The enthalpies of vaporization for the series of pyridinium-based ionic liquids with bis（trifluoromethylsulfonyl）imide anion [CnPy][NTfz] （n = 2, 3, 4, 5, and 6） have been determined with the quartz crystal microb...The enthalpies of vaporization for the series of pyridinium-based ionic liquids with bis（trifluoromethylsulfonyl）imide anion [CnPy][NTfz] （n = 2, 3, 4, 5, and 6） have been determined with the quartz crystal microbalance technique combined with the Langmuir evaporation. The linear dependence of vaporization enthalpies on the chain length has been revealed. New approach based on volumetric, surface tension, and speed of sound measurements has been developed for estimation of heat capacity differences between gas and liquid phase, which were required for adjustment of measured vaporization enthalpies to the ref- erence temperature 298 K.展开更多
基金supported by the National Natural Science Foundation of China(21073189,21006007,20901076,21176033)KnowledgeInnovation Program of DICP,Chinese Academic of Sciences(K2009D03)~~
基金supported by the German Science Foundation (DFG) in frame of the priority program SPP 1191 "Ionic Liquids" (VE 265/5-3)
文摘The enthalpies of vaporization for the series of pyridinium-based ionic liquids with bis（trifluoromethylsulfonyl）imide anion [CnPy][NTfz] （n = 2, 3, 4, 5, and 6） have been determined with the quartz crystal microbalance technique combined with the Langmuir evaporation. The linear dependence of vaporization enthalpies on the chain length has been revealed. New approach based on volumetric, surface tension, and speed of sound measurements has been developed for estimation of heat capacity differences between gas and liquid phase, which were required for adjustment of measured vaporization enthalpies to the ref- erence temperature 298 K.
