The Jiama deposit,a significant porphyry-skarn-type copper polymetallic deposit located within the Gangdese metallogenic belt in Tibet,China,exemplifies a typical porphyry metallogenic system.However,the mineral chemi...The Jiama deposit,a significant porphyry-skarn-type copper polymetallic deposit located within the Gangdese metallogenic belt in Tibet,China,exemplifies a typical porphyry metallogenic system.However,the mineral chemistry of its accessory minerals remains under-examined,posing challenges for resource assessment and ore prospecting.Utilizing electron microprobe analysis and LA-ICP-MS analysis,this study investigated the geochemical characteristics of apatite in ore-bearing granite and monzogranite porphyries,as well as granodiorite,quartz diorite,and dark diorite porphyries in the deposit.It also delved into the diagenetic and metallogenic information from these geochemical signatures.Key findings include:(1)The SiO_(2) content,rare earth element(REE)contents,and REE partition coefficients of apatite indicate that the dark diorite porphyry possibly does not share a cogenetic magma source with the other four types of porphyries;(2)the volatile F and Cl contents in apatite,along with their ratio,indicate the Jiama deposit,formed in a collisional setting,demonstrates lower Cl/F ratios in apatite than the same type of deposits formed in a subduction environment;(3)compared to non-ore-bearing rock bodies in other deposits formed in a collisional setting,apatite in the Jiama deposit exhibits lower Ce and Ga contents.This might indicate that rock bodies in the Jiama deposit have higher oxygen fugacity.Nevertheless,the marginal variation in oxygen fugacity between ore-bearing and non-ore-bearing rock bodies within the deposit suggests oxygen fugacity may not serve as the decisive factor in the ore-hosting potential of rock bodies in the Jiama deposit.展开更多
Rubidium(Rb)deposits mostly occur in the South China and Central Asia orogenic belts and are often closely associated with highly differentiated granites.This study investigates a newly-discovered giant Rb deposit at ...Rubidium(Rb)deposits mostly occur in the South China and Central Asia orogenic belts and are often closely associated with highly differentiated granites.This study investigates a newly-discovered giant Rb deposit at Gariatong in the Central Lhasa terrane in Tibet.Detailed field studies and logging data revealed that the Rb mineralization mainly occurs in monzogranite and is related to greisenization.LA-ICP-MS U-Pb dating of zircon yielded ages of 19.1±0.2 Ma and 19.0±0.2 Ma for greisenized monzogranite and fresh monzogranite,respectively.The monzogranites are characterized as strongly peraluminous,with high contents of SiO2,Al2O3,K2O and Na2O as well as a high differentiation index.They are enriched in light rare earth and large ion lithophile elements with significant negative Eu anomalies and depleted high fieldstrength elements.Petrological and geochemical features of these ore-related monzogranites suggest that they are highly fractionated S-type granites,derived from remelting of crustal materials in a post-collisional setting.The geochemistry of zircon and apatite points to a low oxygen fugacity of the ore-related monzogranite during the magma’s evolution.The discovery of the Gariatong Rb deposit suggests that the Central Lhasa terrane may be an important region for rare metal mineralization.展开更多
蚀变岩帽在地表一般表现为陡倾的正地形,是高温、高氧逸度流体对围岩进行酸性淋滤,形成的一系列高级泥化和泥化等蚀变矿物组合。这种蚀变是浅成低温热液蚀变系统的一部分,其深部可能具有寻找斑岩型矿化的潜力。浙东南陆相火山岩地区普...蚀变岩帽在地表一般表现为陡倾的正地形,是高温、高氧逸度流体对围岩进行酸性淋滤,形成的一系列高级泥化和泥化等蚀变矿物组合。这种蚀变是浅成低温热液蚀变系统的一部分,其深部可能具有寻找斑岩型矿化的潜力。浙东南陆相火山岩地区普遍发育此种蚀变岩帽,但该类型蚀变常被前人定义为"次生石英岩"。本文选择其中典型的后坑蚀变岩帽,通过大比例尺蚀变填图、岩心编录,利用短波红外(ASD)、电子探针(EPMA)、扫描电镜(SEM)、能谱仪(EDS)等分析技术手段,发现蚀变岩帽具有垂直方向和水平方向的蚀变矿物分带。垂直方向由深到浅依次发育刚玉-绢云母,绢云母-叶蜡石,明矾石-高岭石-地开石具分带特征;水平方向上从核部到边部依次发育多孔状石英-金红石、高级泥化带(明矾石-叶蜡石-高岭石-地开石-水铝石-Aluminum Phosphate and sulphates矿物)、泥化带(高岭石-伊利石-蒙脱石)。并得出以下几点认识:①后坑蚀变岩帽中明矾石短波红外特征吸收峰在1480~1491nm之间,以岩浆-热液成因的钾明矾石为主,含少量钠明矾石;②叶蜡石短波红外特征吸收峰在2167nm左右,分为两种成因:早期高级泥化阶段的绢云母经后期热液退变质蚀变而成以及早期高岭石经后期热液进变质作用形成;③蚀变岩帽根部的刚玉被后期热液蚀变形成绢云母,刚玉-绢云母蚀变带之下可能是黄铁绢英岩化带;④早期水铝石被后期热液蚀变形成地开石,代表了热液的多期次性;通过对比后坑蚀变岩帽与其他斑岩-浅成低温热液矿床(如Horse-Ivaal和Vuda等矿床)的蚀变矿物分带后,发现后坑蚀变岩帽蚀变矿物分带与这些典型矿床相似。本文认为后坑蚀变岩帽属于该成矿系统上部的浅成低温热液蚀变部分,其深部具有寻找斑岩矿床的潜力,同时提出浙东南其他发育在陆相火山岩中的蚀变岩帽也属于该蚀变系统,具有寻找斑岩型铜金矿床的较大潜力。展开更多
基金supported by the National Key Research and Development Program of China(Grant No.2022YFC2905001)the National Natural Science Foundation of China(Grant Nos.42272093,42230813)a geological survey project(Grant No.DD20230054).
