Coal mine fires,which can cause heavy casualties,environmental damages and a waste of coal resources,have become a worldwide problem.Aiming at overcoming the drawbacks,such as a low analysis efficiency,poor stability ...Coal mine fires,which can cause heavy casualties,environmental damages and a waste of coal resources,have become a worldwide problem.Aiming at overcoming the drawbacks,such as a low analysis efficiency,poor stability and large monitoring error,of the existing underground coal fire monitoring technology,a novel monitoring system based on non-dispersive infrared(NDIR)spectroscopy is developed.In this study,first,the measurement principle of NDIR sensor,the gas concentration calculation and its temperature compensation algorithms were expounded.Next,taking CO and CH_(4) as examples,the liner correlation coefficients of absorbance and the temperature correction factors of the two indicator gases were calculated,and then the errors of concentration measurement for CO,CO_(2),CH_(4) and C_(2)H_(4) were further analyzed.The results disclose that the designed NDIR sensors can satisfy the requirements of industrial standards for monitoring the indicator gases for coal fire hazards.For the established NDIR-based monitoring system,the NDIRbased spectrum analyzer and its auxiliary equipment boast intrinsically safe and explosion-proof performances and can achieve real-time and in-situ detection of indicator gases when installed close to the coal fire risk area underground.Furthermore,a field application of the NDIR-based monitoring system in a coal mine shows that the NDIR-based spectrum analyzer has a permissible difference from the chromatography in measuring the concentrations of various indicator gases.Besides,the advantages of high accuracy,quick analysis and excellent security of the NDIR-based monitoring system have promoted its application in many coal mines.展开更多
Caprocks play an important role in the trapping of coalbed methane(CBM)reservoirs.To study the sealing capacities of caprocks,five samples with different lithologies of Neogene clayrock,Paleogene redbeds,Permian sands...Caprocks play an important role in the trapping of coalbed methane(CBM)reservoirs.To study the sealing capacities of caprocks,five samples with different lithologies of Neogene clayrock,Paleogene redbeds,Permian sandstone,Permian mudstone and Permian siltstone were collected and tested using experimental methods of microstructure observation,pore structure measurement and diffusion properties determination.Results indicate that with denser structures,lower porosities,much more developed micropores/transition pores and higher pore/throat ratios,mudstone and siltstone have the more ideal sealing capacities for CBM preservation when comparing to other kinds of caprocks;the methane diffusion coefficients of mudstone/siltstone are about 6 times higher than sandstone and almost 90 times higher than clayrock/redbeds.To further estimate the CBM escape through caprocks,a one-dimensional CBM diffusion model is derived.Modeling calculation result demonstrates that under the same thickness,the CBM sealing abilities of mudstone/siltstone are almost 100 times higher than those of clayrock/redbeds,and nearly 17 times higher than sandstone,which indicates that the coal seam below caprocks like clayrock,redbeds or sandstone may suffer stronger CBM diffusion effect than that below mudstone or siltstone.Such conclusion is verified by the case study from III3 District,Xutuan Colliery,where the coal seam capped by Paleogene redbeds has a much lower CBM content than that capped by the Permian strata like mudstone,siltstone and sandstone.展开更多
基金Project(2021MD703848) supported by the China Postdoctoral Science FoundationProjects(52174229, 52174230)supported by the National Natural Science Foundation of China+1 种基金Project(2021-KF-23-04) supported by the Natural Science Foundation of Liaoning Province,ChinaProject(2020CXNL10) supported by the Fundamental Research Funds for the Central Universities,China。
文摘Coal mine fires,which can cause heavy casualties,environmental damages and a waste of coal resources,have become a worldwide problem.Aiming at overcoming the drawbacks,such as a low analysis efficiency,poor stability and large monitoring error,of the existing underground coal fire monitoring technology,a novel monitoring system based on non-dispersive infrared(NDIR)spectroscopy is developed.In this study,first,the measurement principle of NDIR sensor,the gas concentration calculation and its temperature compensation algorithms were expounded.Next,taking CO and CH_(4) as examples,the liner correlation coefficients of absorbance and the temperature correction factors of the two indicator gases were calculated,and then the errors of concentration measurement for CO,CO_(2),CH_(4) and C_(2)H_(4) were further analyzed.The results disclose that the designed NDIR sensors can satisfy the requirements of industrial standards for monitoring the indicator gases for coal fire hazards.For the established NDIR-based monitoring system,the NDIRbased spectrum analyzer and its auxiliary equipment boast intrinsically safe and explosion-proof performances and can achieve real-time and in-situ detection of indicator gases when installed close to the coal fire risk area underground.Furthermore,a field application of the NDIR-based monitoring system in a coal mine shows that the NDIR-based spectrum analyzer has a permissible difference from the chromatography in measuring the concentrations of various indicator gases.Besides,the advantages of high accuracy,quick analysis and excellent security of the NDIR-based monitoring system have promoted its application in many coal mines.
基金Project(2016YFC0801608) supported by the National Key Research and Development Plan,ChinaProject(51574148) supported by the National Natural Science Foundation of China
文摘Caprocks play an important role in the trapping of coalbed methane(CBM)reservoirs.To study the sealing capacities of caprocks,five samples with different lithologies of Neogene clayrock,Paleogene redbeds,Permian sandstone,Permian mudstone and Permian siltstone were collected and tested using experimental methods of microstructure observation,pore structure measurement and diffusion properties determination.Results indicate that with denser structures,lower porosities,much more developed micropores/transition pores and higher pore/throat ratios,mudstone and siltstone have the more ideal sealing capacities for CBM preservation when comparing to other kinds of caprocks;the methane diffusion coefficients of mudstone/siltstone are about 6 times higher than sandstone and almost 90 times higher than clayrock/redbeds.To further estimate the CBM escape through caprocks,a one-dimensional CBM diffusion model is derived.Modeling calculation result demonstrates that under the same thickness,the CBM sealing abilities of mudstone/siltstone are almost 100 times higher than those of clayrock/redbeds,and nearly 17 times higher than sandstone,which indicates that the coal seam below caprocks like clayrock,redbeds or sandstone may suffer stronger CBM diffusion effect than that below mudstone or siltstone.Such conclusion is verified by the case study from III3 District,Xutuan Colliery,where the coal seam capped by Paleogene redbeds has a much lower CBM content than that capped by the Permian strata like mudstone,siltstone and sandstone.