To ensure the security of resource and intelligence sharing in 6G,blockchain has been widely adopted in wireless communications and applications.Although blockchain can ensure the traceability and non-tamperability of...To ensure the security of resource and intelligence sharing in 6G,blockchain has been widely adopted in wireless communications and applications.Although blockchain can ensure the traceability and non-tamperability of data in the concatenated blocks,it cannot guarantee the honest behaviors of users in the application before the generation of transactions.Thus,additional technologies are required to ensure that the source of blockchain data is reliable.In this paper,the detailed procedure is designed for the application-oriented task validation in the blockchainenhanced computing resource sharing and transactions in ultra dense networks(UDN).The corresponding queuing model is built and analyzed with the consideration of the wireless re-transmission and the probability of malicious deception by users.Based on the analysis results,the UDN deployment is optimized to save network cost while ensuring latency performance.Numerical results verify our analysis,and the optimized system deployment including the number and service capacities of both base stations and mobile edge computing(MEC)servers are also given with various system settings.展开更多
Ethics and governance are vital to the healthy and sustainable development of artificial intelligence(AI).With the long-term goal of keeping AI beneficial to human society,governments,research organizations,and compan...Ethics and governance are vital to the healthy and sustainable development of artificial intelligence(AI).With the long-term goal of keeping AI beneficial to human society,governments,research organizations,and companies in China have published ethical guidelines and principles for AI,and have launched projects to develop AI governance technologies.This paper presents a survey of these efforts and highlights the preliminary outcomes in China.It also describes the major research challenges in AI governance research and discusses future research directions.展开更多
To cope with the low latency requirements and security issues of the emerging applications such as Internet of Vehicles(Io V)and Industrial Internet of Things(IIo T),the blockchain-enabled Mobile Edge Computing(MEC)sy...To cope with the low latency requirements and security issues of the emerging applications such as Internet of Vehicles(Io V)and Industrial Internet of Things(IIo T),the blockchain-enabled Mobile Edge Computing(MEC)system has received extensive attention.However,blockchain is a computing and communication intensive technology due to the complex consensus mechanisms.To facilitate the implementation of blockchain in the MEC system,this paper adopts the committee-based Practical Byzantine Fault Tolerance(PBFT)consensus algorithm and focuses on the committee selection problem.Vehicles and IIo T devices generate the transactions which are records of the application tasks.Base Stations(BSs)with MEC servers,which serve the transactions according to the wireless channel quality and the available computing resources,are blockchain nodes and candidates for committee members.The income of transaction service fees,the penalty of service delay,the decentralization of the blockchain and the communication complexity of the consensus process constitute the performance index.The committee selection problem is modeled as a Markov decision process,and the Proximal Policy Optimization(PPO)algorithm is adopted in the solution.Simulation results show that the proposed PPO-based committee selection algorithm can adapt to the system design requirements with different emphases and outperforms other comparison methods.展开更多
Cosensitization based on two or multiple dyes as "dye cocktails" can hit the target on compensating and broadening light-harvesting region.Two indoline D-A-π-A motif sensitizers(WS-2 and WS-39) that possess...Cosensitization based on two or multiple dyes as "dye cocktails" can hit the target on compensating and broadening light-harvesting region.Two indoline D-A-π-A motif sensitizers(WS-2 and WS-39) that possess similar light response area but distinctly reversed feature in photovoltaic performance are selected as the specific cosensitization couple. That is, WS-2 shows quite high photocurrent but low photovoltage, and WS-39 gives relatively low photocurrent but quite high photo voltage. Due to the obvious "barrel effect",both dyes show medium PCE around8.50%. In contrast with the previous cosensitization strategy mostly focused on the compensation of light response region, herein we perform different cosensitization sequence, for taking insight into the balance of photocurrent and photo voltage, and achieving the synergistic improvement in power conversion efficiency(PCE). Electronic impedance spectra(EIS) indicate that exploiting dye WS-39 with high V_(OC) value as the primary sensitizer can repress the charge recombination more effectively, resulting in superior V_(OC) rather than using dye WS-2 with high J_(SC)as the primary sensitizer. As a consequence, a high PCE value of 9.48% is obtained with the delicate cosensitization using WS-39 as primary dye and WS-2 as accessory dye, which is higher than the corresponding devices sensitized by each individual dye(around 8.48-8.67%). It provides an effective optimizing strategy of cosensitization how to combine the individual dye advantages for developing highly efficient solar cells.展开更多
A distinctive method is proposed by simply utilizing ultrasonic technique in Ti02 electrode fabrication in order to improve the optoelectronic performance of dye-sensitized solar cells (DSSCs). Dye molecules are at ...A distinctive method is proposed by simply utilizing ultrasonic technique in Ti02 electrode fabrication in order to improve the optoelectronic performance of dye-sensitized solar cells (DSSCs). Dye molecules are at random and single molecular state in the ultrasonic field and the ultrasonic wave favors the diffusion and adsorption processes of dye molecules. As a result, the introduction of ultrasonic technique at room temperature leads to faster and more well-distributed dye adsorption on TiO2 as well as higher cell efficiency than regular deposition, thus the fabrication time is markedly reduced. It is found that the device based on 40 kHz ultrasonic (within 1 h) with N719 exhibits a Voc of 789 mV, Jsc of 14.94 mA]cm2 and fill factor (FF) of 69.3, yielding power conversion efficiency (PCE) of 8.16%, which is higher than device regularly dyed for 12 h (PCE = 8.06%). In addition, the DSSC devices obtain the best efficiency (PCE = 8.68%) when the ultrasonic deposition time increases to 2.5 h. The DSSCs fabricated via ultrasonic technique presents more dye loading, larger photocurrent, less charge recombination and higher photovoltage. The charge extraction and electron impedance spectroscopy (EIS) were performed to understand the influence of ultrasonic technique on the electron recombination and performance of DSSCs.展开更多
