In the development of rechargeable lithium ion batteries(LIBs),silicon anodes have attracted much attention because of their extremely high theoretical capacity,relatively low Li-insertion voltage and the availability...In the development of rechargeable lithium ion batteries(LIBs),silicon anodes have attracted much attention because of their extremely high theoretical capacity,relatively low Li-insertion voltage and the availability of silicon resources.However,their large volume expansion and fragile solid electrolyte interface(SEI)film hinder their commercial application.To solve these problems,Si has been combined with various carbon materials to increase their structural stability and improve their interface properties.The use of different carbon materials,such as amorphous carbon and graphite,as three-dimensional(3D)protective anode coatings that help buffer mechanical strain and isolate the electrolyte is detailed,and novel methods for applying the coatings are outlined.However,carbon materials used as a protective layer still have some disadvantages,necessitating their modification.Recent developments have focused on modifying the protective carbon shells,and substitutes for the carbon have been suggested.展开更多
The stability of slopes is essential for ensuring safe production in open-pit mines.Analyzing and managing the deformation and failure of the slope rock mass becomes more challenging as the slope height increases.To i...The stability of slopes is essential for ensuring safe production in open-pit mines.Analyzing and managing the deformation and failure of the slope rock mass becomes more challenging as the slope height increases.To investigate the damage patterns of slopes with varying heights,three slope models were developed based on a rock slope in Dagushan,China.The deformation failure processes of slopes under the influence of excavation and unloading were analyzed using the base friction test method in combination with digital image technology contrasting.The results supported the following findings:(1)Unloading tensile stress caused lateral partitioning in the slope.Both the foot and top of the slope underwent initial tensile cracks.(2)The destabilization mechanism of unloading deformation in slopes of different heights involved a combination of traction at the foot of the slope or pushing at the top of the slope,followed by accelerated deformation,deceleration creep,and overall destabilization.(3)The unloading damage patterns of slopes at different heights were summarized as follows:compression tension cracking,traction,and slip damage for medium and low slopes;compression tension cracking,traction,and slip failure for the upper part of high slopes;and relaxation tension cracking,pushing,traction,and slip failure for the lower part.Moreover,the upper part of ultra-high slopes exhibited compression tension cracking,traction,and slip failure,while the middle and lower parts displayed relaxation tension cracking,pushing,traction,and slip patterns.Finally,numerical simulations were conducted to verify the results of the test analyses,which demonstrated good consistency.These research results were of great engineering value for proposing effective safety management measures for high slopes.展开更多
文摘In the development of rechargeable lithium ion batteries(LIBs),silicon anodes have attracted much attention because of their extremely high theoretical capacity,relatively low Li-insertion voltage and the availability of silicon resources.However,their large volume expansion and fragile solid electrolyte interface(SEI)film hinder their commercial application.To solve these problems,Si has been combined with various carbon materials to increase their structural stability and improve their interface properties.The use of different carbon materials,such as amorphous carbon and graphite,as three-dimensional(3D)protective anode coatings that help buffer mechanical strain and isolate the electrolyte is detailed,and novel methods for applying the coatings are outlined.However,carbon materials used as a protective layer still have some disadvantages,necessitating their modification.Recent developments have focused on modifying the protective carbon shells,and substitutes for the carbon have been suggested.
基金funded by the National Natural Science Foundation of China(No.52308316)China Postdoctoral Science Foundation(No.2022M721885)supported by Key Laboratory of Rock Mechanics and Geohazards of Zhejiang Province(No.ZJRMG2022-01)。
文摘The stability of slopes is essential for ensuring safe production in open-pit mines.Analyzing and managing the deformation and failure of the slope rock mass becomes more challenging as the slope height increases.To investigate the damage patterns of slopes with varying heights,three slope models were developed based on a rock slope in Dagushan,China.The deformation failure processes of slopes under the influence of excavation and unloading were analyzed using the base friction test method in combination with digital image technology contrasting.The results supported the following findings:(1)Unloading tensile stress caused lateral partitioning in the slope.Both the foot and top of the slope underwent initial tensile cracks.(2)The destabilization mechanism of unloading deformation in slopes of different heights involved a combination of traction at the foot of the slope or pushing at the top of the slope,followed by accelerated deformation,deceleration creep,and overall destabilization.(3)The unloading damage patterns of slopes at different heights were summarized as follows:compression tension cracking,traction,and slip damage for medium and low slopes;compression tension cracking,traction,and slip failure for the upper part of high slopes;and relaxation tension cracking,pushing,traction,and slip failure for the lower part.Moreover,the upper part of ultra-high slopes exhibited compression tension cracking,traction,and slip failure,while the middle and lower parts displayed relaxation tension cracking,pushing,traction,and slip patterns.Finally,numerical simulations were conducted to verify the results of the test analyses,which demonstrated good consistency.These research results were of great engineering value for proposing effective safety management measures for high slopes.
