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肉豆蔻醇硬脂酸酯的合成工艺研究
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作者 刘兴稳 黄红 +2 位作者 陈莹 王龙耀 张文龙 《化工技术与开发》 CAS 2024年第5期46-48,94,共4页
以肉豆蔻醇和硬脂酸为原料,采用直接酯化法制备了肉豆蔻醇硬脂酸酯。研究了催化剂种类、催化剂用量、酸醇摩尔比、反应温度、反应时间等因素对肉豆蔻醇硬脂酸酯含量的影响。结果表明,以纳米氧化锌为催化剂,催化剂添加量为0.4%,酸醇摩尔... 以肉豆蔻醇和硬脂酸为原料,采用直接酯化法制备了肉豆蔻醇硬脂酸酯。研究了催化剂种类、催化剂用量、酸醇摩尔比、反应温度、反应时间等因素对肉豆蔻醇硬脂酸酯含量的影响。结果表明,以纳米氧化锌为催化剂,催化剂添加量为0.4%,酸醇摩尔比为1∶1.3,反应温度为210℃,反应时间为8h时,可获得较高的酯化转换率,肉豆蔻醇硬脂酸酯的含量达到99.4%。 展开更多
关键词 酯化反应 工艺研究 肉豆蔻醇硬脂酸酯
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微波强化Y型分子筛离子交换技术 被引量:4
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作者 李腾飞 缪赟 +2 位作者 杨柳 王龙耀 朱铧丞 《化工学报》 EI CAS CSCD 北大核心 2021年第S01期406-412,共7页
近年来,随着微波技术的快速发展,微波能作为一种高效的清洁能源已在化工合成、工业催化、生物制药、食品加工等众多领域广泛应用。尤其是在化工合成领域,微波技术的应用展现出了高效加热、易于控制、安全环保的优势。采用微波辅助技术对... 近年来,随着微波技术的快速发展,微波能作为一种高效的清洁能源已在化工合成、工业催化、生物制药、食品加工等众多领域广泛应用。尤其是在化工合成领域,微波技术的应用展现出了高效加热、易于控制、安全环保的优势。采用微波辅助技术对NaNH4Y分子筛与稀土溶液热压离子交换反应进行研究,进一步开发出了无须经高温焙烧工序短流程工艺制备稀土Y分子筛的工艺技术。相比于分子筛传统工业制备技术,大大缩短了制备工艺流程,极大提高了分子筛离子交换改性生产效率并降低了生产能耗。开发的新工艺技术制备的稀土Y分子筛,主要物化性质参数满足工业生产同类型分子筛产品工艺质量指标要求,且制备的分子筛催化剂活性稳定性均不低于传统工业生产分子筛催化剂。新工艺方法对优化催化裂化分子筛工业生产和实现分子筛的短流程工业制备具有重要指导意义。 展开更多
关键词 微波加热 分子筛 离子交换 水热 催化剂 短流程
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Stall Evolution Mechanism of a Centrifugal Compressor with a Wide-Long Vaneless Diffuser
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作者 ZHANG Lei KANG Jiacheng +4 位作者 LANG Jinhua AN Guangyao ZHANG Qian wang longyao wang Qifang 《Journal of Thermal Science》 SCIE EI CAS CSCD 2024年第3期899-913,共15页
The rotating stall mechanism is of high importance for the stability of centrifugal compressors and thermal power cycles.The majority of research concerning this topic has concentrated on the initial stall phase.Howev... The rotating stall mechanism is of high importance for the stability of centrifugal compressors and thermal power cycles.The majority of research concerning this topic has concentrated on the initial stall phase.However,the evolution of stall cells in wide-long diffusers has not been comprehensively studied.In this paper,the causes of rotating stall in the wide-long diffuser and the three-dimensional evolution mechanism of stall cells during the stall process were thoroughly analyzed.During the stall induction phase,an annulus vortex structure was found in the reverse-flow zone near the hub side of the diffuser outlet,which was the initial form of stall cells.The whole evolution process of stall cells was divided into three phases as the flow rate decreased.During the initial stall phase,the dynamic equilibrium was built under effects of the impeller wake and the adverse pressure gradient.As a result,the number of stall cells was kept at seven and the size of stall cells remained constant.During the transition phase,the flow in the diffuser became unstable.Stall cells extended to the impeller outlet,and the effect of the wake flow was strengthened significantly.Stall cells started integrating and separating regularly.As a result,the number and propagation speed of stall cells varied periodically at a constant mass flow rate.During the deep stall phase,the size of stall cells remained unchanged,and the number of stall cells kept at one.This study has important practical guidance and engineering value for the high-efficiency design and safe operation of centrifugal compressors. 展开更多
关键词 centrifugal compressor wide-long vaneless diffuser stall evolution mechanism wake flow
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