Ensuring high power conversion efficiency,partially or completely replacing Pt electrodes with inexpensive materials is one of the important development directions of dye-sensitized solar cells(DSSCs).In this work,we ...Ensuring high power conversion efficiency,partially or completely replacing Pt electrodes with inexpensive materials is one of the important development directions of dye-sensitized solar cells(DSSCs).In this work,we have developed a threecomponent(MWCNTs,carbon black and graphite) carbon(tri-carbon) electrode material for DSSC devices combined with the advantages of high electron transfer kinetics of MWCNTs,plentiful catalytic sites in crystal edges of carbon black and superior electrical conductivity and catalytic activity of graphite.Using a tri-carbon electrode,a Pt electrode,and two N719-sensitized photoanodes,a parallel tandem dye-sensitized solar cells are assembled obtaining a high PCE of 10.26%(V_(OC)=0.70 V,J_(SC)=19.99 mA/cm~2,FF=73.33%).It opens up a new avenue for the development of low-cost and highperformance DSSCs.展开更多
The gated recurrent unit (GRU) deep model is interpreted to predict price’s falling or rising. By using a technique called Tree Regularization of Deep Models for Interpretability, a GRU network is converted to a deci...The gated recurrent unit (GRU) deep model is interpreted to predict price’s falling or rising. By using a technique called Tree Regularization of Deep Models for Interpretability, a GRU network is converted to a decision tree (called GRU-Tree) to interpret its prediction rules. This approach was tested by experimenting on a few sample stocks (e.g., the Gree company) and a main stock market index (SSE Composite Index) in China. The discovered prediction rules actually reflect a general rule called Mean Reversion in stock market. Results show that the GRU-Tree is more effective (higher AUC) than the decision tree directly trained from the data for small and moderate average path length (APL) of trees. And the fidelity between GRU and its generated GRU-Tree is high (about 0.8).展开更多
App store provides rich information for software vendors and customers to understand the market of mobile applications. However, app store analysis don’t consider some vital factors such as version number, app descri...App store provides rich information for software vendors and customers to understand the market of mobile applications. However, app store analysis don’t consider some vital factors such as version number, app description and app name currently. In this paper we propose an approach that App Store Analysis can be used to predict app downloads. We use data mining to extract app name and description and app rank information etc. from the Wandoujia App Store and AppCha App Store. We use questionnaire and sentimentanalysis to quantify some app nonnumeric information. We revealed strong correlations app name score, app rank, app rating with app downloads by Spearman’s rank correlation analysis respectively. Finally, we establish a multiple nonlinear regression model which app downloads defined as dependent variable and three relevant attributes defined as independent variable. On average, 59.28 % of apps in Wandoujia App Store and 66.68 % of apps in AppCha App Store can be predicted accurately within threshold which error rate is 25 %. One can observe the more detailed classification of app store, the more accurate for regression modeling to predict app downloads. Our approach can help app developers to notice and optimize the vital factors which influence app downloads.展开更多
In massive open online courses (MOOCs), peer grading will play an important role to promote MOOCs development. In this paper, we develop a peer grading tool for programming courses on MOOCs. It is capable of dealing w...In massive open online courses (MOOCs), peer grading will play an important role to promote MOOCs development. In this paper, we develop a peer grading tool for programming courses on MOOCs. It is capable of dealing with large and diverse student population, and providing them with targeted subjective assessment. This tool firstly partition the submissions into small chunks to reduce the task of reviewers and give us flexibility to scale the code review process. Next we use code normalization and chunks clustering to assign similar chunks to the same student for increasing reviewer efficiency. Besides, the tool use a random allocation strategy and workload classification to assure reviewers workload balance while every student can get diverse feedback. Finally our evaluation experiments on a number of students in school indicate that the tool has achieved a significant improvement over the peer grading on MOOCs.展开更多
The traits of rural domestic sewage emission are unclear,negatively affecting rural domestic sewage treatment and sewage management.This study used data from the Second National Pollution Source Census Bulletin to est...The traits of rural domestic sewage emission are unclear,negatively affecting rural domestic sewage treatment and sewage management.This study used data from the Second National Pollution Source Census Bulletin to establish a data set.The spatial distribution characteristics and main factors influencing rural sewage discharge in the Northern Region were studied using spatial autocorrelation analysis and structural equations.The findings demonstrated that(l)a significant Spearman correlation between drainage water volume(DwV),chemical oxygen demand(COD),ammonia nitrogen(NH_(3)-N),total nitrogen(TN),and total phosphorus(TP)and that the correlation coefficients between DWV and COD,NH,-N,TNand TP were 0.87**,1.0**,0.99**,0.99**,respectively;(2)rural sewage discharge showed spatial autocorrelation,and rural domestic sewage discharge in the districts and counties with an administration was significantly higher than in the surrounding areas;and(3)social development was the main driver rural domestic sewage changes(path coefficient was 0.407**),and the main factors influencing rural domestic sewage discharge were the urbanization rate,years of education,and population age structure.This study obtained the spatial variation law and clarified the main influencing factors of rural domestic sewage to provide data support and a theoretical basis for subsequent rural sewage collection and treatment.Use of the Inner Mongolia Autonomous Region in northern China as a typical case,provides a theoretical foundation for scientific decision-making on rural domestic sewage treatment at the national and regional levels and offers new perspectives for managing pollutants.展开更多
