The distribution and ecological risks of antibiotics in surface water in key cities along the lower reaches of the Yellow River:A case study of Kaifeng City,China

A large number of antibiotics have been discharged into rivers by human activities,posing a threat to aquatic ecosystems.The surface water of the Yellow River Basin also suffers antibiotic pollution,which hinders the improvement in the aquatic ecological environment.This study investigated and analyzed the characteristics and assessed the ecological risks of antibiotic pollution in surface water bodies such as canals,rivers and fish ponds in Kaifeng,Henan Province,which is a key city along the lower reaches of the Yellow River.The test results are as follows.A total of 15 types of antibiotics were detected in the surface water.They had a total antibiotic concentration of 12.2-249.9μg/L,of which tetracyclines(TCs)and quinolones accounted for the highest percentages.Six types of quinolones had detection rates of up to 100%,and doxycycline(DC)and oxytetracycline(OTC)had average concentrations of 29.52μg/L1 and 13.71μg/L,respectively.The major canals with water diverted from the Yellow River had total concentrations of quinolones and TCs of 22.0μg/L and 14.9μg/L,respectively,which were higher than those in previous studies.This phenomenon may be related to the decrease in the water flow of the Yellow River during the dry season and the increase in the antibiotic consumption of residents in the context of the Covid-19 outbreak.The upper reaches of the Huiji River in the Xiangfu District had higher antibiotic content than other districts in Kaifeng.Specifically,TCs accounted for 72.38%-91.84%of all antibiotics,and the DC and OTC concentrations were significantly higher than other antibiotics in the upper reaches.As indicated by the ecological risk assessment results,TCs had the highest ecological risks to green algae.Among them,DC had medium-high risks;TC,OTC,and chlortetracycline(CTC)had medium-high risks;trimethoprim(TMP)and lomefloxacin(LOM)had low risks;other TC antibiotics had no risk.Compared with green algae,most antibiotics showed higher ecological risks to daphnia and lower ecological risks to fish.DC and OTC dominate antibiotic pollutants in the surface water in Kaifeng City,and especially in Xiangfu District,where DC and OTC have medium-high risks.The TCs in the major Yellow River showed medium risks to both green algae and daphnia.It can be speculated that the antibiotic pollution in the Yellow River might pose a certain threat to the ecological security of water in Kaifeng City.

Factors driving surface deformations in plain area of eastern Zhengzhou City,China

With the rapid socio-economic development and urban expansion,land subsidence has emerged as a major environmental issue,impeding the high-quality development of the plain area in eastern Zhengzhou City,Henan Province,China.However,effective prevention and control of land subsidence in this region have been challenging due to the lack of comprehensive surface deformations monitoring and the quantitative analysis of the factors driving these deformations.In order to accurately identify the dominant factor driving surface deformations in the study area,this study utilized the Persistent Scattered Interferometric Synthetic Aperture Radar(PS-InSAR)technique to acquire the spatio-temporal distribution of surface deformations from January 2018 to March 2020.The acquired data was verified using leveling data.Subsequently,GIS spatial analysis was employed to investigate the responses of surface deformations to the driving factors.The findings are as follows:Finally,the geographical detector model was utilized to quantify the contributions of the driving factors and reveal the mechanisms of their interactions.The findings are as follows:(1)Surface deformations in the study area are dominated by land subsidence,concentrated mainly in Zhongmu County,with a deformation rate of−12.5–−37.1 mm/a.In contrast,areas experiencing surface uplift are primarily located downtown,with deformation rates ranging from 0 mm to 8 mm;(2)Groundwater level,lithology,and urban construction exhibit strong spatial correlations with cumulative deformation amplitude;(3)Groundwater level of the second aquifer group is the primary driver of spatially stratified heterogeneity in surface deformations,with a contributive degree of 0.5328.The contributive degrees of driving factors are significantly enhanced through interactions.Groundwater level and the cohesive soil thickness in the second aquifer group show the strongest interactions in the study area.Their total contributive degree increases to 0.5722 after interactions,establishing them as the primary factors influencing surface deformation patterns in the study area.The results of this study can provide a theoretical basis and scientific support for precise prevention and control measures against land subsidence in the study area,as well as contributing to research on the underlying mechanisms.