High-performance ion-conducting hydrogels(ICHs)are vital for developing flexible electronic devices.However,the robustness and ion-conducting behavior of ICHs deteriorate at extreme tempera-tures,hampering their use i...High-performance ion-conducting hydrogels(ICHs)are vital for developing flexible electronic devices.However,the robustness and ion-conducting behavior of ICHs deteriorate at extreme tempera-tures,hampering their use in soft electronics.To resolve these issues,a method involving freeze–thawing and ionizing radiation technology is reported herein for synthesizing a novel double-network(DN)ICH based on a poly(ionic liquid)/MXene/poly(vinyl alcohol)(PMP DN ICH)system.The well-designed ICH exhibits outstanding ionic conductivity(63.89 mS cm^(-1) at 25℃),excellent temperature resistance(-60–80℃),prolonged stability(30 d at ambient temperature),high oxidation resist-ance,remarkable antibacterial activity,decent mechanical performance,and adhesion.Additionally,the ICH performs effectively in a flexible wireless strain sensor,thermal sensor,all-solid-state supercapacitor,and single-electrode triboelectric nanogenerator,thereby highlighting its viability in constructing soft electronic devices.The highly integrated gel structure endows these flexible electronic devices with stable,reliable signal output performance.In particular,the all-solid-state supercapacitor containing the PMP DN ICH electrolyte exhibits a high areal specific capacitance of 253.38 mF cm^(-2)(current density,1 mA cm^(-2))and excellent environmental adaptability.This study paves the way for the design and fabrication of high-performance mul-tifunctional/flexible ICHs for wearable sensing,energy-storage,and energy-harvesting applications.展开更多
The actual circumstances of daily life are crucial for the purchasing and pricing strategies of supermarkets.Developing strategies based on these circumstances can assist businesses in ensuring profits and fostering w...The actual circumstances of daily life are crucial for the purchasing and pricing strategies of supermarkets.Developing strategies based on these circumstances can assist businesses in ensuring profits and fostering win-win cooperation.This paper explores methods to maximize profit through purchasing and sales strategies.Initially,the relevant data for various categories of vegetables is integrated.Through histograms,their sales patterns are directly understood,highlighting the most popular vegetables.Upon analyzing each vegetable category,it becomes evident that their sales data do not conform to normal distributions.Therefore,Spearman correlation coefficients are calculated,revealing strong correlations between certain categories,such as aquatic roots and edible fungi.A line chart depicting the top ten selling vegetables indicates a noticeable periodicity.Traditional fitting methods struggle to adequately model the sales of each vegetable category and their relationship with cost-plus pricing.To address this,additional factors such as holidays,weeks,and months are incorporated using techniques like random forest regression.This approach yields cost-plus pricing dependence curves that better capture the relationship,while effectively managing noise.Regarding sales volume prediction,the original data displays significant volatility,necessitating the handling of outliers using the threshold method.For missing data,linear interpolation is employed to mitigate the impact of continuous missing values on prediction accuracy.Subsequently,Adam-optimized long short-term memory(LSTM)networks are utilized to forecast incoming quantities for the next seven days.By extrapolating from normal sales volume,market capacity is estimated,allowing for additional sales through discount strategies.This framework has the potential to increase original income by 1.1 times.展开更多
Recently,multifarious deformation approaches in nature have promoted dynamic manipulation for electromagnetic(EM)waves in metamaterials,and those representative strategies are mainly focused on the modulation of spect...Recently,multifarious deformation approaches in nature have promoted dynamic manipulation for electromagnetic(EM)waves in metamaterials,and those representative strategies are mainly focused on the modulation of spectral parameters.Several works have also achieved tunable phase-gradient meta-devices.Here,to broaden the modulation freedom of mechanical deformation,we initially propose two reconfigurable metamaterials consisting of mirrored S-shaped meta-atoms selectively bonded on biaxially pre-stretched substrates.Planar meta-atoms with spin-insensitive transmittance are buckled into 3D morphologies to break residual symmetries by releasing the stress and to facilitate spin-dependent transmittance under circularly polarized incidence.Owing to the geometric anisotropy of S-shaped meta-atoms along the x and y axes,3D chiral meta-atoms exhibit discriminate circularly cross-polarized transmittance under opposite spins.The underlying physical mechanism reveals that EM resonance originates from the excitation of electric dipoles and magnetic dipoles,and their cross coupling finally triggers the chiral effects of 3D meta-atoms.By introducing the gradient-phase design that keeps unchanged under various strains,two types of meta-atoms with specified orientations are interleaved to design a double-foci metalens,and its 2D-to-3D morphology transformation shortens the focusing length and facilitates the intensity change of two foci.Our approach in designing reconfigurable EM metamaterials with 2D-to-3D buckling transformability can be further extended toward terahertz even optical wavebands,and it may assist with deriving more applicable multi-functionalities in the aspects of imaging,sensing,and holograms.展开更多
基金the National Natural Science Foundation of China(11875138,52077095).