The trade-off and synergy relationship of ecosystem services is an important topic in the current assessment.The value of each service provided by the ecosystem is substantially affected by human activities,and conver...The trade-off and synergy relationship of ecosystem services is an important topic in the current assessment.The value of each service provided by the ecosystem is substantially affected by human activities,and conversely,its changes will also affect the relevant human decisions.Due to varying tradeoffs among ecosystem services and synergies between them that can either increase or decrease,it is difficult to optimize multiple ecosystem services simultaneously,making it a huge challenge for ecosystem management.This study firstly develops a global Gross Ecosystem Product(GEP)accounting framework.It uses remote sensing data with a spatial resolution of 1 km to estimate the ecosystem services of forests,wetlands,grasslands,deserts,and farmlands in 179 major countries in 2018.The results show that the range of global GEP values is USD 112e197 trillion,with an average value of USD 155 trillion(the constant price),and the ratio of GEP to gross domestic product(GDP)is 1.85.The tradeoffs and the synergies among different ecosystem services in each continent and income group have been further explored.We found a correspondence between the income levels and the synergy among ecosystem services within each nation.Among specific ecosystem services,there are strong synergies between oxygen release,climate regulation,and carbon sequestration services.A trade-off relationship has been observed between flood regulation and other services,such as water conservation and soil retention services in low-income countries.The results will help clarify the roles and the feedback mechanisms between different stakeholders and provide a scientific basis for optimizing ecosystem management and implementing ecological compensation schemes to enhance human well-being.展开更多
The enhancement of the sensitivity for anthocyanin-based indicator films in food freshness monitoring in real time is important for application.In this study,hydrophilic silica aerogel(SiO2 NA)was incorporated into co...The enhancement of the sensitivity for anthocyanin-based indicator films in food freshness monitoring in real time is important for application.In this study,hydrophilic silica aerogel(SiO2 NA)was incorporated into corn starch(CS)/chitosan(CH)/rose anthocyanins(RACNs)-encapsulated potato amylopectin nanoparticles(APNPs)composite film to increase the sensitivity for shrimp freshness detection.The microstructure of films revealed that the gas absorption capacity was improved by amorphous SiO2 NA via hydrogen interactions.The pore size(1.74–5.60 times),pore volume(3.92–5.60 times),and specific surface area(2.21–2.34 times)of films increased with the addition of SiO2 NA.The sensing of NH3 and pH and the reversibility of films were also reinforced.Meanwhile,the pH-responsive films containing SiO2 NA changed visibly in color from purple–red to orange–gray and finally to gray,enabling effective monitoring of shrimp freshness during storage at 4°C.Thus,anthocyanin-based indicator films with improved sensitivity by adding SiO2 NA were successfully designed for monitoring shrimp freshness.展开更多
Autologous nerve grafting serves is considered the gold standard treatment for peripheral nerve defects;however,limited availability and donor area destruction restrict its widespread clinical application.Although the...Autologous nerve grafting serves is considered the gold standard treatment for peripheral nerve defects;however,limited availability and donor area destruction restrict its widespread clinical application.Although the performance of allogeneic decellularized nerve implants has been explored,challenges such as insufficient human donors have been a major drawback to its clinical use.Tissue-engineered neural regeneration materials have been developed over the years,and researchers have explored strategies to mimic the peripheral neural microenvironment during the design of nerve catheter grafts,namely the extracellular matrix(ECM),which includes mechanical,physical,and biochemical signals that support nerve regeneration.In this study,polycaprolactone/silk fibroin(PCL/SF)-aligned electrospun material was modified with ECM derived from human umbilical cord mesenchymal stem cells(hUMSCs),and a dual-bionic nerve regeneration material was successfully fabricated.The results indicated that the developed biomimetic material had excellent biological properties,providing sufficient anchorage for Schwann cells and subsequent axon regeneration and angiogenesis processes.Moreover,the dual-bionic material exerted a similar effect to that of autologous nerve transplantation in bridging peripheral nerve defects in rats.In conclusion,this study provides a new concept for designing neural regeneration materials,and the prepared dual-bionic repair materials have excellent auxiliary regenerative ability and further preclinical testing is warranted to evaluate its clinical application potential.展开更多
The mitigation of under-coordinated Pb^(2+)(halide vacancy)defect remains an imperative challenge in the perovskite solar cells,especially printable mesoscopic perovskite solar cells(FP-PsCs).Here we re port a commerc...The mitigation of under-coordinated Pb^(2+)(halide vacancy)defect remains an imperative challenge in the perovskite solar cells,especially printable mesoscopic perovskite solar cells(FP-PsCs).Here we re port a commercial-available polyazin anticancer drug Sapanisertib as coordination passivator of halide vacancies in FP-PSCs,thereby achieving the photoelectric conversion efficiency(PCE)to 18.46%,along with a record certified PCE of 18.27%.In polazin Sapanisertib(Sap),there exists two kinds of nitrogen atoms:in-aromatic ring(in purine and oxazole rings,IAR-Ns)and out-aromatic ring(substituted amino groups,OAR-Ns).Through multiple characterizations,and DFT calculations show that substituted amino groups OAR-Ns hardly get interaction with the halide vacancy due to the distribution of charge density in Sapanisertib.Our work suggests that the selective coordination is of great significance for the design of high-performance passivators for printable mesoscopic perovskite solar cells.展开更多
