A review on electrocatalytic CO_(2) conversion via C-C and C-N coupling

Electrochemical C-C and C-N coupling reactions with the conversion of abundant and inexpensive small molecules,such as CO_(2) and nitrogencontaining species,are considered a promising route for increasing the value of CO_(2) reduction products.The development of high-performance catalysts is the key to the both electrocatalytic reactions.In this review,we present a systematic summary of the reaction systems for electrocatalytic CO_(2) reduction,along with the coupling mechanisms of C-C and C-N bonds over outstanding electrocatalytic materials recently developed.The key intermediate species and reaction pathways related to the coupling as well as the catalyst-structure relationship will be also discussed,aiming to provide insights and guidance for designing efficient CO_(2) reduction systems.

Soil Fertility Comparison between Rotations of Tobacco-Rice (TR) and Rape-Rice (RR)

Tobacco-planting plays an important role in ensuring the high-quality tobacco raw materials supply and the local social and economic development in Chenzhou City. In recent years whether tobacco-planting is better for the maintenance and improvement of soil fertility than other crop-planting has been highly concerned. In this study, 16 soil fertility indicators and soil integrated index (IFI) were compared by 21 pairs of fields in Chenzhou city under the rotations of tobacco-rice (TF) and rice-rice (RR), and results showed that, comparing the mean values of soil fertility indicators, the contents of OM, TN, AN, AK, S and IFI were extremely significantly higher in TR than those in RR (p < 0.01), the contents of Cu, Ca, Mg and Fe were significantly higher in TR than those in RR (p < 0.05), but Mn content was significantly lower in TR than those in RR (p < 0.05). Meanwhile the contents of TP, TK and AP were insignificantly higher in TR than those in RR, and the contents of B, Mo and Zn were insignificantly lower in TR than those in RR. The above significant differences in soil fertility indicators were mainly due to relatively higher fertilizer inputs and less nutrient removal during tobacco-growing season than during rape-growing season, the net increase of N, P2O5 and K2O are 8.61, 5.25 and 24.89 kg per 667 m2 respectively in tobacco-growing season, while the net decrease of N, P2O5 and K2O are 8.88, 4.70 and 4.62 kg per 667 m2 respectively in rape-growing season. C.V. of soil fertility indicators and IFI were meanly lower in TR (52.25% and 15.95%, respectively) than those in RR (63.07% and 22.12%, respectively). Comparatively, tobacco-planting can improve soil fertility better than rape-planting when rotated with late rice in Chenzhou city. For tobacco-planting, Mg fertilizer should be applied for 23.8% TR fields, while more N, K, Ca, Mg, S and B fertilizers should be applied for 42.86%, 23.81%, 14.29%, 47.62%, 80.95% and 47.62% RR fields, respectively.

Study on Chemical Characteristics of Rainfall in Tobacco-Growing Regions of Chenzhou, Hunan Province

In order to clarify the chemical properties of rainfall in typical tobacco areas in Chenzhou City, Hunan Province, and analyze its potential for soil and flue-cured tobacco planting, rainfall samples in 2020 were collected by rainfall instruments in Fangyuan Town and Aoquan Town of Guiyang County, and the chemical properties that are closely related to the quality of flue-cured tobacco were determined, such as pH, EC, total nitrogen (TN), nitrate nitrogen (), ammonium nitrogen () and ion concentrations (K+, Na+, Ca2+, Mg2+, , Al3+, , Cl−,). The results show that the pH values of rainfall samples at Fangyuan and Aoquan monitoring sites are in the range of 4.92 - 6.17 and 4.93 - 5.69 respectively, with an average of 5.27 and 5.27 respectively. The acid rain characteristic is very obvious, which is mainly dominated by . The variation of rainfall EC has seasonal characteristics. EC is low from January to September, in the range of 6.09 - 56.72 and 11.83 - 30.93 μS/cm respectively, besides, it is high from October to December, in the range of 102.63 - 174.60 and 25.05 - 86.37 μS/cm respectively. The annual deposition of TN was 22.19 and 20.76 kg/hm2/yr respectively, which were higher than that in the western regions with less human disturbance, but lower than or equal to that in the developed agricultural regions in eastern China. The proportion of in the annual deposition of TN was higher than that of at two monitoring sites, with an average of 56.51% and 38.86% respectively. Ammonia volatilization from agricultural activities contributed more to rainfall nitrogen content. The ratios of ammonium nitrogen to nitrate nitrogen deposition at two monitoring points were 1.84, 1.81, 1.86 and 1.34, 1.46, and 1.29 during the whole year, summer and autumn, winter and spring respectively. The ratio is higher in summer and autumn than in winter and spring. The weighted average equivalent concentrations of the main ions at two monitoring sites were 238.88 μeq/L and 211.21 μeq/L respectively, and the orders of the ion concentrations were slightly different. Both the concentrations of and are higher, while Mg2+, and Al3+ are lower. , and are mainly from human activities with a contribution rate between 91.90% and 99.35%. Ca2+ mainly comes from soil and ground dust, besides, Cl− and Mg2+ mainly come from marine sources and K+ mainly comes from terrestrial sources. In general, the acidic rainfall and higher concentration are beneficial to reducing the high pH value of soil in Aoquan tobacco area and improving the quality of flue-cured tobacco. Higher concentrations of and in rainfall are not conducive to the improvement of flue-cured tobacco quality, because of the high content of soil available sulfur in Chenzhou tobacco area and the characteristics of flue-cured tobacco’s preference for ammonium.

Effectiveness of animal-assisted therapy on pain in children:A systematic review and meta-analysis

Aims:Animal-assisted therapy(AAT)relieves pain by creating a relaxed and comfortable environment to reduce anxiety in children.Yet little is known about its effects on pain in children.This study aims to systematically evaluate the effects of AAT on pain in children.Methods:Eight databases including PubMed,Cochrane Library,Web of Science,CINAHL Complete,Chinese Biomedical Database(CBM),Weipu Database(VIP),China Knowledge Resource Integrated Database(CNKI)and Wanfang Database were retrieved,and all randomized controlled trials or controlled clinical trial using AAT on children’s pain were recruited from inception to October 2019.Two reviewers independently screened literature,extracted data and assessed the risk of bias of the included studies.RevMan 5.3 software was employed for meta-analysis.Results:Seven published studies containing 4 RCTs and 3 CCTs were included for the systematic review.The results of meta-analysis showed that AAT could reduce children’s pain when compared with the control group[MD=-0.53,95%CI(-0.77,-0.30),P<0.00001].Conclusion:Current evidence shows that AAT can relieve pain in children to some extent.Considering the limited quality and quantity of the available studies,more high quality studies should be performed to verify the above conclusion.