文摘High-performance ion-conducting hydrogels(ICHs)are vital for developing flexible electronic devices.However,the robustness and ion-conducting behavior of ICHs deteriorate at extreme tempera-tures,hampering their use in soft electronics.To resolve these issues,a method involving freeze–thawing and ionizing radiation technology is reported herein for synthesizing a novel double-network(DN)ICH based on a poly(ionic liquid)/MXene/poly(vinyl alcohol)(PMP DN ICH)system.The well-designed ICH exhibits outstanding ionic conductivity(63.89 mS cm^(-1) at 25℃),excellent temperature resistance(-60–80℃),prolonged stability(30 d at ambient temperature),high oxidation resist-ance,remarkable antibacterial activity,decent mechanical performance,and adhesion.Additionally,the ICH performs effectively in a flexible wireless strain sensor,thermal sensor,all-solid-state supercapacitor,and single-electrode triboelectric nanogenerator,thereby highlighting its viability in constructing soft electronic devices.The highly integrated gel structure endows these flexible electronic devices with stable,reliable signal output performance.In particular,the all-solid-state supercapacitor containing the PMP DN ICH electrolyte exhibits a high areal specific capacitance of 253.38 mF cm^(-2)(current density,1 mA cm^(-2))and excellent environmental adaptability.This study paves the way for the design and fabrication of high-performance mul-tifunctional/flexible ICHs for wearable sensing,energy-storage,and energy-harvesting applications.
文摘The actual circumstances of daily life are crucial for the purchasing and pricing strategies of supermarkets.Developing strategies based on these circumstances can assist businesses in ensuring profits and fostering win-win cooperation.This paper explores methods to maximize profit through purchasing and sales strategies.Initially,the relevant data for various categories of vegetables is integrated.Through histograms,their sales patterns are directly understood,highlighting the most popular vegetables.Upon analyzing each vegetable category,it becomes evident that their sales data do not conform to normal distributions.Therefore,Spearman correlation coefficients are calculated,revealing strong correlations between certain categories,such as aquatic roots and edible fungi.A line chart depicting the top ten selling vegetables indicates a noticeable periodicity.Traditional fitting methods struggle to adequately model the sales of each vegetable category and their relationship with cost-plus pricing.To address this,additional factors such as holidays,weeks,and months are incorporated using techniques like random forest regression.This approach yields cost-plus pricing dependence curves that better capture the relationship,while effectively managing noise.Regarding sales volume prediction,the original data displays significant volatility,necessitating the handling of outliers using the threshold method.For missing data,linear interpolation is employed to mitigate the impact of continuous missing values on prediction accuracy.Subsequently,Adam-optimized long short-term memory(LSTM)networks are utilized to forecast incoming quantities for the next seven days.By extrapolating from normal sales volume,market capacity is estimated,allowing for additional sales through discount strategies.This framework has the potential to increase original income by 1.1 times.
基金National Natural Science Foundation of China(52175115)。
文摘Recently,multifarious deformation approaches in nature have promoted dynamic manipulation for electromagnetic(EM)waves in metamaterials,and those representative strategies are mainly focused on the modulation of spectral parameters.Several works have also achieved tunable phase-gradient meta-devices.Here,to broaden the modulation freedom of mechanical deformation,we initially propose two reconfigurable metamaterials consisting of mirrored S-shaped meta-atoms selectively bonded on biaxially pre-stretched substrates.Planar meta-atoms with spin-insensitive transmittance are buckled into 3D morphologies to break residual symmetries by releasing the stress and to facilitate spin-dependent transmittance under circularly polarized incidence.Owing to the geometric anisotropy of S-shaped meta-atoms along the x and y axes,3D chiral meta-atoms exhibit discriminate circularly cross-polarized transmittance under opposite spins.The underlying physical mechanism reveals that EM resonance originates from the excitation of electric dipoles and magnetic dipoles,and their cross coupling finally triggers the chiral effects of 3D meta-atoms.By introducing the gradient-phase design that keeps unchanged under various strains,two types of meta-atoms with specified orientations are interleaved to design a double-foci metalens,and its 2D-to-3D morphology transformation shortens the focusing length and facilitates the intensity change of two foci.Our approach in designing reconfigurable EM metamaterials with 2D-to-3D buckling transformability can be further extended toward terahertz even optical wavebands,and it may assist with deriving more applicable multi-functionalities in the aspects of imaging,sensing,and holograms.