Recently software crowdsourcing has become an emerging area of software engineering. Few papers have pre- sented a systematic analysis on the practices of software crowdsourcing. This paper first presents an evaluatio...Recently software crowdsourcing has become an emerging area of software engineering. Few papers have pre- sented a systematic analysis on the practices of software crowdsourcing. This paper first presents an evaluation frame- work to evaluate software crowdsourcing projects with re- spect to software quality, costs, diversity of solutions, and competition nature in crowdsourcing. Specifically, competi- tions are evaluated by the min-max relationship from game theory among participants where one party tries to minimize an objective function while the other party tries to maximize the same objective function. The paper then defines a game theory model to analyze the primary factors in these min- max competition rules that affect the nature of participation as well as the software quality. Finally, using the proposed eval- uation framework, this paper illustrates two crowdsourcing processes, Harvard-TopCoder and AppStori. The framework demonstrates the sharp contrasts between both crowdsourc- ing processes as participants will have drastic behaviors in engaging these two projects.展开更多
Clinical success of the proteasome inhibitor established bortezomib as one of the most effective drugs in treatment of multiple myeloma (MM). While survival benefit of bortezomib generated new treatment strategies, ...Clinical success of the proteasome inhibitor established bortezomib as one of the most effective drugs in treatment of multiple myeloma (MM). While survival benefit of bortezomib generated new treatment strategies, the primary and secondary resistance of MM cells to bortezomib remains a clinical concern. This study aimed to highlight the role of p53-induced RING-H2 (Pirh2) in the acquisition of bortezomib resistance in MM and to clarify the function and mechanism of action of Pirh2 in MM cell growth and resistance, thereby providing the basis for new therapeutic targets for MM. The proteasome inhibitor bortezomib has been established as one of the most effective drugs for treating MM. We demonstrated that bortezomib resistance in MM cells resulted from a reduction in Pirh2 protein levels. Pirh2 overexpression overcame bortezomib resistance and restored the sensitivity of myeloma cells to bortezomib, while a reduction in Pirh2 levels was correlated with bortezomib resistance. The levels of nuclear factor- kappaB (NF-κB) p65, pp65, plKBa, and IKKa were higher in bortezomib-resistant cells than those in parental cells. Pirh2 overexpression reduced the levels of plKBa and IKKa, while the knockdown of Pirh2 via short hairpin RNAs increased the expression of NF-κB p65, plKBa, and IKKa. Therefore, Pirh2 suppressed the canonical NF- κB signaling pathway by inhibiting the phosphorylation and subsequent degradation of IKBa to overcome acquired bortezomib resistance in MM cells.展开更多
Supramolecular polymers with different functionalities have been continuously developed in the past decade because of their indispensable role in soft materials.However,pure organic supramolecular polymers with stable...Supramolecular polymers with different functionalities have been continuously developed in the past decade because of their indispensable role in soft materials.However,pure organic supramolecular polymers with stable room temperature phosphorescence(RTP)emission were very rarely reported for the difficulties of synthesis and achieving RTP in solution.Herein,soluble helical supramolecular polymers with circularly polarized room-temperature phosphorescence were developed via a facile hostguest strategy.Through assembly,a transition from pure fluorescence to almost pure RTP emission was achieved.Adjusting the asymmetry of guest could easily control the chiroptical property of supramolecular polymers.This work provides new opportunities for the design and development of intelligent soft functional soft materials.展开更多
Nowadays,Edge Information System(EIS)has received a lot of attentions.In EIS,Distributed Machine Learning(DML),which requires fewer computing resources,can implement many artificial intelligent applications efficientl...Nowadays,Edge Information System(EIS)has received a lot of attentions.In EIS,Distributed Machine Learning(DML),which requires fewer computing resources,can implement many artificial intelligent applications efficiently.However,due to the dynamical network topology and the fluctuating transmission quality at the edge,work node selection affects the performance of DML a lot.In this paper,we focus on the Internet of Vehicles(IoV),one of the typical scenarios of EIS,and consider the DML-based High Definition(HD)mapping and intelligent driving decision model as the example.The worker selection problem is modeled as a Markov Decision Process(MDP),maximizing the DML model aggregate performance related to the timeliness of the local model,the transmission quality of model parameters uploading,and the effective sensing area of the worker.A Deep Reinforcement Learning(DRL)based solution is proposed,called the Worker Selection based on Policy Gradient(PG-WS)algorithm.The policy mapping from the system state to the worker selection action is represented by a deep neural network.The episodic simulations are built and the REINFORCE algorithm with baseline is used to train the policy network.Results show that the proposed PG-WS algorithm outperforms other comparation methods.展开更多
文摘To ensure the security of resource and intelligence sharing in 6G,blockchain has been widely adopted in wireless communications and applications.Although blockchain can ensure the traceability and non-tamperability of data in the concatenated blocks,it cannot guarantee the honest behaviors of users in the application before the generation of transactions.Thus,additional technologies are required to ensure that the source of blockchain data is reliable.In this paper,the detailed procedure is designed for the application-oriented task validation in the blockchainenhanced computing resource sharing and transactions in ultra dense networks(UDN).The corresponding queuing model is built and analyzed with the consideration of the wireless re-transmission and the probability of malicious deception by users.Based on the analysis results,the UDN deployment is optimized to save network cost while ensuring latency performance.Numerical results verify our analysis,and the optimized system deployment including the number and service capacities of both base stations and mobile edge computing(MEC)servers are also given with various system settings.
