。

Hydrophilic carbon nanotube membrane enhanced interfacial evaporation for desalination

Carbon nanotube-based(CNT-based) interfacial evaporation material is one of the most potential materials for solar desalination. Here, we studied the evaporation rate of the CNT-based membranes with different hydrophilic and hydrophobic chemical modified surfaces using molecular dynamic simulations.We found that the hydrogen bonding density among water molecules at the interface is a key factor in enhancing the evaporation rate. For a hydrophilic CNT-based membrane, the strong interactions between the membrane outer surface and the water molecules can destroy the water-water hydrogen bonding interactions at the interface, resulting in the reduction of the hydrogen bonding density, leading to an enhancement effect in evaporation rate. We also found that there is an optimal thickness for evaporation membrane. These findings could provide some theoretical guidance for designing and exploring advanced CNT-based systems with more beneficial performance in water desalination.

Photochemical effect driven fluid behavior control in microscale pores and channels

Manipulating the fluid transport in the microscale pores and channels is playing a paramount role in the realization of the versatile functions of microfluidics.In recent years,using light to control the fluid behavior in the microchannels/pores has attracted many researchers'attention due to the advantages of light such as non-contact stimulation,tunable excitation,high spatial and temporal resolution.With efforts,great achievements and progresses have been achieved for photochemical effect driven microscale flow control,including fluid pumping,flow rate control,and fluid mixing,etc.In this review,we discuss the responsive mechanisms of photochemical effect driven fluid behavior control at the microscale.We also give a comprehensive review on the latest research progresses in photochemical effect controlled microfluid behaviors.Besides,prospective opportunities for the future development of light control of microscale flow are provided to attract scientific interest for the fast development and applications of various microchannel/pore systems.

流产布鲁氏菌转录调控因子GntR在小鼠模型上诱导的辅助性T细胞免疫应答

【目的】通过对布鲁氏菌gntR基因进行原核表达,分析其诱导机体产生的Th1和Th2型免疫反应。【方法】以布鲁氏菌S2308基因组为模板,根据GenBank上公布的S2308 gntR基因序列设计引物,利用分子克隆技术,将gntR基因片段克隆至原核表达载体pET-30a,转化至大肠杆菌BL21感受态细胞中,诱导GntR蛋白表达;利用SDS-PAGE对GntR重组蛋白(rGntR)进行分析;利用AKTAxpress智能多维纯化系统对rGntR进行纯化;利用Western blotting分析其免疫反应性;用rGntR刺激小鼠巨噬细胞RAW 264.7和小鼠脾细胞,利用ELISA试剂盒检测细胞因子IFN-γ、IL-2、IL-4和IL-5,以及IgG抗体的水平。将rGntR免疫小鼠,检测小鼠血清中IFN-γ和IL-4的水平。【结果】gntR基因大小为735 bp,编码245个氨基酸,大约在35 kDa处出现蛋白条带,纯化后为单一条带。WB显示,rGntR具有较好的免疫反应性。rGntR可诱导宿主细胞和小鼠产生较高水平的IFN-γ、IL-4和IgG。【结论】rGntR可在体内或体外诱导辅助性T细胞(Th1和Th2型)免疫反应。本研究可为布鲁氏菌病疫苗的研发提供科学依据。

Structural and Interfacial Effects on Drug Release Kinetics of Liquid‑Based Fibrous Catheter

Catheterization is indispensable in the field of modern medicine.However,catheter-related thrombosis and infections almost inevitably occur during the process,and as drugs can only be administered at the end of catheter,auxiliary strategies are required for successful implantation.Considering these intractable limitations,a type of self-adaptive,anti-coagulate liquidbased fibrous catheter has been developed.More importantly,it has positional drug release property that traditional catheters desperately need but couldn’t attain.Although enlightening,the feasibility and performance of the positional drug release have only been demonstrated by fluorescents,the specific drug release kinetics remains unknown for adaptation to application scenarios.Therefore,we systematically investigate the structural and interfacial effects of drug molecules and fibrous matrixes on drug release kinetics in a liquid-based fibrous catheter.Theoretical calculations and experiments demonstrate that oleophilic and hydrophilic molecules release slowly due to a dissolution-diffusion mechanism.Amphipathic molecules,however,will significantly affect the gating performance by affecting the interfacial stability,hence they release quickly with emulsifying the gating liquid.Besides the significant impact of molecular properties and interfacial effects,matrix pore size also has a slight influence that molecules release faster in bigger pores.Through this study,the liquid-based fibrous catheter may step further toward practical applications including chemotherapy,haemodialysis,angiography,etc.to overcome the existing catheter-related limitations.