The microstructure and phase composition of high-alumina,chromic oxide,and AZS/Cr refractories containing 30%and 60%(by mass)Cr_(2)O_(3) after exposure to aluminaboronsilicate glasses and basalt melts depending on the...The microstructure and phase composition of high-alumina,chromic oxide,and AZS/Cr refractories containing 30%and 60%(by mass)Cr_(2)O_(3) after exposure to aluminaboronsilicate glasses and basalt melts depending on the type of melts and temperature have been studied.The mechanisms of refractory corrosion by the used melts and the factors contributing to the inhibition of corrosion development have been investigated by the method of petrographic analysis.On the basis of obtained results,the use of high-alumina,chromic oxide,and AZS/Cr refractories in the sections of glass furnace linings,experiencing the intensive impact of aluminaboronsilicate glasses and basalt melts,has been confirmed and scientifically substantiated.展开更多
Fused materials from ZrO2 stabilized by CaO or MgO, or the combined additive consisting of CaO and MgO are made. With using chemical, petrographic, X-ray phase and electron microscopic researches the main characterist...Fused materials from ZrO2 stabilized by CaO or MgO, or the combined additive consisting of CaO and MgO are made. With using chemical, petrographic, X-ray phase and electron microscopic researches the main characteristics of these materials are determined. It is shown that, the materials of all compositions have low water absorption; they are characterized by equal struc-ture. The materials stabilized by the combined additive consisting of CaO and MgO are presented by generally the cubic phase and a small amount of tetragonal and monoclinic ZrO2 phases. Depending on CaO： MgO ratio in the materials the tetragonal ZrO2 phase settles down in a cubic matrix in the form of separate grains, and sites of net like structure in the form of a ＂woven＂ interlacing （2.9% of CaO and 2. 6% of MgO ）. An influence of the above mentioned fused stabilized ZrO2 materials and quantity of monoclinic zirconia, on the forming of zirconia mix on a phosphate bond and properties of＂ .fired samples is studied. The samples from mix based on ZrO2 stabilized by the combined additive consisting of 2.9% CaO and 2.6% MgO with 20% of monoclinic Zr02 are characterized by the highest properties： after .firing at 1 580 ~C open porosity of 14. 3% - 14. 8%, apparent density of 4. 67 -4. 69 g · cm^-5, cold crushing strength of 62 - 68 MPa, thermal shock resistance （ 1 300℃←→air） of 15 thermal cycles, linear growth of 0. 2%. The manufacturing technology of powders mix-ture for ramming mix based on the new fused material .from ZrO2 stabilized by the combined additive is developed and its production is mastered. From this mixture the large-size, shaped products on the phosphate bond are made at one carbon black production plant, which are installed in the combustion chamber of the carbon black production reactor.展开更多
The article gives an introduction to the Ukrainian Research Institute of Refractories and especially its R & D and refractory products for the industries of iron and steel, nonferrous , glass and chemistry etc.
The use of a combined additive consisting of silica-containing additives“F”(thinning)and“S”(accelerating castable hardening)instead of the previously used silica-containing additive“A”and a mixture of dispersing...The use of a combined additive consisting of silica-containing additives“F”(thinning)and“S”(accelerating castable hardening)instead of the previously used silica-containing additive“A”and a mixture of dispersing additives based on polyethylene glycol in low-cement silicon carbide castable allows to improve the castable workability by increasing(in 5.4 times)the flowability of a freshly prepared castable,and increase by 1.2 and 1.1 times the cold crushing strength of heat-treated at temperatures of 110 and 1580°C,respectively,castable samples from low-cement silicon carbide castable with practically equal values of open porosity(15.8%and 16.0%).The petrographic studies of the castable sample microstructure after firing at a temperature of 1580°C showed that the investigated silica-containing additives“F”and“S”contribute to the denser and more uniform structure formation.As a result of the carried out research,the manufacturing technology of a low-cement silicon carbide castable was improved,of which the production was mastered at JSC“URIR named after A.S.Berezhnoy”.展开更多
文摘The microstructure and phase composition of high-alumina,chromic oxide,and AZS/Cr refractories containing 30%and 60%(by mass)Cr_(2)O_(3) after exposure to aluminaboronsilicate glasses and basalt melts depending on the type of melts and temperature have been studied.The mechanisms of refractory corrosion by the used melts and the factors contributing to the inhibition of corrosion development have been investigated by the method of petrographic analysis.On the basis of obtained results,the use of high-alumina,chromic oxide,and AZS/Cr refractories in the sections of glass furnace linings,experiencing the intensive impact of aluminaboronsilicate glasses and basalt melts,has been confirmed and scientifically substantiated.
文摘Fused materials from ZrO2 stabilized by CaO or MgO, or the combined additive consisting of CaO and MgO are made. With using chemical, petrographic, X-ray phase and electron microscopic researches the main characteristics of these materials are determined. It is shown that, the materials of all compositions have low water absorption; they are characterized by equal struc-ture. The materials stabilized by the combined additive consisting of CaO and MgO are presented by generally the cubic phase and a small amount of tetragonal and monoclinic ZrO2 phases. Depending on CaO： MgO ratio in the materials the tetragonal ZrO2 phase settles down in a cubic matrix in the form of separate grains, and sites of net like structure in the form of a ＂woven＂ interlacing （2.9% of CaO and 2. 6% of MgO ）. An influence of the above mentioned fused stabilized ZrO2 materials and quantity of monoclinic zirconia, on the forming of zirconia mix on a phosphate bond and properties of＂ .fired samples is studied. The samples from mix based on ZrO2 stabilized by the combined additive consisting of 2.9% CaO and 2.6% MgO with 20% of monoclinic Zr02 are characterized by the highest properties： after .firing at 1 580 ~C open porosity of 14. 3% - 14. 8%, apparent density of 4. 67 -4. 69 g · cm^-5, cold crushing strength of 62 - 68 MPa, thermal shock resistance （ 1 300℃←→air） of 15 thermal cycles, linear growth of 0. 2%. The manufacturing technology of powders mix-ture for ramming mix based on the new fused material .from ZrO2 stabilized by the combined additive is developed and its production is mastered. From this mixture the large-size, shaped products on the phosphate bond are made at one carbon black production plant, which are installed in the combustion chamber of the carbon black production reactor.
文摘The article gives an introduction to the Ukrainian Research Institute of Refractories and especially its R & D and refractory products for the industries of iron and steel, nonferrous , glass and chemistry etc.
文摘The use of a combined additive consisting of silica-containing additives“F”(thinning)and“S”(accelerating castable hardening)instead of the previously used silica-containing additive“A”and a mixture of dispersing additives based on polyethylene glycol in low-cement silicon carbide castable allows to improve the castable workability by increasing(in 5.4 times)the flowability of a freshly prepared castable,and increase by 1.2 and 1.1 times the cold crushing strength of heat-treated at temperatures of 110 and 1580°C,respectively,castable samples from low-cement silicon carbide castable with practically equal values of open porosity(15.8%and 16.0%).The petrographic studies of the castable sample microstructure after firing at a temperature of 1580°C showed that the investigated silica-containing additives“F”and“S”contribute to the denser and more uniform structure formation.As a result of the carried out research,the manufacturing technology of a low-cement silicon carbide castable was improved,of which the production was mastered at JSC“URIR named after A.S.Berezhnoy”.