文摘Ethics and governance are vital to the healthy and sustainable development of artificial intelligence(AI).With the long-term goal of keeping AI beneficial to human society,governments,research organizations,and companies in China have published ethical guidelines and principles for AI,and have launched projects to develop AI governance technologies.This paper presents a survey of these efforts and highlights the preliminary outcomes in China.It also describes the major research challenges in AI governance research and discusses future research directions.
基金supported by the Natural Science Foundation of Beijing Municipality under Grant No.L192002the National Key R&D Program of China under Grant No.2020YFC1807904the National Natural Science Foundation of China under Grant No.62001011。
文摘To cope with the low latency requirements and security issues of the emerging applications such as Internet of Vehicles(Io V)and Industrial Internet of Things(IIo T),the blockchain-enabled Mobile Edge Computing(MEC)system has received extensive attention.However,blockchain is a computing and communication intensive technology due to the complex consensus mechanisms.To facilitate the implementation of blockchain in the MEC system,this paper adopts the committee-based Practical Byzantine Fault Tolerance(PBFT)consensus algorithm and focuses on the committee selection problem.Vehicles and IIo T devices generate the transactions which are records of the application tasks.Base Stations(BSs)with MEC servers,which serve the transactions according to the wireless channel quality and the available computing resources,are blockchain nodes and candidates for committee members.The income of transaction service fees,the penalty of service delay,the decentralization of the blockchain and the communication complexity of the consensus process constitute the performance index.The committee selection problem is modeled as a Markov decision process,and the Proximal Policy Optimization(PPO)algorithm is adopted in the solution.Simulation results show that the proposed PPO-based committee selection algorithm can adapt to the system design requirements with different emphases and outperforms other comparison methods.
基金supported by NSFC for Creative Research Groups(21421004) and Distinguished Young Scholars(21325625),NSFC/ChinaOriental Scholarship+4 种基金Fundamental Research Funds for the Central Universities(WJ1416005 and WJ1315025)Scientific Committee of Shanghai(14ZR1409700and 15XD1501400)Programme of Introducing Talents of Discipline to Universities(B16017)Science Foundation for the Excellent Youth Scholars of Hebei Education Department(Y2012017)Science Foundation for Oversea Scholars of Hebei(C201400324)
文摘Cosensitization based on two or multiple dyes as "dye cocktails" can hit the target on compensating and broadening light-harvesting region.Two indoline D-A-π-A motif sensitizers(WS-2 and WS-39) that possess similar light response area but distinctly reversed feature in photovoltaic performance are selected as the specific cosensitization couple. That is, WS-2 shows quite high photocurrent but low photovoltage, and WS-39 gives relatively low photocurrent but quite high photo voltage. Due to the obvious "barrel effect",both dyes show medium PCE around8.50%. In contrast with the previous cosensitization strategy mostly focused on the compensation of light response region, herein we perform different cosensitization sequence, for taking insight into the balance of photocurrent and photo voltage, and achieving the synergistic improvement in power conversion efficiency(PCE). Electronic impedance spectra(EIS) indicate that exploiting dye WS-39 with high V_(OC) value as the primary sensitizer can repress the charge recombination more effectively, resulting in superior V_(OC) rather than using dye WS-2 with high J_(SC)as the primary sensitizer. As a consequence, a high PCE value of 9.48% is obtained with the delicate cosensitization using WS-39 as primary dye and WS-2 as accessory dye, which is higher than the corresponding devices sensitized by each individual dye(around 8.48-8.67%). It provides an effective optimizing strategy of cosensitization how to combine the individual dye advantages for developing highly efficient solar cells.
