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掺锰水铁矿-壳聚糖珠对As(Ⅲ)的吸附及影响因素 被引量:1
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作者 叶枫 肖玲 +1 位作者 熊治廷 胡知临 《环境科学与技术》 CAS CSCD 北大核心 2019年第9期7-14,共8页
文章研究了掺锰水铁矿-壳聚糖珠状材料对As(Ⅲ)的吸附及其影响因素。材料制备时的干燥方法影响其结构和吸附性能。冻干的珠状材料内有大量的大孔和介孔,50℃真空干燥的珠状材料的孔相对较小,而25℃自然风干的珠状材料内则无明显孔结构... 文章研究了掺锰水铁矿-壳聚糖珠状材料对As(Ⅲ)的吸附及其影响因素。材料制备时的干燥方法影响其结构和吸附性能。冻干的珠状材料内有大量的大孔和介孔,50℃真空干燥的珠状材料的孔相对较小,而25℃自然风干的珠状材料内则无明显孔结构。珠状材料对As(Ⅲ)的最大吸附量与比表面积的顺序相同,为冻干壳聚糖珠>真空干燥壳聚糖珠>风干壳聚糖珠。冻干壳聚糖珠吸附材料的吸附量是风干壳聚糖珠的2倍。随着p H的上升吸附量逐渐降低;共存阴离子H2PO4^-和SiO3^2-能显著抑制吸附剂对As(Ⅲ)的吸附能力。冻干壳聚糖珠对As(Ⅲ)的吸附符合准二级动力学模型和Langmuir等温线模型。经过3次再生后复合材料的吸附量仍有初始吸附量的88%左右,显示了良好重复使用性。XPS分析显示吸附材料中的Mn(Ⅳ)能氧化As(Ⅲ)为As(Ⅴ),从而明显提高壳聚糖珠对As(Ⅲ)的吸附性。 展开更多
关键词 掺锰水铁矿 壳聚糖珠 吸附
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Effects of insoluble Zn,Cd,and EDTA on the growth,activities of antioxidant enzymes and uptake of Zn and Cd in Vetiveria zizanioides 被引量:17
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作者 XU Weihong LI Wenyi +2 位作者 HE Jianping Balwant Singh xiong zhiting 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2009年第2期186-192,共7页
A root-bag experiment was conducted to study the effects of insoluble Zn, Cd, and ethylenediaminetetraacetic acid (EDTA) on the plant growth, activities of antioxidant enzymes, proline, glutathione (GSH), water-so... A root-bag experiment was conducted to study the effects of insoluble Zn, Cd, and ethylenediaminetetraacetic acid (EDTA) on the plant growth, activities of antioxidant enzymes, proline, glutathione (GSH), water-soluble proteins and malondialdehyde (MDA) of Vetiveria zizanioides. The V. zizanioides uptake capacity of Zn and Cd also determined. The results showed that plant growth of V. zizanioides was inhibited by Zn and Cd. The shoot dry weight (SDW) and root dry weight (RDW) decrease by 14.2%, 14.1%, 17.0% and 17.3%, 32.5%, 35.7%, respectively, compared to the control without EDTA addition. After adding EDTA, shoot and root dry weight decreased over 10% and 15%, respectively. The toxicity from insoluble Zn and Cd in soil on SDW and RDW of V. zizanioides was in order: Zn+Cd 〉 Cd 〉 Zn. The activities of superoxide dismutase (SOD), peroxidase (POD) and catalase (CAT), and contents of MDA and proline increased significantly, while the contents of GSH and water-soluble proteins decreased markedly with increasing Zn and Cd toxicity. With EDTA, shoot and root Zn concentrations increased in the Zn treatment by 7.3% and 37.4%, and Cd concentrations in the combined Zn and Cd treatment increased by 18.6% and 391.9% compared to the treatment without EDTA. However, Zn and Cd concentrations in shoot and roots decreased in the Cd treatment compared to the plants grown in absence of EDTA, with exception of root Cd concentration in the presence of EDTA. 展开更多
关键词 Vetiveria zizanioides antioxidant enzymes GLUTATHIONE MALONDIALDEHYDE PRALINE concentration of Zn and Cd
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Research Progressing of Present Contamination of Cd in Soil and Restoration Method 被引量:3
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作者 WANG Weizhong XU Weihong +1 位作者 ZHOU Kun xiong zhiting 《Wuhan University Journal of Natural Sciences》 CAS CSCD 2015年第5期430-444,共15页
Cadmium is one of the important contaminative heavy metals. Due to continuous increase of discharge of Cadmium in industrial and agriculture production, cadmium contamination of soil is more and more serious day by da... Cadmium is one of the important contaminative heavy metals. Due to continuous increase of discharge of Cadmium in industrial and agriculture production, cadmium contamination of soil is more and more serious day by day, which seriously threatens ecological environment and human health. Treatment of cadmium becomes an urgent issue and research hot point. At present, remedy for cadmium pollution upon soil mainly are physical restoration, chemical restoration and biological restoration, also there are measurements by means of adding external source matter and selecting low-Cd-accumulation varieties so as to reduce cadmium harm upon agricultural products. This article introduces in detail the resource of cadmium in soil and the present condition of cadmium pollution in farmland and processing of domestic cadmium pollution research, processing stage of domestic and foreign research of restoration of cadmium polluted soil as well as various peculiarities of repair methods. Finally, the expectation of research is discussed. 展开更多
关键词 cadmium pollution in soil engineering method chemical restoration biological restoration agricultural technique measurements
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Effect of Exogenous Lanthanum on Accumulation of Cadmium and Its Chemical Form in Tomatoes
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作者 XIE Wenwen xiong Shijuan +3 位作者 XU Weihong CHEN Rong ZHANG Jinzhong xiong zhiting 《Wuhan University Journal of Natural Sciences》 CAS 2014年第3期221-228,共8页
In the condition that soil is polluted by Cd(20 mg·L-1),two varieties of tomato(Lycopersicon esculintum Mill.)(plant high Cd-enriched variety(Yufen109)and plant low Cd-enriched variety(4641))treated wit... In the condition that soil is polluted by Cd(20 mg·L-1),two varieties of tomato(Lycopersicon esculintum Mill.)(plant high Cd-enriched variety(Yufen109)and plant low Cd-enriched variety(4641))treated with LaCl3 of different concentration(0,10 and 20mg·L-1)were determined for their effect on plant dry weight,anti-oxidase activity(CAT,SOD and POD),tomato fruit Cd chemical form and Cd accumulation.The results show that 10 mg?L-1LaCl3 can increase dry weight of plant at various positions and can reduce the concentration of Cd of different forms.Spraying with LaCl3(10,20 mg·L-1)can reduce Cd concentration in leaves,stems,roots and fruits of tomato plants with lowering rates of 13.7%-31.9%,9.5%-30.6%,10.8%-44.5%and 19.4%-37.0%,respectively.Suitable amount of lanthanum(10 mg·L-1 LaCl3)can increase yield of tomatoes,reduce Cd accumulation in the fruit.In the two tomato varieties,Lanthanum and Cadmium react interactively,expressing to be coexisting of both synergism and antagonistic. 展开更多
关键词 interaction of lanthanum and cadmium physiological characterization cadmium accumulation cadmium form tomato varieties
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