文摘The Jiama deposit,a significant porphyry-skarn-type copper polymetallic deposit located within the Gangdese metallogenic belt in Tibet,China,exemplifies a typical porphyry metallogenic system.However,the mineral chemistry of its accessory minerals remains under-examined,posing challenges for resource assessment and ore prospecting.Utilizing electron microprobe analysis and LA-ICP-MS analysis,this study investigated the geochemical characteristics of apatite in ore-bearing granite and monzogranite porphyries,as well as granodiorite,quartz diorite,and dark diorite porphyries in the deposit.It also delved into the diagenetic and metallogenic information from these geochemical signatures.Key findings include:(1)The SiO_(2) content,rare earth element(REE)contents,and REE partition coefficients of apatite indicate that the dark diorite porphyry possibly does not share a cogenetic magma source with the other four types of porphyries;(2)the volatile F and Cl contents in apatite,along with their ratio,indicate the Jiama deposit,formed in a collisional setting,demonstrates lower Cl/F ratios in apatite than the same type of deposits formed in a subduction environment;(3)compared to non-ore-bearing rock bodies in other deposits formed in a collisional setting,apatite in the Jiama deposit exhibits lower Ce and Ga contents.This might indicate that rock bodies in the Jiama deposit have higher oxygen fugacity.Nevertheless,the marginal variation in oxygen fugacity between ore-bearing and non-ore-bearing rock bodies within the deposit suggests oxygen fugacity may not serve as the decisive factor in the ore-hosting potential of rock bodies in the Jiama deposit.
基金supported by the National Key Research and Development Program of China(Grant No.2022YFC2905001)the National Natural Science Foundation of China(Grant Nos.42272093,42230813)+1 种基金the Basic Research Fund of the Chinese Academy of Geological Sciences(Grant Nos.JKYZD202316,KK2116)the China Scholarship Council project and the Geological Survey project(Grant No.DD20230054).
文摘Rubidium(Rb)deposits mostly occur in the South China and Central Asia orogenic belts and are often closely associated with highly differentiated granites.This study investigates a newly-discovered giant Rb deposit at Gariatong in the Central Lhasa terrane in Tibet.Detailed field studies and logging data revealed that the Rb mineralization mainly occurs in monzogranite and is related to greisenization.LA-ICP-MS U-Pb dating of zircon yielded ages of 19.1±0.2 Ma and 19.0±0.2 Ma for greisenized monzogranite and fresh monzogranite,respectively.The monzogranites are characterized as strongly peraluminous,with high contents of SiO2,Al2O3,K2O and Na2O as well as a high differentiation index.They are enriched in light rare earth and large ion lithophile elements with significant negative Eu anomalies and depleted high fieldstrength elements.Petrological and geochemical features of these ore-related monzogranites suggest that they are highly fractionated S-type granites,derived from remelting of crustal materials in a post-collisional setting.The geochemistry of zircon and apatite points to a low oxygen fugacity of the ore-related monzogranite during the magma’s evolution.The discovery of the Gariatong Rb deposit suggests that the Central Lhasa terrane may be an important region for rare metal mineralization.
文摘蚀变岩帽在地表一般表现为陡倾的正地形,是高温、高氧逸度流体对围岩进行酸性淋滤,形成的一系列高级泥化和泥化等蚀变矿物组合。这种蚀变是浅成低温热液蚀变系统的一部分,其深部可能具有寻找斑岩型矿化的潜力。浙东南陆相火山岩地区普遍发育此种蚀变岩帽,但该类型蚀变常被前人定义为"次生石英岩"。本文选择其中典型的后坑蚀变岩帽,通过大比例尺蚀变填图、岩心编录,利用短波红外(ASD)、电子探针(EPMA)、扫描电镜(SEM)、能谱仪(EDS)等分析技术手段,发现蚀变岩帽具有垂直方向和水平方向的蚀变矿物分带。垂直方向由深到浅依次发育刚玉-绢云母,绢云母-叶蜡石,明矾石-高岭石-地开石具分带特征;水平方向上从核部到边部依次发育多孔状石英-金红石、高级泥化带(明矾石-叶蜡石-高岭石-地开石-水铝石-Aluminum Phosphate and sulphates矿物)、泥化带(高岭石-伊利石-蒙脱石)。并得出以下几点认识:①后坑蚀变岩帽中明矾石短波红外特征吸收峰在1480~1491nm之间,以岩浆-热液成因的钾明矾石为主,含少量钠明矾石;②叶蜡石短波红外特征吸收峰在2167nm左右,分为两种成因:早期高级泥化阶段的绢云母经后期热液退变质蚀变而成以及早期高岭石经后期热液进变质作用形成;③蚀变岩帽根部的刚玉被后期热液蚀变形成绢云母,刚玉-绢云母蚀变带之下可能是黄铁绢英岩化带;④早期水铝石被后期热液蚀变形成地开石,代表了热液的多期次性;通过对比后坑蚀变岩帽与其他斑岩-浅成低温热液矿床(如Horse-Ivaal和Vuda等矿床)的蚀变矿物分带后,发现后坑蚀变岩帽蚀变矿物分带与这些典型矿床相似。本文认为后坑蚀变岩帽属于该成矿系统上部的浅成低温热液蚀变部分,其深部具有寻找斑岩矿床的潜力,同时提出浙东南其他发育在陆相火山岩中的蚀变岩帽也属于该蚀变系统,具有寻找斑岩型铜金矿床的较大潜力。