基金supported by the Science Fund for Creative Research Groups(21421004)the National Basic Research 973 Program(2013CB733700)NSFC/China(21172073,21372082,21572062 and 91233207)
文摘A distinctive method is proposed by simply utilizing ultrasonic technique in Ti02 electrode fabrication in order to improve the optoelectronic performance of dye-sensitized solar cells (DSSCs). Dye molecules are at random and single molecular state in the ultrasonic field and the ultrasonic wave favors the diffusion and adsorption processes of dye molecules. As a result, the introduction of ultrasonic technique at room temperature leads to faster and more well-distributed dye adsorption on TiO2 as well as higher cell efficiency than regular deposition, thus the fabrication time is markedly reduced. It is found that the device based on 40 kHz ultrasonic (within 1 h) with N719 exhibits a Voc of 789 mV, Jsc of 14.94 mA]cm2 and fill factor (FF) of 69.3, yielding power conversion efficiency (PCE) of 8.16%, which is higher than device regularly dyed for 12 h (PCE = 8.06%). In addition, the DSSC devices obtain the best efficiency (PCE = 8.68%) when the ultrasonic deposition time increases to 2.5 h. The DSSCs fabricated via ultrasonic technique presents more dye loading, larger photocurrent, less charge recombination and higher photovoltage. The charge extraction and electron impedance spectroscopy (EIS) were performed to understand the influence of ultrasonic technique on the electron recombination and performance of DSSCs.
基金supported financially by the National Natural Science Foundation of China(Nos.21788102,22075083)the Open Foundation of the Key Laboratory of Functional Inorganic Material Chemistry+1 种基金the Ministry of Education National Key R&D Program of China(No.2017YFB0309603)the Programme of Introducing Talents of Discipline to Universities(No.B16017)。
文摘Ensuring high power conversion efficiency,partially or completely replacing Pt electrodes with inexpensive materials is one of the important development directions of dye-sensitized solar cells(DSSCs).In this work,we have developed a threecomponent(MWCNTs,carbon black and graphite) carbon(tri-carbon) electrode material for DSSC devices combined with the advantages of high electron transfer kinetics of MWCNTs,plentiful catalytic sites in crystal edges of carbon black and superior electrical conductivity and catalytic activity of graphite.Using a tri-carbon electrode,a Pt electrode,and two N719-sensitized photoanodes,a parallel tandem dye-sensitized solar cells are assembled obtaining a high PCE of 10.26%(V_(OC)=0.70 V,J_(SC)=19.99 mA/cm~2,FF=73.33%).It opens up a new avenue for the development of low-cost and highperformance DSSCs.
基金National Natural Science Foundation of China (Project No. 61309030)This work is also supported by Central University of Finance and Economics Year 2019 First-class Discipline Construction Project.
文摘The gated recurrent unit (GRU) deep model is interpreted to predict price’s falling or rising. By using a technique called Tree Regularization of Deep Models for Interpretability, a GRU network is converted to a decision tree (called GRU-Tree) to interpret its prediction rules. This approach was tested by experimenting on a few sample stocks (e.g., the Gree company) and a main stock market index (SSE Composite Index) in China. The discovered prediction rules actually reflect a general rule called Mean Reversion in stock market. Results show that the GRU-Tree is more effective (higher AUC) than the decision tree directly trained from the data for small and moderate average path length (APL) of trees. And the fidelity between GRU and its generated GRU-Tree is high (about 0.8).
文摘App store provides rich information for software vendors and customers to understand the market of mobile applications. However, app store analysis don’t consider some vital factors such as version number, app description and app name currently. In this paper we propose an approach that App Store Analysis can be used to predict app downloads. We use data mining to extract app name and description and app rank information etc. from the Wandoujia App Store and AppCha App Store. We use questionnaire and sentimentanalysis to quantify some app nonnumeric information. We revealed strong correlations app name score, app rank, app rating with app downloads by Spearman’s rank correlation analysis respectively. Finally, we establish a multiple nonlinear regression model which app downloads defined as dependent variable and three relevant attributes defined as independent variable. On average, 59.28 % of apps in Wandoujia App Store and 66.68 % of apps in AppCha App Store can be predicted accurately within threshold which error rate is 25 %. One can observe the more detailed classification of app store, the more accurate for regression modeling to predict app downloads. Our approach can help app developers to notice and optimize the vital factors which influence app downloads.
文摘In massive open online courses (MOOCs), peer grading will play an important role to promote MOOCs development. In this paper, we develop a peer grading tool for programming courses on MOOCs. It is capable of dealing with large and diverse student population, and providing them with targeted subjective assessment. This tool firstly partition the submissions into small chunks to reduce the task of reviewers and give us flexibility to scale the code review process. Next we use code normalization and chunks clustering to assign similar chunks to the same student for increasing reviewer efficiency. Besides, the tool use a random allocation strategy and workload classification to assure reviewers workload balance while every student can get diverse feedback. Finally our evaluation experiments on a number of students in school indicate that the tool has achieved a significant improvement over the peer grading on MOOCs.
基金This work was supported by the National Natural Science Foundation of China(No.51838013)the project of Inner Mongolia"Prairie Talents"Engineering Innovation Entrepreneurship Talent Team,and the Innovation Team of the Inner Mongolia academy of Science and Technology(No.CXTD2023-01-016).
