Waste cellulosic biomass obtains various applications due to low-cost and eco-benign characteristics.A general strategy is proposed for waste cellulosic biomass to be modified with dialdehyde functional groups as inte...Waste cellulosic biomass obtains various applications due to low-cost and eco-benign characteristics.A general strategy is proposed for waste cellulosic biomass to be modified with dialdehyde functional groups as intermediates through periodate partial oxidation.Finally,aminothiourea-modified waste cellulosic biomass can be prepared through Schiff reaction.Waste corn stalk,cotton and paper as typical precursors,were used to prepare cellulosic biomass,abbreviated as AT-S,AT-C and AT-P,respectively,and their adsorption behaviors of Au(III)from the hydrochloric acid medium were investigated.The pseudo-second kinetics equation as well as the Langmuir isotherm equation can be used to depict the adsorption process,and the maximum adsorption capacities of Au(III)are21.4,19.0and3.28mol/kg for AT-S,AT-C and AT-P at298K,respectively.The adsorption capacities of Au(III)on aminothiourea modified corn stalk(AT-S)is almost357times greater than that of raw corn stalk.To the best of our knowledge,AT-S has the highest adsorption capacity towards Au(III).AT-S also displays a superior separation selectivity towards Au(III)in the presence of Cu(II),Ni(II),Co(II),Pt(VI),Pd(II)and Rh(III).Furthermore,the characterization analysis of XRD,TG,SEM,TEM and FTIR confirms that AuCl4– has been reduced to elemental Au nanoparticles and deposit onto the surface of the biomass.It shows a prospect for waste corn stalk to be used to adsorb Au(III)from liquid phase and the possible fabrication of gold nanoparticles by a general adsorption process without any reductant.展开更多
基金Projects(51504073,51404081,51672275)supported by the National Natural Science Foundation of ChinaProject(2012CBA01202)supported by the National Key Technology Research and Development Program of the Ministry of Science and Technology,China+1 种基金Project(QianJiaoKeHe KY[2015]433)supported by the Research Program of the Education Department of Guizhou Province,ChinaProject(XJG20141104)supported by the Research Program of Talented Scholars of Guizhou Institute of Technology,China
文摘Waste cellulosic biomass obtains various applications due to low-cost and eco-benign characteristics.A general strategy is proposed for waste cellulosic biomass to be modified with dialdehyde functional groups as intermediates through periodate partial oxidation.Finally,aminothiourea-modified waste cellulosic biomass can be prepared through Schiff reaction.Waste corn stalk,cotton and paper as typical precursors,were used to prepare cellulosic biomass,abbreviated as AT-S,AT-C and AT-P,respectively,and their adsorption behaviors of Au(III)from the hydrochloric acid medium were investigated.The pseudo-second kinetics equation as well as the Langmuir isotherm equation can be used to depict the adsorption process,and the maximum adsorption capacities of Au(III)are21.4,19.0and3.28mol/kg for AT-S,AT-C and AT-P at298K,respectively.The adsorption capacities of Au(III)on aminothiourea modified corn stalk(AT-S)is almost357times greater than that of raw corn stalk.To the best of our knowledge,AT-S has the highest adsorption capacity towards Au(III).AT-S also displays a superior separation selectivity towards Au(III)in the presence of Cu(II),Ni(II),Co(II),Pt(VI),Pd(II)and Rh(III).Furthermore,the characterization analysis of XRD,TG,SEM,TEM and FTIR confirms that AuCl4– has been reduced to elemental Au nanoparticles and deposit onto the surface of the biomass.It shows a prospect for waste corn stalk to be used to adsorb Au(III)from liquid phase and the possible fabrication of gold nanoparticles by a general adsorption process without any reductant.