文摘The traits of rural domestic sewage emission are unclear,negatively affecting rural domestic sewage treatment and sewage management.This study used data from the Second National Pollution Source Census Bulletin to establish a data set.The spatial distribution characteristics and main factors influencing rural sewage discharge in the Northern Region were studied using spatial autocorrelation analysis and structural equations.The findings demonstrated that(l)a significant Spearman correlation between drainage water volume(DwV),chemical oxygen demand(COD),ammonia nitrogen(NH_(3)-N),total nitrogen(TN),and total phosphorus(TP)and that the correlation coefficients between DWV and COD,NH,-N,TNand TP were 0.87**,1.0**,0.99**,0.99**,respectively;(2)rural sewage discharge showed spatial autocorrelation,and rural domestic sewage discharge in the districts and counties with an administration was significantly higher than in the surrounding areas;and(3)social development was the main driver rural domestic sewage changes(path coefficient was 0.407**),and the main factors influencing rural domestic sewage discharge were the urbanization rate,years of education,and population age structure.This study obtained the spatial variation law and clarified the main influencing factors of rural domestic sewage to provide data support and a theoretical basis for subsequent rural sewage collection and treatment.Use of the Inner Mongolia Autonomous Region in northern China as a typical case,provides a theoretical foundation for scientific decision-making on rural domestic sewage treatment at the national and regional levels and offers new perspectives for managing pollutants.
基金the National Natural Science Foundation of China(Grant No.42277491)for its support.
文摘The trade-off and synergy relationship of ecosystem services is an important topic in the current assessment.The value of each service provided by the ecosystem is substantially affected by human activities,and conversely,its changes will also affect the relevant human decisions.Due to varying tradeoffs among ecosystem services and synergies between them that can either increase or decrease,it is difficult to optimize multiple ecosystem services simultaneously,making it a huge challenge for ecosystem management.This study firstly develops a global Gross Ecosystem Product(GEP)accounting framework.It uses remote sensing data with a spatial resolution of 1 km to estimate the ecosystem services of forests,wetlands,grasslands,deserts,and farmlands in 179 major countries in 2018.The results show that the range of global GEP values is USD 112e197 trillion,with an average value of USD 155 trillion(the constant price),and the ratio of GEP to gross domestic product(GDP)is 1.85.The tradeoffs and the synergies among different ecosystem services in each continent and income group have been further explored.We found a correspondence between the income levels and the synergy among ecosystem services within each nation.Among specific ecosystem services,there are strong synergies between oxygen release,climate regulation,and carbon sequestration services.A trade-off relationship has been observed between flood regulation and other services,such as water conservation and soil retention services in low-income countries.The results will help clarify the roles and the feedback mechanisms between different stakeholders and provide a scientific basis for optimizing ecosystem management and implementing ecological compensation schemes to enhance human well-being.
基金Zhejiang Province Key Research and Development Programs(No.2023C02006),China.
文摘The enhancement of the sensitivity for anthocyanin-based indicator films in food freshness monitoring in real time is important for application.In this study,hydrophilic silica aerogel(SiO2 NA)was incorporated into corn starch(CS)/chitosan(CH)/rose anthocyanins(RACNs)-encapsulated potato amylopectin nanoparticles(APNPs)composite film to increase the sensitivity for shrimp freshness detection.The microstructure of films revealed that the gas absorption capacity was improved by amorphous SiO2 NA via hydrogen interactions.The pore size(1.74–5.60 times),pore volume(3.92–5.60 times),and specific surface area(2.21–2.34 times)of films increased with the addition of SiO2 NA.The sensing of NH3 and pH and the reversibility of films were also reinforced.Meanwhile,the pH-responsive films containing SiO2 NA changed visibly in color from purple–red to orange–gray and finally to gray,enabling effective monitoring of shrimp freshness during storage at 4°C.Thus,anthocyanin-based indicator films with improved sensitivity by adding SiO2 NA were successfully designed for monitoring shrimp freshness.
基金funded by the Key Technologies Research and Development Program(2017YFA0104702)the National Natural Science Foundation of China(32171356).
文摘Autologous nerve grafting serves is considered the gold standard treatment for peripheral nerve defects;however,limited availability and donor area destruction restrict its widespread clinical application.Although the performance of allogeneic decellularized nerve implants has been explored,challenges such as insufficient human donors have been a major drawback to its clinical use.Tissue-engineered neural regeneration materials have been developed over the years,and researchers have explored strategies to mimic the peripheral neural microenvironment during the design of nerve catheter grafts,namely the extracellular matrix(ECM),which includes mechanical,physical,and biochemical signals that support nerve regeneration.In this study,polycaprolactone/silk fibroin(PCL/SF)-aligned electrospun material was modified with ECM derived from human umbilical cord mesenchymal stem cells(hUMSCs),and a dual-bionic nerve regeneration material was successfully fabricated.The results indicated that the developed biomimetic material had excellent biological properties,providing sufficient anchorage for Schwann cells and subsequent axon regeneration and angiogenesis processes.Moreover,the dual-bionic material exerted a similar effect to that of autologous nerve transplantation in bridging peripheral nerve defects in rats.In conclusion,this study provides a new concept for designing neural regeneration materials,and the prepared dual-bionic repair materials have excellent auxiliary regenerative ability and further preclinical testing is warranted to evaluate its clinical application potential.
基金supported financially by the National Natural Science Foundation of China(Nos.21421004 and 22075083)the Programme of Introducing Talents of Discipline to Universities(No.B16017).
文摘The mitigation of under-coordinated Pb^(2+)(halide vacancy)defect remains an imperative challenge in the perovskite solar cells,especially printable mesoscopic perovskite solar cells(FP-PsCs).Here we re port a commercial-available polyazin anticancer drug Sapanisertib as coordination passivator of halide vacancies in FP-PSCs,thereby achieving the photoelectric conversion efficiency(PCE)to 18.46%,along with a record certified PCE of 18.27%.In polazin Sapanisertib(Sap),there exists two kinds of nitrogen atoms:in-aromatic ring(in purine and oxazole rings,IAR-Ns)and out-aromatic ring(substituted amino groups,OAR-Ns).Through multiple characterizations,and DFT calculations show that substituted amino groups OAR-Ns hardly get interaction with the halide vacancy due to the distribution of charge density in Sapanisertib.Our work suggests that the selective coordination is of great significance for the design of high-performance passivators for printable mesoscopic perovskite solar cells.
文摘Recently software crowdsourcing has become an emerging area of software engineering. Few papers have pre- sented a systematic analysis on the practices of software crowdsourcing. This paper first presents an evaluation frame- work to evaluate software crowdsourcing projects with re- spect to software quality, costs, diversity of solutions, and competition nature in crowdsourcing. Specifically, competi- tions are evaluated by the min-max relationship from game theory among participants where one party tries to minimize an objective function while the other party tries to maximize the same objective function. The paper then defines a game theory model to analyze the primary factors in these min- max competition rules that affect the nature of participation as well as the software quality. Finally, using the proposed eval- uation framework, this paper illustrates two crowdsourcing processes, Harvard-TopCoder and AppStori. The framework demonstrates the sharp contrasts between both crowdsourc- ing processes as participants will have drastic behaviors in engaging these two projects.
文摘Clinical success of the proteasome inhibitor established bortezomib as one of the most effective drugs in treatment of multiple myeloma (MM). While survival benefit of bortezomib generated new treatment strategies, the primary and secondary resistance of MM cells to bortezomib remains a clinical concern. This study aimed to highlight the role of p53-induced RING-H2 (Pirh2) in the acquisition of bortezomib resistance in MM and to clarify the function and mechanism of action of Pirh2 in MM cell growth and resistance, thereby providing the basis for new therapeutic targets for MM. The proteasome inhibitor bortezomib has been established as one of the most effective drugs for treating MM. We demonstrated that bortezomib resistance in MM cells resulted from a reduction in Pirh2 protein levels. Pirh2 overexpression overcame bortezomib resistance and restored the sensitivity of myeloma cells to bortezomib, while a reduction in Pirh2 levels was correlated with bortezomib resistance. The levels of nuclear factor- kappaB (NF-κB) p65, pp65, plKBa, and IKKa were higher in bortezomib-resistant cells than those in parental cells. Pirh2 overexpression reduced the levels of plKBa and IKKa, while the knockdown of Pirh2 via short hairpin RNAs increased the expression of NF-κB p65, plKBa, and IKKa. Therefore, Pirh2 suppressed the canonical NF- κB signaling pathway by inhibiting the phosphorylation and subsequent degradation of IKBa to overcome acquired bortezomib resistance in MM cells.
基金supported by the National Natural Science Foundation of China(21788102,22125803,22020102006,21871083)the Shanghai Municipal Science and Technology Major Project(2018SHZDZX03)+3 种基金Program of Shanghai Academic/Technology Research Leader(20XD1421300)‘Shu Guang’Project supported by Shanghai Municipal Education Commission and Shanghai Education Development Foundation(19SG26)the Innovation Program of Shanghai Municipal Education Commission(2017-01-07-00-02-E00010)the Fundamental Research Funds for the Central Universitie。
文摘Supramolecular polymers with different functionalities have been continuously developed in the past decade because of their indispensable role in soft materials.However,pure organic supramolecular polymers with stable room temperature phosphorescence(RTP)emission were very rarely reported for the difficulties of synthesis and achieving RTP in solution.Herein,soluble helical supramolecular polymers with circularly polarized room-temperature phosphorescence were developed via a facile hostguest strategy.Through assembly,a transition from pure fluorescence to almost pure RTP emission was achieved.Adjusting the asymmetry of guest could easily control the chiroptical property of supramolecular polymers.This work provides new opportunities for the design and development of intelligent soft functional soft materials.
基金This work was supported by the Science and Technology Foundation of Beijing Municipal Commission of Education(No.KM201810005027)the National Natural Science Foundation of China(No.U1633115)the Beijing Natural Science Foundation(No.L192002).
文摘Nowadays,Edge Information System(EIS)has received a lot of attentions.In EIS,Distributed Machine Learning(DML),which requires fewer computing resources,can implement many artificial intelligent applications efficiently.However,due to the dynamical network topology and the fluctuating transmission quality at the edge,work node selection affects the performance of DML a lot.In this paper,we focus on the Internet of Vehicles(IoV),one of the typical scenarios of EIS,and consider the DML-based High Definition(HD)mapping and intelligent driving decision model as the example.The worker selection problem is modeled as a Markov Decision Process(MDP),maximizing the DML model aggregate performance related to the timeliness of the local model,the transmission quality of model parameters uploading,and the effective sensing area of the worker.A Deep Reinforcement Learning(DRL)based solution is proposed,called the Worker Selection based on Policy Gradient(PG-WS)algorithm.The policy mapping from the system state to the worker selection action is represented by a deep neural network.The episodic simulations are built and the REINFORCE algorithm with baseline is used to train the policy network.Results show that the proposed PG-WS algorithm outperforms other comparation methods.